Basin South China Research Articles

Ecological risks caused by neonicotinoid pesticides in sediments: A case study of freshwater basins in China.

Neonicotinoid insecticides (NNIs) are extensively used in agricultural production in China due to their selective neurotoxicity towards target insects. In recent years, the rapid development of agriculture has increased the use and residue of NNIs. Consequently, the sediment environment, serving as the ultimate sink, is significantly impacted by NNIs. Upon release into the environment, NNIs can enter the human body through the food chain, posing potential ecological and human health risks. This study analyzed 79 sediment samples from two major river basins in North and South China, the Liaohe River basin in Liaoning Province and the Jianjiang River basin in Guangdong Province. The content, composition, distribution, and source of eight NNIs were analyzed, and assess the ecological and human health risks of the target compounds in these regions. The results indicated that the average concentration of NNIs in the sediments of the Jianjiang River basin (2.34 μg/kg) is slightly higher than that of the Liaohe River basin (2.32 μg/kg), and the sources of NNIs in the two areas were different, with differences in the sources of NNIs likely attributable to varying types of agricultural production. The risk assessment revealed that the ecotoxicological and public health risks were more pronounced in the Jianjiang River basin compared to the Liaohe River basin, underscoring the critical need for surveillance and management of hazardous substances like NNIs. The insights findings from this study can provide scientific guidance for the risk evaluation and environmental management of NNIs.

Non-Linear Response of Alpha and Beta Diversity of Taxonomic and Functional Groups of Phytoplankton to Environmental Factors in Subtropical Reservoirs.

Exploring the response of the diversity of phytoplankton species and functional groups to environmental variables is extremely important in maintaining biodiversity in aquatic ecosystems. Although there were more taxonomic units at the species level than at the functional group level, it remained unclear whether species diversity was more sensitive than functional group diversity to environmental variables. In this study, taxonomic composition and alpha-beta diversity of phytoplankton were investigated in 23 subtropical reservoirs located in the Han River Basin in South China during wet and dry seasons. Structural Equation Modelling (SEM) and Generalized Dissimilarity Modelling (GDM) were employed to validate the response of phytoplankton species and functional group alpha-beta diversities to environmental variables. The results indicated that the community compositions of phytoplankton in eutrophic reservoirs were similar between wet and dry seasons, while there were distinct differences for community composition in oligotrophic-mesotrophic reservoirs between the two seasons. Across all reservoirs, there were no significant differences in alpha and beta diversities of species and functional groups between wet and dry seasons. The SEM and GDM results revealed that total phosphorus was the primary driving factor influencing alpha and beta diversities of species and functional groups in the 23 reservoirs. Meanwhile, the non-linear results of species beta diversity were stronger than the non-linear results of functional group beta diversity, indicating that phytoplankton species exhibited a higher explanatory power in responding to environmental changes compared to that of functional groups. Compared to that of species beta diversity, the response of functional group beta diversity to environmental variables was significantly lower in the dry season. These research findings lead to re-evaluating the common practice relating to the use of phytoplankton functional groups to assess environmental conditions, which may overlook the explanatory power of subtle changes at the species level, especially during periods of habitat diversification in the dry season.

An end-Permian two-stage extinction pattern in the deep-water Dongpan Section, and its relationship to the migration and vertical expansion of the oxygen minimum zone in the South China Basin

The diversity and last appearance patterns of different taxa, inhabiting varied palaeo-water depths, can provide significant insights into the deterioration process of palaeoecosystems. This paper systematically summarizes the last appearance of the end-Permian planktons (including deep-water, intermediate-water, and shallow-water radiolarians) and benthos (including ostracods, foraminifers, brachiopods and bivalves) from Dongpan, a deep-water section of South China. Results show that the deep-water radiolarian Albaillellaria was the first order to go extinct, quickly followed by the intermediate- and shallow-water radiolarians and bottom-water ostracods and foraminifers. This was followed by the extinction of the bottom-water brachiopods and bivalves. We propose that the two-stage extinction pattern was related to the end-Permian migration and vertical expansion (both upward and downward) of an oxygen minimum zone (OMZ) along the southern margin of South China.

