Use Of Sources Research Articles

Using a Monte Carlo simulation to analyze the ideal activity for a phosphorus-32 polymeric brachytherapy source for paraspinal tumors

A promising radioactive source for use in intracavitary brachytherapy is phosphorus-32. This source has been prominent as a minimally invasive treatment for craniopharyngiomas and in the treatment of metastatic bone diseases in general and has been developed at Nuclear and Energy Research Institute (IPEN). In this work, a Monte Carlo simulation was used to evaluate the ideal activity this source must have to deliver a 1 Gy/min dose rate. TOPAS was used to model the simulation, and its geometry was simulated with the source centered in the origin point, inserted into an isotropic volume of water of 17.42 cm3. The source has the decay properties of phosphorus-32. The total dose was calculated using volumetric scorers. The results were promising, showing that the initial activity must be 86.14 mCi or 2871 MBq to obtain the 1 Gy/min dose rate. With the initial activity measured in this work, it is possible to minimize the patient’s exposure to radiation, while ensuring the quality of the treatment.

Environmental deterioration, renewable energy, natural resource rents, and schooling in Türkiye: Does the degree of energy transition matter for environmental quality?

Within the literature on energy and environmental economics, it is generally acknowledged that renewable energy can improve environmental quality; however, certain papers suggest that an optimal level of the usage of renewable energy sources may exist. Consequently, the utilization of renewable energy sources can result in environmental degradation up to a certain threshold. Then, environmental quality can be enhanced through the continued application of renewables. This indicates that the link between renewable energy and environmental devastation is inverted U-shaped.This paper presents empirical evidence concerning this possible association between renewable energy and environmental destruction in Türkiye, a country where fossil energy predominates in the energy mix. Additionally, the paper investigates the environmental influences of natural resource rents and schooling. This study utilizes annual data from 1971 to 2020 and implements time series methodologies that rely on the Fourier approximation. The paper thus accounts for an undetermined quantity of structural breaks. The results suggest that an inverted U-shaped link occurs between renewable energy and environmental destruction, signifying renewable energy initially contributes to a diminution in environmental quality before subsequently improving it. Additionally, environmental quality is positively associated with natural resource rents and negatively associated with schooling, according to the findings. Furthermore, the findings reveal that schooling worsens the combined effect of renewable energy on environmental degradation. These conclusions are discussed in the paper.

Comparative analysis of hydrogen production, accumulation, distribution, and storage systems

The global energy demand in the world continues to grow and environmental pollution caused by fossil fuels becomes increasingly serious, the development and utilization of new energy sources has become a hot topic of global concern. The development and utilization of new energy sources is one such possible solution, which can provide clean, renewable energy and thus reduce the impact on the environment. Hydrogen, as a clean, productive, carbon-free secondary energy source, has the potential to be used as a fuel and essential substance for different fields such as heating, transportation, industry, and power generation. As the international community strives to achieve a shift toward a more eco-conscious and sustainable future, hydrogen has received extensive research and attention due to its abundant resources and environmentally friendly properties. The main objective of this study was to describe and comparatively analyze the efficient production, accumulation, distribution and storage of hydrogen. Today the production of hydrogen is centered on the creation or extraction of hydrogen from primary energy sources. The accumulation of hydrogen involves the preservation of surplus hydrogen for subsequent utilization. The distribution of hydrogen encompasses the conveyance and delivery of hydrogen. The storage systems for hydrogen pertain to the technologies and infrastructure employed to retain hydrogen for future deployment. In complex, these constituents establish a comprehensive hydrogen value chain that facilitates the generation, preservation, and distribution of hydrogen as a sustainable and environmentally friendly energy solution. Keywords: comparative analysis, hydrogen, production, accumulation, distribution, storage systems.

