Soybean Straw Research Articles

Biomass activated carbon supported Keggin-type polyoxometalate as an electrode material for high-performance acidic aqueous supercapacitors

Activated carbon (SSAC-OP) with micropore and mesopore was prepared by using soybean straw as a carbon source. Redox-active H3PMo12O40 (PMo12) was introduced into SSAC-OP by solution impregnation to obtain composite PMo12/SSAC-OP. The effect of loading amount of PMo12 on the supercapacitive performance of the composite was investigated. BET and EDS results confirmed that PMo12 is adsorbed in the micropores of 1–2 nm and mesopores of SSAC-OP, as well as on the carbon wall of SSAC-OP. Meanwhile, SSAC-OP with positive charge is more firmly connected with PMo12 anions via the effect of electrostatic attraction. CV and GCD test results proved that the composite materials have both electric double layer capacitance and pseudocapacitance characteristics. The CV curve of 10-PMo12/SSAC-OP obtained from SSAC-OP impregnating the initial concentration of PMo12 solution of 10 mM shows four pairs of obvious reversible redox peaks, which indicates that the protonation of PMo12 anion in the reduction process is sufficient. The composite 10-PMo12/SSAC-OP has a specific capacitance as high as 397.02F g−1 at scan rate of 5 mV s−1. The assembled symmetric supercapacitor delivers an energy density of 23.90 Wh kg−1 under the power density of 1016.05 W kg−1, with 97.96 % capacitance retention after 10,000 cycles at 3 A g−1.

Adsorption characteristics and mechanism of ammonia nitrogen and phosphate from biogas slurry by Ca2+-modified soybean straw biochar.

The utilization of biogas slurry is critical for the sustainable development of animal husbandry. Biomass carbon adsorption is a feasible method for the recycling of nutrients from biogas slurry. However, research on the co-adsorption of ammonia nitrogen and phosphate is scarce. Herein, soybean straw was utilized as the raw material to prepare Ca2+-modified biochar (CaSSB), which was investigated for its ammonia nitrogen and phosphate adsorption mechanisms. Compared with natural biochar (SSB), CaSSB possesses a high H/C ratio, larger surface area, high porosity and various functional groups. Ca2+-modified soybean straw biochar exhibited excellent adsorption performance for NH4+-N (103.18 mg/g) and PO43--P (9.75 mg/g) at pH = 6, using an adsorbent dosage of 2 g/L. The experimental adsorption data of ammonia nitrogen by CaSSB corresponded to pseudo-second-order kinetics and the Langmuir isotherm model, suggesting that the adsorption process was homogeneous and that electrostatic attraction might be the primary adsorption mechanism. Meanwhile, the adsorption of phosphate conformed to pseudo-second-order kinetics and the Langmuir-Freundlich model, whose mechanism might be attributed to ligand exchange and chemical precipitation. These results reveal the potential of CaSSBs as a cost-effective, efficient adsorbent for the recovery of ammonium and phosphate from biogas slurry.

Controlled porous structures of soybean straw-based carbon via green liquefication and N/S in-situ doping facilitate supercapacitor performance at large current density

It is important to maintain supercapacitor performance at high current density by regulating the micropore/mesopore balance and surface functional groups of biomass carbons. Here, the biomass porous carbon was successfully prepared from agroforestry waste of soybean straw by green activation was introduced on the basis of in-situ doping. Effective liquefaction and doping environment for non-metal N/S doping was achieved via green liquefaction using polyethylene glycol 400 (PEG400). The micropore/mesopore ratio, hydrophilic properties, and active sites of the carbon materials were regulated and enhanced by combing N in-situ doping and green activation with potassium citrate. The obtained soybean straw-based carbon with N doping (SSL-N1) showed higher surface area (1698.9 m2 g−1) and mesopore ratio (78.15%). The mesopore/micropore ratio shortened the ion adsorption distance and increased the ion surface accessibility. The specific capacitance of materials could reach 276.8 F g−1 at a current density of 0.5 A g−1. As the current density expand by 20 times, the specific capacitance could be preserved at 216 F g−1, the capacity retention rate is 78.0%. Notably, the SSL-N1//SSL-N1 symmetrical supercapacitor could generated an energy density of 10.14 W h kg−1. The specific porous and surface structures of carbon composite materials could effectively alleviate the capacity attenuation in supercapacitors at high current density.