Moisture sources of precipitation over the Pearl River Basin in South China

AbstractMoisture sources and transport processes play a critical part in hydrological cycle and determine regional precipitation. This paper utilizes the Water Accounting Model‐2layers (WAM‐2layers) and the ERA5 reanalysis data to track the sources of precipitation over the Pearl River Basin (PRB). The contribution of external moisture and the role of local recycling are investigated. The results show that during the period from 1980 to 2020, oceanic sources including the western North Pacific and Indian Oceans serve as the primary moisture sources of precipitation over the PRB. The contributions to total seasonal precipitation are respectively 62.57% in MAM, 54.79% in JJA, 43.70% in SON and 60.88% in DJF. By contrast, the contribution of local recycling is generally below 5.50%. In the dry years of 1994, 1997 and 2001, the contribution of terrestrial sources is about 19.22%; in the wet years of 1989, 2009 and 2011, the contribution is about 16.31%. The summer precipitation anomalies are mainly attributable to moisture anomalies from the Equatorial Indian Ocean in the wet years and from Southeast Asia in the dry years. Furthermore, vertically integrated moisture flux anomalies over the boundaries of the PRB are generally the result of anomalous wind rather than anomalous moisture. In the wet years, low‐pressure systems induce strong cyclonic moisture transports, increasing the PRB precipitation. In the dry years, high‐pressure anomalies over the PRB block the moisture transports from the Indian Ocean and western North Pacific.

New record of conifer wood Agathoxylon from the Upper Jurassic in the Sichuan Basin, southern China, and its palaeobiodiversity and palaeoclimatic significance

ABSTRACT Although abundant and diverse foliage fossils are well recorded in the Upper Triassic and Lower–Middle Jurassic of the Sichuan Basin in South China, the Upper Jurassic plant fossils are rarely documented due to extensively developed red beds in this basin. Decades ago, abundant fossil wood specimens were discovered from the Upper Jurassic Penglaizhen Formation in the Sichuan Basin. However, detailed investigations on the systematic palaeobotany of these wood fossils are very limited, which hinders further understanding of the terrestrial ecosystem and biota. Here, we describe anatomically well-preserved fossil wood specimens from the Penglaizhen Formation at Wangjiagou Village of Shehong City in the central Sichuan Province. These wood fossils exhibit Agathoxylon anatomy with usually uniseriate contiguous radial tracheid pitting and araucarioid cross-field pitting, representing a new record of Agathoxylon in the Sichuan Basin, and contribute to further understanding of the vegetation composition of the southern phytoprovince in China during the Late Jurassic. Independent palaeoclimatic evidence from leaf, pollen and sediments indicates that the Agathoxylon trees from Shehong area have grown under generally hot and semi-arid or arid environmental conditions, probably in habitats at the banks of rivers and lakes with locally abundant water supply, as indicated by the indistinct growth rings.

Dynamics of Land Use/Land Cover Considering Ecosystem Services for a Dense-Population Watershed Based on a Hybrid Dual-Subject Agent and Cellular Automaton Modeling Approach

Land use/land cover represents the interactive and comprehensive influences between human activities and natural conditions, leading to potential conflicts among natural and human-related issues as well as among stakeholders. This study introduced economic standards for farmers. A hybrid approach (CA-ABM) of cellular automaton (CA) and an agent-based model (ABM) was developed to effectively deal with social and land-use synergic issues to examine human–environment interactions and projections of land-use conversions for a humid basin in south China. Natural attributes and socioeconomic data were used to analyze land use/land cover and its drivers of change. The major modules of the CA-ABM are initialization, migration, assets, land suitability, and land-use change decisions. Empirical estimates of the factors influencing the urban land-use conversion probability were captured using parameters based on a spatial logistic regression (SLR) model. Simultaneously, multicriteria evaluation (MCE) and Markov models were introduced to obtain empirical estimates of the factors affecting the probability of ecological land conversion. An agent-based CA-SLR-MCE-Markov (ABCSMM) land-use conversion model was proposed to explore the impacts of policies on land-use conversion. This model can reproduce observed land-use patterns and provide links for forest transition and urban expansion to land-use decisions and ecosystem services. The results demonstrated land-use simulations under multi-policy scenarios, revealing the usefulness of the model for normative research on land-use management.

