Dispersed Structure Research Articles

Does investor base affect the firm-level ex-ante cost of equity capital?

This research investigates how investor base affects the cost of equity capital (COE) in Indian companies, particularly in market conditions with weak investor protection and increased ownership concentration by promoters and families. Using ordinary least squares (OLS), panel fixed effects, and two-step system generalised method of moments (GMM) analysis on data spanning from 2016 to 2021, we discovered that a dispersed ownership structure is linked to a higher ex-ante COE. Our findings indicate that companies with dispersed shareholders have less motivation to monitor managers, which leads to the expropriation of minority shareholders and results in higher COE.

Nonaggregated Anions Enable the Undercooled Aqueous Electrolyte for Low-Temperature Applications.

Aqueous batteries, with the advantages of high safety and low cost, are highly promising for large-scale energy storage. However, freezing of the aqueous electrolyte limits the low-temperature operation. Here, we propose and achieve a highly dispersed solvation structure in the electrolyte by coupling nonaggregated Cl- anions, which reduces the water cluster size and prevents the solidification of the aqueous electrolyte until -136.3 °C. The low-temperature LiCl electrolyte exhibits a high ionic conductivity (1.0 mS cm-1) at -80 °C and enables a stable low-temperature Ag/AgCl reference electrode at -50 °C. Moreover, the polyaniline-based battery can work at an extremely low temperature of -100 °C and shows superior cycling performance of 4000 cycles at -40 °C with 95.7% capacity retention. This work elucidates the correlation between the anion effect and the thermodynamic transition of the electrolyte, offering a novel approach for designing low-temperature electrolytes.

CFD-PBM coupled modeling of the liquid-liquid dispersion characteristics and structure optimization for Kenics static mixer

Kenics static mixers (KSM) are extensively used in industrial mixing–reaction processes by virtue of high mixing efficiency, low power homogenization and easy continuous production. Resolving liquid droplet size and its distribution and thus revealing the dispersion characteristics are of great significance for structural optimization and process intensification in the KSM. In this work, a computational fluid dynamics–population balance model (CFD–PBM) coupled method is employed to systematically investigate the effects of operating conditions and structural parameters of KSM on droplet size and its distribution, to further reveal the liquid–liquid dispersion characteristics. Results indicate that higher Reynolds numbers or higher dispersed phase volume fractions increase energy dissipation, reducing Sauter mean diameter (SMD) of dispersed phase droplets and with a shift in droplet size distribution (DSD) towards smaller size. Smaller aspect ratios, greater blade twist and assembly angles amplify shear rate, leading to smaller droplet size and a narrower DSD in the smaller range. The degree of impact exerted by the aspect ratio is notably greater. Notably, mixing elements with different spin enhance shear and stretching efficiency. Compared to the same spin, SMD becomes 3.7–5.8 times smaller in the smaller size range with a significantly narrower distribution. Taking into account the pressure drop and efficiency in a comprehensive manner, optimized structural parameters for the mixing element encompass an aspect ratio of 1–1.5, a blade twist angle of 180°, an assembly angle of 90°, and interlaced assembly of adjacent elements with different spin. This work provides vital theoretical underpinning and future reference for enhancing KSM performance.

The surface treatment of PVA fibres to enhance fibre distribution and mechanical properties of foam concrete

