Natural Gas Sources Research Articles

Decarbonizing Public Transportation: A Multi-Criteria Comparative Analysis of Battery Electric Buses and Fuel Cell Electric Buses

To combat global warming, many industrialized countries have announced plans to ban vehicles powered by fossil fuel in the near future. In alignment with this global initiative, many countries across the globe are committed to decarbonizing their public transportation sector, which significantly contributes to increased greenhouse gas emissions. A promising strategy to achieve this goal is the adoption of electric buses, specifically battery electric buses and fuel cell electric buses. Each technology offers distinct advantages and drawbacks, making the decision-making process complex. This research aims to answer two critical questions: What is the optimal choice for decarbonizing the bus transportation sector—electric battery buses or fuel cell electric buses? And what are the best energy carrier pathways for charging or refueling these buses? We propose a methodological framework based on multi-criteria decision-making to address these questions comprehensively. This framework utilizes the entropy weighting and the Technique for Order Preference by Similarity to the Ideal Solution (TOPSIS) methodologies to rank alternative bus technologies along with energy carrier pathways. The framework evaluates a range of criteria, including economic viability, energy demand, and environmental aspects. To illustrate the framework, we considered Qatar as a case study. Our results indicate that, with respect to economic viability and energy consumption, the operation of battery electric buses is favored over fuel cell electric buses, regardless of the energy pathway utilized during both the energy production and bus operation phases. However, from an environmental perspective, operating both bus alternatives using energy from green sources provides superior performance compared to when these buses are powered by natural gas sources.

Characteristics and Origin of Natural Gas in Yongfeng Sub-Sag of Bogda Mountain Front Belt

By systematically analyzing the natural gas composition, carbon isotopes, and source rock characteristics in the Yongfeng sub-sag of the Bogda Mountain front belt, natural gas characteristics were determined, and the genetic types and sources of natural gas were investigated. The research results indicate that methane is the main component of natural gas in the Yongfeng sub-sag, with low levels of heavy hydrocarbons and a high drying coefficient. These characteristics make it dry gas, which refers to natural gas with a methane content of over 95%. The ethane carbon isotope δ13C2 of natural gas is −28.5‰ and belongs to oil type gas. The methane carbon isotope δ13C1 of natural gas is −58.6‰~−59.4‰, has a relatively depleted methane carbon isotope value, shows significant differences from the surrounding natural gas methane carbon isotope, and belongs to the category of biogenic gas. The Permian Lucaogou Formation is the main source rock in the study area, with good organic matter abundance. The microscopic components of kerogen are mainly composed of sapropelic formations and the organic matter type is I–II1. The source rock has a high maturity and has reached the mature stage, mainly consisting of oil and wet gas. The ethane carbon isotope of natural gas in the Yongfeng sub-sag shows as oil type gas, which is consistent with the kerogen type of the Lucaogou Formation source rocks, indicating that the natural gas mainly comes from the Lucaogou Formation source rocks. Based on comprehensive data and information on natural gas composition, carbon isotopes, and burial history of the source rocks, it is believed that some of the crude oil generated from the Lucaogou Formation in the early stage underwent biodegradation due to tectonic uplift, resulting in biogenic methane and the formation of crude oil biodegraded gas.

Characterization and source apportionment of ambient VOC concentrations: Assessing ozone formation potential in the Barnett shale oil and gas region

Atmospheric concentration and distribution of volatile organic compounds (VOC) are influenced by localized emissions and the fate and transport of secondary products formed through photochemical reactions. This study identifies the sources of VOC and its contribution to ozone formation in the Barnett Shale region, specifically in Denton, Texas, during the ozone seasons of 2015 through 2022. A total of 31 critical ozone precursor VOC compounds were observed at this site with an average total VOC concentration of 146 ppb-C, with n-alkanes from extensive oil and gas activities in the area contributing to 96.64% of the total VOC. Source apportionment using dispersion normalized positive matrix factorization (DN-PMF) identified eight VOC sources, with natural gas emissions (72%) being the dominant source followed by a combined source of natural gas combustion and aviation emissions (8.3%). Ozone formation potential (OFP) by VOC species was calculated using the propylene-equivalent concentration (propy-equiv) method. OFP calculated for all the apportioned sources highlighted that natural gas sources contributed significantly to the ozone formation in this region besides isoprene from biogenic sources and reactive alkenes from urban and industrial activities. This study underscores the critical role of slow-reacting n-alkanes along with other highly reactive VOC from urban and industrial sources influencing ambient air quality and it identifies strategies for mitigating ground-level ozone in urban areas affected by oil and gas extraction and production.

