The electric polarization of single crystal YMn 2 O 5 was investigated in strong pulsed magnetic fields up to H = 250 kOe at low temperatures. It was shown that at T ∼ 40 K magnetic and structural phase transitions occur, with the structural changes taking place improperly (magnetically induced). We have also shown the existence of the structural phase transition at T ∼ 20 K with the onset of spontaneous polarization P b . The quadratic magnetoelectric effect at temperatures T < 40 K was observed (with b-component domination), the magnetoelectric susceptibility below T = 20 K greatly increased for all field orientations. When H Á a the magnetoelectric effect changed its sign which in analogue with EuMn 2 O 5 was attributed to non-commensurate to commensurate structural change. The polarization anomalies in strong magnetic fields were observed with the former being due to complex magnetic structure changes and the process of spontaneous polarization induction by magnetic field.
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