Fibres are often used to improve the mechanical properties of foam concrete. However, the poor dispersion of PVA fibres in foam concrete significantly restricts their reinforcement efficiency. Limited studies have been conducted on improving the distribution of PVA fibres in a cementitious matrix, particularly in relation to foam concrete. This is noteworthy because pore structure, which can be significantly influenced by the fibres and fibre treatment agents, is a critical parameter that affects the mechanical properties of foam concrete. Therefore, this study employed polar agents (non-ionic surfactants) to treat the fibre surface, aiming to enhance the distribution and reinforcement efficiency of PVA fibres in foam concrete. In view of safety and feasibility, two non-hazardous polar agents, namely PEG-PPG-PEG (designated as PA A) and Polyoxyethylene (20) cetyl ether (designated as PA B), were used to treat the PVA fibres. The impact of fibre treatments on fibre dispersion and pore structure was investigated, and the compressive strength and flexural behaviour of foam concrete were measured before and after the treatments. PA A was found to be unsuitable for fibre treatment due to its poor bonding with the fibre surface. On the other hand, PA B exhibited good bonding with PVA fibres, resulting in enhanced fibre dispersion and pore structure in the foam concrete. Compared to plain foam concrete, the fibres treated with PA B increased the compressive and flexural strength by 47.4 % and 190.3 %, respectively. Moreover, the treated fibres (by PA B) were observed to improve the 0.8 mm toughness of foam concrete by 27.2 %.

<새끼 서 발> 설화의 놀이적 성격

The folktale Six-yard [seo-bal] Straw Rope is unique. Its formal characteristic of cumulative repetition is prominent, and the story is well-developed, making it seem sufficiently open to interpretation. However, discussing the meaning is not as easy as anticipated. This is because the coherence of characters and the causality of events, often emphasized when understanding works centered on content, is lacking, and the structure of the ending is dispersed. This study addresses these issues by focusing on the formal characteristics of the work; it seeks to reinterpret these formal features from a playful perspective.
 The Six-yard Straw Rope follows a format similar to phrase-tail linking folk songs. The gradual exchange process from the six-yard straw rope to the maiden unfolds as a weaving play characterized by phrase-tail linking. The key in narrativizing lies in ‘creating a situation,’ which entails crafting a specific and appropriate situation where two objects can be exchanged. Ultimately, Six-yard Straw Rope is created by aptly weaving various situations where low- and high-value items can be exchanged into a narrative. This study names it the ‘Situation-Weaving Play.’ The lack of consistency in character portrayal and causality in event development and the dispersed structure of the resolution all stem from the playful nature of the work.
 The playful characteristic of the Six-yard Straw Rope is deeply related to the situational thinking encouraged in oral culture. Utilizing common objects found in everyday spaces to create appropriate situations in folktales is the ultimate play that enhances situational thinking in oral culture. Folktales with a situational play abound beyond Six-yard Straw Rope, with Mole’s Wedding being a prime example. The charm of situational play, based on situational thinking, lies in the fact that humble objects like a six-yard straw rope can become a maiden or silk when well combined with situations, and even a humble mole can become the finest groom in the world under various situations.

Повышение износостойкости цилиндрических поверхностей трения комбинированной электромеханической обработкой

Processing technology and technological equipment for the formation of a wear-resistant surface layer by implanting materials based on tungsten carbide (WC), are viewed. The effect of implanted WC powder on the formation of gradient wear-resistant structures in the friction surface of carbon steel formed during the implementation of combined electromechanical processing (WRCEMP) technology, has been studied. Resulting from heat and pressure impact in the zone of plastic deformation, intensive austenization of steel occurs with dissolution of WC powder and subsequent formation of highly dispersed composite structures caused by the decomposition of undercooled tangstem-supersaturated austenite. Combined comparative friction and wear tests were carried out for structural steel 45 with a graded structure of a hardened surface and rather expensive and technologically- difficult to obtain modern wear-resistant coatings and materials. The issue of WRCEMP technology practical application used for the «axis of satellite – satellite» friction pair is viewed. An assessment of the durability increase of the «axis of satellite – satellite» interface during the implementation of the considered processing methods and innovative technology was taken. Recommendations for the use of combined electromechanical processing technology at machine-building enterprises as a highly effective way to ensure and improve the performance of machine parts at the stage of their manufacture are given.

