Subzero Temperatures Research Articles

Anionic Hofmeister Effect Regulated Conductivity in Polyelectrolyte Hydrogels for High-Performance Supercapacitor.

The Hofmeister effect not only affects the stability and solubility of protein colloids but also has specific effects on the polymer molecules. Here, the impact of the Hofmeister effect on the electrochemical properties of polyelectrolyte hydrogels at room temperature and subzero temperature studied for the first time. Polyelectrolyte hydrogels exhibit an anti-polyelectrolyte effect in low concentrations of ammonium salt, while they exhibit an obvious Hofmeister effect in high concentrations of ammonium salt. Kosmotropic ions demonstrate strong interaction with water molecules or polymer chains, resulting in the reduction of conductivity of polyelectrolyte hydrogels. However, chaotropic ions exhibit weak interactions with water molecules or molecular chains, leading to an increase in conductivity. The Hofmeister effect has a more significant effect on the polyzwitterion electrolyte. The conductivity of polyzwitterion hydrogel soaked in chaotropic ion is up to 6.2 mS cm-1 at -40°C. The supercapacitor assembled by polyzwitterion electrolytes maintains a capacitance retention rate of 85% and ≈100% coulomb efficiency after 15 000 cycles at -40°C. This study elucidates the influence of the Hofmeister effect on conductivity in polyelectrolytes and expands the regulatory approach for improving the performance of energy storage devices.

Innovative dodecane-hexadecane/expanded graphite composite phase change material for sub-zero cold storage applications

Utilization of phase change materials (PCMs) for cold energy storage has garnered increasing attention. This study focuses on the development of a composite PCM by integrating a novel eutectic dodecane-hexadecane (DD-HD) PCM into expanded graphite (EG), to cater to the demands of sub-zero cold energy storage applications, such as cold chain logistics. The study identified the optimal mass ratio of DD-HD as 80:20. A series of DD-HD/EG composites were fabricated through a combination of high-speed emulsification and physical adsorption methods. The adsorption capacity of EG for the eutectic PCM mixture was evaluated by examining the impact of EG fraction on the leakage of the composite PCM, revealing that the optimum EG fraction is 10 wt%. The composite PCM displayed a sub-zero phase change temperature of -12.09 ℃, a high melting enthalpy of 178.75 kJ/kg, and a high thermal conductivity of 5.18 W/(m•K). The thermal conductivity of the composite was enhanced by 22.52 times compared to the base PCM. Thermogravimetric analysis indicated that the decomposition temperature of DD-HD/EG was significantly higher than that of the base PCM. The composite demonstrated outstanding thermal reliability, as evidenced by thermal cycle tests. With its impressive thermal characteristics, this composite shows great potential for various cold energy storage applications.

Optimized Partial Freezing Protocol Enables 10-Day Storage of Rat Livers.

Preserving organs at subzero temperatures with halted metabolic activity holds the potential to prolong preservation and expand the donor organ pool for transplant. Our group recently introduced partial freezing, a novel approach in high-subzero storage at -15°C, enabling 5 days storage of rodent livers through precise control over ice nucleation and unfrozen fraction. However, increased vascular resistance and tissue edema suggested a need for improvements to extend viable preservation. Here, we describe an optimized partial freezing protocol with key optimizations including increased concentration of propylene glycol to reduce ice recrystallization and maintained osmotic balance through an increase in bovine serum albumin, all while minimizing sheer stress during cryoprotectant unloading with an acclimation period. These approaches ensured the viability during preservation and recovery processes, promoting liver function and ensuring optimal preservation. This was evidenced by increased oxygen consumption, decreased vascular resistance and edema. Ultimately, we show that using the optimized protocol, livers can be stored for 10 days with comparable vascular resistance and lactate levels to 5 days, outperforming the viability of time-matched cold stored livers as the current gold standard. This study represents a significant advancement in expanding organ availability through prolonged preservation and thereby revolutionizing transplant medicine.

