The development of stable air electrodes for Solid Oxide Cells operating at reduced temperatures (≤700°C) creates unique material design challenges. These electrodes must not only show excellent oxygen evolution and oxygen reduction reaction rates, but also be able to maintain these fast rates over the 40,000hr lifetimes envisioned for solid oxide cells. One material of significant interest for this is Sr(Ti0.3Fe0.7)O3-δ (STF), which is a mixed ionic-electronic conducting (MIEC) perovskite that has shown performance similar to that of LaxSr1-xCoyFe1-yO3-δ (LSCF) (1). Performance and stability substantially better than that of LSCF can be achieved by substitution of as little as 7% Cobalt onto the B-site of STF. (2) Reducing or eliminating the Cobalt while maintaining performance is desirable to avoid issues with its toxicity, availability, and cost. In this work, we explore Cobalt-free STF-based air electrodes; strategies explored include composites of STF and Gd0.1Ce0.9O2-δ (GDC), PrOX infiltration, and alternative B-site substitutions of STF with Ni and Cu.One of the aims of GDC-STF composite electrodes is to improve the thermal expansion coefficient (TCE) match and adhesion with the GDC reaction barrier layer, presumably making them more robust in thermal cycling. The 50% STF – 50 % GDC composites yielded polarization resistance values similar to those of pure STF electrodes, ~ 0.2 Wcm2 at 700C in air. Over the temperature range of 200°C-850°C, the coefficient of thermal expansion (CTE) of STF-GDC closely matches the CTE of GDC (~12×10-6 K-1), representing a significant improvement compared to STF. As previously discussed by Lu et al (3), the performance of pure STF electrodes can be significantly improved by infiltration with PrOx. Here we show that infiltration of STF-GDC composites with 1, 2, or 3 PrOx infiltration steps significantly decreases initial polarization resistance, e.g., from 0.5 to < 0.2 Wcm2 at 650C, with two infiltration steps yield the lowest polarization resistance. Furthermore, long term stability tests over >2 kh show that STF-GDC electrode degradation rates can be decreased by a factor of 4 through infiltration.Additional results for STF substituted with alternatives to Co, including Cu, Ni, and Cu-Ni, will be presented, along with the effects of exsolution induced by pre-reduction. S.-L. Zhang, D. Cox, H. Yang, B.-K. Park, C.-X. Li, C.-J. Li and S. A. Barnett, Journal of Materials Chemistry A, 7, 21447 (2019).S.-L. Zhang, H. Wang, M. Y. Lu, A.-P. Zhang, L. V. Mogni, Q. Liu, C.-X. Li, C.-J. Li and S. A. Barnett, Energy & Environmental Science, 11, 1870 (2018).M. Y. Lu, R. Scipioni, B.-K. Park, T. Yang, Y. A. Chart and S. A. Barnett, Materials Today Energy, 14, 100362 (2019).
Read full abstract