PtTe2 photodetectors with negative photoconductivity under different wavelength laser irradiation

Platinum telluride (PtTe2), as a newly emerged type II Dirac semimetal, has attracted much attention. Due to its excellent linear dispersive band structure and ultra-high carrier mobility, PtTe2 show great potential in the new quantum phenomena, topological phase transitions, unconventional superconductivity and other photodetecting fields. In this paper, we report the negative photoelectric effect of photodetectors based on the type II Dirac semimetal PtTe2 film under the laser irradiation of 405 nm, 532 nm and 808 nm. Under the condition of applying 1 V voltage, the R of the PtTe2 device under 405 nm laser irradiation was 20 A/W and the D* was 6.9×109 Jones; the R of the PtTe2 device under 532 nm laser irradiation was 1.3 A/W and the D* was 4.1×108 Jones; the R of the PtTe2 device under 808 nm laser irradiation was 0.6 A/W and the D* was 2.1×108 Jones. Under normal atmospheric pressure and room temperature conditions, we observed a negative photoconductivity phenomenon for the PtTe2 device, where the change in photoconductivity is attributed to the light-induced desorption of O or H2O molecules from the surface of the material. In addition, a single-site scanning imaging system based on a PtTe2 photodetector was designed to test the detection capability of the device. The analysis of the photocurrent effect produced by the PtTe2 device further deepens the understanding of the photoconductivity mechanism in the field of photodetection.

Sodium dodecyl sulphate-treated nanohydroxyapatite as an efficient shale stabilizer for water-based drilling fluids

Drilling water-sensitive shale formations often leads to wellbore instability, resulting in drilling problems because of the clay's high-water affinity. To solve this problem, different nanoparticles (NPs), such as nanosilica, have been used to formulate water-based muds with potassium chloride (KCl-WBM). Nevertheless, the unmatched pore size of shale pores when using nanosilica fails to completely prevent shale swelling and dispersion. This study discusses the effects of KCl-WBM with sodium dodecyl sulphate-treated nanohydroxyapatite (nHAp/SDS) on shale swelling inhibition through various laboratory techniques. These techniques encompass the linear swell meter (LSM), the dynamic linear swell meter (DLSM), hot-rolling dispersion, suspension stability, and pore structure characterization of shale. The rheological and filtration characteristics of nHAp/SDS and compatibility tests were also studied, and the results were compared with those of nanosilica and KCl-WBM. At all concentrations, the performance of the nHAp/SDS test fluids surpassed that of nanosilica. When compared with KCl-WBM system at 10 cP and 25 °C, the nHAp/SDS and nanosilica concentrations increased the plastic viscosity by 20–90 % and 10–70 %, respectively. The inhibitory effect of nHAp/SDS surpasses that of conventional KCl-WBM and inorganic nanosilica. By adding 2.0 wt% nHAp/SDS to KCl-WBM, the shale swelling decreased from 10.1 to 4.7 % (a 53.4 % reduction). Nanosilica also reduced the swelling to 6.1 % (a 39.6 % reduction) during the LSM test at 25 °C. Under the DLSM test conditions, the shale swelling increased due to the activation of the clay platelet site at an increased temperature of 80 °C. For instance, between 25 and 80 °C, the DLSM test revealed that the shale plug height expanded from 6.1 to 9.8 % for 2.0 wt% nanosilica, 4.7–7.6 % for 2.0 wt% nHAp/SDS, and 10.1–18.8 % for KCl-WBM. Furthermore, the recovery rate of hot-rolled shale plugs with KCl-WBM increased from 89.8 to 96.2 % for nHAp/SDS and 76.6 to 88.8 % for nanosilica from the initial rates of 52.1–63.3 % between 65 and 120 °C. The contact angle results showed that nHAp/SDS is hydrophobic, reducing shale-water attraction. Moreover, the 12 nm nanosilica matches nanopore sizes to partially block shale pores. This research found that nHAp/SDS has the potential to improve wellbore stability.