Liquid Water Visualization in the Pt‐Loading Cathode Catalyst Layers of Polymer Electrolyte Fuel Cells Using Operando Synchrotron X‐ray Radiography

Water management is important for addressing the challenges posed by next‐generation fuel cell electric vehicles. Although X‐ray imaging techniques are useful for probing the mechanism of water transport in the gas diffusion layer of polymer electrolyte fuel cells, they cannot be easily applied to the Pt‐loading catalyst layer because of its low X‐ray transmittance due to the high absorption coefficient of Pt. Herein, a method to realize the high‐resolution X‐ray imaging of a 30 μm‐thick cathode catalyst layer in polymer electrolyte fuel cells using synchrotron X‐ray radiography is proposed, thus bridging the above gap. The results of operando synchrotron X‐ray radiography measurements reveal that water accumulation in the cathode catalyst layer depends on the cell temperature, feed gas humidity, and cell voltage, while time‐slice analysis shows that the water accumulation rate in the cathode catalyst layer immediately after the power generation is faster than that in the cathode gas diffusion layer. The proposed imaging method can be used to evaluate the water storage capacity of the catalyst layer and thus deepen the understanding of flooding phenomena and cold‐start behavior at subzero temperatures.

Battery pack passive insulation strategies of electric vehicles under a frigid environment

Further application of electric vehicles (EVs) in frigid regions is hindered by the diminished performance of lithium-ion batteries (LIBs) at sub-zero temperatures. Developing efficient heat preservation strategies has significant implications for the broad application of EVs and LIBs. This study focuses on passive heat preservation strategies (PHPS) for battery packs in frigid environments (−30 °C). A validated 3D battery pack heat preservation model integrated with airflow is constructed in this paper, and the model analysis results indicate that arranging aerogels at the pack level provides superior heat preservation compared to cell and module levels. Additionally, the influence of flow field distribution (FFD) schemes on heat preservation performance is discovered. Both experimental and simulation results confirm that the proposed scheme can optimize the cooling rate to about 2.3 °C/h. Commencing from an initial temperature of 30 °C, extending the battery pack retention time above 0 °C to over 12 h under −30 °C can significantly expand the application of electric vehicles in frigid regions. This paper explores the primary factors affecting the heat dissipation of battery packs in the frigid temperature environment, which have great significance in guiding the heat preservation design of battery systems.

Adaptation to appropriate sub-freezing temperatures through reduction of mycelial porosity and alteration of cell wall composition in Stropharia rugosoannulata

Sub-zero temperatures are avoided for storing mushrooms due to freeze damage. Stropharia rugosoannulata (S. rugosoannulata) often encounter such low temperatures prior to harvest. To preserve S. rugosoannulata, sub-freezing was studied at −2 °C, −6 °C, and −10 °C. The mechanism that caused the differences in the quality was analyzed from the perspective of water distribution and microstructure. The results revealed that at −2 ℃, S. rugosoannulata achieved a firmness and flavor that was comparable to that of the fresh samples. Water migration was observed at −2 ℃. However, at this temperature, S. rugosoannulata exhibited a lower drip loss compared to the fresh samples, and there was no significant variation in the malondialdehyde (MDA) and the electrolyte leakage rate (EL). Despite the swelling of the cells, the mycelial porosity decreased and the cell wall protein and water-soluble polysaccharide content increased to acclimate to the low temperature. In summary, the results of this study imply that it is possible to store S. rugosoannulata at suitable sub-freezing temperatures.

Study of three factors for commercial-size PEM fuel cell stack cold start: Manifold, endplate, and assisted heating

Numerical investigation on a proton exchange membrane fuel cell stack comprising 400 single cells under subzero temperatures is essential for automotive applications. In this work, a one-dimensional multi-phase PEMFC stack cold start model is built to investigate the effect of manifold configuration and endplates on the cold start process. It is noticed that the U-shape manifold configuration is more conducive to the distribution of reaction gas than the Z-shape, while the Z-shape manifold configuration is more likely to cause damage to the stack due to the dilute oxygen concentration in certain cells. The endplate effect has an important effect on the temperature, ice fraction, and cell voltage of the 20 cells near the endplates. The number of cells affected by the endplate effect is independent of the convective heat transfer coefficient. Finally, the strategy of leveraging the PEMFC stack’s output energy to heat the stack can effectively boost the likelihood of a successful cold start, which can aid the stack achieve a successful cold start at −24℃. The arrangement of two single cells separated by a heating pad provides the best cold start capacity and consistency in the stack.

Water rotational relaxation time measurement by shortwave infrared micro spectroscopy(SWIR) at sub-zero temperatures

The shortwave infrared spectroscopy (SWIR) is the noble method which allows to evaluate the rotational relaxation time of water (RRTW) in a sample. Because SWIR requires the reference sample of pure water, the measurement temperature is limited only at above 0 °C. In this study, we expanded this temperature limitation of SWIR by using alternative reference solutions with freezing points below 0 °C, including sugar and glycerol solutions. The results showed that some reference sample solutions are useable for evaluating RRTW in samples below 0 °C. It was found that RRTW in solution measured by newly proposed SWIR agrees with RRTW measured by dielectric spectroscopy in 10% accuracy when it is shorter than 100psec.

