Subpicosecond Laser Research Articles

Dynamics of mid-infrared semiconductor switching controlled by femtosecond laser pulses

Semiconductor switching of sub-picosecond mid-infrared laser pulses between 10 and 14 µm is characterized in GaAs, n-Ge, and ZnSe controlled by 30 fs pulses with photon energy above the band gap of the material. The reflectivity and lifetime are studied for multiple wavelengths. Time domain dynamics of semiconductor plasma reflectivity observed in experiments correlate with that derived in diffusion-recombination theory. Potential application of ultrafast semiconductor switching as a photonic device for use in high-power mid-infrared laser systems is discussed.

Model for Proton Acceleration in Strongly Self-Magnetized Sheath Produced by Ultra-High-Intensity Sub-Picosecond Laser Pulses

Recently, it has been experimentally shown that the sheath acceleration of protons from ultra-thin metal targets irradiated by sub-picosecond laser pulses of intensities above 1021 W/cm2 is suppressed compared to well-established models. This detrimental effect has been attributed to a self-generation of gigagauss-level quasi-static magnetic fields in expanded plasmas on the rear side of a target. Here we present a set of numerical simulations which support this statement. Based on 2D full-scale PIC simulations, it is shown that the scaling of a cutoff energy of the accelerated protons with intensity deviates from a well-established Mora model for laser pulses with a duration exceeding 500 fs. This deviation is showed to be connected to effective magnetization of the hottest electrons producing at the maximum of the laser pulse intensity. We propose a modification of the Mora model which incorporates the effect of the possible electron magnetization. Comparing it to the simulation results shows that by appropriately choosing a single fitting parameter, the model produces results that quantitatively coincide with simulations.

Sub-picosecond mode-locked laser operation in a femtosecond-laser-inscribed Yb:CaF2 channel waveguide

We present the successful demonstration of both Q-switched mode-locked (QSML) and continuous-wave mode-locked (CWML) operation in a femtosecond-laser-inscribed Yb:CaF2 double-track waveguide (WG) structure. A semiconductor saturable absorber output coupler (SOC) was used as the mode locker with fine tuning of the intracavity group delay dispersion (GDD) achieved through the Gires-Tournois interference (GTI) effect induced by an air gap. To ensure sufficient fluence on the saturable absorber, the cavity was extended to 50 cm by inserting two lenses between the SOC and WG, resulting in a repetition frequency of ∼300 MHz. In the QSML regime, the laser exhibited an amplitude modulation period of 65 kHz within Q-switched pulses of 3-µs duration. Notably, in the purely CWML regime, the laser generated a maximum output power of 51 mW near 1036 nm with a pulse width of 979 fs.

On estimation of betatron radiation spectrum characteristics of DLA electrons in NCD plasma

Action of a relativistically intense subpicosecond laser pulse on the near critical density (NCD) plasma can give rise to the formation of ion channel inside the plasma and effective acceleration of background electrons. Thus, one can produce high current (electron charges from tens nCl to several mkCl), high energy (from several MeV to several hundreds of MeV) electron bunches, demanded in different practical applications. Synchrotron (betatron) radiation of these electrons can serve as an important tool both for practical applications and also for diagnostic of the process in laser plasma, which is important for better understanding of these processes and for optimization of experimental conditions. For the last goals, an approximate model is proposed for calculating the spatial and energy characteristics of a bunch of DLA (direct laser accelerated) electrons in the ion channel formed in the NCD plasma and the characteristics describing the spectrum of their synchrotron radiation. For the considered example of a powerful laser pulse action on NCD plasma, the predictions of the proposed model are in good agreement with the results of particles in cell simulations and with the experimental measurements of the synchrotron radiation specter. It is shown that with the assumption of the rotation of the initial plane of motion of DLA electrons, the experimental data on the measurements of synchrotron radiation specters can be explained on the basis of the concept of betatron radiation of electrons accelerated in NCD plasma by DLA mechanism.

Velocimetry of GHz elastic surface waves in quartz and fused silica based on full-field imaging of pump–probe reflectometry

This study reports an imaging method for gigahertz surface acoustic waves in transparent layers using infrared subpicosecond laser pulses in the ablation regime and an optical pump-probe technique. The reflectivity modulations due to the photoelastic effect of generated multimodal surface acoustic waves were imaged by an sCMOS camera illuminated by the time-delayed, frequency-doubled probe pulses. Moving the delay time between , image stacks of wave field propagation were created. Two representative samples were investigated: wafers of isotropic fused silica and anisotropic x-cut quartz. Rayleigh (SAW) and longitudinal dominant high-velocity pseudo-surface acoustic wave (HVPSAW) modes could be observed and tracked along a circular grid around the excitation center, allowing the extraction of angular profiles of the propagation velocity. In quartz, the folding of a PSAW was observed. A finite element simulation was developed to predict the measurement results. The simulation and measurement were in good agreement with a relative error of 2% to 5%. These results show the potential for fast and full-field imaging of laser-generated ultrasonic surface wave modes, which can be utilized for the characterization of thin transparent samples such as semiconductor wafers or optical crystals in the gigahertz frequency range.

