Sublimation Rate Research Articles

Snow Sublimation in Mountain Environments and Its Sensitivity to Forest Disturbance and Climate Warming

AbstractSnow sublimation is an important component of the snow mass balance, but the spatial and temporal variability of this process is not well understood in mountain environments. This study combines a process‐based snow model (SnowModel) with eddy covariance (EC) measurements to investigate (1) the spatio‐temporal variability of simulated snow sublimation with respect to station observations, (2) the contribution of snow sublimation to the ablation of the snowpack, and (3) the sensitivity and response of snow sublimation to bark beetle‐induced forest mortality and climate warming across the north‐central Colorado Rocky Mountains. EC‐based observations of snow sublimation compared well with simulated snow sublimation at stations dominated by surface and canopy sublimation, but blowing snow sublimation in alpine areas was not well captured by the EC instrumentation. Water balance calculations provided an important validation of simulated sublimation at the watershed scale. Simulated snow sublimation across the study area was equivalent to 28% of winter precipitation on average, and the highest relative snow sublimation fluxes occurred during the lowest snow years. Snow sublimation from forested areas accounted for the majority of sublimation fluxes, highlighting the importance of canopy and sub‐canopy surface sublimation in this region. Simulations incorporating the effects of tree mortality due to bark‐beetle disturbance resulted in a 4% reduction in snow sublimation from forested areas. Snow sublimation rates corresponding to climate warming simulations remained unchanged or slightly increased, but total sublimation losses decreased by up to 6% because of a reduction in snow covered area and duration.

Optimization of CO2 production rate for firefighting robot applications using response surface methodology

A carbon dioxide gas-powered pneumatic actuation has been proposed as a suitable power source for an autonomous firefighting robot (CAFFR), which is designed to operate in an indoor fire environment in our earlier study. Considering the consumption rate of the pneumatic motor, the gas-powered actuation that is based on the theory of phase change material requires optimal determination of not only the sublimation rate of carbon dioxide but also the sizing of dry ice granules. Previous studies that have used the same theory are limited to generating a high volume of carbon dioxide without reference to neither the production rate of the gas nor the size of the granules of the dry ice. However, such consideration remains a design requirement for efficient driving of a carbon dioxide-powered firefighting robot. This paper investigates the effects of influencing design parameters on the sublimation rate of dry ice for powering a pneumatic motor. The optimal settings of these parameters that maximize the sublimation rate at the minimal time and dry ice mass are presented. In the experimental design and analysis, we employed full-factorial design and response surface methodology to fit an acceptable model for the relationship between the design factors and the response variables. Predictive models of the sublimation rate were examined via ANOVA, and the suitability of the linear model is confirmed. Further, an optimal sublimation rate value of 0.1025 g/s is obtained at a temperature of 80°C, the mass of 16.1683 g, and sublimation time of 159.375 s.

Freezing and Sublimation in Porous Media

A model for coupled heat and mass transfer for self-freezing in a porous matrix is set up and solved. A stability criterion for the phase interface is linked with well-known parameters like under cooling and freezing rate. It is shown that heat and mass transfer balance at the interface can affect stability. The effect of parameters on freezing and sublimation rates is examined. Applications in food processing, freeze drying and temperature control of buildings are possible.

Study of evaporating the irradiated graphite in equilibrium low-temperature plasma

The paper describes a problem of accumulation of irradiated graphite due to operation of uranium-graphite nuclear reactors. The main noncarbon contaminants that contribute to the overall activity of graphite elements are iso-topes 137Cs, 60Co, 90Sr, 36Cl, and 3H. A method was developed for processing of irradiated graphite ensuring the volu-metric decontamination of samples. The calculation results are presented for equilibrium composition of plasma-chemical reactions in systems “irradiated graphite−argon” and “irradiated graphite−helium” for a wide range of tem-peratures. The paper describes a developed mathematical model for the process of purification of a porous graphite surface treated by equilibrium low-temperature plasma. The simulation results are presented for the rate of sublimation of radioactive contaminants as a function of plasma temperature and plasma flow velocity when different plasma-forming gases are used. The extraction coefficient for the contaminant 137Cs from the outer side of graphite pores was calculated. The calculations demonstrated the advantages of using a lighter plasma forming gas, i.e., helium.