Extended supercooled storage of red blood cells

Red blood cell (RBC) transfusions facilitate many life-saving acute and chronic interventions. Transfusions are enabled through the gold-standard hypothermic storage of RBCs. Today, the demand for RBC units is unfulfilled, partially due to the limited storage time, 6 weeks, in hypothermic storage. This time limit stems from high metabolism-driven storage lesions at +1-6 °C. A recent and promising alternative to hypothermic storage is the supercooled storage of RBCs at subzero temperatures, pioneered by our group. Here, we report on long-term supercooled storage of human RBCs at physiological hematocrit levels for up to 23 weeks. Specifically, we assess hypothermic RBC additive solutions for their ability to sustain supercooled storage. We find that a commercially formulated next-generation solution (Erythro-Sol 5) enables the best storage performance and can form the basis for further improvements to supercooled storage. Our analyses indicate that oxidative stress is a prominent time- and temperature-dependent injury during supercooled storage. Thus, we report on improved supercooled storage of RBCs at −5 °C by supplementing Erythro-Sol 5 with the exogenous antioxidants, resveratrol, serotonin, melatonin, and Trolox. Overall, this study shows the long-term preservation potential of supercooled storage of RBCs and establishes a foundation for further improvement toward clinical translation.

Dynamic mechanical behaviours of frozen rock under sub-zero temperatures and dynamic loads

Dynamic mechanical behaviours of frozen rocks are essential for dealing with the design and stability of various engineering structures in cold regions. A dynamic-cryogenic testing system integrated with high-speed Digital Image Correlation (DIC) is adopted to investigate the dynamic mechanical behaviours of rock subjected to ambient room and sub-zero temperatures, along with high-rate loading. Dynamic compression, tensile and Mode I dynamic fracture tests were performed at 20, -20, −50 and −70 °C using dry and saturated sandstone from Yulong Copper Mine at high-altitude cold region. A DIC-based approach using pixel-based virtual extensometers is proposed to accurately capture the real-time cracking speed with high precision. The proportion of ice and unfrozen water in rock pores across various temperatures is quantified using the nuclear magnetic resonance (NMR) method. The results indicate significant temperature and rate dependencies in dynamic fracture toughness, crack propagation velocity, dynamic tensile strength, dynamic compressive strength, and failure modes; These parameters exhibit an increase with decreasing ambient temperature as unfrozen water transitions into ice, demonstrating the frozen effect of ice filling pores, supporting the rock skeleton, and bonding ice-rock interfaces. With decreasing temperature, crack branching becomes more pronounced in dynamic notched semi-circular bending (NSCB) tests. Additionally, dynamically compressed frozen rocks tend to transition from pulverization (Type II) to splitting (Type I) with multiple elongations, attributed to the strengthening effect. The findings elucidate the failure mechanisms observed in a higher proportion of larger blast blocks and hold valuable implications for blasting designs and dynamic disaster prevention in cold regions.

Assessment of quality indicators in construction

Introduction. Ensuring proper quality of construction is one of the pressing challenges of our time. Consumers expect cheap products from developers in the form of commercial or residential real estate that meet all the required quality indicators. Most accidents in monolithic construction occur due to non-compliance with technological procedures at low temperatures. The purpose of the study is to develop a framework for assessing the quality of concrete work at subzero temperatures (during winter work) based on the results of studies of technological parameters of winter concreting, their impact on the quality and safety of erected monolithic structures of industrial and civil buildings (structures).Materials and methods. The study used the method of approximating distributions of random variables, expert estimates, the theory of multiple principles, and mathematical statistics. The experiments were carried out in the laboratories of the Don State Technical University, as well as in the conditions of actual concrete work on a construction site in winter. The work uses a correlation-regression analysis of the dependence of the organizational and technological causes of inconsistencies (factors) and quality indicators of concrete work production. Statistical information on structural damage and collapse of buildings during their operation was processed. To make organizational and technological decisions to improve the quality of concrete work, it is proposed to take the influence of defects on the load-bearing capacity of buildings as an indicator of the quality level.Results. Using practical and expert methods, the most significant reasons (factors) for the occurrence of inconsistencies in the level of quality of concrete work production have been established. Factors have been identified that have the greatest influence on the change in the load-bearing capacity and reliability of buildings and structures being erected when performing the main types of construction and installation work. The nomenclature of technological quality indicators during winter production of concrete work, their influence on quality substantiated, and methods for assessing the quality of winter concreting technology are developed. Quantitative indicators of the quality of construction of monolithic reinforced concrete structures were obtained.Discussion and conclusions. The practical value of the work lies in the development of a methodological tool for creating a regulatory framework for operational construction control of the production of monolithic and prefabricated monolithic construction and installation works under conditions of exposure to low temperatures, as well as for acceptance control of compliance of completed construction projects with quality requirements. Proposals are given for establishing regulatory tolerances, ways to improve the manufacturability of the equipment used, a new method for designing winter concreting technology, and a quality control method focused on ensuring structural safety have been developed. By developing the research, it is further possible to develop methods for calculating technology parameters taking into account technological variability, as well as establish new indicators to regulate the required level of quality and safety of buildings being built.

