We study the six-dimensional solvmanifolds that admit complex structures of splitting type classifying the underlying solvable Lie algebras. In particular, many complex structures of this type exist on the Nakamura manifold X , and they allow us to construct a countable family of compact complex non- \partial\bar{\partial} manifolds X_k , k\in\mathbb Z , that admit a small holomorphic deformation \{(X_{k})_{t}\}_{t\in\Delta_k} satisfying the \partial\bar{\partial} -lemma for any t\in\Delta_k except for the central fibre. Moreover, a study of the existence of special Hermitian metrics is also carried out on six-dimensional solvmanifolds with splitting-type complex structures.