The significance of vertical moisture diffusion on drifting snow sublimation near snow surface

Abstract. Sublimation of blowing snow is an important parameter not only for the study of polar ice sheets and glaciers, but also for maintaining the ecology of arid and semi-arid lands. However, sublimation of near-surface blowing snow has often been ignored in previous studies. To study sublimation of near-surface blowing snow, we established a sublimation of blowing snow model containing both a vertical moisture diffusion equation and a heat balance equation. The results showed that although sublimation of near-surface blowing snow was strongly reduced by a negative feedback effect, due to vertical moisture diffusion, the relative humidity near the surface does not reach 100 %. Therefore, the sublimation of near-surface blowing snow does not stop. In addition, the sublimation rate near the surface is 3–4 orders of magnitude higher than that at 10 m above the surface and the mass of snow sublimation near the surface accounts for more than half of the total snow sublimation when the friction wind velocity is less than about 0.55 m s−1. Therefore, the sublimation of near-surface blowing snow should not be neglected.

Global Sensitivity Analysis as Good Modelling Practices tool for the identification of the most influential process parameters of the primary drying step during freeze-drying

Pharmaceutical batch freeze-drying is commonly used to improve the stability of biological therapeutics. The primary drying step is regulated by the dynamic settings of the adaptable process variables, shelf temperature Ts and chamber pressure Pc. Mechanistic modelling of the primary drying step leads to the optimal dynamic combination of these adaptable process variables in function of time. According to Good Modelling Practices, a Global Sensitivity Analysis (GSA) is essential for appropriate model building. In this study, both a regression-based and variance-based GSA were conducted on a validated mechanistic primary drying model to estimate the impact of several model input parameters on two output variables, the product temperature at the sublimation front Ti and the sublimation rate ṁsub. Ts was identified as most influential parameter on both Ti and ṁsub, followed by Pc and the dried product mass transfer resistance αRp for Ti and ṁsub, respectively. The GSA findings were experimentally validated for ṁsub via a Design of Experiments (DoE) approach. The results indicated that GSA is a very useful tool for the evaluation of the impact of different process variables on the model outcome, leading to essential process knowledge, without the need for time-consuming experiments (e.g., DoE).

Improved freeze drying efficiency by ice nucleation proteins with ice morphology modification

This study aims to use ice nucleation proteins (INPs) as a novel approach to improve the efficiency of freeze drying process and investigate the related mechanism of ice morphology. Our results show that INPs can significantly improve freeze drying efficiency with increased primary drying rate under the increase of INP concentration from 0 to 10−2mg/mL. Moreover, such improvement was more significant at higher subzero freezing temperatures with the addition of INPs, when the control samples were unable to freeze. Those improvements further lead to reduced total drying time, which suggests an estimated total energy saving of 28.5% by INPs. Our ice morphology results indicate the ability of INPs to alter ice morphology with lamellar ice structure and larger crystal size, which both show linear relationships with primary drying rate. The results further suggest that these ice morphology characteristics induced by INPs are very likely to facilitate the water vapor flow and improve the sublimation rate. Additionally, the increase of freeze drying efficiency can also be achieved by INPs in other food systems like coffee and milk with elevated primary drying rate. The results of this study suggest great potential of using INPs to improve the efficiency of freeze drying process for a wide range of food products and other related applications. This study also provides new insights into the relationship between process efficiency and ice morphology.

