Spectroscopic Temperature Measurements Research Articles

Effects of Self-Heating on Performance Degradation in AlGaN/GaN-Based Devices

A self-consistent electrothermal transport model that couples electrical and thermal transport equations is established and applied to AlGaN/GaN device structures grown on the following three different substrate materials: 1) SiC; 2) Si; and 3) sapphire. Both the resultant I-V characteristics and surface temperatures are compared to experimental I -V measurements and Raman spectroscopy temperature measurements. The very consistent agreement between measurements and simulations confirms the validity of the model and its numerical rendition. The results explain why the current saturation in measured I-V characteristics occurs at a much lower electric field than that for the saturation of electron drift velocity. The marked difference in saturated current levels for AlGaN/GaN structures on SiC, Si, and sapphire substrates is directly related to the different self-heating levels that resulted from the different biasing conditions and the distinctive substrate materials.

Importance of Using Complementary Process Analyzers for the Process Monitoring, Analysis, and Understanding of Freeze Drying

The aim of the present paper is to demonstrate the importance of using complementary process analyzers (PAT tools) for the process monitoring, analysis, and understanding of freeze drying. A mannitol solution was used as a model system. Raman spectroscopic, near-infrared (NIR) spectroscopic, plasma emission spectroscopic, and wireless temperature measurements (TEMPRIS) were simultaneously performed in-line and real-time during each freeze-drying experiment. The combination of these four process analyzers to monitor a freeze-drying process is unique. The Raman and NIR data were analyzed using principal component analysis (PCA) and multivariate curve resolution (MCR), while the plasma emission spectroscopic and wireless temperature measurement data were analyzed using univariate data analysis. It was shown that the considered process analyzers do not only complement but also mutually confirm each other with respect to process step end points, physical phenomena occurring during freeze drying (process understanding), and product characterization (solid state). Furthermore and most important, the combined use of the process analyzers helped to identify flaws in previous studies in which these process analyzers were studied individually. Process analyzers might wrongly indicate that some process steps are fulfilled. Finally, combining the studied process analyzers also showed that more information per process analyzer can be obtained than previously described. A combination of Raman and plasma emission spectroscopy seems favorable for the monitoring of nearly all critical freeze-drying process aspects.

Temperature‐depending Raman line‐shift of silicon carbide

AbstractSilicon carbide (SiC) is often used for electronic devices operating at elevated temperatures. Spectroscopic temperature measurements are of high interest for device monitoring because confocal Raman microscopy provides a very high spatial resolution. To this end, calibration data are needed that relate Raman line‐shift and temperature. The shift of the phonon wavenumbers of single crystal SiC was investigated by Raman spectroscopy in the temperature range from 3 to 112°C. Spectra were obtained in undoped 6HSiC as well as in undoped and nitrogen‐doped 4HSiC. All spectra were acquired with the incident laser beam oriented parallel as well as perpendicular to the c‐axis to account for the anisotropy of the phonon dispersion. Nearly all individual peak centers were shifting linearly towards smaller wavenumbers with increasing temperature. Only the peak of the longitudinal optical phonon A1(LO) in nitrogen‐doped 4HSiC was shifting to larger wavenumbers. For all phonons, a linear dependence of the Raman peaks on both parameters, temperature and phonon frequency, was found in the given temperature range. The linearity of the temperature shift allows for precise spectroscopic temperature measurements. Temperature correction of Raman line‐shifts also provides the ability to separate thermal shifts from mechanically induced ones. Copyright © 2009 John Wiley & Sons, Ltd.