Collaborative communication-based ocean observation research with heterogeneous unmanned surface vessels

Unmanned surface vehicles (USVs) are crucial in ensuring maritime safety and observation, attracting widespread attention and research. However, a single USV exhibits limited performance and cannot effectively observe complex marine environments. In contrast, clusters of USVs can collaborate to execute complex maritime tasks, thereby enhancing the overall operational efficiency. USVs typically form heterogeneous clusters by combining vehicles with varying maneuverabilities and communication network capabilities. This has sparked an increased interest in cooperative communication research within heterogeneous USV clusters. The heterogeneous USVs discussed in this paper share the same dynamic model; however, they differ in dynamic parameters and communication capabilities. First, this study establishes a three-degree-of-freedom motion mathematical model for an underdriven USV considering environmental interference. It estimates the dynamic parameters of four USVs and evaluates their communication abilities, laying the foundation for researching the cooperative control of heterogeneous USV clusters and their application in Ocean Observation. Next, the communication capability of the USVs is assessed by studying the communication mode and signal transmission loss within the USV clusters. This study investigates the problem of cooperative communication in USV cluster formation, starting with the communication delay of USV clusters under a directed switching topology. Finally, a coherent formation controller is designed under a switching communication topology to address the dynamic transformation of communication topologies within heterogeneous USV clusters. This verifies that heterogeneous USV clusters can seamlessly form and maintain formation shapes during communication topology transformations through formation simulation experiments involving four heterogeneous USVs was 22% higher than that of dispersed control topology structures. This study provides a solid foundation for future investigations into the cooperative control of heterogeneous USV clusters and their applications in marine observations.

Use of Dry Milk Molasses with Lactulose in the Yogurt Production Technology with Ultrasonic Treatment

Dry milk molasses with lactulose is a product of processing by-products in the lactose production. Its use in the fermented milk drinks technology offers new opportunities to expand the food product range with a prebiotic effect. The research aims at studying the use possibility of dry milk molasses with lactulose in yogurt production technology, as well as to distinguish the ultrasonic treatment impact on the quality characteristics of finished products. The authors revealed that the use of dry milk molasses with lactulose in the yogurt production in an amount of 3 % of the total mass of the milk mixture enables to intensify the fermentation process and obtain a prebiotic fermented milk drink with high consumer properties. The study results demonstrated that the use of ultrasonic treatment with a frequency of 24 kHz and a specific power of 840–860 W/dm3 enables to obtain a finished product with improved quality characteristics in the production technology of yogurt with milk molasses with lactulose. Ultrasonic treatment facilitates a more finely dispersed structure formation of the milk mixture: at the end of the lag phase of the lactic acid cultures growth, the average diameter of protein particles and fat balls in a mixture with ultrasonic treatment is 1.47 and 2.89 times smaller, respectively, in relation to the fermented system without the ultrasound use. The results of microscopy, rheological and organoleptic properties determination of yogurt enable to conclude that there is a more homogeneous mesh protein matrix in the milk clot, the effective viscosity coefficient value increases (by 1.3–3.9 times), the appearance and consistency of the finished product improve during ultrasonic treatment.

Neurite Orientation Dispersion and Density Imaging (NODDI) of Brain Microstructure in Adolescent Cannabis and Nicotine Use.