Strategies for economic sustainability: An empirical study on Muri, Mura, and Muda in the readymade garment sector

Achieving economic sustainability in the garment manufacturing industry necessitates the implementation of several strategic measures. Basic strategies like adoption of automation, utilization of sustainable energy sources, diversification of markets and products, enhancement of supply chain resilience, etc. lead to the attainment of economic sustainability in the garment manufacturing industry. Additionally, the underlying component of these strategies for ensuring economic sustainability is the minimization of process waste, which can be effectively achieved through the application of lean manufacturing principles, specifically targeting the elimination of Muri, Mura, and Muda. This strategic commitment ensures business longevity amid evolving industrial landscapes, fostering innovation and competitiveness. In emerging economies like Bangladesh, pinpointing precise approaches to reduce waste is vital. This study explores into Muri, Mura, and Muda in the RMG sector, utilizing Pareto analysis, Fuzzy theory, Total Interpretative Structural Modeling (TISM), and Matriced’ Impacts Cruoses Multiplication Applique an un Classement (MICMAC) analysis. After the initial identification of 21 (twenty) factors, Pareto analysis pinpointed the primary 16 (sixteen) factors. Subsequently, these factors underwent analysis through fuzzy TISM and fuzzy MICMAC. The results highlighted “Demand variation”, “Supplier variation”, “Workforce variation”, and “Energy supply variation” as the most crucial factors. The novelty of this study lies in exploring Muri and Mura factors in correlation with Muda employing the existing hybrid and effective methodology that combines Pareto analysis, Fuzzy MICMAC, and Fuzzy TISM methodologies. It offers fresh perspectives on their significance for economic sustainability in the garment sector. Prior research has not explored this integrated approach to reduce process waste by addressing Muri and Mura factors in emerging economies’ garment industries. This research is poised to significantly impact waste reduction in the RMG sector, enhancing competitiveness, appealing to environmentally conscious consumers, and ensuring industry standards adherence essential for sustained success. The contribution of this research is grounded in helping the practitioners and entrepreneurs in developing nations make strategic choices that will lead to the RMG sector’s resilience and, ultimately, economic sustainability.

Decentralized Smart Energy Management in Hybrid Microgrids: An Evaluation of Operational Modes, Resource Optimization, and Environmental Impacts in Nigeria

Escalating energy demands and climate change challenges necessitate the adaptation of renewable-based microgrid systems in the energy sector. The proposed work employs a robust Multi Agent System (MAS) technique to achieve efficient and automated control of the hybrid microgrid operation. The hybrid microgrid system incorporates Renewable Energy Sources (RES), a diesel generator, and a battery storage system. The operation of the hybrid microgrid consists of three distinct modes: islanded, transition to grid, and grid-oriented mode. The system’s performance is optimized by considering factors like climatic patterns, energy costs, connected source characteristics, and load demand. Different climatic scenarios are assessed for each mode of operation, where the best, extreme sunny, extreme cloudy, and worst climate conditions are considered for islanded mode; sunny and cloudy scenarios are considered for transition to grid mode as well as grid-feed and grid-tied modes are considered for grid-oriented operation of the microgrid. The simulation studies are performed using the MATLAB/Simulink R2021a environment. Furthermore, Particle Swarm Optimization (PSO) is implemented to optimize power allocation within the microgrid and enhance its cost-effectiveness. The optimization results demonstrate efficient utilization of available energy sources along with effective energy management facilitated by the MAS control system. The results emphasize the importance of adopting a MAS approach for achieving smart energy management through comprehensive analysis and integrating decentralized energy management techniques for optimal accommodation of distributed energy resources in hybrid microgrids

