Stacked Layers Research Articles

Host Engineering of Deep‐Blue‐Fluorescent Organic Light‐Emitting Diodes with High Operational Stability and Narrowband Emission

AbstractThe realization of highly operationally stable blue organic light‐emitting diodes (OLEDs) is a challenge in both academia and industry. This paper describes the development of anthracene–dibenzofuran host materials, 2‐(10‐(naphthalen‐1‐yl)anthracen‐9‐yl)naphtho[2,3‐b]benzofuran (Host 1) and 2‐(10‐([1,1′‐biphenyl]‐2‐yl)anthracen‐9‐yl)naphtho[2,3‐b]benzofuran (Host 2), namely for use in the emissive layer of an OLED stack. A multiple‐resonance thermally activated delayed serves as the blue fluorescence emitter and exhibits an initial luminance of 1000 cd m−2 and long operational stability (i.e., time to decay to 90% of initial luminance) of 249 h. Furthermore, a deep‐blue OLED with an optimized top‐emitting architecture with a high current efficiency of 154.3 cd A−1, is fabricated and calibrated to a Commission International de l’Éclairage y chromaticity coordinate of 0.048. Moreover, the emission spectrum of this OLED has a narrowband peak at 476 nm with a full width at half maximum (FWHM) of 16 nm. This work provides valuable insights into the design of anthracene‐based host materials and highlights the importance of host optimization in improving the operational stability of OLEDs.

Crack characteristics of pulsed laser brazed diamond grinding wheel

Experiments on pulsed laser brazing of diamond grinding wheels were carried out in this paper. The crack characteristics and residual stress of brazed layer were detected and evaluated. The influence laws of pulse width, frequency, diamond mixing ratio, number of stacked layers, powder thickness and preheating temperature on crack characteristics were investigated. The pulsed laser characteristic coefficients (peak pulse power density/pulse interval time) and the correlation law between thermal stresses and cracks are discussed. The results show that the pulse width and frequency of the pulsed laser affect the cracking rate by varying the energy input and the time between pulses. The existence of a suitable value for the pulse characteristic coefficient corresponding to pulse width and frequency corresponds to a lower cracking rate. Thermal stress variations due to changes in process conditions at different diamond percentages, number of stacked layers, and preheating temperatures are the main causes of crack rate variations. Cracking is not only affected by thermal stresses, but also by the quality of the formed surface when pulsed laser brazing diamond to nickel–chromium alloy brazing material. For example, the main reason for the variation in cracking rate is the change in the morphology of the molded surface due to the variation in the thickness of the powder spread at different variations in the thickness of the powder spread.

A Cross-Layer Approach to Analyzing Energy Consumption and Lifetime of a Wireless Sensor Node

Several wireless communication technologies, including Wireless Sensor Networks (WSNs), are essential for Internet of Things (IoT) applications. WSNs employ a layered framework to govern data exchanges between sender and recipient, which facilitates the establishment of rules and standards. However, in this conventional framework, network data sharing is limited to directly stacked layers, allowing manufacturers to develop proprietary protocols while impeding WSN optimization, such as energy consumption minimization, due to non-directly stacked layer effects on network performance. A Cross-Layer (CL) framework addresses implementation, modeling, and design challenges in IoT systems by allowing unrestricted data and parameter sharing between non-stacked layers. This holistic approach captures system dynamics, enabling network design optimization to address IoT network challenges. This paper introduces a novel CL modeling methodology for wireless communication systems, which is applied in two case studies to develop models for estimating energy consumption metrics, including node and network lifetime. Each case study validates the resulting model through experimental tests, demonstrating high accuracy with less than 3% error.

Layer stacking effect on structural, vibrational, and electronic properties of Janus-Ga2SeTe crystals