Despite evidence suggesting deleterious effects of cannabis and nicotine tobacco product (NTP) use on white matter integrity, there have been limited studies examining white matter integrity among users of both cannabis and nicotine. Further, updated white matter methodology provides opportunities to investigate use patterns on neurite orientation dispersion and density (NODDI) indices and subtle tissue changes related to the intra- and extra-neurite compartment. We aimed to investigate how cannabis and NTP use among adolescents and young adults interacts to impact the white matter integrity microstructure. A total of 221 participants between the ages of 16 and 22 completed the Customary Drinking and Drug Use Record (CDDR) to measure substance use, and underwent a magnetic resonance imaging (MRI) session. Participants were divided into NTP-control and NTP groupings and cannabis-control and cannabis groupings (≥26 NTP/cannabis uses in past 6 months). Tract-Based Spatial Statistics (TBSS) and two-way between-subjects ANOVA investigated the effects of NTP use group, cannabis use group, and their interaction on fractional anisotropy (FA) and NODDI indices while controlling for age and biological sex. NTP use was associated with decreased FA values and increased orientation dispersion in the left anterior capsule. There were no significant effects of cannabis use or the interaction of NTP and cannabis use on white matter outcomes. NTP use was associated with altered white matter integrity in an adolescent and young adult sample. Findings suggest that NTP-associated alterations may be linked to altered fiber tract geometry and dispersed neurite structures versus myelination, as well as differential effects of NTP and cannabis use on white matter structure. Future work is needed to investigate how altered white matter is related to downstream behavioral effects from NTP use.

Structured Catalysts and Catalytic Processes: Transport and Reaction Perspectives.

The structure of catalysts determines the performance of catalytic processes. Intrinsically, the electronic and geometric structures influence the interaction between active species and the surface of the catalyst, which subsequently regulates the adsorption, reaction, and desorption behaviors. In recent decades, the development of catalysts with complex structures, including bulk, interfacial, encapsulated, and atomically dispersed structures, can potentially affect the electronic and geometric structures of catalysts and lead to further control of the transport and reaction of molecules. This review describes comprehensive understandings on the influence of electronic and geometric properties and complex catalyst structures on the performance of relevant heterogeneous catalytic processes, especially for the transport and reaction over structured catalysts for the conversions of light alkanes and small molecules. The recent research progress of the electronic and geometric properties over the active sites, specifically for theoretical descriptors developed in the recent decades, is discussed at the atomic level. The designs and properties of catalysts with specific structures are summarized. The transport phenomena and reactions over structured catalysts for the conversions of light alkanes and small molecules are analyzed. At the end of this review, we present our perspectives on the challenges for the further development of structured catalysts and heterogeneous catalytic processes.

STRUCTURE AND MECHANICAL PROPERTIES OF A SERIES OF STRUCTURAL STEEL AFTER HEAT TREATMENT WITH ENDURANCE IN THE INTERCRITICAL TEMPERATURE INTERVAL

Purpose. To show the effectiveness of various methods of heat treatment of the studied steels with heating in ITI, as a result of which their mechanical properties are increased, which is due to the acquisition of a multiphase structure, one of the components of which in some cases is metastable austenite.
 Research methods. Steels 14Г2, 20ГЛ, 20ГФЛ 45Г were investigated. Various types of heat treatment were carried out with heating in the intercritical temperature interval. In the studied steels, a multiphase structure dispersed in chemical composition was obtained. Durometric, metallographic and X-ray research methods were used. Mechanical properties under tension and impact toughness were determined. These properties were compared with those obtained from the studied steels after typical heat treatment.
 Obtained results. It is shown that in the investigated steels, when performing various methods of heat treatment, there is no need to obtain a single-phase austenite structure, which is homogeneous in terms of its chemical composition, during heating. The creation of a multiphase dispersed micro-inhomogeneous structure in the studied steels by heat treatment methods, which include regulated heating and holding in ITI, allows to obtain after normalization, hardening and high or low tempering, as well as isothermal tempering, a good combination of strength and plastic properties, the level of which exceeds that obtained after the usual process.
 Scientific novelty. The paper considers an alternative point of view, according to which to improve the mechanical and service properties of steels, it is necessary to obtain multiphase dispersed micro-inhomogeneous structures in them, consisting of martensite, bainite, ferrite, carbides, carbonitrides and metastable residual austenite, as well as their various combinations. In order to obtain such structures, it is advisable to use heating and holding in ITI during the heat treatment of pre-eutectoid steels, in which austenite is formed, along with ferrite and carbides. At the same time, austenite has chemical micro-heterogeneity, because the carbon concentration at its boundary with carbide is significantly higher than at the boundary with ferrite. This makes it possible to obtain a multiphase dispersed micro-inhomogeneous structure after heat treatment.
 Practical value. Increasing the mechanical properties of steels makes it possible to increase the operational stability of machine parts, which is an important task of materials science. One of the directions of its solution is to obtain a multiphase structure in steels, one of the components of which is metastable austenite, in which the dynamic deformation martensitic transformation (DSMT) and the effect of self-hardening under load (SHL) occur under load. Methods of heat treatment with heating at ITI are easily implemented in production conditions and allow for energy savings. Modes of their implementation should be chosen taking into account obtaining the necessary properties, the initial structure, its defects and the cross-section of the products.

