Morphological Studies Research Articles

Influence of 60Co gamma radiation on the structural, morphological and optical properties of hydrothermally synthesized MoO3-CeO2 nanocomposite.

The influence of 60Co gamma radiation on Molybdenum Oxide-Cerium Oxide (MoO3-CeO2) nanocomposite is investigated in the present study. The MoO3-CeO2 nanocomposite was synthesized by conventional hydrothermal route. Ammonium hepta molybdate tetrahydrate [(NH4)6Mo7O24.4H2O] and cerium nitrate [Ce (NO3)3.4H2O] were used as the precursors. The composite was subjected to high energy gamma irradiation for different doses of 50, 100 and 150 kGy using 60Co gamma irradiation chamber. The structural study was carried out using X-ray diffraction, the morphological studies were carried out using scanning electron microscopy and ultraviolet-visible spectroscopy was carried out to study the optical properties before and after irradiation. The crystallite size was found to increase with increasing doses of gamma irradiation. The morphology of the samples shows that the nanoparticles tend to agglomerate with increasing doses of gamma radiation. The energy bandgap of the MoO3-CeO2 nanocomposite was calculated before and after irradiation and found to decrease with increasing doses of irradiation upto 100 kGy and then increases for 150 kGy.

Study of multi-elemental concentration and nano-micro structural morphology in medicinal plants by FE-SEM and EDX method.

Medicinal plants of the Moraceae family, such as Ficus racemosa linn, have been traditionally used in the North Karnataka region for treating various ailments. This study aims to analyze the elemental composition and nano-micro structural morphology of selected species of Moraceae family medicinal plants, focusing on their potential therapeutic applications. Samples were collected from the Dharwad and Gadag districts in North Karnataka. The surface morphology at nano and micro levels was examined using a field emission scanning electron microscope, while the elemental composition was analyzed through energy-dispersive X-ray spectroscopy. The study emphasizes the detailed examination of the specific weight percent of elemental concentration and the morphological features observed. The analysis revealed fine, irregularly shaped particles with an average diameter of 20 to 50 μm on the plant surface. Elemental composition analysis showed the presence of Mg, Al, Si, Cl, K, Ca, Mn, Fe, Cu, and Zn within WHO-recommended limits.

First Report of Trichoderma hamatum Causing Postharvest Bulb Rot on Lilium davidii var. willmottiae in China.