Towards the hydrological effects of land use change in karst area, a case study in Lijiang River Basin, China

With economic and social development, the inevitable conflict between growing populations and land use change has become increasingly prominent. In karst areas, such as the Lijiang River Basin (LRB) in South China, land use has undergone rapid and intense changes over the past few decades due to urbanization and agricultural development. Assessing the hydrological effects of future land use change scenarios in karst areas is essential for estimating potential flood risks. In this study, we constructed hydrological models for the LRB based on a widely used hydrological model (SWAT, Soil and Water Assessment Tool), analyzed the runoff coefficient (Rc) at event scale, and evaluated the hydrological effects under future land use scenarios in 2100 based on five shared socio-economic pathways (SSPs). The results indicate that the simulated streamflow effectively replicated the hydrographs of the LRB. The model exhibited good performance, as evidenced by daily streamflow simulation with NSE greater than 0.65 and PBIAS within the range of ± 15 %. This demonstrates the applicability of SWAT in karst areas. The analysis of storm events revealed that severe storms in the LRB mainly took place between April and July and in November, with relatively long durations and high Rc values. Under all five SSP-based future land use scenarios, it is predicted that flood risk will increase in the LRB. Notably, the severity of flood events during the dry season is expected to escalate, with Rc potentially increasing by up to 16 %. To address environmental degradation and achieve sustainable development, it is imperative to adopt appropriate environment-friendly land use practices and implement effective land management strategies.

Lower to Middle Triassic conodont biostratigraphy and carbonate carbon isotope chemostratigraphy of the Zuodeng area, Guangxi, South China, and its relevance for stratigraphic correlation from the Induan to the Anisian

The Nanpanjiang Basin in South China is a vital area for studying the Early Triassic marine ecosystem recovery in the aftermath of the end-Permian mass extinction (EPME). The Zuodeng sections (A, B, and C) are located on the Debao platform, one of the isolated shallow-water platforms within the Nanpanjiang Basin. This area preserves a relatively complete conodont succession from the Lower Triassic to the lower Middle Triassic. Here, a total of 12 conodont zones and 4 subzones are established, namely, the Hindeodus postparvus Zone, the Hindeodus sosioensis Zone, the Neoclarkina krystyni Zone, the Neoclarkina discreta Zone, the Neospathodus dieneri Zone (including the Neospathodus dieneri M1 and Neospathodus dieneri M3 subzones), the Neospathodus cristagalli Zone, the Neospathodus pakistanensis Zone, the Novispathodus waageni eowaageni Subzone, the Novispathodus waageni waageni Subzone, the Neospathodus yangtzeensis-Novispathodus shani Zone, the Novispathodus pingdingshanensis Zone, the Triassospathodus homeri Zone, the Neospathodus triangularis Zone and the Chiosella timorensis Zone.The Permian-Triassic boundary is placed at the base of Bed 48 in the Zuodeng A section, coinciding with the base of the widespread microbialite beds and the carbon isotope excursion. The Induan-Olenekian boundary is placed at the bases of Bed 86 and Bed 21 in the Zuodeng A and Zuodeng B sections, respectively, where Nv. ex gr. waageni occurs at or slightly below the peak of the positive δ13Ccarb excursion. The Smithian-Spathian boundary is recognized at the bases of Bed 92 and Bed 33 in the Zuodeng A and Zuodeng B sections, respectively, based on the first occurrence (FO) of Nv. pingdingshanensis near the middle point of the positive δ13Ccarb excursion. The Olenekian-Anisian boundary is drawn at the top of Bed 5 in the Zuodeng C section based on the FO of Ch. timorensis. The conodont zones recognized in the Zuodeng area correlate well with sections in South China and elsewhere worldwide. The Ns. yangtzeensis-Nv. shani Zone is newly established, and the recognition of this zone in several sections significantly improves the accuracy of stratigraphic subdivision and correlation of the Smithian. The conodont zones in the Zuodeng area thus provide a high-precision time scale for future studies on marine ecosystem recovery in the aftermath of the EPME and environmental events during the Early Triassic.

Dynamic evolution of marine productivity, redox, and biogeochemical cycling track local and global controls on Cryogenian sea-level change