The van der Waals stacking of Janus Ga2SeTe quadruple-atomic layers leads to the formation of polytype bulk crystals, where the stacking order plays a critical yet elusive role in their fundamental properties. Here, we perform first-principles density functional theory calculations to investigate the stacking-dependent structural, electronic, and vibrational properties of four Ga2SeTe polytypes. Our results indicate that the γ polytype has two sub-phases of γ [ABC] and γ [ACB]. Lattice vibration studies manifest that symmetry operations depend on the stacking orders, in which the irreducible representations of optically active modes at Γ for the β, ε, γ, and δ phases are Γ = 3A1 + 4B1 + 4E2 + 3E1, Γ = 7E+7A1, Γ = 11A1 + 11E, and Γ = 8E2 + 7E1 + 8B1 + 7A1, respectively. Moreover, taking spin–orbit coupling into account, the estimated indirect bandgaps are 0.967, 0.926, 0.879, 0.925, and 0.950 eV for β, ε, γ [ABC], γ [ACB], and δ polytypes, respectively, in which the bandgap differences between indirect and direct transitions are within 10 meV. The Bader charge analysis indicates that the stacking order modulates the charge distribution among the compositional layers. These findings provide valuable insights for the development of optoelectronic devices based on Janus structures.

Robot dynamics-based cable fault diagnosis using stacked transformer encoder layers

Robot dynamics-based cable fault diagnosis using stacked transformer encoder layers

Opto-twistronic Hall effect in a three-dimensional spiral lattice.

Studies of moiré systems have explained the effect of superlattice modulations on their properties, demonstrating new correlated phases1. However, most experimental studies have focused on a few layers in two-dimensional systems. Extending twistronics to three dimensions, in which the twist extends into the third dimension, remains underexplored because of the challenges associated with the manual stacking of layers. Here we study three-dimensional twistronics using a self-assembled twisted spiral superlattice of multilayered WS2. Our findings show an opto-twistronic Hall effect driven by structural chirality and coherence length, modulated by the moiré potential of the spiral superlattice. This is an experimental manifestation of the noncommutative geometry of the system. We observe enhanced light-matter interactions and an altered dependence of the Hall coefficient on photon momentum. Our model suggests contributions from higher-order quantum geometric quantities to this observation, providing opportunities for designing quantum-materials-based optoelectronic lattices with large nonlinearities.

The process and mechanism of coke gasification dissolution loss in hydrogen-rich blast furnace

Blast furnace (BF) hydrogen-rich smelting has become an important way for low-carbon ironmaking. The coke gasification dissolution loss will be accelerated by H2O generated through hydrogen reduction, which is the fundamental reason for the limited injection rate of hydrogen-rich gas in BF. The gasification dissolution loss experiments of coke were carried out under different conditions. Experimental results indicate that: The pore size of coke containing H2O is larger under the same gasification time. The quantitative relationship between pore size and gasification time, flow rate of H2O is obtained. The pore wall around the inner hole will gradually be eroded, the pore wall gradually dissolves along the edge of the inner hole. The connectivity between two pores starts from the deep layers of the pores, the pore walls in the deep layers of pores are first connected. The carbon layer spacing slightly decreases with gasification time, which indicates that the microcrystalline cells inside the coke have contracted in the vertical direction. The carbon layer stacking height shows an overall upward trend with the increase of temperature and gasification time, and it will reach a maximum value for a certain temperature. The carbon layer diameter increases with the prolongation of gasification time, the aromatic carbon layers continue to grow as gasification progresses. The dynamic model of H2O diffusion is established, the effective internal diffusion coefficients of H2O under different conditions are calculated, the diffusion ability of H2O is stronger than that of CO2. The mechanism of H2O dissolution loss of coke based on surface active sites is summarized, whether the gasification dissolution loss reaction can occur depends on whether there are active sites on the adsorbed surface. The competitive gasification always occurs vigorously at active sites, the gasification reaction between H2O and C is easier and the reaction rate is higher.

CO2 sensing via periodic Array of graphene disks

This work aims to introduce a gas detection structure based on stacked layers of graphene-spacer-metal. The presented structure consists of three stacked layers. The first layer is the periodic arrays of graphene disks on top of a typical dielectric such as TOPAS or KAPTON with a known refractive index. Then the second layer provides an air gap opening room for a sample environment. Finally, the third layer includes the dielectric and a continuous graphene sheet. All the exploited elements are modeled by circuit element while the equivalent impedance of the whole structure is calculated. The impedance matching concept is also exploited to obtain absorption power based on the calculated impedance. Additionally, full-wave simulation is performed to investigate the circuit modeling accuracy. Achieving a perfect match for absorption versus frequency verifies the developed method's robustness. Furthermore, comprehensive and ample simulation results are reported to highlight the sensitivity and reliability of the proposed gas detector.