Preparation of Autoclavable and Injectable Silk Fibroin Cryogels for Tissue Engineering Applications.

A cryogel is a supermacroporous gel network that is generated at subzero temperatures by polymerizing monomers or gelating polymeric precursors. Since cryogels possess inherent characteristics such asinterconnectedmacroporous structures, excellent mechanical properties,and high resistanceto autoclave sterilization,they are highly desirable for tissue engineering and regenerative medicine. Silk fibroin, a natural protein obtainedfrom Bombyx morisilkworms, is an excellent raw material for cryogel preparation. The aim of this study is toestablish acontrolled method for preparing silk fibroincryogels with suitable properties for application as tissue engineering scaffolds. Using a dual crosslinking strategy consisting of low-temperature radical polymerization coupled with methanol-induced conformational transformation, porous cryogels are prepared. The cryogelsdisplay many unique characteristics, such as an interconnected macroporous structure, a high water absorption capacity, water-triggered shape memory, syringe injectability, and strong resilience to autoclave sterilization. Furthermore, the cryogels demonstrate excellent biocompatibility and cell affinity, facilitating cell adhesion, migration, andproliferation. The interconnected supermacroporous architecture resembling the nativeextracellular matrix, together with their unique physical properties and autoclaving stability, suggests that cryogels are promising candidate scaffolds for tissue engineering and cell therapy.

Cryoethanolic Extraction, Purification of Allicin from Allium sativum and HPTLC analysis

The significance of this research extends beyond the mere extraction and purification of allicin, encompassing its potential applications across diverse industries. Allicin exhibits a plethora of biological activities, including antimicrobial, antifungal, antiviral, and antiprotozoal properties. Its mechanism of action involves the inhibition of thiol-containing enzymes in microorganisms, rendering it effective against a wide array of pathogens. Moreover, allicin has demonstrated promising anticancer properties, eliciting apoptosis and inhibiting cell proliferation in various cancer cell lines. Additionally, its anti-inflammatory and cardioprotective effects underscore its potential therapeutic utility in mitigating cardiovascular diseases and other inflammatory conditions. This study presents a novel method for extracting and purifying allicin from raw garlic cloves. Dry ice ensures the ethanol to reach its cryo temperature (hilled to sub-zero temperatures ranging from -40°C to -80°C). The process involves the use of ethanol, dry ice and ascorbic acid as solvents, vacuum stirring, and subsequent crystallization. The final product, a hygroscopic powder, was analyzed using High-Performance Thin-Layer Chromatography (HPTLC) to determine allicin content. The extraction yielded 5 grams of whitish hygroscopic powder from 21 grams of crude extract, with an allicin content of 5%. Chromatographic conditions included a mobile phase of acetonitrile: water: Formic acid (30:8:2) and derivatization with ninhydrin, with detection under UV light at 366 nm. This method provides an efficient way to isolate and purify allicin for various applications.

Mobility of Zn and Cu in Bentonites: Implications for Environmental Remediation.