Spectroscopic measurements of temperature and plasma impurity concentration during magnetic reconnection at the Swarthmore Spheromak Experiment

Electron temperature measurements during counterhelicity spheromak merging studies at the Swarthmore Spheromak Experiment (SSX) [M. R. Brown, Phys. Plasmas 6, 1717 (1999)] are presented. VUV monochromator measurements of impurity emission lines are compared with model spectra produced by the non-LTE excitation kinematics code PRISMSPECT [J. J. MacFarlane et al., in Proceedings of the Third Conference on Inertial Fusion Science and Applications (2004)] to yield the electron temperature in the plasma with 1 μs time resolution. Average Te is seen to increase from 12 to 19 eV during spheromak merging. Average C III ion temperature, measured with a new ion Doppler spectrometer (IDS) [C. D. Cothran et al., Rev. Sci. Instrum. 77, 063504 (2006)], likewise rises during spheromak merging, peaking at ∼22 eV, but a similar increase in Ti is seen during single spheromak discharges with no merging. The VUV emission line measurements are also used to constrain the concentrations of various impurities in the SSX plasma, which are dominated by carbon, but include some oxygen and nitrogen. A burst of soft x-ray emission is seen during reconnection with a new four-channel detector (SXR). There is evidence for spectral changes in the soft x-ray emission as reconnection progresses, although our single-temperature equilibrium spectral models are not able to provide adequate fits to all the SXR data.

Copolymers of N-vinylcarbazole with Acrylic Acid, Itaconic Acid, and N-isopropylacrylamide: Synthesis, Determination of Monomer Reactivity Ratios, and Electrochemical Properties

Free radical copolymerizations of N-vinylcarbazole (NVCz) with acrylic acid (AA), itaconic acid (IA), and N-isopropylacrylamide (NIPAAm) at different feed ratios were conducted in 1,4-dioxane at 50°C. The copolymers were characterized by UV and FT-IR spectroscopic techniques, viscosity, and glass transition temperature measurements. The monomer reactivity ratios were determined by application of the extended Kelen-Tüdós method, which is one of the conventional linearization methods, and found to be rNVCz = 0.29 and rNIPAAm = 0.12, rNVCz = 0.84 and rIA = 0.12, rNVCz = 0.86 and rAA = 0.31 by UV, and rNVCz = 0.32 and rNIPAAm = 0.07 by FT-IR. Polymer-modified electrodes having electroactive, ionic, and hydrophobic properties were prepared by electro-oxidation using PNVCz, NVCz/NIPAAm, and NVCz/IA copolymers and tested as sensor electrodes to dopamine.

Unified modelling of near-cathode plasma layers in high-pressure arc discharges

A model of a near-cathode region in high-pressure arc discharges is developed in the framework of the hydrodynamic (diffusion) approximation. Governing equations are solved numerically in 1D without any further simplifications, in particular, without explicitly dividing the near-cathode region into a space-charge sheath and a quasi-neutral plasma. Results of numerical simulation are reported for a very high-pressure mercury arc and an atmospheric-pressure argon arc. Physical mechanisms dominating different sections of the near-cathode region are identified. It is shown that the near-cathode space-charge sheath is of primary importance under conditions of practical interest. Physical bases of simplified models of the near-cathode region in high-pressure arc discharges are analysed. A comparison of results given by the present model with those given by a simplified model has revealed qualitative agreement; the agreement is not only qualitative but also quantitative in the case of an atmospheric-pressure argon plasma at moderate values of the near-cathode voltage drop. The modelling data are compared with results of spectroscopic measurements of the electron temperature and density in the near-cathode region.

Validation experiments for spatially resolved one-dimensional emission spectroscopy temperature measurements by dual-pump CARS in a sooting flame

In this work, an emission spectroscopic (ES) technique for the determination of soot temperatures in an axisymmetric flame is validated against coherent anti-Stokes Raman spectroscopy (CARS) as preparation for a zero gravity measurement campaign. In order to reduce valuable measurement times during the parabolic flights, a setup for spatially resolved one-dimensional measurements along a line has been built up using an imaging spectrometer and a CCD-camera for data acquisition.In order to assess the performance of the ES technique, accurate coherent anti-Stokes Raman scattering (CARS) measurements have been performed at the same conditions. Hereby, great care has to be taken to minimize the known interferences in sooting flames. The non-resonant signal contribution was suppressed by a polarization technique and the signal wavelength was shifted to an interference free region. These modifications are discussed in detail. The temperatures obtained by both methods are in good agreement in most regions of the flame. It turned out that the described approach for ES is an appropriate and robust alternative for measuring temperatures in sooting axisymmetric flames, if more accurate techniques cannot be applied, e.g., during investigations in zero-g parabolic flight experiments.

