A study was made of relaxation properties of aromatic polybenzoxazole over a wide range of temperature and deformation. Detailed analysis of the relaxation behaviour of this polymer revealed substates distinguished by different rates of relaxation processes in the range of glass-like states. It was established that linearity of mechanical behaviour of polybenzoxazole is observed over a fairly wide range of temperature and deformation. It was shown that the principle of temperature-time analogy holds good fairly satisfactory both at low and high deformations, although the temperature dependence of the shear factor does not conform to the Williams-Lundell-Ferry equation in the entire range glass temperature.
Read full abstract