The Cryogenian period of the Neoproterozoic was marked by two Snowball Earth glaciations that bookended a non-glacial interval that lasted roughly 10 million years. The break-up of Rodinia in the early Neoproterozoic gave rise to numerous rift basins whose time-varying redox dynamics, linked to marine productivity and biogeochemical cycling, were likely controlled by varying degrees of basin restriction in response to sea-level change. Those drivers were associated with both global glaciations (Sturtian deglaciation and the possibly early onset of the Marinoan) and local tectonics (regional basin uplift/subsidence). To explore these relationships, we focus on the Datangpo Formation, an exceptional shale sequence deposited in a marginal rift basin in South China. The Datangpo succession comprises lower organic-rich black shales and upper organic-lean gray shales/siltstones. As elucidated by our integrated data, the former were deposited in H2S-rich, deep-water settings underlying highly productive surface waters. We attribute this productivity to elevated nutrient supplies replenished from the open ocean following a sea-level rise, as augmented by high terrestrial input of phosphate in the wake of the Sturtian deglaciation. By contrast, the gray shales/siltstones were associated with relatively shallow deposition in an oxic/suboxic water column with suppressed primary production. The major driver of this dramatic shift in water chemistry may lie with a greater extent of basin isolation and the corresponding reduction in nutrient fluxes from the global ocean due to a significant sea-level fall—possibly linked to regional basin uplift. At this time, the basin experienced an elevated influx of detrital clays and organic material, perhaps triggered by lower sea level. Surprisingly, we found that euxinic conditions prevailed in the water column for a substantial period following the onset of more isolated conditions. This relationship can be attributed to redox-dependent phosphorus cycling. Specifically, H2S-replete conditions facilitated regeneration of bioavailable phosphorus, initiating a positive feedback that allowed the persistence of anoxic waters. This study advances our understanding of nutrient cycling and biogeochemical evolution during the Cryogenian under the influence of large-scale sea-level fluctuations and associated time-varying connectivity to the open ocean that must have been common in many basins at this time. Furthermore, our study sheds novel light on the iron proxy and early sulfur cycling. Almost all of the terrestrial silicate-bound iron was likely converted into highly reactive phases due to strong chemical weathering, while sulfur data revealed isotopic stratification in the wake of Sturtian deglaciation, with important messages for interpretations of analogous data in the aftermath of other climate upheavals in Earth history.

Interannual variations of westward extension area of western Pacific subtropical high and its relationship with precipitation in East Asia

The western Pacific subtropical high (WPSH) is viewed as an important part of the East Asian summer monsoon system and its western boundary location significantly affects regional weather and climate. Based on characteristics of the WPSH western boundary in boreal summer, this study proposes a new index of WPSH, the westward extension area (WEA) index, defined as the area enclosed by the 587 dagpm contour in the region (10°–50°N, 105°–130°E), which can reasonably describe the area variations of WPSH when approaching and landing coastal regions. Compared with the canonical area index of WPSH, the WEA index can more effectively represent the WPSH-associated atmospheric circulation, water vapor transport, and convective activities in the boreal-summer East Asia-northwestern Pacific. A big WEA index significantly indicates flood in the middle reaches of Yangtze River basin and drought in South China. The WEA of WPSH has a significant connection with precipitation in Maritime Continent, due to the convection-circulation interaction in Philippine Sea. There, the WPSH-related sea surface temperature (SST) cooling and rainfall deficiency can excite Rossby waves, which induces the anomalous anticyclone development and the westward stretching and intensifying of WPSH that in turn further reduces rainfall in Philippine Sea. Moreover, the WEA index is significantly modulated by the preceding El Niño-type and tropical Indian Ocean SST anomalies, which may provide a highly predictable indicator of the continental precipitation in East Asia.

Paleostress reconstruction of the Chaling-Yongxing basin in the central South China Block: Bulk (areal or multisite) vs. site stress tensors

A critical problem in fault-slip data stress analysis is separating the heterogeneous fault-slip data into homogeneous subsets. Recent attempts to solve this problem use tectonostratigraphic criteria based on the age of the sites where site stress tensors are calculated with a best-fit stress inversion method. The present study calculates bulk (areal or multisite) stress tensors from fault-slip data published in the Chaling-Yongxing Basin (CYB) in central South China with the Tensor Ratio Method (TRM). These tensors are compared with published site stress tensors to examine whether bulk or site stress tensors define regional or local stress regimes and similar or not paleostress history. Two regional stress regimes for the Late Cretaceous-Paleogene period, describing an older Late Cretaceous stage with transpression-strike-slip (TRP-SS) tectonics (NNE-SSW contraction and WNW-ESE extension) and a younger Paleogene stage with radial-pure (RE-PE) extensional tectonics (WNW-ESE extension), are defined. These stages are interpreted to be transitive through a transtension (TRN) tectonics of similar WNW-ESE extension and responsible for the formation and evolution of the CYB under tectonic processes related to the India-Asia collision and the retreat of the (Paleo)Pacific plate. The present analysis shows that tectonostratigraphic criteria based on the age of the exposed rocks might be insufficient for the coherent correlation of stress tensors resolved in sites of limited size and, thus, for unraveling the paleostress history of a region.