Widespread coastal upwelling along the marginal Yangtze Platform (South China) during the early Cambrian: Implications for hyper-enrichment of organic matter

Early Cambrian Earth history witnessed significant changes in marine environments and biological evolution contemporaneous with extensive accumulation of organic-rich shale. However, major factors controlling hyper-enrichment of organic matter (OM) of lower Cambrian shale deposits remain controversial. Black shale of the lower Cambrian Niutitang Formation (NTT) of the Marginal Yangtze Platform (South China) deposited during the Cambrian middle Age 2 are especially organic-rich, with total organic carbon (TOC) concentrations of as much as 13.0 wt%. Geochemical evidence suggests that cool, dry paleo-climatic conditions that prevailed on the Yangtze Platform during the Cambrian Fortunian-late Age 2, induced vigorous coastal upwelling. Paleo-productivity level assessments indicate that the magnitude of primary productivity contemporaneous with deposition of the NTT shale deposits exceeded that of modern upwelling systems (e.g., Peruvian Margin). The widespread occurrence of phosphate nodules within these deposits and decreased Co-EF × Mn-EF values of associated lower Cambrian black shale successions deposited along the margin of the Yangtze carbonate platform suggest extensive coastal upwelling. Widespread and strong coastal upwelling in tandem with elevated surface water primary productivity and anoxic (even euxinic) bottom water conditions are manifested by deposition of OM hyper-enriched black shale during Cambrian Fortunian to middle Age 2 time. However, weakened seasonal upwelling that appears to have prevailed during the late Cambrian Age 2 was accompanied by accumulation of NTT shale deposits of diminished TOC content. In summary, this study provides robust evidence of extensive coastal upwelling along the Marginal Yangtze Platform during early Cambrian time that favored accumulation of OM hyper-enriched shale. These results help to elucidate the distribution of high-quality lower Cambrian natural gas source rocks in South China.

Synthesis and performance evaluation of polymer-ceramic composite microcapsules as reservoir protectant for natural gas hydrate drilling.

Natural gas hydrate is a promising unconventional natural gas source due to its high energy density and huge global reserves. During exploitation, the drilling fluid may invade the hydrate formation and induce hydrate decomposition, causing reservoir damage. Herein, a novel reservoir protectant made by bio-degradable temporary plugging material (BDTPM) was developed in the form of polymer-ceramic composite microcapsules. As an additive to the drilling fluid, the BDTPM can minimize drilling fluid intrusion by plugging the reservoir during drilling and afterwards maximize permeability recovery by degrading the material. The particle size distribution was in the range of 1-130μm. The optimal mass ratio between modified ceramic particles, ethyl cellulose and epoxy resin was found to be 4:2:1. The plugging rate was 100% when ethyl cellulose and epoxy resin were mixed to coat the ceramic particles to form BDTPM, and the plugging performance was the best. At a temperature close to the typical hydrate reservoir environment (5°C), 0.02 wt% low-temperature complex enzyme can degrade BDTPM, and the permeability recovery rate is 64.66%. The efficient reservoir protectant developed in this work could play an important role in the successful drilling of natural gas hydrate reservoirs.

Study on natural gas-source correlation and hydrocarbon accumulation of the Lianggaoshan Formation in the east of Sichuan Basin, China

Study on natural gas-source correlation and hydrocarbon accumulation of the Lianggaoshan Formation in the east of Sichuan Basin, China

Geochemical Characteristics and Origin of Natural Gas in the Middle of Shuntuoguole Low Uplift, Tarim Basin: Evidence from Natural Gas Composition and Isotopes