Effects of controlled nucleation on freeze-drying lactose and mannitol aqueous solutions

ABSTRACTThe lyophilization of lactose and mannitol aqueous solutions was investigated with an emphasis on analyzing the effects of controlled nucleation, temperature of nucleation, and pore size distribution on the freeze-drying process. The experimental procedure involved the depressurization technique of controlled nucleation, in-vial temperature measurements as well as measurements of the chamber pressure, which allowed the analysis of the product batch, loaded in the laboratory lyophilizator. The average pore enlargement was 93 and 58% with the incorporation of the controlled nucleation step in the lyophilization of 6 wt% lactose and 6 wt% mannitol solutions, respectively. Consequently, the primary drying times were lowered from 450 to 500 min in both cases. The pore sizes were determined to be as important as the solid material itself in the scope of the sublimation rates. Namely, the average equivalent diameter of the pores was larger in the dried mannitol cake compared to the lactose cake. However, despite the higher porosity of the dried mannitol cake, the end of the sublimation in the primary drying step was observed approximately 500 min earlier during the lyophilization of the lactose solution with the same initial concentration as the mannitol solution in a comparable freeze-drying protocol. In addition, an increase in mannitol concentration from 3 to 12 wt% was found to substantially extend the time required for the sublimation phase of the lyophilization.

Thermophysics of fractures on comet 67P/Churyumov-Gerasimenko

Context. The camera OSIRIS on board Rosetta obtained high-resolution images of the nucleus of comet 67P/Churyumov-Gerasimenko (67P). Great parts of the nucleus surface are composed of fractured terrain. Aims. Fracture formation, evolution, and their potential relationship to physical processes that drive activity are not yet fully understood. Observed temperatures and gas production rates can be explained or interpreted with the presence of fractures by applying appropriate modelling methods. Methods. We followed a transient thermophysical model approach that includes radiative, conductive, and water-ice sublimation fluxes by considering a variety of heliocentric distances, illumination conditions, and thermophysical properties for a set of characteristic fracture geometries on the nucleus of 67P. We computed diurnal temperatures, heat fluxes, and outgassing behaviour in order to derive and distinguish the influence of the mentioned parameters on fractured terrain. Results. Our analysis confirms that fractures, as already indicated by former studies about concavities, deviate from flat-terrain topographies with equivalent properties, mostly through the effect of self-heating. Compared to flat terrain, illuminated cometary fractures are generally warmer, with smaller diurnal temperature fluctuations. Maximum sublimation rates reach higher peaks, and dust mantle quenching effects on sublimation rates are weaker. Consequently, the rough structure of the fractured terrain leads to significantly higher inferred surface thermal inertia values than for flat areas with identical physical properties, which might explain the range of measured thermal inertia on 67P. Conclusions. At 3.5 AU heliocentric distance, sublimation heat sinks in fractures converge to maximum values >50 W / m2 and trigger dust activity that can be related mainly to H2O. Fractures are likely to grow through the erosive interplay of alternating sublimation and thermal fatigue.

Blowing snow sublimation and transport over Antarctica from 11 years of CALIPSO observations

Abstract. Blowing snow processes commonly occur over the earth's ice sheets when the 10 m wind speed exceeds a threshold value. These processes play a key role in the sublimation and redistribution of snow thereby influencing the surface mass balance. Prior field studies and modeling results have shown the importance of blowing snow sublimation and transport on the surface mass budget and hydrological cycle of high-latitude regions. For the first time, we present continent-wide estimates of blowing snow sublimation and transport over Antarctica for the period 2006–2016 based on direct observation of blowing snow events. We use an improved version of the blowing snow detection algorithm developed for previous work that uses atmospheric backscatter measurements obtained from the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) lidar aboard the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) satellite. The blowing snow events identified by CALIPSO and meteorological fields from MERRA-2 are used to compute the blowing snow sublimation and transport rates. Our results show that maximum sublimation occurs along and slightly inland of the coastline. This is contrary to the observed maximum blowing snow frequency which occurs over the interior. The associated temperature and moisture reanalysis fields likely contribute to the spatial distribution of the maximum sublimation values. However, the spatial pattern of the sublimation rate over Antarctica is consistent with modeling studies and precipitation estimates. Overall, our results show that the 2006–2016 Antarctica average integrated blowing snow sublimation is about 393 ± 196 Gt yr−1, which is considerably larger than previous model-derived estimates. We find maximum blowing snow transport amount of 5 Mt km−1 yr−1 over parts of East Antarctica and estimate that the average snow transport from continent to ocean is about 3.7 Gt yr−1. These continent-wide estimates are the first of their kind and can be used to help model and constrain the surface mass budget over Antarctica.