Cooling an optical fiber to 4.5 K by indirect thermal contact with a liquid-helium flow and spectroscopic temperature measurements

We have made it possible to cool a 10-m-long optical fiber to 4.5 K in a compact helium-flow cryostat. The cryostat is vacuum loaded and the cooling principle is based on thermal contact with a copper holder cooled by the liquid-helium flow. To measure the temperature directly, we employed two different spectroscopic methods depending on the temperature regions. One was photon-counting Raman spectroscopy and the other was Brillouin spectroscopy. We used certain devices to improve the cooling efficiency and confirmed that the fiber was uniformly cooled to 4.5 K.

Time-Resolved Spectroscopic Temperature Measurement of Break Arcs in a D.C.42 V Resistive Circuit

In a D.C.42V-10A resistive circuit, break arcs are generated between electrical contact pairs. The materials of the contact pairs are Ag, Ag/C 2wt%, Ag/SnO2 12wt%, and Ag/ZnO 12wt%. The arc spectral intensities are measured by a time-resolved spectroscopic temperature measurement system. The arc temperature is calculated from the spectral intensities by using the method of relative intensities of two spectra. The experimental results are as follows. The arc temperature gradually decreases with increase of the gap of electrical contacts. The ranges of arc temperature for Ag, Ag/C 2wt%, Ag/SnO2 12wt%, and Ag/ZnO 12wt% contacts pairs are 4500-11000K, 4000-6000K, 4000-7000K, and 4000-11000K, respectively.

Spectroscopic temperature measurements in hydrogen inductively-driven plasmas at low pressures

Optical emission spectroscopy is applied to obtain the rotational and gas temperatures of an inductively-driven tandem plasma source of negative hydrogen ions. Discharges are maintained in hydrogen at fixed frequency f = 27 MHz, applied power P = 500 W, and low gas pressure in the range p = (26 - 60) mTorr. The rotational and gas temperatures are determined by analyzing the intensity distribution of the H2 Fulcher-α band (d 3∏u → a3σg+) line emission.

Evolution of Absorption Spectra in the Process of Nucleation in Photo-Thermo-Refractive Glass

Photo-thermo-refractive (PTR) glass belongs to a class of photosensitive multicomponent silicate glasses which demonstrate photo-thermo-induced precipitation of a crystalline phase. Photo-induced crystallization of sodium fluoride results in refractive index variations in exposed areas of PTR glass which was successfully applied for phase hologram recording. However, even if this glass is widely used for advanced optical applications such as the stabilization of laser diodes or spectral beam combining, the detailed mechanism of its photosensitivity is not well known. We present in this paper an analysis of the evolution of the absorption spectra of UVexposed PTR glass at the early stages of the thermal treatment (nucleation). Absorption spectra were measured on samples nucleated at constant temperature for different periods. Analysis of the structure of these spectra shows that the optimum of the nucleation process is associated with the appearance of a new absorption band in visible range that disappears when the crystal growth process starts. Analogous study was performed during the nucleation process. High temperature spectroscopic measurements were performed during the thermal treatment. It was found that absorption spectra evolve with a change of temperature, i.e. the band structure of these spectra is different whether or not the temperature is decreased below a temperature of ~400°C. We associate this process with the change of phase of the silver bromide nuclei (liquid/solid) that appears during the cooling or heating processes.