Multiple types of reservoirs, including volatile oil reservoirs, condensate gas reservoirs, and dry gas reservoirs, have been discovered in ultra-deep layers buried at depths greater than 7500 m. Understanding the genetic types of natural gas is of utmost importance in evaluating oil and gas exploration potential. The cumulative proved reserves of the super deep layer in the Shuntuoguole low uplift area of the Tarim Basin exceed 1 × 108 t (oil equivalent). The origin, source, and accumulation characteristics of natural gas still remain a subject of controversy. By analyzing the composition and carbon isotope of natural gas, a detailed investigation was conducted to examine the unique geochemical and reservoir formation characteristics of the Ordovician ultra-deep natural gas within different fault zones in the middle region of the Shuntuoguole low uplift. It was determined that most of the natural gas in this area is displaying a characteristic of wet gas with a drying coefficient ranging from 0.41 to 0.99. The carbon isotope composition of methane in the gas reservoir shows relatively light values, ranging from −49.4‰ to −42‰. The carbon and hydrogen isotopes of the components are distributed in a positive order. The natural gas is oil type gas, which is derived from marine sapropelic organic matter and has a good correspondence with the lower Yuertusi formation. The maturity of natural gas in Shunbei No. 1 and No. 5 fault zones is about 1.0%, which is the associated gas of normal crude oil, while the maturity of No. 4 and No. 8 fault zones is higher than 1.0%, which is the mixture of kerogen pyrolysis gas and crude oil pyrolysis gas. The variations in the drying coefficient and carbon isotope composition of the natural gas provide evidence for the migration patterns within the Shuntuoguole low uplift central region. It indicates that the Shunbei No. 5 and No. 8 fault zones have likely migrated from south to north, while the No. 4 fault zone has migrated from the middle to both the north and south sides. These migration patterns are primarily controlled by high and steep strike-slip faults, which facilitate the vertical migration of natural gas along fault planes. Consequently, the gas accumulates in fractured and vuggy reservoirs within the Ordovician formation.

An optimisation method for planning and operating nearshore island power and natural gas energy systems

As the development and use of offshore islands increase, so do the diversity of their energy needs, the cost of utilising the mainland for resource replenishment, and the instability of island energy systems. To address this challenge, this paper introduces an innovative system integrating fossil and renewable energy tailored for these islands, considering seasonal variations and external energy fluctuations. Leveraging a P-graph, an optimisation framework is designed to assess different optimised solutions. A comprehensive analysis is also performed to compare the solutions, while sensitivity assessments evaluate factors including electricity and gas price fluctuations, renewable energy availability, and natural gas demand. Additionally, the carbon emissions resulting from different power generation scenarios are visually represented and thoroughly analysed. The results support two key findings: 1) the cost of combined energy supply is lowest when wind energy accounts for 59 % of the total energy, mainland grid connection accounts for 3 %, fossil fuel energy accounts for 28 %, and natural gas accounts for 10 % of the energy mix; and 2) the price of electricity and natural gas supplied to the islands and the variability in the energy sources of wind and natural gas can significantly affect the cost of the energy system.

Analysis of the Role of Aquatic Gases in the Formation of Sea-Ice Porosity

The porosity of freshwater ice and sea ice is one of the main parameters that determine their strength. The strength of ice varies over a wide range of values, and the differences in the intensity of the mechanisms of ice porosity formation in different water areas can be one of the possible reasons for these variations. The water mass contains gases in two forms: gases dissolved in the water mass, as well as gas bubbles that are formed when wind waves break up, and bubbles that float up from the seabed. This article presents the results of an analysis of the role of each of these forms in the formation of gas inclusions (pores) in the crystal structure of ice. The results showed that the main source of gas pores in ice crystals is the gas bubbles coming to the surface from the bottom, formed during the decomposition of bottom sediments or during gas leaks from near-bottom oil and gas fields. The possibility of gas bubbles occurring and rising to the ice–water boundary depends on the presence of bottom sources of the gases, the intensity of dissolution of the bubbles and the depth of the water area. Therefore, the variation in the porosity and the strength of ice over the space of the water areas can be associated with the changes in their depths, and the presence and location of the natural gas sources.