Lilium davidii var. willmottiae, known as Lanzhou lily, is a famous edible crop that is mostly distributed in the middle area of Gansu Province in China. In the winter of 2019, symptoms of bulb rot were observed on Lanzhou lilies harvested from Lanzhou, Gansu Province, during storage at the Institute of Grassland, Flowers and Ecology (39°57'55.984" N, 116°20'8.124" E), Beijing Academy of Agriculture and Forestry Sciences, at an incidence of nearly 50%. The decayed bulb (Fig.1a)was washed under tap water and surface disinfested with 75% ethanol for 1 min, followed by 2.5% sodium hypochlorite for 5 min, and washed with sterile distilled water three times. The 5 mm×5 mm tissue pieces from the junction of the diseased part and the healthy part were clipped, placed on potato dextrose agar (PDA) medium and subsequently incubated at 25 °C. Thirteen dominant pure fungal isolates with the same morphological characteristics were obtained by the hyphal-tip method. Three representative isolates LZ-8, LZ-9-2 and LZ-10 were chosen for phylogenetic analyses. The internal transcribed spacer (ITS), translation elongation factor 1-alpha (TEF-1a), and RNA polymerase II second largest subunit (RPB2) sequences were PCR amplified using the primer pairs ITS1/ITS4 (White et al. 1990), EF1-728F/EF1-986R (Carbone and Kohn 1999), and RPB2-5F2/RPB2-7cR (O'Donnell et al. 2022), respectively. BLAST analysis showed that the ITS,TEF-1a, and RPB2 sequences of the isolates LZ-8 (GenBank accession nos. PP422096, PP447248, and PP447251), LZ-9-2 (GenBank accession nos. PP422098, PP447249, and PP447252) and LZ-10 (GenBank accession nos. PP422099, PP447250, and PP447253) had 99.27 to 99.71% identity with multiple GenBank sequences of Trichoderma hamatum, and the three DNA fragments of the three isolates showed 100% sequence identity. A phylogenetic tree based on concatenated sequences of the three genes using maximum -likelihood analyses revealed that the three isolates LZ-8, LZ-9-2 and LZ-10 were in the same clade with T. hamatum strains (Fig.2). One representative isolate, LZ-10, was chosen for morphological studies and test of the pathogenicity. The colony of LZ-10 on PDA appeared white with cotton-shaped aerial hyphae early, which later turned light green to green and formed concentric rings (Fig.1d-1f). At the end of conidiophores, three to six pear-shaped branches were irregularly gathered(Fig.1h). Conidia were ellipsoid with the size of 3.1 to 4.4 × 2.2 to 3.1 µm (n =20) (Fig.1g). These morphological characteristics were consistent with the description of Trichoderma hamatum. (Kamala et al. 2015, Han et al. 2017).To test pathogenicity, healthy bulbs were punctured with disposable sterilized needles and soaked in equal amounts of sterile water and conidial suspension (1×107 conidia/mL) for 30 min respectively. The pathogenicity experiment was repeated three times. After 6 days of inoculation at 25 °C and 80% relative humidity, the surface of the inoculated bulbs produced water-stained spots and mycelium layers(Fig.1b-1c) consistent with the symptoms exhibited by Lilium davidii var. willmottiae bulbs during storage, meanwhile the uninoculated lily bulbs remained symptomless. Trichoderma hamatum was reisolated from the infected bulbs and identified based on morphological and molecular characteristics, fulfilling Koch's postulates. To our knowledge, this is the first report of bulb rot on Lilium davidii var. willmottiae caused by Trichoderma hamatum in China. This study will contribute to a better understanding and controlling of this postharvest disease in Lilium davidii var. willmottiae.

First Record of Snakehead Gudgeon (Ophiocara porocephala) in Sorong, West Papua, Indonesia

Aims: As reported this paper, the new record of O. porocephala has helped to improved the knowledge of the species as it extends the distribution range. Study Design: Short Communication. Place and Duration of Study: This research was conducted from September to November 2021. Sampling was carried out in the Tampa Garam mangrove forest swamp located in Tampa Garam Village, Maldum Mes Distric, Sorong City. Methodology: The morphology of fishes has been the primary source of information for taxonomic and evolutionary studies. There were numerous characters available for morphological study. Results: O. porocephala had a horizontally and terminally wide mouth with a large enough distance from the posterior area of ​​the eye. O. porocephala had ideal eye spacing with small eyelids and large corneas, two dorsal fins and an anal fin each with a distance of 1 and 22mm between the dorsal fins, the anterior dorsal consists of spines fins, while the posterior was weak fins. Fish habitat was found in mangrove areas or in estuarine areas with a salinity of 11 ppt, small fish lived in shallow areas while larger fish lived in deeper areas. The brightness of the air when the fish were isolated was 100%. Oxygen levels at 4 mg/l. O. Porocephala obtained during the study, consisting of gender is 1 female and unidenified. Meanwhile, the fish size in the class 10,9-225,39 cm and gonad weight is 2,62 of female fish with categorie gonad maturity is 3. Conclusion: Based on the results of research, fish that live in mangrove areas are carnivorous, with large fish species having a total length of 18,4 cm and small fish less than 10 cm, further research needs to be carryout base on the feed habit and maturity of this fish.