Freeze-Drying From Organic Cosolvent Systems, Part 1: Thermal Analysis of Cosolvent-Based Placebo Formulations in the Frozen State

The use of cosolvent systems has been demonstrated to shorten lengthy freeze-drying processes and improve the solubility and stability of certain active pharmaceutical ingredients. The goal of the present study was to evaluate the suitability of 2 thermal characterization techniques, differential scanning calorimetry and freeze-dry microscopy, and to identify an optimal cosolvent system. Binary mixtures of a cosolvent (tert-butanol, dimethyl sulfoxide, 1,4-dioxane, acetone, or ethanol) and water were investigated. Ternary mixtures of frequently used excipients (50 mg/g mannitol, sucrose, glycine, or polyvinylpyrrolidone [PVP]) and a solvent-water system were then analyzed for their thermal properties. PVP presented a particularly high glass transition temperature (Tg′) in 70% tert-butanol at −17.9°C. Large needle-shaped crystals that have been shown to be associated with improved processability were observed with mannitol and PVP in 40% 1,4-dioxane. A heterogeneous sublimation rate of the solvent and water whose impact on product stability remained unclear was observed with PVP in 40% 1,4-dioxane. Freeze-dry microscopy analysis demonstrated a possible extension of the process time for PVP in 99% dimethyl sulfoxide due to a slowly moving sublimation front. Conceivable negative consequences and the need for special treatment for low-melting cosolvents, such as ethanol and acetone, were predicted and discussed.

Water and energy fluxes over northern prairies as affected by chinook winds and winter precipitation

Chinooks are the North American variety of foehn: strong, warm and dry winds that descend lee mountain slopes. The strong wind speeds, high temperatures and substantial humidity deficits have been hypothesized to remove important prairie near-surface water storage from agricultural fields via evaporation, sublimation and blowing snow, as well as change the phase of near surface water via snowmelt and ground thaw. This paper presents observations of surface energy and water balances from eddy covariance instrumentation deployed at three open sites in southern Alberta, Canada during winter 2011–2012. Energy balances, snow and soil moisture budgets of three select chinook events were analysed in detail. These three events ranged in duration from two to nine days, and are representative of winter through early spring chinooks. Precipitation data from gauges and reanalyses (CaPA and ERA-interim) were used to assess water balances. Variations in precipitation and snowpacks caused the greatest differences in energy and water balances. Cumulative winter precipitation varied by a factor of two over the three sites: heaviest at the more northern site immediately east of the Rocky Mountains and lightest at the easternmost and southernmost site. The temporal progression of chinook-driven surface water loss is explained, beginning with strong blowing snow events through to evaporation of meltwater as snowpacks disappear. At the two sites with considerable winter precipitation and snowcover, large upward latent heat fluxes, often exceeding 100Wm−2, were driven by downward sensible heat fluxes but were unrelated to net radiation. Conversely, at the southernmost site with little snowcover, upward latent heat fluxes were much smaller (less than 50Wm−2) and were associated with periods of positive net radiation. Upward sensible heat fluxes during periods of positive net radiation were observed at this site throughout winter, but were not observed at the more northerly sites until March when the snowcovers ablated. Daily sublimation plus evaporation rates during chinooks at the sites with heaviest and lightest precipitation were 1.3–2.1mm/day and 0.1–0.3mm/day, respectively. Evaporation of soil water occurred while soils were partially to fully unfrozen in November. There was little change in soil water content between fall freeze-up and spring thaw (December through most of March), indicating that over-winter infiltration was balanced by soil water evaporation and both terms were likely to be small. Winter precipitation resulted in only 2% to 4% increases in near-surface water storage at the more northern sites with greater precipitation, whereas there was a net loss over winter at the southernmost site.