The aim of this study was to evaluate the mobility of copper (Cu) and zinc (Zn) and their impact on the properties of bentonites and unfrozen water content. Limited research in this area necessitates further analysis to prevent the negative effects of metal interactions on bentonite effectiveness. Tests involved American (SWy-3, Stx-1b) and Slovak (BSvk) bentonite samples with Zn or Cu ion exchange. Sequential extraction was performed using the Community Bureau of Reference (BCR) method. Elemental content was analyzed via inductively coupled plasma optical emission spectrometry (ICP-OES). Unfrozen water content was measured using nuclear magnetic resonance (1H-NMR) and differential scanning calorimetry (DSC). Results showed a significant influence of the main cation (Zn or Cu) on ion mobility, with toxic metal concentrations increasing mobility and decreasing residual fractions. Mobile Zn fractions increased with larger particle diameters, lower clay content, and shorter interplanar spacing, while the opposite was observed for Cu. Zn likely accumulated in larger clay pores, while Cu was immobilized in the bentonite complex. The stability of Zn or Cu ions increased with higher clay content or specific surface area. Residual Zn or Cu fractions were highest in uncontaminated bentonites with higher unfrozen water content, suggesting the potential formation of concentrated solutions in sub-zero temperatures, posing a threat to the clay-water environment, especially in cold regions.

Polyextremophile engineering: a review of organisms that push the limits of life.

Nature exhibits an enormous diversity of organisms that thrive in extreme environments. From snow algae that reproduce at sub-zero temperatures to radiotrophic fungi that thrive in nuclear radiation at Chernobyl, extreme organisms raise many questions about the limits of life. Is there any environment where life could not "find a way"? Although many individual extremophilic organisms have been identified and studied, there remain outstanding questions about the limits of life and the extent to which extreme properties can be enhanced, combined or transferred to new organisms. In this review, we compile the current knowledge on the bioengineering of extremophile microbes. We summarize what is known about the basic mechanisms of extreme adaptations, compile synthetic biology's efforts to engineer extremophile organisms beyond what is found in nature, and highlight which adaptations can be combined. The basic science of extremophiles can be applied to engineered organisms tailored to specific biomanufacturing needs, such as growth in high temperatures or in the presence of unusual solvents.

VCA supercooling in a swine partial hindlimb model

Vascularized composite allotransplantations are complex procedures with substantial functional impact on patients. Extended preservation of VCAs is of major importance in advancing this field. It would result in improved donor-recipient matching as well as the potential for ex vivo manipulation with gene and cell therapies. Moreover, it would make logistically feasible immune tolerance induction protocols through mixed chimerism. Supercooling techniques have shown promising results in multi-day liver preservation. It consists of reaching sub-zero temperatures while preventing ice formation within the graft by using various cryoprotective agents. By drastically decreasing the cell metabolism and need for oxygen and nutrients, supercooling allows extended preservation and recovery with lower ischemia–reperfusion injuries. This study is the first to demonstrate the supercooling of a large animal model of VCA. Porcine hindlimbs underwent 48 h of preservation at − 5 °C followed by recovery and normothermic machine perfusion assessment, with no issues in ice formation and favorable levels of injury markers. Our findings provide valuable preliminary results, suggesting a promising future for extended VCA preservation.

Требования и методы испытаний средств индивидуальной защиты органов дыхания и зрения пожарных в российских и европейских стандартах

Due to the specifics of firefighting work, a significant amount of requirements is applied for compressed air breathing apparatuses. Many various test methodologies included in Russian national and European standards were developed to assess breathing apparatuses and their components. Such requirements and test methodologies in the abovementioned standards are, to a certain extent, similar; e.g., the requirement for technical variables, their values, and verification methods as the variables are based on the physiology of human breathing. Requirements and test methods for the ergonomics of products are similar as well. However, there are some differences in requirements and test methods stipulated in the Russian and European standards. It is primarily the climatic design of compressed air-breathing apparatuses and their components, for instance, the front parts. The requirements for the values of subzero temperatures at which climatic tests for breathing apparatuses are conducted are stricter in Russian standards, which is primarily caused by the climatic conditions on the territory of the Russian Federation. At the same time, European standards apply stricter requirements for the resistance of compressed air breathing apparatuses and their front parts to the impact of hazardous factors of fire, mainly thermal factors (exposure to open flame). The flame temperature during tests under the European standard is 100 °С higher. However, European standards contain no requirements for resistance to certain mechanical impacts, e.g., vibration. There is a difference in the structural design of the test equipment applied. It can be concluded that most of the requirements and test methods for compressed air breathing apparatuses contained in Russian and European standards are similar. A more thorough analysis to make conclusions regarding the applicability of European requirements and methods for compressed air breathing apparatuses produced in Russia is possible on the basis of comparative tests.