2023년 행정법 중요 판례 평석: 건설행정법 판례를 중심으로

The Supreme Court sentenced a number of meaningful administrative law rulings in 2023. Many of them are based on individual public law regulations and specific problems arising from them. In this article, several rulings related to the ‘Public Construction Law’ were selected and examined. ① The Supreme Court’s sentence of 2022DU31143 on September 21, 2023 confirms once again that it is necessary to obtain ’the legal status of being allowed to development’for construction in addition to securing a source of use of land. It is meaningful in that it declared that the above requirements are also necessary for notification of building construction. Considering the judgment, it has been more clearly confirmed that the notification of building construction is bound to be regarded as a notification requiring acceptance, and the need for a legislative review of the overall building construction notification system emerges. ② The Supreme Court’s sentence of February 2, 2023, 2020DU43722 is a question of whether the guidelines for the operation of development permission, which are orders of the Ministry of Land, Infrastructure and Transport prepared based on Article 56 (4) of the Enforcement Decree of the National Land Planning Act, are externally binding legal orders. Aside from the evaluation of the conclusions of the judgment, the judgment provides various issues regarding the handling of administrative rules and normative control. ③ The Supreme Court’s ruling on February 23, 2023, 2020Du36724 is meaningful in that it revealed the relationship between members and landowners in housing redevelopment projects in accordance with the Urban Improvement Act, and that the right to receive a house in housing redevelopment projects should be based on the status of members. ④ The Supreme Court’s ruling on October 18, 2023, 2023DU42584 dealt directly with whether indemnity for possession of state property can be imposed on a person who is in a legal position to justify the possession and use of state property but does not get a use permit or sign loan contract. Although we can accept the conclusion of the judgment, it raises the question of the court’s interpretation of the law and its limitations. The above two judgments are examples of how the purpose of a public law can be considered in the interpretation and application of individual public law regulations, and provide implications regarding the legal interpretation method of administrative law.

EFFORTS OF THE TRANSPORT AND ENERGY SECTORS TOWARD RENEWABLE ENERGY FOR CLIMATE NEUTRALITY

The integration and utilization of renewable energy sources in the energy and transport sectors are the main actions undertaken to attain climate neutrality by 2050. The connection and indication of the relations occurring in these two sectors constitute the novelty of the current research. Key actions include increasing the share of low- and zero-emission transport, such as electric cars, bicycles, trains, and buses; reducing emissions from aviation and shipping; and improving energy efficiency and transport safety by modernizing the vehicle fleet, introducing intelligent transport systems, applying emission and fuel quality standards, and promoting technological and digital innovation. A novel and significant aspect of the research is its comprehensive approach to key economic sectors that exert a profound influence on climate change. Through the conducted studies, it has been demonstrated what essential actions must be undertaken to transition towards a low or zero-emission economy. This paper points to a strong nexus between the transport sector, the energy sector, and climate change, underscoring the imperative for collaborative efforts and strategic initiatives among these sectors to address the pressing challenges associated with achieving climate neutrality.

Energy mix management: A new look at the utilization of renewable sources from the perspective of the global energy transition

Energy mix management: A new look at the utilization of renewable sources from the perspective of the global energy transition

Forward osmosis membrane process: A review of temperature effects on system performance and membrane parameters from experimental studies

Forward osmosis (FO) offers a promising solution for concentration and material recovery, characterized by its low energy consumption and high separation efficiency. Temperature exerts a significant influence on FO, affecting permeation performance, membrane characteristics, and solution chemistry. The review article shows that increasing temperatures enhance forward permeate flux and solvent recovery by modifying mass transfer coefficients, membrane structure, and solution properties like osmotic pressure, diffusivity, and viscosity. This helps alleviate concentration polarization, a key challenge in FO applications. However, higher temperatures can exacerbate reverse solute flux, diminish solute rejection, and amplify membrane fouling, impacting operational efficiency and effluent quality. Studies involving thermoresponsive compounds or high-solute-content solutions yield conflicting results, further complicated by thermo-osmosis in scenarios with temperature gradients between solutions. In water and wastewater treatment, a huge quantity of solutions is treated, and temperature control is difficult. Managing solution temperatures through the utilization of waste hot streams or available heat sources can offer a viable strategy for enhancing system efficiency and mitigating the detrimental impacts of temperature fluctuations, while the solution volume should be effectively reduced before the treatment. A nuanced comprehension of temperature’s impacts is imperative for refining FO systems and addressing challenges across various industrial and environmental sectors.

