This study explores the impact of emerging vehicle technologies on direct urban traffic emissions. It investigates emission reduction potential from shifts in fleet compositions and modal choices, especially considering climate change. To achieve this, three key research areas are explored for historical, current, and future scenarios (up to 2050): mode choice, emission factors for different vehicle categories, and diverse vehicle propulsion technologies. The estimation of the modal split is pivotal, developing a methodology utilizing Stated Preference survey data, discrete choice modeling, Monte Carlo simulations, and macroscopic traffic simulations. Future scenarios derive from the reference year’s modal split, and emission factors and fleet compositions are predetermined via an extensive literature review, aiding the assessment of their respective emissions. A subsequent sensitivity analysis identifies the impact of specific parameters on emissions, guiding future research focus. Study results underscore differences in greenhouse gas emissions and primary air pollutants between base and future scenarios.