Subpicosecond laser ablation behavior of a magnesium target and crater evolution: Molecular dynamics study and experimental validation

Abstract The micro-ablation processes and morphological evolution of ablative craters on single-crystal magnesium under subpicosecond laser irradiation are investigated using molecular dynamics (MD) simulations and experiments. The simulation results exhibit that the main failure mode of single-crystal Mg film irradiated by a low fluence and long pulse width laser is the ejection of surface atoms, which has laser-induced high stress. However, under high fluence and short pulse width laser irradiation, the main damage mechanism is nucleation fracture caused by stress wave reflection and superposition at the bottom of the film. In addition, Mg[0001] has higher pressure sensitivity and is more prone to ablation than Mg [ 10 1 ¯ 0 ] . The evolution equation of crater depth is established using multi-pulse laser ablation simulation and verified by experiments. The results show that, under multiple pulsed laser irradiation, not only does the crater depth increase linearly with the pulse number, but also the quadratic term and constant term of the fitted crater profile curve increase linearly.

Terahertz and far infrared radiation generation in air plasma created by bichromatic subpicosecond laser pulses

Here, we report on terahertz (THz) radiation generation in air driven by the fundamental and second harmonic of Yb:KGW laser pulses with durations of a few hundred femtoseconds. It was found that the spectrum of generated THz pulses surprisingly spans up to 50 THz, which is comparable to that usually obtained using much shorter Ti:sapphire laser pulses. The broad bandwidth is attributed to a strong spatiotemporal reshaping of the pump pulses in a filament. The achieved energy conversion efficiency is comparable to the one usually obtained from much shorter pump pulses and could be further improved by an optimized experimental setup. The obtained results indicate that compact Yb-based sources provide an attractive alternative to much larger and expensive laser systems.

Characterization of bright betatron radiation generated by direct laser acceleration of electrons in plasma of near critical density

Directed x-rays produced in the interaction of sub-picosecond laser pulses of moderate relativistic intensity with plasma of near-critical density are investigated. Synchrotron-like (betatron) radiation occurs in the process of direct laser acceleration (DLA) of electrons in a relativistic laser channel when the electrons undergo transverse betatron oscillations in self-generated quasi-static electric and magnetic fields. In an experiment at the PHELIX laser system, high-current directed beams of DLA electrons with a mean energy ten times higher than the ponderomotive potential and maximum energy up to 100 MeV were measured at 1019 W/cm2 laser intensity. The spectrum of directed x-rays in the range of 5–60 keV was evaluated using two sets of Ross filters placed at 0° and 10° to the laser pulse propagation axis. The differential x-ray absorption method allowed for absolute measurements of the angular-dependent photon fluence. We report 1013 photons/sr with energies >5 keV measured at 0° to the laser axis and a brilliance of 1021 photons s−1 mm−2 mrad−2 (0.1%BW)−1. The angular distribution of the emission has an FWHM of 14°–16°. Thanks to the ultra-high photon fluence, point-like radiation source, and ultra-short emission time, DLA-based keV backlighters are promising for various applications in high-energy-density research with kilojoule petawatt-class laser facilities.

A Sub-Picosecond Laser System Based on High-Energy Yb:YAG Chirped-Pulse Regenerative Amplification

In this study, we have successfully demonstrated a high-energy subpicosecond Yb:YAG laser system based on chirped-pulse regenerative amplification. Our experimental results demonstrate a pulse energy of 3 mJ with a pulse duration of 829.8 fs and a repetition rate of 1 kHz. Additionally, we conducted an extensive investigation into the system’s recompression capability under various modulation and seeding conditions. Our findings suggest that the system can achieve effective recompression over a broad range of parameters, with the ability to compensate for a considerable degree of chirp. Our study provides valuable insights into the fundamental physic of high-energy laser systems and the performance characteristics of chirped-pulse regenerative amplification.

Gigahertz electromagnetic pulse emission from femtosecond relativistic laser-irradiated solid targets.