Wintertime surface energy balance of a high-altitude seasonal snow surface in Chhota Shigri glacier basin, Western Himalaya

Abstract We describe a time series of meteorological parameters and surface energy balance components of a seasonal snow cover from an automatic weather station (4863 m a.s.l., 32.28° N, 77.58° E), for a winter season from 1 December 2012 to 30 March 2013, located on a moraine close to the equilibrium line altitude of Chhota Shigri glacier, Himachal Pradesh, India. The analysis shows that for over 80% of the time in winter, the snow surface was at a cooling phase. During late winter however, the surface had some positive residual energy which induced some melt during peak hours of the day. The net all-wave radiation was mostly negative during winter because of the high reflective property of snow and reduced incoming longwave radiation due to low cloud. The sensible heat flux heats the surface at night and enhances the cooling during day. The latent heat flux is always negative, showing that the surface is losing mass through sublimation processes (−0.83 mm w.e./day). A correlation between the energy fluxes and temperature shows a distinct relationship between fluxes. A comparison between the two studies performed on- and off-glacier reveals a significant difference in some parameters. A higher value (−1.08 mm/day) of sublimation rate at 4863 m a.s.l. shows that a large amount of energy available at the surface was used in sublimation processes. A comparatively lower albedo, relative humidity and net longwave radiation and higher latent heat flux, wind speed and net shortwave radiation yield a distinctive surface energy balance, highlighting the need for a large number of stations at different zones to achieve a coherent picture of energy balance in the region.

Experimental reflectance study of methane and ethane ice at Titan’s surface conditions

Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) has provided evidence of several different hydrocarbons on the surface of Titan using seven atmospheric windows. Methane (CH4) and ethane (C2H6) are suggested to exist in both the liquid and solid states on Titan. Even if the average surface temperature (90–94 K) of Titan is clearly in the liquid stability field of both CH4 and C2H6, the particles can condense in the atmosphere (∼65 km for C2H6 and lower stratosphere for CH4 Anderson et al. in Icarus, 243:129–138, 2014) and precipitate allowing them to melt and/or sublimate. It is also suggested that these liquids can freeze on the surface due to evaporative cooling. We conducted a laboratory study at Titan surface conditions to determine the phase change of CH4 and C2H6 and to test if they would freeze on the surface of Titan. Using NIR reflectance spectroscopy, we calculated the reflectivity ratio ( $R_{\mathrm{solid}}/R_{\mathrm{liquid}}$ ) of CH4 and C2H6 of 1.08 and 1.36, respectively, suggesting an 8% increase in reflectivity for CH4 and a 36% increase for C2H6 during phase change. The low albedo in liquid phase for both CH4 and C2H6 is consistent with observations made by VIMS in both Titan’s northern and southern latitudes. We also find the evaporation rate of amorphous CH4 close to Titan conditions, which is $9.0 \pm 0.3 \times 10^{-5}~\mbox{kg}\,\mbox{s}^{-1}\,\mbox{m}^{-2}$ at 87 K and we estimated a sublimation rate of $0.22 \times 10^{-5}~\mbox{kg}\,\mbox{s}^{-1}\,\mbox{m}^{-2}$ at 83 K for a 1.5 bar N2 atmosphere. The freezing rate of ∼46 m/year for C2H6 was observed whereas, for CH4, we observed that CH4 does not freeze at 87 K due to a high N2 dissolution rate. However, the viscosity of CH4 increases with a decreasing temperature that results in amorphous CH4. The results show a remarkable difference between the formation of ice for two liquids with different N2 dissolution rates. Consequently, using the results obtained from the laboratory study we predict that the observed change is albedo during and after rainfall on Titan is caused by CH4 due to evaporative cooling processes.