Multistage utilization of soybean straw-derived P-doped biochar for aquatic pollutant removal and biofuel usage

Biochar is of great importance to realizing solid biowastes reduction and environmental remediation. Modifying biochar for better performance is also of great concern to achieve property improvement. P-doped biochar from soybean straw is prepared for multistage utilization to realize water pollutant removal and biofuel usage. The results suggest that the prepared biochar is adequate for sulfadiazine adsorption and has stable performance under coexisting ions and aquatic pH. Furthermore, the higher heating value of the biochar is close to coal and thus can be an alternative to fossil fuel. The maximum sulfadiazine adsorption amount of P-doped biochar is 252.24 mg·g-1, and the P-doped biochar HHV is 24 MJ·kg−1 which can be an alternative to coal. The greenhouse gas and pollutant emission potential are also considered to explore the environmental impact of P-doped biochar production and usage. Overall, the optimal ratio of soybean straw: K3PO4 is 3:1.

Decomposition of Agriculture Farm Wastes by Cellulolytic Bacteria

The most important component of the greatest material flow in the biosphere is the microbial consumption of cellulose. Despite the abundance of cellulase manufacturers, there aren't enough microorganisms that can effectively create enough of the enzyme to effectively break down cellulose into fermentable compounds. Despite the fact that bacteria have a very high level of natural variety and the potential to manufacture stable enzymes, little attention has been paid to their ability to produce cellulase. The present study aimed at the isolation and selection of cellulose degrading bacteria isolated from different samples for agriculture waste decomposition. Bacterial cultures were applied on agriculture waste material comprising soybean straw, pigeonpea straw; wheat straw and cotton stalk to investigate their percentage loss in weight. Among all the cultures, CDB 19 has shown the highest weight loss of the substrate (99.99%) followed by CDB 20 (99%), CDB5 (94.2%), CDB2 (92.8%) and CDB14 (88.6%). It was also observed that maximum weight loss of cotton straw (99.99%) was recorded by mixed culture followed by Pigeonpea straw and Soybean straw, while Wheat straw recorded minimum weight loss at 60 days of decomposition.

Investigation on Pb2+ adsorption characteristics by AAEMs-rich biochar in aqueous solution: Performance and mechanism

Biochar derived from soybean straw with AAEMs (alkali and alkaline earth metals) enrichment could efficiently remove heavy metals from contaminated water. In this study, the influences of pyrolysis temperature on the physicochemical property and adsorption performance of soybean straw biochar were investigated. The contributions of different adsorption mechanisms were analyzed quantitatively. The results show that the soybean straw biochar exhibits excellent Pb2+ adsorption performance (157.2–227.2 mg g−1), with an order of BC800 > BC400 > BC600 > BC700 > BC500. The mechanisms of metal ion exchange (37.49%–72.58%) and precipitation with minerals (22.38%–58.03%) mainly control the Pb2+ adsorption, whereas complexation with organic functional groups (OFGs) and cation-Cπ interaction make the less contribution. The order of cation exchange capacity (CEC) is BC400 > BC800 > BC700 > BC600 > BC500, showing a high correlation (0.965) with the contribution of metal ion exchange with AAEMs. Moreover, Ca exhibits the strongest exchange capacity. The contribution of precipitation is consistent with the variation of soluble CO32− content in biochar. These results suggest that soybean straw biochar rich in AAEMs is a prospective adsorbent for Pb2+ elimination.

Optimization of The Modified Soybean Straw Activated Carbon for Adsorption of Methylene Blue Dye by Response Surface Methodology

Optimization of The Modified Soybean Straw Activated Carbon for Adsorption of Methylene Blue Dye by Response Surface Methodology

Multiparametric optimization and statistical modelling of pelletization process: Effect of independent variables on physicochemical properties of soybean straw pellets

The main objectives of present experimental wok are to perform the statistical optimization, physicochemical characterization and economic analysis of soybean straw pellets obtained from tractor driven pelleting machine. In physicochemical characterization a detailed proximate analysis, ultimate analysis, thermal efficiency, Thermogravimetric analysis, Fourier transform infrared spectroscopic, and scanning electron microscopy analysis of soybean straw pellets were performed. Considering the Box-Behnken design findings, the pellet density, durability, compressive strength and power required were found to be 615.23 kg/m3, 91.47 %, 39.86 N/mm2 and 7.39 kWh respectively. Based on characterization results soybean straw pellets had an ash content of 5.20 %, a calorific value of 18.81 MJ/kg and a thermal efficiency of 19.46 %, respectively. TGA analysis indicates the maximum mass loss in the active zone due to the degradation of cellulose and hemicellulose. The pelleting machine for soybean straw, the benefit-cost ratio and the payback period were recorded to be around 1.18 and 2.10 years, respectively.