The interactions between high-intensity laser and matter produce particle flux and electromagnetic radiation over a wide energy range. The generation of extremely intense transient fields in the radio frequency-microwave regime has been observed in femtosecond-to-nanosecond laser pulses with 1011-1020-W/cm2 intensity on both conductive and dielectric targets. These fields typically cause saturation and damage to electronic equipment inside and near an experimental chamber; nevertheless, they can also be effectively used as diagnostic tools. Accordingly, the characterization of electromagnetic pulses (EMPs) is extremely important and currently a popular topic for present and future laser facilities intended for laser-matter interaction. The picosecond and sub-picosecond laser pulses are considerably shorter than the characteristic electron discharge time (∼0.1 ns) and can be efficient in generating GHz EMPs. The EMP characterization study of femtosecond laser-driven solid targets is currently mainly in the order of 100 mJ laser energy, in this study, the EMP generated by intense (Joule class) femtosecond laser irradiation of solid targets has been measured as a function of laser energy, laser pulse duration, focal spot size, and target materials. And a maximum electric field of the EMP reaching up to 105 V/m was measured. Analyses of experimental results confirm a direct correlation between measured EMP energy and laser parameters in the ultrashort pulse duration regime. The EMP signals generated by femtosecond laser irradiation of solid targets mainly originate from the return current inside the target after hot electron excitation. Numerical simulations of EMP are performed according to the target charging model, which agree well with the experimental results.

Investigation on laser absorption and x-ray radiation in microstructured titanium targets heated by short-pulse relativistic laser pulses

The enhancement effect of a microstructured surface on laser absorption and characteristic Kα emission has been investigated by measuring K-shell emission from titanium (Ti) targets irradiated with high-intensity (∼1020Wcm−2), subpicosecond (500 fs) laser pulses. The experimental results indicate a modest enhancement (1.6×) of Kα emission from microstructured targets compared to flat foils, but with a similar intensity and profile of Heα and Li-like satellites. Particle-in-cell (PIC) simulations are implemented to further understand the underlying physical processes in the laser interaction with both targets, interpreting the mechanisms responsible for the Kα enhancement. The reasons for the lower-than-expected enhancement of Kα emission are discussed. The rapid heating of the bulk plasma might result in the premature shutdown of Kα emission before the thermalization of hot electrons or even the end of laser pulses, suggesting that the use of Kα emission as a diagnostic of the hot-electron yield or relaxation could lead to a misinterpretation. Published by the American Physical Society 2024

Sub-picosecond laser surface modification of Ti–Ni alloy and its antibacterial activity

Surface modification of titanium nickelide (Ti–Ni) alloy improves its properties, forming a barrier oxidized/carbonized subsurface layer, which blocks the release of toxic nickel ions. We have modified Ti–Ni alloys by structuring the surface with sub-picosecond laser at different radiation parameters. The modified surface was characterized using scanning electron microscopy and layer-by-layer energy dispersive x-ray spectroscopy. The antibacterial properties of structured surfaces were tested against the planktonic culture of Staphylococcus aureus, and the viability was measured by ‘Live/Dead’ microbiological staining method.

Electro-Optic Sampling of a Free-Running Terahertz Quantum-Cascade-Laser Frequency Comb

Quantum-cascade-laser (QCL) frequency combs are compact semiconductor light sources operating in the mid-IR and terahertz frequencies. Achieving subpicosecond laser pulses with high peak power is of vital importance for performing nonlinear time-resolved spectroscopy as well for exploring nonlinear phenomena. Therefore, investigation and characterization of time-resolved free-running laser emission is a key for further improvement and optimization of these intersubband devices. In this work, we demonstrate a direct electric field measurement of a free-running terahertz QCL frequency comb using electro-optic sampling in combination with computational phase correction, where we retrieve the electric field profile and access the comb parameters. The demonstrated method is of high interest for time-resolved low-power laser emission characterization, typical for ring terahertz QCL frequency combs and investigation of phase-compensated emission via waveguide dispersion engineering for broadband comb operation.

Optoelectronic performance of indium tin oxide thin films structured by sub-picosecond direct laser interference patterning

A route to increase the efficiency of thin film solar cells is improving the light-trapping capacity by texturing the top Transparent Conductive Oxide (TCO) so that the sunlight reaching the solar absorber scatters into multiple directions. In this study, Indium Tin Oxide (ITO) thin films are treated by infrared sub-picosecond Direct Laser Interference Patterning (DLIP) to modify the surface topography. Surface analysis by scanning electron microscopy and confocal microscopy reveals the presence of periodic microchannels with a spatial period of 5 µm and an average height between 15 and 450 nm decorated with Laser-Induced Periodic Surface Structures (LIPSS) in the direction parallel to the microchannels. A relative increase in the average total and diffuse optical transmittances up to 10.7% and 1900%, respectively, was obtained in the 400–1000 nm spectral range as an outcome of the interaction of white light with the generated micro- and nanostructures. The estimation of Haacke’s figure of merit suggests that the surface modification of ITO with fluence levels near the ablation threshold might enhance the performance of solar cells that employ ITO as a front electrode.