The Dialectic of Teleological Journeys

Researchers’ attention has been drawn to parallels between Homer’s Odyssey and the Epic of Gilgamesh. However, hitherto, no connections have been observed between Kazantzakis’s Sequel and the Mesopotamian work. Convergent are the primary motivations and actions undertaken by the protagonists of both poems, particularly their “peregrinations” to the boundaries of the world, dictated by eschatological anxieties. Moreover, the hero of Kazantzakis’s Sequel undergoes a transformation analogous to the legendary ruler of Uruk: under the influence of concerns, the proud kings opt for solitary wanderings, which results in better self-understanding and higher axiological awareness. The comparison of symbols, such as the sun, fire, lightning, the Water of Life and Death, and theriomorphic allegories, indicates Kazantzakis’s utilization of numerous intermediary sources stemming from the ancient Near Eastern tradition. An additional aim of the article is to indicate interpretative possibilities of books describing the wanderings of the Odyssean spirit after abandoning the project of building the “ideal city,” as versions of ars moriendi: the art of overcoming the fear of death.

The combine impact of stock market, international investment and clean energy consumption on ecological footprint in emerging countries

Purpose Emerging nations strive to diminish their ecological impact to meet net-zero targets, yet encounter formidable hurdles in curbing their environmental footprint. This purpose necessitated the study into impact of stock market, renewable energy and international investment on the ecological footprint in emerging countries from 1990 to 2020. Design/methodology/approach The study used augmented mean group (AMG) estimator, cointegration and heterogenous panel causality approach. Findings Results from the AMG show that renewable energy consumption reduces environmental pollution in most countries except Mexico. The study disclosed that stock market capitalization decreases ecological footprint in emerging countries. Using both the Kao and Pedroni cointegration methods, the study affirms the existence of stable equilibrium relationship in the long term. The causality test concluded a bidirectional relationship between stock market and ecological footprint and a unidirectional link between international investment, clean energy and ecological footprint. Research limitations/implications The research is limited to only emerging countries. Therefore, future research should examine the environmental impacts of renewable energy consumption in different countries and regions, taking into account the local environmental conditions, policies and practices. This would help to identify the best practices and standards for minimizing the ecological footprint of renewable energy technologies and maximizing their benefits for environmental sustainability. Practical implications The study found that stock market capitalization reduces ecological footprint in Brazil, China, Turkey and India. To foster a culture of sustainability in stock market development impact, academic policies should emphasize the integration of environmental education across disciplines. By promoting awareness of the ecological consequences of stock market activities, societies can cultivate a mindset that values responsible economic practices. This, in turn, can lead to informed decision-making at individual and institutional levels. Social implications First, since the study found that clean energy reduces ecological footprint, advocating for utilization of clean energy sources could be a key priority in emerging countries. Governments should incentivize the development and adoption of renewable energy technologies, such as wind and solar power, by providing subsidies and tax benefits. Furthermore, increasing awareness among residents about the benefits of clean energy and promoting its utilization in both residential and commercial environments can expedite the transition to a more environmentally friendly energy combination. Originality/value First, it pioneers an exploration into the interplay between stock market capitalization, international investment, clean energy and ecological footprint in emerging countries. Secondary unlike, unlike prior research, this study uses methodologies that account for cross-sectional dependencies and a unique characteristic specific to each country. In addition, by using common correlated effects mean group, AMG, cointegration and causality procedures, this study distinctly isolates and analyzes empirical findings for each country, leading to policy-oriented outcomes.

The Phylogeny and Metabolic Potentials of an Aromatics-Degrading Marivivens Bacterium Isolated from Intertidal Seawater in East China Sea.

