AbstractPolar stratospheric clouds (PSCs) play a key role in Arctic amplification and stratospheric ozone destruction in polar regions. In this paper, we used the CALIPSO data to analyze the spatiotemporal distribution of Arctic PSCs from 2006 to 2021. We found that Arctic PSCs mainly appear in December, peak in late December and early January, disappearing in late February and early March. PSCs can extend from heights near the tropopause to over 25 km. However, there is the lowest fraction of PSCs in the 2014/2015 winter. This study found that the temperature in the 2014/2015 winter was warmer than the 15‐year average temperature, with the lowest temperature slightly below the PSCs formation temperature of about 5 K. The formation of the Ural blocking high accompanied by the poleward propagation of the planetary wave caused a sudden stratospheric warming (SSW) event on 3 January 2015, during which the warm air entered the polar vortex and divided it into two lobes. Additionally, a reduction in SO2 column mass density before the SSW event resulted PSCs occurring with a frequency of only 0.148 and dissipating rapidly in December. Moreover, the concentration of H2O and HNO3 in the gravitational settling process of PSCs decreased by 20–50%, the reduction of condensation nuclei made PSCs with the highest frequency of 0.074 in February appear briefly and then disappear. The chemical and dynamic analysis of PSCs formation is needed to further understand the spatiotemporal distribution of Arctic PSCs and to better predict future Arctic amplification and ozone destruction.