The article discusses modern approaches to the study of weathering and soil formation processes in soils. It offers comparative characteristics of migration-segregation (ordinary carbonate) chernozems and textural-calcareous (southern) chernozems formed under conditions of the steppe regions in the Crimea and Rostov region. Lithochemical indices were used to determine the relative age of soils and establish the relationship between soil formation and weathering. CIA index characterizes the degree of soil weathering and its mineralogical features, while CIW index determines the degree of maturity of fine aluminosiliciclastics. The determined gross chemical (elemental) composition of soils and rocks formed the initial data for such reconstructions. In addition, the research included calculations of the molar ratios of silica to sesquioxides (SiO2:R2O3) and the eluviation coefficient (Ke) (excluding sodium) in soils and soil-forming rocks. It has been established that the relative age of chernozems in the Crimean Peninsula is less compared to the similar subtypes of chernozems in the Rostov region. This is due to the peculiarities of the soil-forming material. In the Rostov region, chernozems are formed on more weathered clay parent rocks, while the formation of Crimean chernozems is confined mainly to the eluvium of sedimentary rocks. Down the profile, the intensity of soil formation and weathering processes in the soils of the South and South-East of the East European Plain noticeably decreases due to a lower rate of secondary weathering of minerals. This can be explained by the limited energy characteristics of the environment in which these processes occur. Among such limiting environmental factors, on the major factors are an insufficient amount of moisture in the spring-summer period.