Comparison of Levitation Properties between Bulk High-Temperature Superconductor Blocks and High-Temperature Superconductor Tape Stacks Prepared from Commercial Coated Conductors.

Bulk high-temperature superconductors (HTSs) such as REBa2Cu3O7-x (REBCO, RE = Y, Gd) are commonly used in rotationally symmetric superconducting magnetic bearings. However, such bulks have several disadvantages such as brittleness, limited availability and high costs due to the time-consuming and energy-intensive fabrication process. Alternatively, tape stacks of HTS-coated conductors might be used for these devices promising an improved bearing efficiency due to a simplification of manufacturing processes for the required shapes, higher mechanical strength, improved thermal performance, higher availability and therefore potentially reduced costs. Hence, tape stacks with a base area of (12 × 12) mm2 and a height of up to 12 mm were prepared and compared to commercial bulks of the same size. The trapped field measurements at 77 K showed slightly higher values for the tape stacks if compared to bulks with the same size. Afterwards, the maximum levitation forces in zero field (ZFC) and field cooling (FC) modes were measured while approaching a permanent magnet, which allows the stiffness in the vertical and lateral directions to be determined. Similar levitation forces were measured in the vertical direction for bulk samples and tape stacks in ZFC and FC modes, whereas the lateral forces were almost zero for stacks with the REBCO films parallel to the magnet. A 90° rotation of the tape stacks with respect to the magnet results in the opposite behavior, i.e., a high lateral but negligible vertical stiffness. This anisotropy originates from the arrangement of decoupled superconducting layers in the tape stacks. Therefore, a combination of stacks with vertical and lateral alignment is required for stable levitation in a bearing.

Light-responsive biowaste-derived and bio-inspired textiles: Dancing between bio-friendliness and antibacterial functionality

Functional antibacterial textiles fabricated from a hybrid of organic waste-derived and bio-inspired materials offer sustainable solutions for preventing microbial infections. In this work, we developed a novel antibacterial textile created through the valorization of spent coffee grounds (SCG). Electrospinning and electrospraying techniques were employed to integrate the biowaste within a polymeric nanofiber matrix, ensuring uniform particle distribution and providing structural support for enhanced applicability. Modification with polydopamine (PDA) significantly enhanced the textile's photothermal performance. Specific attention was paid to understanding the relation between temperature change and key variables, including the surrounding liquid volume, textile layer stacking, and applied laser power. Developed platforms demonstrated excellent photothermal stability. While the SCG-based textile demonstrated exceptional biocompatibility, the PDA-modified textile effectively eradicated Staphylococcus aureus (S. aureus) under near-infrared (NIR) irradiation. The developed textiles in our work demonstrate a dynamic balance between biocompatibility and on-demand antibacterial functionality, offering adaptable solutions in accordance with the desired application.

Advanced Electrospun Composites Based on Polycaprolactone Fibers Loaded with Micronized Tungsten Powders for Radiation Shielding.

Exposure to high levels of radiation can cause acute, long-term health effects, such as acute radiation syndrome, cancer, and cardiovascular disease. This is an important occupational hazard in different fields, such as the aerospace and healthcare industry, as well as a crucial burden to overcome to boost space applications and exploration. Protective bulky equipment made of heavy metals is not suitable for many advanced purporses, such as mobile devices, wearable shields, and manned spacecrafts. In the latter case, the in-space manufacturing of protective shields is highly desirable and remains an unmet need. Composites made of polymers and high atomic number fillers are potential means for radiation protection due to their low weight, good flexibility, and good processability. In the present work, we developed electrospun composites based on polycaprolactone (polymer matrix) and tungsten powder for application as shielding materials. Electrospinning is a versatile technology that is easily scalable at an industrial level and allows obtaining very lightweight, flexible sheet materials for wearables. By controlling tungsten powder size, we engineered homogeneous, stable and processable suspensions to fabricate radiation composite shielding sheets. The shielding capability was assessed by an in vivo model on prototype composite sheets containing 80 w% of W filler in a polycaprolactone (PCL) fibrous matrix by means of irradiation tests (X-rays) on mice. The obtained results are promising; as expected, the shielding effectivity of the developed composite material increases with the thickness/number of stacked layers. It is worth noting that a thin barrier consisting of 24 layers of the innovative shielding material reduces the extent of apoptosis by 1.5 times compared to the non-shielded mice.