670 高温加熱炭酸ガス流の分光温度測定(OS9-2 宇宙軌道・姿勢・熱制御技術,OS9 宇宙工学技術)

670 高温加熱炭酸ガス流の分光温度測定(OS9-2 宇宙軌道・姿勢・熱制御技術,OS9 宇宙工学技術)

Spectroscopic Measurements of Electron Temperature and Electron Density in Electron Beam Plasma Generator Based on Collisional Radiative Model

The current work describes a spectroscopic method for determining the electron temperature and electron density in an electron beam generator using argon spectral lines based on a collisional radiative model. Neutral and first‐ionized Ar lines emitted from the electron beam generator are studied experimentally. A collisional radiative code was developed to simulate the Ar (I) and Ar (II) spectral emission and to compare the results with the experimental data for electron density and temperature determination. Ar lines and excited level densities were calculated by solving rate equations using the Gauss elimination method. The argon spectrum is recorded experimentally by superposing two discharges, namely a low pressure DC glow discharge and a high current pulsed discharge. Spectral lines between 350 nm and 950 nm were recorded using an integrated signal technique on a charge‐coupled device. Electron temperature is determined by the relative intensity ratio method of two spectral lines. The relative intensity ratios of each peak are compared in a specific pressure range at various values, and good correlation is reported.

Spectroscopy of smooth deuterated carbon films redeposited from plasma discharge in the tokamak T-10

Smooth deuterated carbon films redeposited from a deuterium plasma discharge in the tokamak T-10 vacuum chamber have been investigated by different spectroscopic methods and temperature measurements. The photoluminescence excitation spectra of sp 3-sp 2 nanostructures of tokamak films and sp 2 nanostructures of fullerite C60 films are compared. The effect of defect states on the photoluminescence and its temperature quenching is discussed. It is concluded that the mechanism of thermal luminescence quenching for smooth deuterated tokamak films is close to the corresponding mechanism for amorphous a-C:H films.

Spectroscopic Temperature Measurement of Breaking Arcs Near Cathode and Anode Surfaces of Copper Contacts

Breaking arcs are generated between a pair of Cu electrical contacts in a DC 42 V/10.5 A circuit, and the arc voltage, the arc current and the time-resolved arc spectral intensities near contact surfaces are simultaneously measured. The arc temperature is calculated from some spectral intensities emitted from Cu neutral atoms using the Boltzmann plot method. The arc temperatures near the cathode and anode surfaces are measured, and the following experimental results were obtained. (1) Time evolutions of the spectral intensities and the calculated arc temperature have similar characteristics. (2) The arc temperature near the anode surface is higher than that near the cathode surface, and the temperature fluctuation near the anode surface is larger than that near the cathode. (3) Just before arc extinction, the arc temperature near the cathode surface is almost constant for many breaking operations but the arc temperature near the anode surface varies.

Binding of tetrakis(pyrazoliumyl)porphyrin and its copper(II) and zinc(II) complexes to poly(dG-dC)2 and poly(dA-dT)2

Interactions of cationic porphyrins bearing five-membered rings at the meso position, meso-tetrakis(1,2-dimethylpyrazolium-4-yl)porphyrin (MPzP; M is H2, Cu(II) or Zn(II)), with synthetic polynucleotides poly(dG-dC)2 and poly(dA-dT)2 have been characterized by viscometric, visible absorption, circular dichroisim and magnetic circular dichroism spectroscopic and melting temperature measurements. Both H2PzP and CuPzP are intercalated into poly(dG-dC)2 and are outside-bound to the major groove of poly(dA-dT)2, while ZnPzP is outside-bound to the minor groove of poly(dA-dT)2 and surprisingly is intercalated into poly(dG-dC)2. The binding constants of the porphyrin and poly(dG-dC)2 and poly(dA-dT)2 are on the order of 10(6) M(-1) and are comparable to those of other cationic porphyrins so far reported. The process of the binding of the porphyrin to poly(dG-dC)2 and poly(dA-dT)2 is exothermic and enthalpically driven for H2PzP, whereas it is endothermic and entropically driven for CuPzP and ZnPzP. These results have revealed that the kind of the central metal ion of metalloporphyrins influences the characteristics of the binding of the porphyrins to DNA.