Activation of persulfate by iron‐loaded soybean straw biochar for efficient degradation of dye contaminants: Synthesis, performance, and mechanism

AbstractBiochar loaded with metal ions has been widely used to activate persulfate to degrade organic pollutants. However, the preparation conditions of catalysts are always controversial. In this study, the co‐heating conditions of soybean straw with high carbon and low nitrogen and nano‐iron oxide were systematically discussed by response surface method, and an efficient catalyst (Fe@BC) was obtained. Fe@BC can effectively activate sodium persulfate (PS) and degrade three synthetic azo dyes (Methyl orange (MO), Amino black 10B (AB10B), and Orange II) and rhodamine B (RhB). Under the optimum conditions, the removal rate of total organic carbon of these four dyes reached 41.1%–89.8% and the final degradation rate could reach 100%. The physicochemical properties of Fe@BC were studied by SEM, BET, XRD, XPS and TGA. The results revealed that the specific surface area of Fe@BC was 195.6m2/g. Further, reducing iron oxide by C generated C0.09Fe1.91 and zero‐valent iron. Free radical scavenging experiments and electron paramagnetic resonance (EPR) measurements showed that the main reactive oxide species (ROS) in the Fe@BC/PS system were hydroxyl radicals (•OH) and singlet oxygen (1O2). Finally, Several Fe@BC modification systems were explored, the optimum pH of Fe@BC/PS system was analyzed, and the effects of Fe@BC and PS dosage on degradation performance were also studied. This study provides a scientific basis for the production of efficient catalysts and biochar energy, and an effective treatment scheme for printing and dyeing wastewater.

Experimental investigation on the effect of soil solarization incorporating black, silver, and transparent polythene, and straw as mulch, on the microbial population and weed growth

Soil solarization is a non-chemical method for eliminating crop-threatening weeds and selectively decontaminating soil. The effect of various soil solarization with black, silver, transparent polythene sheet and straw as mulching on the microbial count and weed growth was studied experimentally. The farm investigation comprised six soil solarization treatments: mulching with black, silver, and transparent polyethylene sheets of 25 μm (μ), organic mulch (soybean Straw), weed-free, and control. All six treatments were repeated in four sets in a Randomized Block Design (RBD) plot size of 5.4 m × 4.8 m. Black, silver, and transparent polythene mulches significantly reduced fungal count compared to non-solarized soil. Straw mulch significantly increased soil fungal count. Solarized treatments had much lower bacterial populations than straw mulch, weed-free, and control treatments. Black, silver, straw mulch, and transparent polythene had 18746, 22763, 23999, and 3048 weeds ha−1 at 45 days after transplanting (DAT). The analysis of dry weed weight demonstrated a significantly low weed dry weight of 0.44 t/ha for black polythene (T1) based soil solarization, representing an 86.66% reduction in dry weed biomass. Soil solarization had the lowest weed index (WI), with black polythene mulch (T1) reducing weed competition. Among various soil solarization treatments, black polythene (T1) showed the highest weed control efficiency of 85.84%, indicating its suitability for use in weed control. The results suggest that soil solarization is effective for soil disinfestation and weed control with polyethene mulch and summer heat in central India.

Characterization of Dissolved Organic Matter Released from Aged Biochar: A Comparative Study of Two Feedstocks and Multiple Aging Approaches.

Dissolved organic matter (DOM) plays important roles in environmental ecosystems. While many studies have explored the characteristics of aged biochar, limited information is available about the properties of DOM derived from aged biochar. In this study, biochar obtained from maize stalk and soybean straw were aged using farmland or vegetable-soil solution, as well as soil solution containing hydrogen peroxide (H2O2). Chemical composition of the extracted DOM from the aged biochar was analyzed via excitation-emission matrix coupled with fluorescence regional integration (FRI) and parallel factor analysis (PARAFAC). Obtained results showed that biochar aged with H2O2-enriched soil solution had higher water-soluble organic carbon, ranging from 147.26-734.13% higher than the controls. FRI analysis revealed fulvic and humic-like organics as the key components, with a considerable increase of 57.48-235.96% in the humic-like component, especially in soybean-straw-aged biochar. PARAFAC identified four humic-like substance components. Concurrently, the aromaticity and humification of the aged-biochar-derived DOM increased, while the molecular weight decreased. These findings suggest that DOM derived from aged biochar, with a high content of humic-like organics, might impact the mobility and toxicity of pollutants in soil.