Runoff Prediction in the Xijiang River Basin Based on Long Short-Term Memory with Variant Models and Its Interpretable Analysis

The Long Short-Term Memory (LSTM) neural network model is an effective deep learning approach for predicting streamflow, and the investigation of the interpretability of deep learning models in streamflow prediction is of great significance for model transfer and improvement. In this study, four key hydrological stations in the Xijiang River Basin (XJB) in South China are taken as examples, and the performance of the LSTM model and its variant models in runoff prediction were evaluated under the same foresight period, and the impacts of different foresight periods on the prediction results were investigated based on the SHapley Additive exPlanations (SHAP) method to explore the interpretability of the LSTM model in runoff prediction. The results showed that (1) LSTM was the optimal model among the four models in the XJB; (2) the predicted results of the LSTM model decreased with the increase in foresight period, with the Nash–Sutcliffe efficiency coefficient (NSE) decreasing by 4.7% when the foresight period increased from one month to two months, and decreasing by 3.9% when the foresight period increased from two months to three months; (3) historical runoff had the greatest impact on streamflow prediction, followed by precipitation, evaporation, and the North Pacific Index (NPI); except evaporation, all the others were positively correlated. The results can provide a reference for monthly runoff prediction in the XJB.

Predictive simulation and optimal allocation of surface water resources in reservoir basins under climate change

Predicting and allocating surface water resources are becoming increasingly important tasks for addressing the risk of water shortages and challenges of climate change, especially in reservoir basins. However, surface water resource management includes many systematic uncertainties and complexities that are difficult to address. Thus, advanced models must be developed to support predictive simulations and optimal allocations of surface water resources, which are urgently required to ensure regional water supply security and sustainable socioeconomic development. In this study, a soil and water assessment tool-based interval linear multi-objective programming (SWAT-ILMP) model was developed and integrated with climate change scenarios, SWAT, interval parameter programming, and multi-objective programming. The developed model was applied to the Xinfengjiang Reservoir basin in South China and was able to identify optimal allocation schemes for water resources under different climate change scenarios. In the forecast year 2025, the optimal water quantity for power generation would be the highest and account for ∼60% of all water resources, the optimal water quantity for water supply would account for ∼35%, while the optimal surplus water released from the reservoir would be the lowest at ≤5%. In addition, climate change and reservoir initial storage would greatly affect the surplus water quantity but not the power generation or water supply quantity. In general, the SWAT-ILMP model is applicable and effective for water resource prediction and management systems. The results from different scenarios can provide multiple alternatives to support rational water resource allocation in the study area.

Age and origin of a Guadalupian tuff in the E'Xi rift basin in South China: Evidence for the Emeishan continental hotspot track?

AbstractUnlike oceanic hotspot tracks, continental hotspot tracks are difficult to recognise, although they can provide unique insights into crustal deformation and intraplate magmatism. Here, we present whole‐rock geochemical and Sr–Nd isotope, and zircon U–Pb age and Hf isotope data for a tuff from the E'Xi rift basin in the South China Block. The zircons yielded a 206Pb/238U age of 267.0 ± 2.0 Ma, which coincides with the Roadian–Wordian boundary. The whole‐rock geochemical and Sr–Nd isotope data for the tuff indicate it had a mixed mantle–crust source. The zircon trace element and εHf(t) (−6.32 to +7.06) data are also consistent with such a source. Based on the sedimentological and tectonic history, and the geochronology and geochemistry of the tuff, we propose the tuff erupted in a rift and records the hidden hotspot track of the Emeishan mantle plume beneath the northern SCB.