A revision of Rhombuniopsis Haas, 1920 (Unionida, Unionidae) endemic to the ancient lakes of Yunnan, China, with descriptions of two new species

Freshwater mussels are an important component of the macrobenthic fauna but due to modern environmental pollution and destruction, the abundance of freshwater mussels has declined rapidly, and this fauna is one of the most threatened animal groups in the world. China is the country with the second highest diversity of freshwater mussels in the world. Rhombuniopsis is a genus of freshwater mussels endemic to the ancient lakes and surrounding area in Yunnan Province, China. Species in this genus are threatened with extinction and have not been recorded alive for many years. We present a revision of Rhombuniopsis based on the morphological study of the museum materials and newly collected specimens, and propose two species new to science: Rhombuniopsis linan sp. nov. and Rhombuniopsis songmeng sp. nov. The two new species are considered extinct because the lakes they inhabited were completely dried up due to human activity. We compare our recent data with the historical studies to trace the population change of the Rhombuniopsis species in different lakes. We revise the distribution and assess the conservation status for each species. The present work confirms the importance of conservation of molluscs in the ancient lakes of Yunnan and suggest that several species are already extinct.

Ultrasonic assisted green synthesis of CuO nanoparticles: a real catalytic and antimicrobial agent

ABSTRACT This study reported facile biosynthesis of CuO nanoparticles employing leaf extract of Prosopis glandulosa as a stabilising agent by modest ultrasonic assisted technique. The synthesised nanoparticles were characterised via greatly refined systems comprising UV-visible, FTIR, XRD, SEM EDX, Zeta sizer, and Zeta potential. These facilities triggered the study of optical, functionality, crystallinity, surface morphology, elemental composition, and surface potential of the synthesised nanoparticles. The SEM and FT-IR analysis confirmed the semi-spherical shapes and functionalities of the synthesised NPs respectively. The zeta size and zeta potential of CuO NPs were established to be 65 nm and −1.42 mV respectively. The resultant NPs were applied as an efficient antimicrobial and catalytic candidate for the successful degradation of Eriochrome Black T (EBT) dye. Various factors were optimised such as dose, time, and NaBH4 concentration to achieve maximum catalytic efficiency of CuO nanoparticles. The NPs show excellent catalytic performance of about 92% degradation of EBT within 30 minutes. The antimicrobial performance was also tested by varying the concentration of NPs (250, 500, 1000, and 2000 g/mL via disc diffusion protocol. The results show that CuO NPs have excellent antibacterial activity alongside E. coli at MIC values of 250 g/mL as equated to S. areas and Aspergillus niger.

Grape Seed Extract as an Environment-Friendly Green Inhibitor for Corrosion of Mild Steel in 1 M Sulfamic Acid

AbstractA corrosion inhibition study of mild steel in 1 M sulfamic acid was conducted using grape seed extract (GSE) as a possible green inhibitor. Electrochemical techniques were adopted to measure the corrosion rate in both the absence and presence of the GSE. Conditions were standardized to obtain optimum inhibition efficiency by varying the concentration of inhibitor and temperature. The kinetic parameters were calculated using the Arrhenius equation. Surface analysis was conducted by scanning electron microscope (SEM) and atomic force microscope (AFM) techniques. A suitable mechanism was proposed for the corrosion inhibition process. Grape seed extract showed a maximum efficiency of 65%, with a concentration of 0.24 g/L at 303 K from potentiodynamic polarization (PDP) studies. With the increase in temperature, the efficiency decreased, resulting in the GSE inhibitor’s physical adsorption. Surface morphology studies supported the adsorption of GSE on mild steel. GSE acted as an efficient green inhibitor with environmental benefits.

Cysts of the ligamentum flavum are often linked to ischemic conditions: A morphological study.