Analysis on Fermentation Quality, Chemical Composition and Bacterial Communities of Corn Straw and Soybean Straw Mixed Silage

In this study, the effects of mixed silage on the fermentation quality, chemical composition and bacterial communities of corn straw and soybean straw were assessed. Corn straws, soybean straws or a mixture of corn straws and soybean straws in a 1:1 mass ratio were uniformly mixed and processed using the same method to produce bagged silage weighing 50 kg per bag. At days 0, 14 and 60 of the fermentation process, the nutritional composition and fermentation quality indicators of each group were measured. A complete factorial design to assess the effect of the ensiling time, types of fermented straw (treatment group) and their interactions on the assessed parameters was performed. In addition, metabolomics sequencing and microbial community analysis were performed on the samples on the 60th day of fermentation. Compared with the corn straw group and the soybean straw group, the silage fermentation quality of the corn straw–soybean straw group is better, which is reflected in higher crude protein rate (p < 0.05), higher lactic acid content (p < 0.05) and lower ammonia nitrogen content (p < 0.05). The combined analysis of differential microbial taxa (species level) and differential metabolites revealed a positive correlation between certain bacterial species, such as manihotivorans, brevis and zeae, and significantly downregulated metabolites, such as pyrocatechol and N-benzoyltyramine. Similarly, positive correlations were observed between certain bacterial species, such as dublinensis, marcescens and agglomerans, and upregulated metabolites, such as D-xylonic acid and neochlorogenic acid. These findings suggest that the key microbial–metabolite pathways identified are responsible for the good fermentation quality observed during mixed fermentation of corn straw and soybean straw at a 1:1 mass ratio.

Effect of Moisture Content and Particle Size on Characteristics of Fuel Pellets Using Flat Die Type Pelleting Machine

Fuel pellets are a popular form of biomass energy due to their high energy density, ease of handling, and reduced emissions. The quality of fuel pellets is influenced by various factors, including the moisture content and particle size of the raw materials (Soybean straw and cotton stalk) used during the pelletization process. In this study, the effect of moisture content and particle size on the characteristics of fuel pellets produced using a flat die type pelleting machine was investigated. Different moisture content levels (ranging from 20 to 30%) and particle sizes (ranging from 4 to 8 mm) were used to pelletize a biomass feedstock. The pellet characteristics, including pellet durability, bulk density and water resistance and energy consumption were evaluated. The results showed that both moisture content and particle size significantly influenced the characteristics of the fuel pellets as well as energy consumption. Based on the findings, an optimal moisture content of 25% and particle size of 6 mm were determined for producing fuel pellets with desirable characteristics and low energy consumption was required using the flat die type pelleting machine. These results can provide valuable insights for biomass pellet producers and researchers in optimizing the pelletization process to achieve high-quality fuel pellets with improved properties.

Impact of different dietary fibre sources on production performance, bacterial composition and metabolites in the caecal contents of rabbits.

This study was conducted to investigate the effects of different dietary fibre sources on growth performance, gastrointestinal tract development, caecal fermentation and bacterial composition in the caecal contents of rabbits. A total of 120 35-day-old weaned Minxinan black rabbits were divided into three groups and fed a diet composed of peanut straw powder (Group A), alfalfa powder (Group B) and soybean straw powder (Group C) as the main fibre source. The final body weight and average daily gainin Group B were higher than those in Group C, and the average daily feed intakeand feed conversion ratio in Group A were lower than those in Group C (p < 0.05). The relative weights of the stomach, small intestine and caecum of rabbits in Group C were higher than those in Groups of B and A, and the relative weights of the caecal contents in Group C were lower than those in Groups A or B (p < 0.05). The pH value and propionic acid, butyric acid and valeric acid concentrations in the caecum of Group C were lower than those in the caecum of Groups A orB, and the concentration of acetic acid in the caecum was lower (p < 0.05). The dominant microbes in the caecal contents of Minxinan black rabbits were Firmicutes, Bacteroidetes and Proteobacteria at the phylum level, and the number of species, Chao1 index and ACE index measured was different between the B-C and A-C groups (p < 0.05). Different dietary fibre sources could affect the growth performance, gastrointestinal tract development and intestinal microbiota of rabbits, and the nutritional value of alfalfa powder was better than that of peanut straw and soybean straw.

