The coordination of reservoir operation is critical for water systems' efficiency. Improved coordination requires sharing information, demanding a clear understanding of the potential gains and its distribution among the users to motivate engagement in coordinated operations and bearing of transaction costs. In a multiuser, multireservoir system, the evaluation of the potential coordination gains is not trivial because it requires the simultaneous evaluation of numerous trade offs. This paper presents a methodology to identify the likely upper and lower bounds in multireservoir system benefits, providing a reference framework for analyzing the economic value of coordination. The methodology is applied to a large‐scale multireservoir system in Brazil. The methods rely on the comparison between two management scenarios. The first one mimics typical system operation based on individually designed rule curves, which are likely to perform on the lower bound. This is compared with fullscale system‐wide optimization through an Stochastic Dual Dynamic Programming algorithm to represent fully coordinated reservoir operation (upper bound). For our case study, results indicate that better coordination reduced spills and improved releases timing according to reservoirs characteristics and location, allowing overall gains between 3% and 8% in energy and 7.9% in revenues, with revenues mostly improved by coordination in dry years. Larger reservoirs presented the highest gains in absolute terms, while the smaller ones presented the highest relative increases. By indicating individual gains at each reservoir, valuable information is produced to support future negotiations and benefit sharing among different agents, being water agencies or power companies.