Two-dimensional distribution of impurity lines emitted from ergodic layer with stochastic magnetic field lines in Large Helical Device (LHD) has been observed using a space-resolved extreme ultraviolet (EUV) spectrometer. The two-dimensional electron temperature distribution in the ergodic layer is successfully measured using the line intensity ratio of Li-like NeVIII 2s-3p ( 2 S1/2- 2 P3/2: 88.09 A, 2 S1/2- 2 P1/2: 88.13 A) to 2p-3s ( 2 P1/22 S1/2: 102.91 A, 2 P3/2- 2 S1/2: 103.09 A) transitions emitted from radial location near Last Closed Flux Surface (LCFS). The intensity ratio analyzed with ADAS code shows no dependence on the electron density below 10 14 cm −3 . The result indicates a little higher temperature, i.e., 220 eV, in the poloidal location at high-field side near helical coils called O-point compared to the temperature near X-point, i.e., 170 eV. The electron temperature profile is also measured at the edge boundary of ergodic layer using the line intensity ratio of Li-like CIV 2p-3d ( 2 P1/2- 2 D3/2: 384.03 A, 2 P3/2- 2 D5/2: 384.18 A) to 2p-3s ( 2 P1/2- 2 S1/2: 419.53 A, 2 P3/2- 2 S1/2: 419.71 A) transitions. The intensity ratios analyzed with CHIANTI, ADAS and T.Kawachi codes show a slightly higher temperature near O-point, i.e., 25 eV for CHIANTI, 21 eV for ADAS and 11 eV for T.Kawachi’s codes, compared to the temperature at X-point, i.e., 15 - 21 eV for CHIANTI, 9 - 15 eV for ADAS and 6 - 9 eV for T.Kawachi codes. It suggests that the transport coefficient in the ergodic layer is varied with three-dimensional structure.