Light and dispersal strategies structure palm community along an elevation gradient in the Atlantic Forest

Light and dispersal strategies structure palm community along an elevation gradient in the Atlantic Forest

IMPLEMENTATION OF A GEOGRAPHIC INFORMATION SYSTEM IN MONITORING THE IMPLEMENTATION OF HOUSING CONSTRUCTION

Building the 864-unit housing complex was a significant construction undertaking. Within an implementation period of 18 months and a project area of approximately 34 hectares, this project demanded efficient management to control the time and budget that had been set. To achieve this goal, it is necessary to implement effective planning, organization, management and resource allocation processes. This process aims to break down project management into simpler tasks or activities, provide time estimates for each task, and continuously monitor their progress. Although conventional planning tools such as Primavera and Msproject can provide a time representation of the tasks to be performed, they are not yet able to provide spatial or geographic monitoring of these tasks within the scope of the project. By integrating Geographic Information Systems (GIS), this project can gain additional benefits. GIS allows identifying data about the progress of construction tasks, and then presenting them in the form of maps. This not only visualizes overall progress graphically and geographically, but also makes it easy to extract useful summaries to support project decision making. With GIS, construction project monitoring not only becomes more efficient, but also more up-to-date and relevant to the scope of the project involving various dispersed structures. It is hoped that GIS integration can improve project management control and optimize the final results of the construction of the 864 housing complexes.

The second-order coherence analysis of number state propagation through dispersive non-Hermitian multilayered structures

To examine the second-order coherence of light propagation of quantum states in arbitrary directions through dispersive non-Hermitian optical media, we considered two sets of non-Hermitian periodic structures that consist of gain/loss unit cells. We show that each batch can satisfy the parity-time symmetry conditions at a distinct frequency. We then varied the gain/loss strength in the stable electromagnetic regime to evaluate the transmittance of N-photon number states through each structure. The results show both sets preserve their antibunching characteristics under specific incident light conditions. Furthermore, s(p)-polarized light exhibits higher (lower) second-order coherence at larger incident angles. In addition, the antibunching features of the transmitted states degrade with an increase in the number of unit cells in multilayered structures for both polarizations.

Dispersive shock wave structure analysis for the defocusing Lakshmanan–Porsezian–Daniel equation

Via the finite-gap integration theory, we study the defocusing Lakshmanan–Porsezian–Daniel (LPD) equation. Meanwhile, we derive the degenerate forms for the single-phase periodic solution. In addition, we obtain the basic and combined structures of the dispersive shock wave through the Whitham modulation equation parameterized by the Riemann invariant.