The role of plasma induced substrate heating during high rate deposition of microcrystalline silicon solar cells

A 13.56 MHz parallel plate hydrogen-diluted silane plasma, operated at high pressure and high power, was used to deposit microcrystalline silicon solar cells with efficiencies of 6–9% at high deposition rates of 0.4–1.2 nm/s. In this regime new challenges arise regarding temperature control, since the high plasma power causes the substrate to heat up significantly during film deposition. We investigated this effect of plasma-induced substrate heating experimentally by means of pyrometric substrate temperature measurements and spectroscopic gas temperature measurements. The substrate temperature was observed to increase by up to 100 K during film deposition, depending on power density and deposition time. Performance of deposited solar cells decreased whenever the plasma induced heating caused a drift outside the ideal temperature window, of around 475 K (∼200 °C). Further analysis related this decrease in performance to the substrate temperature's influence on film crystallinity and open circuit voltage.

Development and use of localized arc filament plasma actuators for high-speed flow control

The paper discusses recent results on the development of localized arc filament plasma actuators and their use in controlling high-speed and high Reynolds number jet flows. Multiple plasma actuators (up to 8) are controlled using a custom-built 8-channel high-voltage pulsed plasma generator. The plasma generator independently controls pulse repetition rate (0–200 kHz), duty cycle and phase for each individual actuator. Current and voltage measurements demonstrated the power consumption of each actuator to be quite low (20 W at 20% duty cycle). Emission spectroscopy temperature measurements in the pulsed arc filament showed rapid temperature increase over the first 10–20 µs of arc operation, from below 1000 °C to up to about 2000 °C. At longer discharge pulse durations, 20–100 µs, the plasma temperature levels off at approximately 2000 °C.Modelling calculations using an unsteady, quasi-one-dimensional arc filament model showed that rapid localized heating in the arc filament on a microsecond time scale generates strong compression waves. The results of the calculations also suggest that flow forcing is most efficient at low actuator duty cycles, with short heating periods and sufficiently long delays between the pulses to allow for convective cooling of high-temperature filaments. The model predictions are consistent with laser sheet scattering flow visualization results and particle imaging velocimetry measurements. These measurements show large-scale coherent structure formation and considerable mixing enhancement in an ideally expanded Mach 1.3 jet forced by eight repetitively pulsed plasma actuators. The effects of forcing are most significant near the jet preferred mode frequency (ν = 5 kHz). The results also show a substantial reduction in the jet potential core length and a significant increase in the jet Mach number decay rate beyond the end of potential core, especially at low actuator duty cycles.

Spectroscopic measurements of the electron temperature in low pressure radiofrequency Ar/H2/C2H2 and Ar/H2/CH4 plasmas used for the synthesis of nanocarbon structures

This paper deals with optical emission spectroscopy studies of low pressure (0.1–0.5 Torr) capacitively coupled radiofrequency hydrocarbon/argon-rich plasmas used for the synthesis of nanocarbon structures. The main goal of this paper is to obtain the electron temperature of such far-from-equilibrium plasmas as a function of the pressure, the excitation power and the argon content. In doing so, we have found that the argon upper energy levels used for electron temperature estimation remain close to corona balance. The latter has allowed us to use a modified Boltzmann plot technique to derive the electron temperature. It was found that, for the plasmas investigated, an increase of the argon population density (from 10% to 95%) leads to a pronounced decrease of the electron temperature while an increase of the processing pressure produces a moderate increase of the electron temperature. Additionally, the increase of the power from 50 to 300 W produces a very slight growth of the electron temperature.

Measurement and analysis of OH emission spectra following laser-induced optical breakdown in air.

The measured emission spectra of the OH radical subsequent to laser-induced optical breakdown in air are analyzed to infer spectroscopic temperature and species number density. Emissions from the UV A2sigma+ --> X2IIi transition dominate the spectra in the wavelength range of 306-322 nm and for time delays from the optical breakdown of 30-300 micros. Contributions from other species to the recorded OH emission spectra were also investigated for spectroscopic temperature measurements in the range of 2000-6000 K and for OH number densities in the range of 10(14) - 2 x 10(16) cm(-3). Monte Carlo simulations are applied to estimate errors in the analysis of the hydroxyl spectra.