Insight into the soil aggregate-mediated restoration mechanism of degraded black soil via biochar addition: Emphasizing the driving role of core microbial communities and nutrient cycling

Soil microbial communities are responsive to biochar application. However, few studies have investigated the synergistic effects of biochar application in the restoration of degraded black soil, especially soil aggregate-mediated microbial community changes that improve soil quality. From the perspective of soil aggregates, this study explored the potential microbial driving mechanism of biochar (derived from soybean straw) addition in black soil restoration in Northeast China. The results showed that biochar significantly improved the soil organic carbon, cation exchange capacity and water content, which play crucial roles in aggregate stability. The addition of biochar also significantly increased the concentration of the bacterial community in mega-aggregates (ME; 0.25–2 mm) compared with micro-aggregates (MI; <0.25 mm). Microbial co-occurrence networks analysis showed that biochar enhanced microbial interactions in terms of the number of links and modularity, particularly in ME. 16 S rRNA sequencing predicted that the expression of genes related to carbon (rbcL, acsA, gltS, aclB, and mcrA) and nitrogen (nifH and amoA) transformation increased after the addition of biochar. Furthermore, the functional microbes involved in carbon fixation (Firmicutes and Bacteroidetes) and nitrification (Proteobacteria) were significantly enriched and are the key regulators of carbon and nitrogen kinetics. Structural equation model (SEM) analysis further showed that the application of biochar promoted soil aggregates to positively regulate the abundance of soil nutrient conversion-related microorganisms, thereby increasing soil nutrient content and enzyme activities. These results provide new insights into the mechanisms of soil restoration through biochar addition.

Dual-activated biochar with a multichannel structure enhanced electrosorption capacity of capacitive deionization for sulfate removal from mining wastewater

Electrode material is the key factor for improving the electrochemical performance of capacitive deionization. In this study, a multichannel electrode material derived from soybean straw was prepared by pyrolytic carbonization and dual-activation, characterized, and used as an electrode material in capacitive deionization (CDI) cells to remove sulfate. The results showed that the sulfate adsorption capacity of dual-activated CA-NPSSC-1 of 17.16 mg/g was higher than that of pristine SSC (3.28 mg/g) due to its larger specific surface area, suitable pore structure, superior conductivity, and larger specific capacitance. The electrosorption mechanism of CA-NPSSC-1 electrode included EDL ion storage and pseudocapacitance storage. The EDL contribution and pseudocapacitance contribution were 72.06 % and 27.94 %, respectively, at a scan rate of 5 mV/s. Actual wastewater experiments have shown that the sulfate concentration in mining wastewater was reduced to 158.85 mg/L after recycling treatment, which meets the relevant standards. This work provides new ideas and methods for the treatment of high-salinity mining wastewater.

Maize/peanut intercropping has greater synergistic effects and home-field advantages than maize/soybean on straw decomposition.

The decomposition of plant litter mass is responsible for substantial carbon fluxes and remains a key process regulating nutrient cycling in natural and managed ecosystems. Litter decomposition has been addressed in agricultural monoculture systems, but not in intercropping systems, which produce species-diverse litter mass mixtures. The aim here is to quantify how straw type, the soil environment and their combined effects may influence straw decomposition in widely practiced maize/legume intercropping systems. Three decomposition experiments were conducted over 341 days within a long-term intercropping field experiment which included two nitrogen (N) addition levels (i.e. no-N and N-addition) and five cropping systems (maize, soybean and peanut monocultures and maize/soybean and maize/peanut intercropping). Experiment I was used to quantify litter quality effects on decomposition; five types of straw (maize, soybean, peanut, maize-soybean and maize-peanut) from two N treatments decomposed in the same maize plot. Experiment II addressed soil environment effects on root decomposition; soybean straw decomposed in different plots (five cropping systems and two N levels). Experiment III addressed 'home' decomposition effects whereby litter mass (straw) was remained to decompose in the plot of origin. The contribution of litter and soil effects to the home-field advantages was compared between experiment III ('home' plot) and I-II ('away' plot). Straw type affected litter mass loss in the same soil environment (experiment I) and the mass loss values of maize, soybean, peanut, maize-soybean, and maize-peanut straw were 59, 77, 87, 76, and 78%, respectively. Straw type also affected decomposition in the 'home' plot environment (experiment III), with mass loss values of maize, soybean, peanut, maize-soybean and maize-peanut straw of 66, 74, 80, 72, and 76%, respectively. Cropping system did not affect the mass loss of soybean straw (experiment II). Nitrogen-addition significantly increased straw mass loss in experiment III. Decomposition of maize-peanut straw mixtures was enhanced more by 'home-field advantage' effects than that of maize-soybean straw mixtures. There was a synergistic mixing effect of maize-peanut and maize-soybean straw mixture decomposition in both 'home' (experiment III) and 'away' plots (experiment I). Maize-peanut showed greater synergistic effects than maize-soybean in straw mixture decomposition in their 'home' plot (experiment III). These findings are discussed in terms of their important implications for the management of species-diverse straw in food-production intercropping systems.