Metastable phase separation and crystalline orientation feature of electromagnetic levitation processed CoCrCuFeNi high entropy alloy

The metastable liquid phase separation and rapid solidification kinetics of CoCrCuFeNi high entropy alloy (HEA) has been investigated by electromagnetic levitation (EML) technique. The maximum liquid undercooling attained 452 K (0.27TL), and the critical undercooling to initiate phase separation was determined as 172 K. By modulating the degree of alloy undercooling, the overall macrosegragation pattern achieved a transition from homogeneous dendrites into dispersed structures and finally into core-shell structures. Both microstructure and electron backscatter diffraction (EBSD) characterizations revealed that liquid undercooling played a crucial role in the modulation of dendritic anisotropy correlated with crystalline orientations. Coarse high entropy face-centered cubic (HEF) dendrites were produced with 〈100〉 preferred orientation at small undercoolings. Once undercooling exceeded the threshold of 172 K, the previously uniform liquid alloy was separated into Cu-depleted and Cu-rich zones. Numerous equiaxed HEF grains of relatively random orientation together with some twin crystals were displayed in Cu-depleted zone, whereas in Cu-rich zone HEF phase solidified into many slender dendrites. Theoretical analyses indicated that equiaxed grains were produced in the regime of thermal diffusion-controlled dendritic growth with actual solidifying velocity up to 42.7 m s−1. Furthermore, physical properties examinations demonstrated that large liquid undercoolings enhanced the alloy microhardness and low temperature saturated magnetization but reduced its electrical resistivities.

Dispersal synchronizes giant kelp forests.

Spatial synchrony is the tendency for population fluctuations to be correlated among different locations. This phenomenon is a ubiquitous feature of population dynamics and is important for ecosystem stability, but several aspects of synchrony remain unresolved. In particular, the extent to which any particular mechanism, such as dispersal, contributes to observed synchrony in natural populations has been difficult to determine. To address this gap, we leveraged recent methodological improvements to determine how dispersal structures synchrony in giant kelp (Macrocystis pyrifera), a global marine foundation species that has served as a useful system for understanding synchrony. We quantified population synchrony and fecundity with satellite imagery across 11 years and 880 km of coastline in southern California, USA, and estimated propagule dispersal probabilities using a high-resolution ocean circulation model. Using matrix regression models that control for the influence of geographic distance, resources (seawater nitrate), and disturbance (destructive waves), we discovered that dispersal was an important driver of synchrony. Our findings were robust to assumptions about propagule mortality during dispersal and consistent between two metrics of dispersal: (1) the individual probability of dispersal and (2) estimates of demographic connectivity that incorporate fecundity (the number of propagules dispersing). We also found that dispersal and environmental conditions resulted in geographic clusters with distinct patterns of synchrony. This study is among the few to statistically associate synchrony with dispersal in a natural population and the first to do so in a marine organism. The synchronizing effects of dispersal and environmental conditions on foundation species, such as giant kelp, likely have cascading effects on the spatial stability of biodiversity and ecosystem function.

Comparison of surface modification and corrosion resistance of Ti6Al4V alloy using matcha tea extract-based silver and copper oxide nanoparticles

In this study, our aim was to investigate the application of green-synthesized silver nanoparticles (Ag NPs) and copper oxide nanoparticles (CuO NPs) for surface modification, specifically focusing on their influence on the corrosion properties of Ti6Al4V alloy. The green NPs were thoroughly characterized, and their role in enhancing the anticorrosive performance of Ti6Al4V was carefully evaluated. Various coating methods and drying temperatures were utilized to coat Ti6Al4V samples with the NPs, aiming to assess their impact on corrosion resistance. The electrochemical corrosion behavior was examined through electrochemical polarization tests in Ringer's bio-liquid. The study underscored the significant impact of coating type, coating method, and drying temperature (25 °C and 60 °C) in achieving favorable anticorrosive performance. Notably, samples oven-dried at both temperatures and coated with Ag NPs and CuO NPs using spray coating demonstrated the most effective substrate protection, achieving protection efficiencies of 97.37 % and 90.56 %, respectively. This outcome can be attributed to the unique spherical and homogeneously dispersed particulate structure of the NPs, effectively reducing microporosity. In summary, the combination of increased surface area and reduced microporosity resulting from the surface properties of the NPs underscores the potential of well-designed surface modification approaches in advancing the development of titanium-based implants for biomedical applications.