The influence of chamber pressure and Si-doping on the growth rate, surface morphology and Hall mobility was investigated for β-Ga2O3 thin films homoepitaxially grown by metalorganic vapor phase epitaxy on Mg-doped β-Ga2O3 (100) substrates with 4° miscut. Transitions from step-bunching to step-flow to 2D island growth modes were achieved by varying the chamber pressure from 10 mbar to 40 mbar and/or by varying the O2/Ga ratio. High-quality β-Ga2O3 homoepitaxial thin films with a high electron mobility of 153 cm2 Vs−1 have been obtained at a chamber pressure of 25 mbar and a growth rate of 3.6 nm min−1. The Si-doped films show electron concentrations in the range of 1 × 1017 to 2 × 1019 cm−3. When increasing the chamber pressure to 40 mbar step-flow growth mode and high charge carrier mobility can only be preserved by adjusting the O2/Ga ratio and increasing the Ar push gas flow. Secondary ion mass spectrometry and Hall measurements for Si and electron concentration, respectively, revealed Si compensation at higher tetraethyl orthosilicate flux.