The Study of Optimal Adsorption Conditions of Phosphate on Fe-Modified Biochar by Response Surface Methodology.

A batch of Fe-modified biochars MS (for soybean straw), MR (for rape straw), and MP (for peanut shell) were prepared by impregnating biochars pyrolyzed from three different raw biomass materials, i.e., peanut shell, soybean straw, and rape straw, with FeCl3 solution in different Fe/C impregnation ratios (0, 0.112, 0.224, 0.448, 0.560, 0.672, and 0.896) in this research. Their characteristics (pH, porosities, surface morphologies, crystal structures, and interfacial chemical behaviors) and phosphate adsorption capacities and mechanisms were evaluated. The optimization of their phosphate removal efficiency (Y%) was analyzed using the response surface method. Our results indicated that MR, MP, and MS showed their best phosphate adsorption capacity at Fe/C ratios of 0.672, 0.672, and 0.560, respectively. Rapid phosphate removal was observed within the first few minutes and the equilibrium was attained by 12 h in all treatment. The optimal conditions for phosphorus removal were pH = 7.0, initial phosphate concentration = 132.64 mg L-1, and ambient temperature = 25 °C, where the Y% values were 97.76, 90.23, and 86.23% of MS, MP, and MR, respectively. Among the three biochars, the maximum phosphate removal efficiency determined was 97.80%. The phosphate adsorption process of three modified biochars followed a pseudo-second-order adsorption kinetic model, indicating monolayer adsorption based on electrostatic adsorption or ion exchange. Thus, this study clarified the mechanism of phosphate adsorption by three Fe-modified biochar composites, which present as low-cost soil conditioners for rapid and sustainable phosphate removal.

Enhanced activation of peroxydisulfate by regulating pyrolysis temperature of biochar supported nZVI for the degradation of oxytetracycline

BackgroundBiochar-loaded zero-valent iron composites have been widely studied due to their potential applications in the degradation of organic pollutants. However, increasing the content of zero-valent iron in composites faces challenges. MethodsA series of biochar-supported nano-zero-valent iron catalysts (nZVI-BC) were prepared by co-pyrolysis of soybean straw and Fe2O3 at different pyrolysis temperatures. The results of N2 adsorption/desorption, XRD, XPS, and FT-IR show that different pyrolysis temperatures have great influence on the maximum N2 adsorption capacity and the content of nano-zero-valent iron (nZVI) in nZVI-BC. The total organic carbon (TOC) content results indicate that the nZVI-BC/PDS system resulted in a successful conversion of organic carbon to CO2. The •SO4−, •OH, and 1O2 are the main active species in nZVI-BC1000/PDS system. Significant findingAt the pyrolysis temperature of 1000 °C, nZVI-BC1000 exhibited high-efficiency activation performance for peroxydisulfate (PDS) and high-efficiency degradation performance for oxytetracycline (OTC). The strong catalytic activity of the nZVI-BC1000 for PDS is due to the high content of the nZVI in nZVI-BC1000. Finally, the pyrolysis temperature has great influence on the preparation and catalytic performance of nZVI-BC. This study provides a scientific guidance for the development of biochar energy and the optimization of catalysts in advanced oxidation technology.

Heavy metal content in soybean production waste in the southern zones of the Amur region

The Amur region is one of the main agricultural areas of the Far East. The main agricultural crop in the fields of the southern zone of the Middle Priamurye is soybean. Soybean production waste, such as soybean straw and soybean husk, are most often used by livestock breeders as roughage in the main diet. According to the monitoring results of heavy metal content in soybean production waste in the farms of the southern zone of the Amur region, it can be noted that these indicators do not exceed the maximum allowable concentrations. There is also an insufficient content of such elements as copper and zinc in soybean straw and soybean husks, which must be taken into account when formulating diets for farm animal feeding and introduce additional mineral supplements to prevent metabolic diseases.