Theoretical and experimental constraints on hydrogen isotope equilibrium in C1-C5 alkanes

Stable isotope ratios of C1–C5 alkanes, the major constituents of subsurface gaseous hydrocarbons, can provide valuable insights on their origins, transport, and fates. Equilibrium isotope effects are fundamental to interpreting stable isotope signatures, as recognition of them in natural materials indicates reversible processes and constrains the temperatures of equilibrated systems. Hydrogen isotope equilibrium of C1–C5 alkanes is of particular interest because evidence shows that alkyl H can undergo isotopic exchange with coexisting compounds under subsurface conditions. We present the results of a combined experimental and theoretical effort to determine equilibrium hydrogen isotope distributions in mixtures of these hydrocarbon compounds. We created two mixtures: one with C1, C2 and C3 (where C1 indicates methane, C2 ethane, etc., hereinafter called ‘C1–C3 mixture’) and another one with C2, C3, iC4, nC4, iC5 and nC5 (hereinafter called ‘C2–C5 mixture’); in both cases, the mixtures were created to start out of hydrogen isotope equilibrium. We tested the performance of several metal catalysts as aids to H isotopic exchange by exposing these mixtures to different metal catalysts at 100 or 200 °C and analyzing the compound-specific hydrogen isotope ratios of the product gases. The C1–C3 mixture exchanged hydrogen isotopes among the starting gas components rapidly in the presence of Ru/Al2O3 at 200 °C. The isotope ratios reach a steady-state (presumably equilibrium) after 72 h of heating (up to 120 h). The hydrogen isotopic ratios of alkanes in the C2–C5 mixture shifted significantly in the presence of Rh/Al2O3 at 100 °C and C3-C5 compounds approached steady state after 70 h, whereas C2 had not yet reached a steady state D/H ratio after 216 h of heating. We evaluated the reaction progress of isotope exchange for each compound as a function of time with a reaction-network model informed by constraints on chemical kinetics. The model indicates that C3, iC4, nC4, iC5 and nC5 in the C2-C5 mixture reached internal isotope equilibrium after 70 h, hence we used their values to calculate experimental equilibrium results. We also calculated equilibrium isotope fractionations with the Bigeleisen-Mayer theorem using vibrational frequencies computed from the density functional theory (B3LYP/aug-cc-pVTZ). We included torsional conformers and explicit H positions in the calculations. We found that the experimental results from both the 200 ˚C C1–C3 experiment and 100 ˚C C2–C5 experiment are consistent with theoretical equilibrium results within experimental uncertainty. Additionally, our reaction-network model for catalyzed hydrogen isotope exchange between alkanes succeeded in fitting our experimental results. This modeling framework can be adjusted to simulate exchange in natural settings for constraining temperature histories and sources of natural gases.

Analysis of methods of natural gas technical loss determination and technical loss norms in gas supply network

In modern times, the role of energy resources is very large. One of the important energy resources is natural gas. The biggest advantage of using natural gas as a fuel is its high heat capacity and complete combustion without the formation of harmful substances. The process of natural gas distribution in the gas supply network is observed with gas loss. This is an objective, natural situation and creates a number of difficulties for natural gas enterprises. The article focuses on gas consumption in technological processes in the gas supply network, gas purges from pipelines during pipeline repair works, gas flushing out from the pipeline and determination of gas technological losses during the removal of air from the pipeline. Determination of gas losses caused by non-hermeticity of external gas pipelines and equipment, gas pressure regulation station (GPRS), cabinet-type gas control points (GCP), universal pressure regulator (UPR) and gas losses occurring during repairing of other technological equipment are discussed. Also, the determination of technical losses of natural gas at meters, sampling nodes, safety valves, gas distribution stations (GDS) (from gas losses during the management of shut-off valves, during purge of process instrumentation and automatics, when taking gas samples, during purges proses of safety valves, apparatus and pulse lines) is discussed. The article describes the principle of formation of technical losses in the gas supply network. Technical loss sources of natural gas in the process of gas supply, methods of calculating loss norms, the amount of small loss of which is determined separately for each specified loss source, are mentioned. Keywords: gas supply; natural gas; technical losses; pipeline; GPRS; GCP; UPR; gas meters; safety valves; gas distribution station.