"Cysts of the ligamentum flavum (cysts-LF)" is the term for non-neoplastic cystic lesion involving LF. The aim of the present study was to elucidate the histopathological characteristics and pathogenesis of "cysts-LF". Herein, we defined cysts-LF as spinal cysts containing degenerative LF components. From archival cases, we investigated 18 symptomatic cysts-LF surgically removed from 18 patients (13 males and five females; median age 68.5 years [range, 42-86 years]). The elastic fibers of LF components in the wall were separated and/or torn, and cyst walls were accompanied by chondroid metaplasia (17 cases), myxoid changes (13 cases), ossification (11 cases), amyloid deposits (14 cases), hemosiderosis (six cases), granular/smudgy calcification (four cases), synovial cell linings (three cases), and severe inflammatory infiltrates (one case). These histologic features of our cysts-LF were shared by previously reported "cysts-LF." Fourteen cysts-LF demonstrated vascular stenosis/occlusion, and eight showed thick hyalinized vessels, suggesting local circulatory insufficiency. Eight cases (44%) exhibited lipomembranous fat necrosis, accompanied by hyalinized vascular changes (p = 0.003). Ischemic conditions were observed in nearly half of the present cysts-LF, and may be one of the main contributing factors for the formation of cysts-LF, via degeneration and cystic changes in the LF.

Study of Morphology of Gas–Liquid Interfaces in Tank with Central Column in CSS under Different Gravity Conditions

Study of Morphology of Gas–Liquid Interfaces in Tank with Central Column in CSS under Different Gravity Conditions

A morphological study on the question of the hybrid origin of Astrophytum coahuilense (Cactaceae)

Two alternative hypotheses may explain the origin of Astrophytum coahuilense. One hypothesis is that A. coahuilense is an ancient diploid hybrid derived from interbreeding between A. capricorne and A. myriostigma. An alternative is that A. coahuilense arose via allopatric speciation and its similarity to A. myriostigma in vegetative characters is due to convergent evolution. The two hypotheses are tested, applying univariate analysis and Non-metric Multidimensional Scaling analysis to morphological datasets. Univariate analysis, which is based on 13 vegetative and 10 reproductive characters, shows that the morphology of A. coahuilense is complex, consisting of a combination of vegetative and reproductive characters shared with both A. capricorne and A. myriostigma as well as several intermediate traits. Furthermore, the morphology of A. coahuilense lacks unique, fixed characteristics. Non-metric Multidimensional Scaling analysis of 15 characters (three vegetative and 12 reproductive traits) produced a two-dimensional scatterplot in which the cluster representing A. coahuilense occupies a position intermediate between the clusters of the two parental species along Dimension 1. Thus, both analyses support the hypothesis that Astrophytum coahuilense originated through hybridization between A. capricorne and A. myriostigma. Biological and ecological factors that may have facilitated homoploid hybrid speciation are discussed.

A Fully Biodegradable and Ultra‐Sensitive Crack‐Based Strain Sensor for Biomechanical Signal Monitoring

AbstractA fully biodegradable, ultra‐sensitive, and soft strain sensor is pivotal for temporary, real‐time monitoring of microdeformations, crucial in disease diagnosis, surgical precision, and prognosis of muscular, and vascular conditions. Nevertheless, the strain sensitivity of previous biodegradable sensors, denoted by gauge factor (GF) up to ≈100, falls short of requirements for complex biomedical monitoring scenarios, specifically monitoring cardio‐cerebrovascular diseases with microscale variations in vascular surface strain. Here, a fully biodegradable, ultra‐sensitive crack‐based flexible strain sensor is introduced achieving GF of 1355 at 1.5% strain through integration of molybdenum (Mo) film, molybdenum trioxide (MoO3) adhesion layer, and polycaprolactone (PCL) substrate. Analysis of crack morphology of biodegradable thin‐film metals, including Mo, tungsten (W), and magnesium (Mg), reveals material‐dependent sensitivity and repeatability of crack‐based strain sensors. The effect of the adhesion layer and polymer substrate is also investigated. Overall morphological studies on the sensor present a comprehensive understanding of metal film cracking behavior and corresponding performance characterization, showing significant potential for highly sensitive sensors. A hybrid membrane composed of candelilla wax (Cw), beeswax (Bw), and polybutylene adipate‐co‐terephthalate (PBAT) is introduced to provide hydrophobic, yet flexible encapsulation. In vivo, short‐term (≈3 days) monitoring of vascular pulsatility underscores the potential of the sensing tool for rapid, accurate, and temporal disease diagnosis and treatment.