Lignocellulosic materials, made up of cellulose, hemicellulose, and lignin, constitute some of the most prevalent types of biopolymers in marine ecosystems. The degree to which marine microorganisms participate in the breakdown of lignin and their impact on the cycling of carbon in the oceans is not well understood. Strain LCG002, a novel Marivivens species isolated from Lu Chao Harbor's intertidal seawater, is distinguished by its ability to metabolize lignin and various aromatic compounds, including benzoate, 3-hydroxybenzoate, 4-hydroxybenzoate and phenylacetate. It also demonstrates a broad range of carbon source utilization, including carbohydrates, amino acids and carboxylates. Furthermore, it can oxidize inorganic gases, such as hydrogen and carbon monoxide, providing alternative energy sources in diverse marine environments. Its diversity of nitrogen metabolism is supported by nitrate/nitrite, urea, ammonium, putrescine transporters, as well as assimilatory nitrate reductase. For sulfur assimilation, it employs various pathways to utilize organic and inorganic substrates, including the SOX system and DSMP utilization. Overall, LCG002's metabolic versatility and genetic profile contribute to its ecological significance in marine environments, particularly in the degradation of lignocellulosic material and aromatic monomers.

The cytoplasmic phosphate level has a central regulatory role in the phosphate starvation response of Caulobacter crescentus

In bacteria, the availability of environmental inorganic phosphate is typically sensed by the conserved PhoR-PhoB two-component signal transduction pathway, which uses the flux through the PstSCAB phosphate transporter as a readout of the extracellular phosphate level to control phosphate-responsive genes. While the sensing of environmental phosphate is well-investigated, the regulatory effects of cytoplasmic phosphate are unclear. Here, we disentangle the physiological and transcriptional responses of Caulobacter crescentus to changes in the environmental and cytoplasmic phosphate levels by uncoupling phosphate uptake from the activity of the PstSCAB system, using an additional, heterologously produced phosphate transporter. This approach reveals a two-pronged response of C. crescentus to phosphate limitation, in which PhoR-PhoB signaling mostly facilitates the utilization of alternative phosphate sources, whereas the cytoplasmic phosphate level controls the morphological and physiological adaptation of cells to growth under global phosphate limitation. These findings open the door to a comprehensive understanding of phosphate signaling in bacteria.

High-efficiency, environment-friendly extraction of lithium from waste LAS glass-ceramics by roasting with KOH at low temperature

Recovering lithium from waste lithium aluminum silicate-based glass ceramics (LASGC) is one of the effective strategies to alleviate the shortage of lithium resources. Lithium extraction currently faces the problems of high energy consumption (>1000 °C) and secondary pollution. It is urgent to develop a high-efficiency, environment-friendly and low-temperature lithium extraction technology. In this work, KOH roasting combined with a water immersion strategy including lithium extraction, desilication, lithium precipitation, and the synthesis of silica hydroxyl intermediates was adopted to study the feasibility and advantages of lithium extraction from waste LASGC. When the roasting temperature is as low as 300 °C, the recovery rate of lithium can reach above 90 %, and the high-value conversion of solid waste in the whole process can be realized. In addition, the mechanism of lithium extraction was clarified through a series of characterizations. This work may provide a valuable reference for the efficient recovery and utilization of secondary lithium sources.

Robust co-planning of transmission expansion and merchant energy storage investments considering long- and short-term uncertainties

The decreasing cost of energy storage technologies and the increasing utilization of renewable energy sources have made distributed transmission-scale energy storage economically viable. Merchant energy storage investors can collect significant profits through spatiotemporal energy arbitrage from congested transmission lines. This paper formulates a three-stage, four-level min–min–max–min problem from the viewpoint of power system operators and planners such that they will build new transmission lines and identify potential locations for profitable merchant energy storage investments. The first level determines transmission expansion decisions from the system operator’s perspective. The second level plans potential investments in merchant energy storage to ensure profitability at a desired rate of return. The third level realizes the worst-case situations of long-term uncertainties related to the expansion of wind farms and peak load growth in each regional zone, while the fourth level simulates market clearing for representative days, modeling short-term uncertainties. A novel iterative nested column and constraint generation (C&CG) technique is adopted to cope with numerical issues caused by binary variables of transmission lines and storage blocks and the enormous size of the problem. The case study of a modified IEEE 24-bus test system was used to assess the effectiveness of the proposed algorithm.