Influence of solid-surface vibrations on mass transfer

The results of an experimental study of mass transfer from a vibrating flat disk to a gas medium have been given. It has been shown that a substantial increase in the rate of sublimation of solid naphthalene in a laminar air flow is observed in the frequency range of 20–200 Hz and at amplitudes of 0.08–7.02 mm. An empirical dependence that connects the Sh number with the vibrational Re number has been obtained.

Cliffs versus plains: Can ROSINA/COPS and OSIRIS data of comet 67P/Churyumov-Gerasimenko in autumn 2014 constrain inhomogeneous outgassing?

Context. This paper describes the modelling of gas and dust data acquired in the period August to October 2014 from the European Space Agency’s Rosetta spacecraft when it was in close proximity to the nucleus of comet 67P/Churyumov-Gerasimenko.Aims. With our 3D gas and dust comae models this work attempts to test the hypothesis that cliff activity on comet 67P/Churyumov-Gerasimenko can solely account for the local gas density data observed by the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) and the dust brightnesses seen by the Optical, Spectroscopic, and Infrared Remote Imaging System (OSIRIS) in the considered time span.Methods. The model uses a previously developed shape model of the nucleus. From this, the water sublimation rates and gas temperatures at the surface are computed. The gas expansion is modelled with a 3D Direct Simulation Monte Carlo algorithm. A dust drag algorithm is then used to compute dust volume number densities in the coma, which are then converted to brightnesses using Mie theory and a line-of-sight integration. Furthermore we have studied the impact of topographic re-radiation on the models.Results. We show that gas activity from only cliff areas produces a fit to the ROSINA/COPS data that is as statistically good as a purely insolation-driven model. In contrast, pure cliff activity does not reproduce the dust brightness observed by OSIRIS and can thus be ruled out. On the other hand, gas activity from the Hapi region in addition to cliff activity produces a statistically better fit to the ROSINA/COPS data than purely insolation-driven outgassing and also fits the OSIRIS observations rather well. We found that topographic re-radiation does not contribute significantly to the sublimation behaviour of H2 O but plays an important role in how the gas flux interacts with the irregular shape of the nucleus.Conclusions. We demonstrate that fits to the observations are non-unique. We can conclude however that gas and dust activity from cliffs and the Hapi region are consistent with the ROSINA/COPS and OSIRIS data sets for the considered time span and are thus a plausible solution. Models with activity from low gravitational slopes alone provide a statistically inferior solution.

Growth and Characterization of β-RDX Single-Crystal Particles

1,3,5-Trinitrohexahydro-s-triazine (RDX) single-crystal particles crystallized in the β phase have been successfully grown by sublimation–recrystallization. Synchrotron X-ray diffraction results confirm that the recrystallized products are β-RDX single crystals. Compared to the traditional solution deposition methods, the sublimation method used in this work breaks through the mass limitations during the growth of β-RDX. The distribution of α- and β-RDX on different substrates reveals that hydrophilic substrates are prone to grow β-RDX single crystals and that hydrophobic substrates prefer α-RDX single crystals. The sublimation rate dominates the growth of pure β-RDX. The mechanisms of the phase transition from β-RDX to α-RDX during the process of sublimation–recrystallization have been studied. The current results can promote the potential application of β-RDX in the propellant, explosives, and military fields.

Application of Optical Coherence Tomography Freeze-Drying Microscopy for Designing Lyophilization Process and Its Impact on Process Efficiency and Product Quality.