A re-evaluation of Diaporthe: refining the boundaries of species and species complexes

AbstractDiaporthe is an important plant pathogenic genus, which also occurs as endophytes and saprobes. Many Diaporthe species that are morphologically similar proved to be genetically distinct. The current understanding of Diaporthe taxonomy by applying morphological characters, host associations and multi-gene phylogeny are problematic leading to overestimation/underestimation of species numbers of this significant fungal pathogenic genus. Currently, there are no definite boundaries for the accepted species. Hence, the present study aims to re-structure the genus Diaporthe, based on single gene phylogenies (ITS, tef, tub, cal and his), multi-gene phylogeny justified by applying GCPSR (Genealogical Concordance Phylogenetic Species Recognition) methodology as well as the coalescence-based models (PTP—Poisson Tree Processes and mPTP—multi-rate Poisson Tree Processes). Considering all available type isolates of Diaporthe, the genus is divided into seven sections while boundaries for 13 species and 15 species-complexes are proposed. To support this re-assessment of the genus, 82 Diaporthe isolates obtained from woody hosts in Guizhou Province in China were investigated and revealed the presence of two novel species and 17 previously known species. Synonymies are specified for 31 species based on molecular data and morphological studies. Dividing Diaporthe into several specific sections based on phylogenetic analyses can avoid the construction of lengthy phylogenetic trees of the entire genus in future taxonomic studies. In other words, when one conducts research related to the genus, only species from the appropriate section need to be selected for phylogenetic analysis.

A morphological study on the question of the hybrid origin of Astrophytum coahuilense (Cactaceae)

Two alternative hypotheses may explain the origin of Astrophytum coahuilense. One hypothesis is that A. coahuilense is an ancient diploid hybrid derived from interbreeding between A. capricorne and A. myriostigma. An alternative is that A. coahuilense arose via allopatric speciation and its similarity to A. myriostigma in vegetative characters is due to convergent evolution. The two hypotheses are tested, applying univariate analysis and Non-metric Multidimensional Scaling analysis to morphological datasets. Univariate analysis, which is based on 13 vegetative and 10 reproductive characters, shows that the morphology of A. coahuilense is complex, consisting of a combination of vegetative and reproductive characters shared with both A. capricorne and A. myriostigma as well as several intermediate traits. Furthermore, the morphology of A. coahuilense lacks unique, fixed characteristics. Non-metric Multidimensional Scaling analysis of 15 characters (three vegetative and 12 reproductive traits) produced a two-dimensional scatterplot in which the cluster representing A. coahuilense occupies a position intermediate between the clusters of the two parental species along Dimension 1. Thus, both analyses support the hypothesis that Astrophytum coahuilense originated through hybridization between A. capricorne and A. myriostigma. Biological and ecological factors that may have facilitated homoploid hybrid speciation are discussed.

A re-evaluation of Diaporthe: refining the boundaries of species and species complexes

AbstractDiaporthe is an important plant pathogenic genus, which also occurs as endophytes and saprobes. Many Diaporthe species that are morphologically similar proved to be genetically distinct. The current understanding of Diaporthe taxonomy by applying morphological characters, host associations and multi-gene phylogeny are problematic leading to overestimation/underestimation of species numbers of this significant fungal pathogenic genus. Currently, there are no definite boundaries for the accepted species. Hence, the present study aims to re-structure the genus Diaporthe, based on single gene phylogenies (ITS, tef, tub, cal and his), multi-gene phylogeny justified by applying GCPSR (Genealogical Concordance Phylogenetic Species Recognition) methodology as well as the coalescence-based models (PTP—Poisson Tree Processes and mPTP—multi-rate Poisson Tree Processes). Considering all available type isolates of Diaporthe, the genus is divided into seven sections while boundaries for 13 species and 15 species-complexes are proposed. To support this re-assessment of the genus, 82 Diaporthe isolates obtained from woody hosts in Guizhou Province in China were investigated and revealed the presence of two novel species and 17 previously known species. Synonymies are specified for 31 species based on molecular data and morphological studies. Dividing Diaporthe into several specific sections based on phylogenetic analyses can avoid the construction of lengthy phylogenetic trees of the entire genus in future taxonomic studies. In other words, when one conducts research related to the genus, only species from the appropriate section need to be selected for phylogenetic analysis.