Alternative Cover Crops and Soil Management Practices Modified the Macronutrients, Enzymes Activities, and Soil Microbial Diversity of Rainfed Olive Orchards (cv. Chetoui) under Mediterranean Conditions in Tunisia

In Tunisia, the olive is the most cultivated fruit crop in the northern region, where annual rainfall exceeds 400 mm. This olive-growing area is characterized by a wide coverage of marginal soil with a high slope gradient. Therefore, the inclusion of cover crops in olive orchards is a sustainable solution to enhance ecosystem productivity, improve soil fertility, and increase oil yields. This study aimed to investigate the short-term (two cropping seasons in 2021 and 2022) effects of different seeded cover crops and soil management practices on soil characteristics, as well as soil health by measuring soil enzyme activities and microbial diversity. Six cover crop types consisting of wheat, vetch, oat, fenugreek, a vetch–oat mixture, and spontaneous vegetation were tested in association with rainfed olive trees (cv. Chetoui) in the north of Tunisia and compared to a control (which was tilled periodically three times per year without intercropping). During the first cropping season, cover crops were cut as animal feed, and only residues were incorporated into the soil. However, during the second year, all cover crop biomass was incorporated into the soil. The results indicated that the dry biomass production and carbon uptake were significantly higher in grass species (wheat and oat). All of the cover crops, including the spontaneous vegetation, significantly increased soil organic matter (SOM) and macronutrient levels, mainly, available phosphorus. On the other hand, the highest level of soil nitrogen was found in the fenugreek cover crop. The soil enzyme activities in the cover crops of wheat, oat, and the vetch–oat mix were higher than those in the control. Together with the increase in soil organic matter (SOM), this demonstrates a significant improvement in soil health with cover crops. Furthermore, this study proves that the utilization of carbon sources was dominated by amides, amines, and amino acids in the fenugreek plot, while it was dominated by polymers and carboxylic acids in the case of the wheat and oat. Overall, this study demonstrates that seeding cover crops is a sustainable management practice not only to integrate livestock but also to improve soil health in semiarid olive orchards.

Potentials of roots, stems, leaves, flowers, fruits, and seeds extract for the synthesis of silver nanoparticles.

Silver nanoparticles (AgNPs) have gained significant attention in various applications due to their unique properties that differ from bulk or macro-sized counterparts. In the advancement of nanotechnology, a reliable, non-toxic, and eco-friendly green synthesis has widely been developed as an alternative method for the production of AgNPs, overcoming limitations associated with the traditional physical and chemical methods. Green synthesis of AgNPs involves the utilization of biological sources including plant extracts with silver salt as the precursor. The potential of phytochemicals in plant extracts serves as a reducing/capping and stabilizing agent to aid in the bio-reduction of Ag+ ions into a stable nanoform, Ag0. This review provides insights into the potentials of various plant parts like root, stem, leaf, flower, fruit, and seed extracts that have been extensively reported for the synthesis of AgNPs.

Coordinated configuration of hybrid energy storage for electricity-hydrogen integrated energy system

This paper proposes an optimal coordinated configuration method of hybrid electricity and hydrogen storage for the electricity‑hydrogen integrated energy system (EH-ES) to promote the renewable energy source (RES) utilization and reduce the deployment cost. To simulate the practical operation of EH-ES, an energy hub framework with a discrete state space system matrix is designed to characterize the internal interconnection topology and quantify the steady-state production, storage, conversion and utilization processes of electricity and hydrogen energy carriers within EH-ES. A chronological operation simulation based electricity and hydrogen storage configuration model over a year-round time horizon is formulated to collaboratively optimize the capacity of the electrolyzer, fuel cell, battery energy storage (BES) and hydrogen storage tank. In this model, the power and capacity complementarity of BES and generalized hydrogen storage is fully exploited to compensate for power and energy imbalances, and additional capacity configuration of BES is considered to mitigate the drastic electrolytic power fluctuation. Besides, a typical source-load scenario reduction method based on K-means and ordered clustering is developed to avoid a large number of operation variables due to year-round hourly simulation. Comparative studies demonstrate that the proposed methodology can achieve the RES consumption rate of 98.873 % while the equipment investment cost can be reduced by 10.034 %.