Multiple enhancement effects of dipoles within polyimide cathode promoting highly efficient energy storage of lithium-ion batteries

Polyimide (PI) has been recognized as a potential organic cathode for Li-ion batteries (LIBs) due to its programmable structural design, high theoretical capacity, and resource availability. However, the poor intrinsic electrical conductivity of PI means that PI-based cathodes of LIBs have inefficient energy storage performance, especially at high current densities. In this work, the molecular structure of PI is optimized to obtain a layer-stacked crystalline PI with significantly enhanced dipoles, denoted NT-B for the first time. The dipoles in this PI are induced by the electronegative carbonyl groups from the monomer biuret and further enhanced via a π-π layer stacking effect. This work is the first to verify that the co-directional dipole enhancement effect of biuret is surprisingly different from that of monomer urea. A series of ex-situ/in-situ and theoretical DFT simulations are carried out to understand the functional mechanism of such effects. The multiple enhancement effects of the dipoles synergistically promoting the generation of a strong built-in electric field (BIEF) within NT-B are proposed based on the results obtained. It is confirmed that this BIEF plays a significant role in accelerating electron transport, which enhances the electrochemical activity of LIB cathodes. This work provides a new idea for the structural design of high-performance PI cathodes for LIBs.

Self-grown carbon nanotubes supported fluorine-free Mo2CTx conductive layers for efficient potassium storage

Mo2CTx is relatively less studied among MXenes family, especially for rechargeable alkali metal ion batteries. Herein, a systematic investigation has been conducted to unlock its potential as electrode materials in potassium-ion battery (PIBs), including innovative fluorine-free synthesis strategy, construction of heterostructure, and exploration of suitable electrolyte systems. Firstly, Cetyltriethylammnonium bromide (CTAB)-assisted etching route was provided to fabricate high-quality multilayer Mo2CTx with expanded interlayer space (C-Mo2CTx). The as-obtained C-Mo2CTx demonstrates a large specific capacity of 200 mAh g−1over 300 cycles in potassium-ion battery, surpassing the HF etched counterparts (F-Mo2CTx) by about 300 %. Afterwards, Zeolitic Imidazolate Frameworks (ZIF-67) derived Co, N-codoped carbon nanotubes (Co@NCNTs) were homogenously grown on the surface of Mo2CTx, working as embedding spacer to open the stacked Mo2CTx conductive layers (Mo2CTx-Co@NCNTs). Mo2CTx-Co@NCNTs electrode represents stable reversible capacity of 280 mA h g−1 over 300 cycles. The highly conductive matrix constructed by the strong bond between CNTs arrays and Mo2CTx conductive layer could provide numerous K-ion-diffusion pathways, and buffer volume strain and facilitate electron transfer. The present work proves the potential of Mo2CTx in PIBs and gives the systematic research methodologies on Mo2CTx-based materials in alkali metal ion storage.

Fabrication of functional surfaces using layer height method in material extrusion type 3D printing

Various layer stacking methods have been employed in material extrusion type three-dimensional (3D) printing to utilize their potential for addressing the inherent technological limitation of reduced surface quality due to layer stacking. The process involved fabricating a material extrusion type 3D printed mold using diverse layer height-changing methods and subsequently replicating the surface pattern with the polymer. This approach is called the layer height method (LHM) and comprises three distinct variations. The first method involves altering the height of the individual layers to generate diverse surface morphologies and, consequently, varying the range of water contact angles. The second method focuses on rapid layer height changes to facilitate liquid deposition within regions with low contact angles. Finally, a layer height gradient was systematically established within the mold, resulting in a wettability gradient surface capable of controlling the movement of water droplets across the surface. The performance of these functional surfaces was successfully validated using various experimental methods. This study introduces a manufacturing technique based on changing layer heights within the framework of material extrusion-type 3D printing technology. A wide range of intricate and diverse functional surfaces can be produced by extending the manufacturing method proposed in this study to 3D printing technologies beyond the scope of material extrusion type 3D printing.