Co-solvent and additive joint engineering enable long-life and wide-temperature Zn metal battery

The dendrite growth and interfacial side reactions pose significant threaten to the practical applications of aqueous zinc metal batteries (AZMBs), especially at subzero temperature environments. To this end, co-solvent and additive joint engineering is proposed to design hybrid electrolyte, which consists of a mixture of 1,2-propanediol (1,2-PG) solvent and H2O with trace amounts of 18-crown-6 molecules, for constructing stable wide-temperature AZMBs. Notably, the 18-crown-6 and 1,2-PG molecules can both disturb the original hydrogen-bond network of H2O molecules. Interestingly, the 18-crown-6 molecules predominantly tends to absorb on the Zn anode surface and form favorable organic-inorganic hybrid SEI layer to regulate Zn deposition behaviors. The 1,2-PG molecules are responsible for reconstructing the solvation structure of Zn2+ and lowering the solid-liquid transition temperature of aqueous electrolyte, suppressing the H2O-induced side reactions and improving the antifreezing capability of electrolyte. Furthermore, the hybrid electrolyte induces the preferential Zn(002) plane deposition under the low temperature environments due to the synergistic effect of 18-crown-6 and 1,2-PG molecules, enhancing the Zn2+ transport and deposition kinetics. Consequently, the hybrid electrolyte endows the assembled cells with enhanced cycling lifespan and reversibility within the wide temperature range from -50 to 25 °C, expanding the application range of AZMBs.

Highly sulfonated poly ether ether ketone chelated with Cu2+ as a proton exchange membrane at sub-zero temperatures

Improving the proton conductivity (σ) of proton exchange membranes at low temperatures is very important for expanding their application areas. Here, sulfonated poly ether ether ketone (SPEEK) membranes were prepared with different sulfonation degrees, and its maximum ion exchange capacity is 3.15 mmol/g for 10 h at 60 °C. Highly sulfonated SPEEK membrane exhibits ultra-high water uptake and excellent proton conductivity of 0.074 S/cm at −25 °C due to its abundant −SO3H. Nevertheless, its high swelling ratio and low mechanical strength are not conducive to the practical application of the membrane. Luckily, by employing the chelation of Cu2+ with −SO3− on the SPEEK chain, Cu2+-coordinated SPEEK membranes were prepared, and they not only retain high −SO3H content but also possess robust mechanical properties and good dimensional stability compared to pristine SPEEK membrane. Meanwhile, the σ of the SPEEK-Cu membrane reaches 0.054 S/cm at −25 °C, and its fuel cell maximum power (Wmax) reaches 0.42 W/cm2 at −10 °C, demonstrating superior low-temperature performance in comparison to other reported materials. Particularly, water states in the prepared membranes are quantified by low-temperature differential scanning calorimetry. Because much more water bound to the plentiful −SO3H and Cu2+ inside the membrane endows it with anti-freezing performance, the decay of the σ and the Wmax for the SPEEK-Cu membrane is retarded at sub-zero temperatures. It is envisioned that composite membranes comprising metal ions such as Cu2+-SPEEK have a high potential for sub-zero fuel cell applications.

Exploring large language model for generic and robust state-of-charge estimation of Li-ion batteries: A mixed prompt learning method

State-of-charge (SOC) estimation is important to ensure safe functioning of Li-ion batteries (LIBs). However, distinct measurements, harsh temperatures, and dynamic operations pose challenges in estimating intricate SOC changes of multiple LIBs with one estimator. Hence, this paper proposes a novel mixed prompt learning method to explore a large-scale pretrained language model (PLM) for SOC estimation. A new hard prompt generator is proposed to translate LIB data into instruction and answer text, eliciting the inherent representational capability of PLM to jointly learn the sequential patterns and contextual semantics of measurements through language modeling for accurate SOC estimation. A new soft prompt adapter is proposed to encode task-specific information of different LIBs into a small set of independent vectors, ensuring PLM adaptation with minimal parameters while maintaining good generalization. By integrating soft prompt vectors along the forward propagation, the hidden states of PLM are dynamically regulated to characterize volatile and variable SOC for robust estimation. Extensive experiments show that by leveraging mixed hard-soft prompts, PLM can make accurate, generic, and robust estimates for multiple LIBs simultaneously in subzero temperature, charge-pause-discharge, and low-capacity discharge scenarios, with the average MAE, RMSE, and MAX of all tasks as low as 1.20 %, 1.51 %, and 5.29 %, respectively.