Iron Age ceramics from Thracian rock-cut complexes from Bulgaria – Mineral magnetic relics of technological production and use

The Gluhite kamani Thracian rock-cut complex in the Eastern Rhodopes Mountain is famous with its more than 500 rock niches carved in the rock at heights up to 20 m. Continuous habitation starting from the final Chalcolithic (the second quarter of the 4th millenium BCE) until the Late Classical – Early Hellenistic period (late 5th – 4th century BCE) provides unique opportunity for studying diachronic changes in pottery production and use. In this contribution, systematic analysis of a collection of 135 ceramic sherds from five archaeological periods at the site was carried out using a combined mineral magnetic and geochemical approach. Magnetic susceptibility (χ), frequency-dependent magnetic susceptibility (χfd%) and firing temperature (Tfire), determined using the magnetic susceptibility method, were combined with data from elemental XRF analyses. Thermomagnetic measurements, employed for identification of magnetic minerals revealed the dominant presence of (titano)magnetite with low Ti-content and/or a fraction of single-domain magnetite and in few cases hematite. Although varying in a wide range, median χ values of ceramic sherds from the Early Iron Age (EIA) periods show similar distribution, while for Late Iron Age (LIA) with the introduction of the wheel-thrown pottery, χ values are higher, presumably due to decreased amount of silica-rich clastics in the clay. Concurrently, χfd% values decrease in ceramics from the LIA, indicating predominant presence of stable single-domain magnetite in the iron oxide composition of the ceramics. Firing temperatures (Tfire) estimations display a systematic pattern of two groups – higher (Tfire between 760 and 800 °C) and lower (Tfire ∼ 400–––600 °C). During the EIA periods both Tfire groups are present, characterized by systematic gradual decrease of the median value of the low Tfire when going from EIA1 towards the EIA2. Wheel-thrown pottery from the LIA show low Tfire ∼ 400 °C only. Based on the differences in thermomagnetic properties of ceramics, their magnetic parameters and Tfire estimates, two possible hypotheses are suggested to explain the observed changes in EIA ceramic characteristics: i) utilization of two differently sourced clay materials (illite-dominated and montmorillonite-dominated) for production of ceramics fired at higher and lower temperatures, respectively; and ii) utilization of one raw clay source, while using two firing regimes – firing at higher temperature for prolonged time, and fast firing to high temperature with successive stage of longer firing at lower temperature. Differences in thermomagnetic properties of wheel-thrown pottery from the LIA period leads to the assumption for utilization of diverse clay source for their production, as compared clay sources for the Early Iron Age periods.

Active release of diatomite-MgAl-layered double hydroxide nanostructures on corrosive inhibitors to effectively suppresses corrosion of LA51 alloy

Two-dimensional (2D) materials have been potentially applicable for the corrosive resistance of alloys in corrosive media. Nevertheless, a challenge remains in adapting the 2D nanomaterial layered double hydroxide (LDH) with diatomaceous earth (DE) as two inorganic nanocontainers homogeneously combined and loaded with controlled release corrosion inhibitors. In this research, the high-efficiency anti-corrosion nanofiller for LA51 alloy protection was obtained by integrating MgAl-LDH with Sodium phosphate (SP) utilizing the unique hollow porous structure of DE as a template. As a result, the incorporation of DE-LDH-P provides a 3-order of magnitude enhancement in coating immersion in 3.5 wt% NaCl solution for 40 days compared to pure epoxy. Furthermore, two nanocontainers of DE and LDH with corrosion inhibitor loading up to 15 wt% still demonstrated excellent corrosive protection after 120 h of salt spray. The key to its protective performance is promoting controlled corrosion inhibitor release through a scientific approach that fully utilizes the slow-release properties of DE and LDH. This strategy offers a straightforward and effective approach for formulating anti-corrosion additives tailored for use in corrosive settings, with potential applications across various industrial sectors. Specifically, we advocate for the utilization of maritime instrumentation, underwater armaments, and seawater-based power sources within the domains of ship construction and marine engineering.