Effect of pre‐aging intermediate layers on the performance of multi‐layer organic photovoltaic devices

AbstractUnderstanding the degradation behaviour of organic photovoltaic (OPV) devices is an essential part to improve their stability prior to massive production. Accelerated aging can help to assess their stability and study the underlying degradation mechanisms of OPVs. Most studies focus on individual layers or a full device, and little is known about the role a pre‐aged layer stack plays in the performance of a device. Herein, we report the investigation of the effects of pre‐aging of multiple layers on the performance of OPVs. Instead of aging a single layer or an entire stack (sequential layers: ITO/PEDOT:PSS/MoOx/F‐BsubPc/C60/BCP/Ag), our process involved aging the intermediate layer stack for 24 h after depositing a specific layer before continuing with the subsequent depositions to fully fabricate/manufacture OPVs. Aging was conducted under four controlled conditions considering parameters including moisture, gas type, and temperature in the absence of light according to the International Summit on Organic Photovoltaic Stability (ISOS) protocols. Short of PEDOT:PSS we found that multiple layers, being subjected to the parameters, resulted in a decline in OPV device performance after being fully manufactured. Device performance is evaluated based on short‐circuit current density (Jsc), power conversion efficiency (PCE), and open‐circuit voltage (Voc). Our analysis provides insight into the degradation mechanisms of layered/planar OPV structures and offers strategic guidance for optimizing fabrication processes, particularly during the layer deposition transitions. We recommend that during OPV vacuum deposited fabrication, intermediate layers should be protected from moisture, O2, high temperature, and even inert gases, preferably in a low‐vacuum environment.

Supercapacitively Liquid-Solid Dual-State Optoelectronics.

Photo-transduction of solid-state optoelectronics occurs in semiconductors or their interfaces. Considering the confined active area and interfacial capacitance of solid-state materials, solid-state optoelectronics faces inherent limitations in photo-transduction, especially for bionic vision, and the performance is lower than that of living systems. For example, a photoreceptor generates pA-level photocurrent when absorbing a single photon. Here, a liquid-solid dual-state phototransistor is demonstrated, in which photo-transduction and modulation take place at the microporous interface between semiconductors and water, mimicking principles of the photoreceptor. When operating in the water, an orderly stacked photo-harvesting covalent organic framework layer generates supercapacitively photogating modulation of the channel conductivity via a dual-state interface, achieving responsivity of 4.6×1010 AW-1 and detectivity of 1.62×1016 Jones at room temperature, several orders of magnitude higher than other photodetectors. Such bio-inspired dual-state optoelectronics enables high-contrast scotopic neuromorphic imaging with responsivity greater than photoreceptors, holding promise for constructing optoelectronic systems with performance beyond conventional solid-state optoelectronics.

Application of High‐ and Low‐Reactivity Cokes in Hydrogen‐Rich Blast Furnaces

The effects of two cokes with different reactivity on the lump ore's metallurgical properties and coke's solution loss are investigated under the high‐temperature load reduction. The work used an improved test device for softening‐melting and dropping characteristics of iron ores in both CO2 and CO2H2O atmospheres. The deterioration behavior of highly reactive cokes is expounded under hydrogen‐rich conditions. High‐reactivity cokes under hydrogen‐rich conditions are more favorable for enhancing the breathability of charge and the penetration of the coke layer. However, it increased the thickness of the softening zone. High‐reactivity cokes had obvious internal and external reaction gradients. The solution loss reaction mostly occurred on the surface, with selectivity. The longitudinal stacking height, layer number, and order degree in the carbon structure decreases after the reaction. The carbon‐structure difference weakens between the shell and core. The enhancement of coke's reactivity, however, results in the significant loss of coke powders on its surface. Unreduced FeO and refractory Fe2SiO4 are more likely to appear in the droplets, which is not conducive to the reduction of Fe and the generation of slag crust in the furnace. The difficulty in separating lump ores and cokes is aggravated, and more iron‐containing charge remain in the furnace.