Integrated membrane process of tubular ultrafiltration-nanofiltration-electrodialysis-reverse osmosis for treating fracturing flowback fluid

As an underground source of natural gas, shale gas is important for ensuring national energy security and promoting the “dual carbon” target. However, shale gas extraction produces flowback fluid that requires efficient treatment to avoid negative impacts on the environment and human health. In this study, a pilot plant was constructed to implement a novel membrane-integrated process to treat fracturing flowback fluid. This process employs an aeration reaction sedimentation (ARS) tank and a tubular ultrafiltration (TUF) membrane for pretreatment, followed by three separate membranes for nanofiltration (NF), electrodialysis (ED), and reverse osmosis (RO). The pretreatment removed 99.3% of total hardness, 99.4% of total suspended solids (TSS), and 88.1% of total organic carbon (TOC). Four different types of TUF membranes were tested and compared. It was also found that physico-chemical cleaning of the TUF membrane using the ceramic particle technology resulted in a flux recovery rate of up to 98%. In addition, the NF and ED membranes can remove 99.4% of Na2SO4 and 90% of NaCl, respectively, resulting in an 85.6% decrease in TSS. Water recovery rate of the total system can reach 90%. Based on concept of sustainable green development, carbon footprint of integrated membrane process for treating fracturing flowback fluid was approximately 86.7 kgCO2 eq lower than that of traditional process. Low carbon emissions and no generation of secondary pollutants have become the keys to treat fracturing wastewater. In summary, the integrated TUF-NF-ED-RO process based on membranes is very promising for treating fracturing flowback fluid.

Gas-phase reaction of CH4 and H2S – Evidence from pyrolysis experiments and case study from the Sichuan Basin

The application of routine geochemical analyses for identification of dry natural gas sources and post generation processes poses a challenge as its hydrocarbon composition is typically dominated by CH4 (∼≥99 %) while the presence of non-hydrocarbons may be limited. In particular, the possibility of dry gas interaction with H2S at reservoir conditions (low temperatures, high pressures, millions of years residence time) is not established as previous studies of this reaction focused on conditions typical for industrial reactors (high temperature, ambient pressure, residence time of seconds). To address these issues, we studied the molecular and isotopic (δ34S) composition of volatile organic sulfur compounds (VOSC) formed during pyrolysis experiments between CH4 and H2S at 360 °C (4–96 h), reaching %Ro equivalent of 0.80–1.25 which represents thermally mature oil and gas reservoirs. The results demonstrated that methanethiol (MeSH) is the main product of the reaction, while its δ34S value suggest equilibrium isotopic effect with its parent H2S. Subsequent analysis of the molecular and isotopic (δ13C, δ2H, δ34S) composition of thermogenic, H2S containing, dry natural gases from the Jiannan gas field in China revealed the presence of short thiols and sulfides dominated by MeSH. The δ34S of the VOSC identified suggests they all formed by gas-phase reaction of alkanes (mainly CH4) with the associated H2S.This study demonstrates the applicability of VOSC as a proxy for identification of interaction between H2S and dry gas and identification of H2S sources within a gas reservoir or a basin.

Femtosecond laser ablation responses of kerogen-rich, argillaceous, and bituminous shale rocks

Shale rocks have become one of the major sources of natural gas and oil. Laser drilling has emerged as a promising technique that can be incorporated into horizontal drilling and hydraulic fracturing processes. In this study, we selected three types of shales (kerogen-rich, argillaceous, and bituminous) with distinct compositions and microstructures and performed femtosecond laser irradiation with different power and energy to investigate their ablation characteristics. Evidence of melting and solidification was observed in all samples, despite the ultra-high pulse frequency of the femtosecond laser. Among the three types of shale rocks, the kerogen-rich shale exhibited the highest ablation rate, while argillaceous and bituminous shale showed lower and comparable rates. The above observations highlight the significance of shale chemistry in influencing laser ablation characteristics under femtosecond laser irradiation. Furthermore, no ablation rate anisotropy was observed when irradiating the samples parallel with and perpendicular to the bedding direction, although shale rocks are microstructurally and mechanically anisotropic.

Primary and oxidative source analyses of consumed VOCs in the atmosphere

Consumed VOCs are the compounds that have reacted to form ozone and secondary organic aerosol (SOA) in the atmosphere. An approach that can apportion the contributions of primary sources and reactions to the consumed VOCs was developed in this study and applied to hourly VOCs data from June to August 2022 measured in Shijiazhuang, China. The results showed that petrochemical industries (36.9 % and 51.7 %) and oxidation formation (20.6 % and 35.6 %) provided the largest contributions to consumed VOCs and OVOCs during the study period, whereas natural gas (5.0 % and 7.6 %) and the mixed source of liquefied petroleum gas and solvent use (3.1 % and 4.2 %) had the relatively low contributions. Compared to the non-O3 pollution (NOP) period, the contributions of oxidation formation, petrochemical industries, and the mixed source of gas evaporation and vehicle emissions to the consumed VOCs during the O3 pollution (OP) period increased by 2.8, 3.8, and 9.3 times, respectively. The differences in contributions of liquified petroleum gas and solvent use, natural gas, and combustion sources to consumed VOCs between OP and NOP periods were relatively small. Transport of petrochemical industries emissions from the southeast to the study site was the primary consumed pathway for VOCs emitted from petrochemical industries.