Sensitivity Analysis of Oil and Gas Production in the In Situ Pyrolysis of Oil Shale

The Maoming basin in south China is rich in oil shale resources, whereas the Youganwo formation is a potential area for large-scale in situ exploration because of its relatively large thickness, high oil content, and good continuity. Based on previous geologic studies on the Maoming basin and the laboratory experimental data, in situ pyrolysis models for shale oil are established using the CMG-STARS software to simulate the in situ heating and reactions. To analyze the major influencing factors, the CMOST module is employed to conduct the sensitivity analysis with accumulated oil and gas production as the target functions. The initial kerogen concentration, formation permeability, activation energy of pyrolysis reaction, frequency factor, heating rate, heating power, heat loss, heat conductivity, heat capacity, and bottom-hole pressure are chosen to be the controlling parameters. A total of 128 cases are calculated for each target function with the fractional factorial sampling method. The sensitivity analysis results demonstrate that the heating power, initial kerogen concentration, and reaction activation energy are the major influencing factors for oil and gas production. The simulation results also reveal that high non-uniformity of the temperature field will cause the light oil to convert to gas and char at the high-temperature zone near the heater well. It is suggested that proper control of formation temperature, such as increasing permeability to promote oil and gas flow and form a more uniform temperature field, will help to prevent oil production loss caused by secondary reactions.

Copula-based comprehensive drought identification and evaluation over the Xijiang River Basin in South China

The reasonable and appropriate drought indicator is a crucial instrument for drought investigation and assessment, which can objectively compare the severity, duration, and frequency of drought events, so as to achieve the purpose of accurately monitoring and evaluating drought. However, a univariate drought index is often difficult to precisely describe the complex drought situation, and it is urgent to establish a multivariate comprehensive drought index to identify and reveal the drought characteristics. Based on Copula models, combined with meteorological factors precipitation and hydrological factors runoff, this paper constructed a Multivariate Standardized Drought Index (MSDI), which can characterize meteorological drought and hydrological drought simultaneously and evaluate the spatial–temporal evolution characteristics of drought over the Xijiang River Basin (XJB) in South China. The results indicated that: (1) the proposed MSDI can capture the occurrence of drought as sensitively as the Standardized Precipitation Index (SPI), and can represent the termination of drought as effectively as the Standardized Runoff Index (SRI), which can comprehensively depict the drought situation in the XJB, China; (2) since the 1980 s, there was a tendency of aridity with a mutation point of 1983 in the downstream of Xijiang River (DXJB), and the worst comprehensive drought occurred in 1989; (3) among the tributaries, the comprehensive drought severity was the heaviest in the DXJB, with an average MSDI value of –0.75; (4) based on the run theory and Copula model, the most serious drought event occurred from September 1988 to October 1990, with a drought severity of 33.36, a drought duration of 27 months, and a drought return period exceeding 50 years; and (5) the drought evolution was significantly influenced by abnormal atmospheric circulation factors, while ENSO had the largest influence on the drought variation in the XJB, followed by sunspot.

Study on the driving mechanism of lagged effects based on different time scales in a karst drainage basin in South China

Compared to earthquakes and volcanoes, drought is one of the most damaging natural disasters and is mainly affected by rainfall losses, especially by the runoff regulation ability of the underlying watershed surface. Based on monthly rainfall runoff data recorded from 1980 to 2020, in this study, the distributed lag regression model is used to simulate the rainfall-runoff process in the karst distribution region of South China, and a time series of watershed lagged-flow volumes is calculated. The watershed lagged effect is analyzed by four distribution models, and the joint probability between the lagged intensity and frequency is simulated by the copula function family. The results show that (1) the watershed lagged effects simulated by the normal, log-normal, P-III and log-logistic distribution models in the karst drainage basin are particularly significant, with small mean square errors (MSEs) and significant time-scale characteristics. (2) Affected by spatiotemporal distribution differences in rainfall and the impacts of different basin media and structures, the lag response of runoff to rainfall differs significantly among different time scales. Especially at the 1-, 3- and 12-month scales, the coefficient of variation (Cv) of the watershed lagged intensity is greater than 1, while it is less than 1 at the 6- and 9-month scales. (3) The lagged frequencies simulated by the log-normal, P-III and log-logistic distribution models are relatively high (with medium, medium–high and high frequencies, respectively), while that simulated by the normal distribution is relatively low (medium–low and low frequencies). (4) There is a significant negative correlation (R < − 0.8, Sig. < 0.01) between the watershed lagged intensity and frequency. For the joint probability simulation, the fitting effect of the gumbel Copula is the best, followed by the Clayton and Frank-1 copulas, and while that of the Frank-2 copula is relatively weak. Consequently, the propagation mechanism from meteorological drought to agricultural or hydrological drought and the conversion mechanism between agricultural and hydrological drought are effectively revealed in this study, thereby providing a scientific basis for the rational utilization of water resources and drought resistance and disaster relief in karst areas.