Unraveling the influence of deposited layers on Ti/RuO2 anodes to define the electroactivity of oxygen evolution and active chlorine reactions

Ti/RuO2 were synthesized using Pechini method with 4, 8 and 16-RuO2 layers, to account for the influence of their physical properties upon their behavior towards reactive oxygen evolution (OER) and active chlorine reaction (CER). Rietveld refinement conducted using X-Ray diffraction (XRD) measurements confirmed the formation of TiO2 (P42/mnm) and RuO2 (P42/mnm, poor rutile-type), which grew on a thin native TiO2 layer forming a solid solution. This analysis corroborated that the smaller RuO2 crystallite size was obtained using 4-layers, unlike the trend of increasing sizes with more layer’s numbers. This situation is not conducive to accessing reactive sites and electronic conduction issues. Interestingly, exchange current densities (j0) in NaCl(aq) presence were higher than Na2SO4(aq) for 4 and 8-layers, evidencing an inhibition of OER to catalyze CER due to RuO2. This behavior is not related to the electroactive area, since this property decreased by rising the number of layers. The 4-layers anode showed the largest production of CER after 20 min of electrolysis, but the lower accelerated lifetime (ALT). Thus, the stacking of more RuO2 layers creates a higher resistance for charge transfer. Likewise, Ti substrate is important to define the CER catalysis, whence a low coverage of RuO2 will be more catalytic than a high coverage of this oxide. The electrode activity was assessed through the removal of 132 µmol L−1 Acetaminophen (ACM), revealing that 93, 80, and 50 % was removed using 4, 8 and 16-layers of RuO2 coating respectively, at 10 mA and 0.1 molL−1 NaCl. Density functional theory (DFT) and high-performance liquid chromatograph coupled to a mass spectrometer (HPLC-MS) were used to propose a reaction mechanism for ACM degradation. Four byproducts with m/z ACM-I-1 (C8H5Cl4NO3) 304, ACM-I-2 (C8H6Cl3NO3) 274, ACM-I-3 (C6H4Cl3NO2) 227, and ACM-I-4 (C6H3Cl3O3) 229 were identified corresponding to the addition of chlorine in the amide group and aromatic ring, as a susceptible site to electrophilic attack.

Highly Tunable Light Absorber Based on Topological Interface Mode Excitation of Optical Tamm State.

Optical absorbers based on Tamm plasmon states are known for their simple structure and high operational efficiency. However, these absorbers often have limited absorption channels, and it is challenging to continuously adjust their light absorption rates. Here, we propose a Tamm plasmon state optical absorber composed of a layered stack structure consisting of one-dimensional topological photonic crystals and graphene nano-composite materials. Using the four-by-four transfer matrix method, we investigate the structural relationship of the absorber. Our results reveal that topological interface states (TISs) effectively excite the optical Tamm state (OTS), leading to multiple absorption peaks. This expands the number of absorption channels, with the coupling number of the TIS determining the transmission quality of these channels-a value further adjustable by the period number of the photonic crystals. Tuning the filling factor, refractive index, and thickness of the graphene nano-composite material allows for a wide range of control over the device's absorption rate, from 0 to 1. Additionally, adjusting the defect layer thickness, incident angle, and Fermi energy enables us to control the absorber's operational bandwidth and the switching of its absorption effect. This work presents a new approach to expanding the tunability of optoelectronic devices.

Ultra-low-thickness, highly sensitive, and perfect-absorption THz refractive index and temperature sensors based on Tamm plasmon polaritons and Fabry-Perot resonators

In this paper, an ultra-low thickness with high sensitivity and perfect absorption based on the excitation of Tamm plasmon polaritons and Fabry-Perot resonance for sensing applications is presented. The sensor comprises a graphene sheet, a spacer layer, an analyte region, and a one-dimensional periodic stack of the dielectric and metal layers. The sensor’s performance is evaluated using the transfer matrix method under different conditions, including the presence of the graphene sheet and metallic layers of the periodic stack, a change in the chemical potential of the graphene sheet, the thickness of the layers, as well as the incident polarization and angle. The simulation results show that the presence of the graphene sheet causes stimulation of Tamm plasmon polaritons, and the presence of metal layers simultaneously increases the absorption and decreases the thickness of the sensor. The sensitivity of the sensor is 0.9667 THz/RIU (equivalent to 305 μm/RIU) with an absorption peak of 99.99 %. The use of silicon as the analyte allows the proposed structure to perform as a temperature sensor in the range of 1 THz, which results in a temperature sensitivity of 0.055 THz/°C (equivalent to 16.45 nm/°C). The proposed sensor has the advantages of extremely thin thickness, perfect absorption, high sensitivity, tunability, and fabrication-friendly structure. The proposed sensor has high potential for use in various sensing applications.