Low‐velocity impact characterization of polyurethane rubber/nano‐clay enriched sustainable sandwich composites: Synergy of experimentation and simulations

AbstractThis research proposes a novel sustainable composite using basalt (B), hemp (H) and polyurethane rubber (Pu) reinforced in nano clay functionalised epoxy matrix for sacrificial structural applications prone to low‐velocity impact (LVI). To this end, symmetric and asymmetric laminates such as HHHH, BBBB, BHHB, BHPuHB, BBPuHH and BPuBPuHPuH are fabricated using compression molding techniques and subjected to LVI at three different impact energies of 19.66, 39.39, and 59.05 J. The hemp fibers were treated with NaOH solution before fabrication. Material characterization such as X‐ray diffraction, Raman spectroscopy and morphological studies has been carried out. The impact and post‐impact properties of the proposed composites are experimentally evaluated and validated with the finite element (FE) results. The effect on the residual tensile strength degradation of laminates at different interlayers and energy levels is also investigated using the Caprino analytical model. The barely visible impact damages (BVID) are investigated through non‐destructive dye‐penetration tests, which facilitate easy identification of the prominent LVI damages like “Plateau” and “Cliff‐drop” impressions. Based on the impact energy absorption and residual tensile strength, proposed laminates followed BHPuHB > BBBB > BHHB > HHHH. The experimentation suggests that Polyurethane core laminates support maximum impact energy absorption by favoring a structural change in interlayers. Also, the residual tensile strength decreases as impact velocity increases.Highlights Low‐velocity impact behavior of sustainable composites is experimented. Basalt, hemp and polyurethane rubber are reinforced in nano clay epoxy matrix. A FE framework to validate the experimentation is proposed. Dye penetrant NDT is adopted to investigate the damages. Morphological studies are conducted to understand LVI responses.

Low‐velocity impact characterization of polyurethane rubber/nano‐clay enriched sustainable sandwich composites: Synergy of experimentation and simulations

AbstractThis research proposes a novel sustainable composite using basalt (B), hemp (H) and polyurethane rubber (Pu) reinforced in nano clay functionalised epoxy matrix for sacrificial structural applications prone to low‐velocity impact (LVI). To this end, symmetric and asymmetric laminates such as HHHH, BBBB, BHHB, BHPuHB, BBPuHH and BPuBPuHPuH are fabricated using compression molding techniques and subjected to LVI at three different impact energies of 19.66, 39.39, and 59.05 J. The hemp fibers were treated with NaOH solution before fabrication. Material characterization such as X‐ray diffraction, Raman spectroscopy and morphological studies has been carried out. The impact and post‐impact properties of the proposed composites are experimentally evaluated and validated with the finite element (FE) results. The effect on the residual tensile strength degradation of laminates at different interlayers and energy levels is also investigated using the Caprino analytical model. The barely visible impact damages (BVID) are investigated through non‐destructive dye‐penetration tests, which facilitate easy identification of the prominent LVI damages like “Plateau” and “Cliff‐drop” impressions. Based on the impact energy absorption and residual tensile strength, proposed laminates followed BHPuHB > BBBB > BHHB > HHHH. The experimentation suggests that Polyurethane core laminates support maximum impact energy absorption by favoring a structural change in interlayers. Also, the residual tensile strength decreases as impact velocity increases.Highlights Low‐velocity impact behavior of sustainable composites is experimented. Basalt, hemp and polyurethane rubber are reinforced in nano clay epoxy matrix. A FE framework to validate the experimentation is proposed. Dye penetrant NDT is adopted to investigate the damages. Morphological studies are conducted to understand LVI responses.

