This work is devoted to solve integral equations formulated in terms of the kernel functions and Nemytskii operators. This type of equations appear in different applied problems such as electrostatics and radiative heat transfer problems. We deal with both cases separable and non-separable kernels by setting the theoretical semilocal convergence results for an adequate iterative scheme that can be useful for approximating the solution of the infinite dimensional problem. We pay special attention to non-separable kernels avoiding the solution given in previous works where the original nonlinear integral equation has been approximated by means of an equation with separable kernel. However, in this case, we introduce an approximation of the derivative operator that it is needed for applying the iterative scheme considered. Moreover, we study the localization and separation of possible solutions of nonlinear integral equation by means of a result of semilocal convergence for the iterative scheme considered. The theoretical results obtained have been tested with some applied problems showing competitive results.