Optical coherence tomography freeze-drying microscopy (OCT-FDM) is a novel technique that allows the three-dimensional imaging of a drug product during the entire lyophilization process. OCT-FDM consists of a single-vial freeze dryer (SVFD) affixed with an optical coherence tomography (OCT) imaging system. Unlike the conventional techniques, such as modulated differential scanning calorimetry (mDSC) and light transmission freeze-drying microscopy, used for predicting the product collapse temperature (Tc), the OCT-FDM approach seeks to mimic the actual product and process conditions during the lyophilization process. However, there is limited understanding on the application of this emerging technique to the design of the lyophilization process. In this study, we investigated the suitability of OCT-FDM technique in designing a lyophilization process. Moreover, we compared the product quality attributes of the resulting lyophilized product manufactured using Tc, a critical process control parameter, as determined by OCT-FDM versus as estimated by mDSC. OCT-FDM analysis revealed the absence of collapse even for the low protein concentration (5mg/ml) and low solid content formulation (1%w/v) studied. This was confirmed by lab scale lyophilization. In addition, lyophilization cycles designed using Tc values obtained from OCT-FDM were more efficient with higher sublimation rate and mass flux than the conventional cycles, since drying was conducted at higher shelf temperature. Finally, the quality attributes of the products lyophilized using Tc determined by OCT-FDM and mDSC were similar, and product shrinkage and cracks were observed in all the batches of freeze-dried products irrespective of the technique employed in predicting Tc.

Spatially resolved evolution of the local H2O production rates of comet 67P/Churyumov-Gerasimenko from the MIRO instrument on Rosetta

Aims. Using spectroscopic and continuum data measured by the MIRO instrument on board Rosetta of comet 67P/Churyumov-Gerasimenko, it is possible to derive and track the change in the water production rate, to learn how the outgassing evolves with heliocentric distance. The MIRO data are well suited to investigate the evolution of 67P, in unprecedented spatial and temporal detail.Methods. To obtain estimates of the local effective Haser production rates we developed an efficient and reliable retrieval approach with precalculated lookup tables. We employed line area ratios (H2 16 O/H2 18 O) from pure nadir observations as the key variable, along with the Doppler shift velocity, and continuum temperature. This method was applied to the MIRO data from August 2014 until April 2016. Perihelion occurred on August 13, 2015 when the comet was 1.24 AU from the Sun.Results. During the perihelion approach, the water production rates increased by an order of magnitude, and from the observations, the derived maximum for a single observation on August 29, 2015 is (1.42 ± 0.51) ×1028 . Modeling the data indicates that there is an offset in the peak outgassing, occurring 34 ± 10 days after perihelion. During the pre-perihelion phase, the production rate changes with heliocentric distance as r h −3.8±0.2 ; during post-perihelion, the dependence is r h −4.3±0.2 . The comet is calculated to have lost 0.12 ± 0.06 % of its mass during the perihelion passage, considering only water ice sublimation. Additionally, this method provides well sampled data to determine the spatial distribution of outgassing versus heliocentric distance. The time evolution is definitely not uniform across the surface. Pre- and post-perihelion, the surface temperature on the southern hemisphere changes rapidly, as does the sublimation rate with an exponent of ~−6. There is a strong latitudinal dependence on the r h exponent with significant variation between northern and southern hemispheres, and so the average over the comet surface may only be of limited importance. We present more detailed regional variation in the outgassing, demonstrating that the highest derived production rates originate from the Wosret, Neith and Bes regions during perihelion.

Investigation of the Process of Formation of Hafnium Carbide on Carbon-Carbon Composite Material in the System HfCl4–CH4–Ar

The first stage in the development of the technique for producing thin coatings of hafnium carbide on carbon-carbon composite material (CCCM) surfaces at relatively low synthesis temperatures for reducing the arising thermal stresses is presented. The process of formation of hafnium carbide on the surface of CCCM in the HfCl4–CH4–Ar system was investigated at 1050°C and atmospheric pressure. The rate of sublimation of hafnium (IV) chloride was studied at different flow rates of the carrier. Histograms showing the particle size distributions of hafnium carbide particles were constructed. A polydisperse distribution of particles on the surface of the CCCM was established with two maxima for the average diameters of 5.4 μm and 295 nm.