Three-dimensional printing of silica glass with sub-micrometer resolution

Silica glass is a high-performance material used in many applications such as lenses, glassware, and fibers. However, modern additive manufacturing of micro-scale silica glass structures requires sintering of 3D-printed silica-nanoparticle-loaded composites at ~1200 °C, which causes substantial structural shrinkage and limits the choice of substrate materials. Here, 3D printing of solid silica glass with sub-micrometer resolution is demonstrated without the need of a sintering step. This is achieved by locally crosslinking hydrogen silsesquioxane to silica glass using nonlinear absorption of sub-picosecond laser pulses. The as-printed glass is optically transparent but shows a high ratio of 4-membered silicon-oxygen rings and photoluminescence. Optional annealing at 900 °C makes the glass indistinguishable from fused silica. The utility of the approach is demonstrated by 3D printing an optical microtoroid resonator, a luminescence source, and a suspended plate on an optical-fiber tip. This approach enables promising applications in fields such as photonics, medicine, and quantum-optics.

Mapping extended reaction coordinates in photochemical dynamics

Mapping extended reaction coordinates in photochemical dynamics

Fast wavelength-swept polarization maintaining all-fiber mode-locked laser based on a piezo-stretched fiber Lyot filter.

We demonstrate for the first time a strain-controlled all polarization-maintaining (PM) fiber Lyot filter based on a piezoelectric lead zirconate titanate (PZT) fiber stretcher. This filter is implemented in an all-PM mode-locked fiber laser to serve as a novel wavelength-tuning mechanism for fast wavelength sweeping. The center wavelength of the output laser can be tuned across a range from 1540 nm to 1567 nm linearly. And the strain sensitivity achieved in the proposed all-PM fiber Lyot filter is 0.052nm/με, which is 43 times higher than that achievable by other strain-controlled filters such as a fiber Bragg grating filter (0.0012nm/με). Wavelength-swept rates up to 500 Hz and wavelength tuning speeds up to 13,000 nm/s are demonstrated, which is hundreds of times faster than what is attainable with conventional sub-picosecond mode-locked lasers based on mechanical tuning methods. This highly repeatable and swift wavelength-tunable all-PM fiber mode-locked laser is a promising source for applications requiring fast wavelength tunability, such as coherent Raman microscopy.

Generation of 1.3 µm femtosecond pulses by cascaded nonlinear optical gain modulation in phosphosilicate fiber.

Nonlinear optical gain modulation (NOGM) is a simple and effective approach to generate highly coherent ultrafast pulses with a flexible wavelength. In this work, we demonstrate 34 nJ, 170 fs pulse generation at 1319 nm through a piece of phosphorus-doped fiber by two-stage cascaded NOGM with a 1064 nm pulsed pump. Beyond the experiment, numerical results show that 668 nJ, 391 fs pulses at 1.3 µm can be produced with up to 67% conversion efficiency by increasing the pump pulse energy and optimizing the pump pulse duration. This would offer an efficient method to obtain high-energy sub-picosecond laser sources for applications such as multiphoton microscopy.

Sub-ps Pulsed Laser Deposition of Boron Films for Neutron Detector Applications.

In view of the demand for high-quality thermal neutron detectors, boron films have recently attracted widespread research interest because of their special properties. In this work, we report on the deposition of boron films on silicon substrates by sub-picosecond pulsed laser deposition (PLD) at room temperature. Particular emphasis was placed on the investigation of the effect of the laser energy density (fluence) on the ablation process of the target material, as well as on the morphological properties of the resulting films. In addition, based on the study of the ablation and deposition rates as a function of the fluence, the ablation/deposition mechanisms are discussed. We show that well-adherent and stable boron films, with good quality surfaces revealing a good surface flatness and absence of cracks, can be obtained by means of the PLD technique, which proves to be a reliable and reproducible method for the fabrication of thick boron coatings that are suitable for neutron detection technology.

Interactions of Atomistic Nitrogen Optical Centers during Bulk Femtosecond Laser Micromarking of Natural Diamond

Micromarks were formed in bulk natural IaAB-type diamond laser-inscribed by 515 nm 0.3 ps femtosecond laser pulses focused by a 0.25 NA micro-objective at variable pulse energies in sub-picosecond visible-range laser regimes. These micromarks were characterized at room temperature (25 °C) by stationary 3D confocal photoluminescence (PL) microspectroscopy at 405 nm and 532 nm excitation wavelengths. The acquired PL spectra exhibit the increasing pulse-energy-dependent yield in the range of 550–750 nm (NV0, NV− centers) at the expense of the simultaneous reciprocal reduction in the blue–green (490–570 nm, H-band centers) PL yield. The detailed analysis indicates low-energy intensity rise for H-band centers as an intermediate product of vacancy-mediated dissociation of B1 and B2 centers, with H4 centers converting to H3 and NV centers at higher pulse energies, while the laser exposure effect demonstrates the same trend. These results will help solve the problem of direct laser writing technology, which is associated with the writing of micromarks in bulk natural diamond, and promising three-dimensional micro-electrooptical and photonic devices in physics and electronics.