Demand Response Power-Gas Interconnection Energy System and Power Metering Based on SOGA

Under the double background of global energy crisis and environmental pollution, China vigorously develops renewable energy while accelerating the construction of energy Internet. Taking demand response into account, this paper proposes the optimal design of power-gas interconnection energy system and power metering, and establishes the optimization research model of IEGES (integrated electricity-gas energy system) with demand response. Firstly, the structure model of the electric-gas interconnection energy system with CHP (Cogeneration, combined heat and power) as the core is constructed, and the energy conversion relationship and different energy flow directions of the coupling equipment are expounded from three aspects. The natural gas source point, pipeline equation, power side branch equation, voltage and current equation are modeled and sorted out, and the square term in the equation is linearized by second-order cone programming method, and the mixed integer nonlinear programming problem is transformed into mixed integer linear programming problem. A single objective genetic algorithm with “elite strategy” was selected to solve the equipment capacity optimization problem of IEGES system with system economy as the optimization objective. After a long time of parameter combination attempts, the current population size is 30, the number of iterations is 600, the crossover rate is 0.8, and the heritability is 0.3. The above parameters can obtain better convergence results on the basis of considering the operation time. Finally, a stochastic optimization method of energy Internet considering integrated demand response and uncertainty of wind power is proposed, which aims to meet the energy demand of end users while minimizing the operating cost of the system. The comprehensive demand response strategy including internal and external demand response is considered in the model. Internal demand response is realized by adjusting the internal operation mode of EH, while external demand response is implemented by the end user’s active response, and the load is time-shifted or interrupted under the guidance of external signals.

Energy Cost Optimization for Incorporating Energy Hubs into a Smart Microgrid with RESs, CHP, and EVs

The energy carrier infrastructure, including both electricity and natural gas sources, has evolved and begun functioning independently over recent years. Nevertheless, recent studies are pivoting toward the exploration of a unified architecture for energy systems that combines Multiple-Energy Carriers into a single network, hence moving away from treating these carriers separately. As an outcome, a new methodology has emerged, integrating electrical, chemical, and heating carriers and centered around the concept of Energy Hubs (EHs). EHs are complex systems that handle the input and output of different energy types, including their conversion and storage. Furthermore, EHs include Combined Heat and Power (CHP) units, which offer greater efficiency and are more environmentally benign than traditional thermal units. Additionally, CHP units provide greater flexibility in the use of natural gas and electricity, thereby offering significant advantages over traditional methods of energy supply. This article introduces a new approach for exploring the steady-state model of EHs and addresses all related optimization issues. These issues encompass the optimal dispatch across multiple carriers, the optimal hub interconnection, and the ideal hub configuration within an energy system. Consequently, this article targets the reduction in the overall system energy costs, while maintaining compliance with all the necessary system constraints. The method is applied in an existing Smart Microgrid (SM) of a typical Greek 17-bus low-voltage distribution network into which EHs are introduced along with Renewable Energy Sources (RESs) and Electric Vehicles (EVs). The SM experiments focus on the optimization of the operational cost using different operational scenarios with distributed generation (DG) and CHP units as well as EVs. A sensitivity analysis is also performed under variations in electricity costs to identify the optimal scenario for handling increased demand.

