The paper concerns destructive and non-destructive (NDT) evaluation of the effect of the addition of superabsorbent polymer (SAP) used as a carrier of mixing water and a means of internal curing on the durability of concrete. The research concerns testing of five concretes-an ordinary reference concrete and four concretes differing in the content of mixing water introduced into the concrete mix in the form of pre-saturated SAP particles (25%, two variants of 50% and 75% of the total mixing water in the form of SAP hydrogel). The research consisted of 4 stages of tests. The subsequent stages involved the analysis of the effect of using SAP as a carrier of mixing water on the particular characteristics of concrete mix and hardened concrete, i.e., consistency and density of concrete mix (1st stage), carbonation tested using two indicators-phenolphthalein and thymol phenolphthalein (2nd stage), and finally: the homogeneity of the concretes' structure by means of ultrasonic method (determination of ultrasonic pulse velocity) 28 days after production (3rd stage) and 3 years after production (4th stage). The ultrasonic pulse (or wave) velocity was then correlated with the content of water applied in the form of SAP hydrogel. The statistical analysis of results showed that the method of introducing the mixing water into the concrete mix in the form of pre-absorbed superabsorbent polymer, although it changed the concrete mix consistency, did not significantly affect the concrete ability to resist carbonation. Meanwhile, after 3 years, the densification of the microstructure of concrete with SAP has been observed.