Synthesis of composite films using polymer blends of chitosan and cellulose nanocrystals from marine origin

Thin films reinforced with chitosan and cellulose nanocrystals (CNC) were produced using the casting process. In this study, the impact of plasticisers and sizing agents such as glycerol and polyvinyl alcohol (PVA) respectively on morphological, structural, thermal, and mechanical properties was investigated. The results showed the blends of CNC/PVA/glycerol gave better results when compared to films produced by blends of chitosan/PVA/glycerol films and chitosan/CNC/PVA/glycerol films. The UV spectroscopy showed 65% transmittance for chitosan/PVA/glycerol films, while the film of CNC/PVA/glycerol showed transmittance of 40%. The transmittance of chitosan/CNC/PVA/glycerol showed 75%. The films formed by the combination of CNC/PVA/glycerol showed better stress/strain properties than other films. The films of all combinations showed good thermal stability between the range of 350 and 450 °C. The morphological study using SEM revealed smooth texture for all the films. The study suggests that the films produced may be used for the food packaging applications due to its thermal stability and stress/strain properties.

Synthesis of composite films using polymer blends of chitosan and cellulose nanocrystals from marine origin

Thin films reinforced with chitosan and cellulose nanocrystals (CNC) were produced using the casting process. In this study, the impact of plasticisers and sizing agents such as glycerol and polyvinyl alcohol (PVA) respectively on morphological, structural, thermal, and mechanical properties was investigated. The results showed the blends of CNC/PVA/glycerol gave better results when compared to films produced by blends of chitosan/PVA/glycerol films and chitosan/CNC/PVA/glycerol films. The UV spectroscopy showed 65% transmittance for chitosan/PVA/glycerol films, while the film of CNC/PVA/glycerol showed transmittance of 40%. The transmittance of chitosan/CNC/PVA/glycerol showed 75%. The films formed by the combination of CNC/PVA/glycerol showed better stress/strain properties than other films. The films of all combinations showed good thermal stability between the range of 350 and 450 °C. The morphological study using SEM revealed smooth texture for all the films. The study suggests that the films produced may be used for the food packaging applications due to its thermal stability and stress/strain properties.

Novel magnetic iron oxide-dextran sulphate nanocomposites as potential anticoagulants: Investigating interactions with blood components and assessing cytotoxicity

Examining the critical role of anticoagulants in medical practice, particularly their central function in preventing abnormal blood clotting, is of the utmost importance. However, the study of interactions between blood proteins and alternative anticoagulant nano-surfaces is still understood poorly. In this study, novel approach involving direct functionalisation of magnetic iron oxide nanoparticles (MNPs) as carriers with sulphated dextran (s-dext) is presented, with the aim of evaluating the potential of magnetically-responsive MNPs@s-dext as anticoagulants. The physicochemical characterisation of the synthesised MNPs@s-dext includes crystal structure analysis, morphology study, surface and electrokinetic properties, thermogravimetric analysis and magnetic properties` evaluation, which confirms the successful preparation of the nanocomposite with sulfonate groups. The anticoagulant potential of MNPs@s-dext was investigated using a standardised activated partial thromboplastin time (APTT) test and a modified APTT test with a quartz crystal microbalance with dissipation (QCM-D) which confirmed the anticoagulant effect. Time-resolved solid-liquid interactions between the MNPs@s-dext and model blood proteins bovine serum albumin and fibrinogen were also investigated, to gain insight into their hemocompatibility, and revealed protein-repellence of MNPs@s-dext against blood proteins. The study also addressed comprehensive cytotoxicity studies of prepared nanocomposites, and provided valuable insights into potential applicability of MNPs@s-dext as a promising magnetic anticoagulant in biomedical contexts.

Morphological and anatomical study of fruits of Crataegus flabellatа

Morphological and anatomical study of fruits of Crataegus flabellatа