Anthropogenic-driven changes in concentrations and sources of winter volatile organic compounds in an urban environment in the Yangtze River Delta of China between 2013 and 2021

Volatile organic compounds (VOCs) serve as crucial precursors to surface ozone and secondary organic aerosols (SOA). In response to severe air pollution challenges, China has implemented key air quality control policies from 2013 to 2021. Despite these efforts, a comprehensive understanding of the chemical composition and sources of urban atmospheric VOCs and their responses to emission reduction measures remains limited. Our study focuses on analyzing VOCs composition and concentrations during the winters of 2013 and 2021 through online field observations in urban Nanjing, a typical city in the Yangtze River Delta region of China. Using a machine learning approach, we found a notable reduction in total VOCs concentration from 52.4 ± 30.4 ppb to 33.9 ± 21.6 ppb between the two years, with dominant contributions (approximately 94.3 %) associated with anthropogenic emission control. Furthermore, alkanes emerged as the major contributors (48.6 %) to such anthropogenic-driven decline. The total SOA formation potential decreased by approximately 27.4 %, with aromatics identified as the major contributing species. Positive matrix factorization analysis identified six sources. In 2013, prominent contributors were solid fuel combustion (43.6 %), vehicle emission (16.7 %), and paint and solvent use (12.8 %). By 2021, major sources shifted to solid fuel combustion (31.9 %), liquefied petroleum gas and natural gas (26.8 %), and vehicle emission (25.5 %). Solid fuel combustion emerged as the primary driver for total VOCs reduction. The lifetime carcinogenic risk in 2021 decreased by 72.6 % relative to 2013, emphasizing the need to address liquefied petroleum gas and natural gas source, and vehicle emissions for improved human health. Our findings contribute critical insights for policymakers working on effective air quality management.

Sources of natural gas in the Middle-Permian carbonate succession in the central-northern Sichuan Basin, Southwest China

Natural gas-source correlation is a challenging aspect of natural gas exploration in deep strata. The Middle-Permian carbonate succession in the Sichuan Basin, southwest China, particularly in the Maokou Formation, is a hotspot for natural gas exploration. However, determining the natural gas source in the Maokou Formation is challenging because of the high maturity and complexity of potential source rocks. In this study, we analyzed the genesis and sources of natural gas in the central-northern Sichuan Basin while considering the geological conditions and systematically utilizing the gas components, stable and rare-gas isotopes, and solid bitumen biomarkers. The results indicate that (1) the natural gas in the northern Sichuan Basin comprises a mixture originating from the source rocks of the Maokou and Wujiaping formations; (2) the Qiongzhusi Formation is the major source of natural gas in the north slope (and the Maokou Formation source rock could be used as an important supplement); (3) the natural gas in the Moxi-Longnvsi structure comprises a mixture originating from the source rocks of the Qiongzhusi and Maokou formations. From south to north and west to east, the major source rocks of the gas reservoirs changed from belonging to the Qiongzhusi Formation to the Maokou and Wujiaping formations. This study is the first to combine multiple geochemical methods and consider different geological settings to identify the gas source of a deep carbonate gas reservoir. Our study provides a reliable method for determining the natural gas-source correlation of gas reservoirs that contain highly mature and complex gas sources.

Dynamic environmental quality effect of nuclear energy intensity, structural changes, and natural resources in Pakistan: testing load capacity factor hypothesis evidence

AbstractWith both electricity and clean energy cooking accessible to 40 million and over 100 million people respectively, Pakistan’s ecological challenges could persist as long as the energy-related issues remained unsolved. This is the motivation for examining the drivers of the country’s biocapacity and ecological footprint vis-a-vis load capacity factor (LCF) from the perspective of nuclear energy intensity, natural resources, structural change, and economic growth. By using the recently developed simulation of autoregressive distributed lag for dataset that covers 1971 to 2021, this investigation found that nuclear energy intensification and structural change both improves environmental quality by increasing the country’s ratio of biocapacity against its ecological footprint in the long run. Specifically, nuclear energy intensity and structural change have respective elasticities of 0.02 and 0.34 with LCF. With the country’s nuclear energy supply far below the natural gas, oil, and biofuels and waste sources, the country might as well be encouraged to increase the development of nuclear energy in tackling the persistent environmental woes. Contrarily, the investigation established that natural resources in the country is detrimental to environmental quality but only in the short run because a percent increase in natural resources is responsible for ~ 0.035 percent decline in LCF. Importantly, an inverted U-shaped relationship ensued between economic growth and LCF but only statistically significant in the long-run i.e. invalidating LCF hypothesis, thus suggesting an undesirable environmental consequence of economic prosperity. As a policy, and given the novel perspectives of nuclear energy intensity and structural change dynamics, these results incentivize Pakistan’s nuclear energy development drive and among among other environmental and economic policy initiatives. Graphical abstract