Seismically imaged lithospheric delamination and its controls on the Mesozoic Magmatic Province in South China

The current lithospheric root of the South China Block has been partly removed, yet what mechanisms modified the lithospheric structure remain highly controversial. Here we use a new joint seismic inversion algorithm to image tabular high-velocity anomalies at depths of ~90–150 km in the asthenosphere beneath the convergent belt between the Yangtze and Cathaysia blocks that remain weakly connected with the stable Yangtze lithosphere. Based on obtained seismic images and available geochemical data, we interpret these detached fast anomalies as partially destabilized lower lithosphere that initially delaminated at 180–170 Ma and has relaminated to their original position after warming up in the mantle by now. We conclude that delamination is the most plausible mechanism for the lithospheric modification and the formation of a Mesozoic Basin and Range-style magmatic province in South China by triggering adiabatic upwelling of the asthenosphere and consequent lithospheric extension and extensive melting of the overlying crust.

Basin‐Scale CO2 Emissions From the East River in South China: Importance of Small Rivers, Human Impacts and Monsoons

AbstractRiverine carbon dioxide (CO2) emissions are an essential component of the riverine carbon cycle, but an accurate assessment of riverine CO2 emission fluxes is still hindered by the spatial and temporal variations among river basins caused by differences in climate, watershed characteristics, and human activity. Here, we evaluate the riverine CO2 flux from the subtropical East River Basin (ERB) in south China, a region strongly affected by monsoon climate and anthropogenic land use changes. Our results suggest small rivers are major contributors to riverine CO2 emissions, even with relatively low CO2 concentrations and small water surface areas (SAs). They contribute disproportionately to 74.4% of the total fluxes due to high gas transfer velocity (k) across the water‐air interface. Land use changes have substantially enhanced CO2 emissions from river networks. Normalized areal riverine CO2 fluxes in the urban‐ and cropland‐dominated Middle and Lower ERB (27.6 and 39.4 g C m−2 yr−1) were two and three times higher than the 9.1 g C m−2 yr−1 in the forest‐dominated Upper ERB. Due to the larger water SA and higher k caused by monsoon‐induced precipitation, the East River acts as a stronger carbon source during the wet season, emitting 0.67 Tg C yr−1 to the atmosphere, which is about twice that during the dry season (0.33 Tg C yr−1). Our study illustrated how monsoon climate and land use in the ERB have regulated its riverine CO2 emissions. Our findings also provided valuable insights into the role of small rivers in the basin‐wide carbon cycle.

Enrichment of mercury in the Lower Cambrian sedimentary successions by submarine hydrothermal venting

• Widespread sedimentary Hg enrichments in the Early Cambrian can be attributed to periodic hydrothermal ventilation. • Prevailing hydrothermal ventilation was an important source of Hg in sediments in the Early Cambrian. • The accumulation of Hg in sediments may be more effective in euxinic environments. Although extremely high Hg contents are known in the Lower Cambrian sedimentary successions, the extent and spatial-temporal distribution of sedimentary Hg anomalies in these successions remain unclear. Here, we report concentrations of Hg, total organic carbon (TOC), total sulfur (TS), and major and rare earth elements of the Lower Cambrian (∼525 Ma) sedimentary rocks at the Dongxihe section in the interior of the Yangtze Platform, South China. We investigated the sedimentary Hg enrichment mechanism and the spatial-temporal fluctuations of Hg in the Lower Cambrian and compiled published Hg (Hg/TOC) data from the Upper Neoproterozoic to the Lower Cambrian to trace the potential Hg sources. Our study verified that hydrothermal vents provide an excess Hg source for the sedimentary Hg enrichment in the Dongxihe section, which is supported by the positive Eu anomaly and major element. The major elements show more Fe and Mn enrichment in the upper part than the lower part, indicating more hydrothermal contribution in the upper part. Additionally, the records of the spatial-temporal distribution of Hg show that most of the sections (including shelf, slope, and basin) in South China show strong sedimentary Hg enrichment, which can be attributed to widespread hydrothermal venting. By reconstructing fluctuations of Hg during the Late Neoproterozoic to the Early Cambrian, we proposed that in the context of the Gondwana continent assembly, the prevalent hydrothermal ventilation event during the Early Cambrian not only induced the abnormal enrichment of sedimentary Hg but also played a crucial role in shaping the marine environment and ecosystem during this period.