Solid Phase Volume Research Articles

Small volume solid phase extraction method for comprehensive analysis of neonicotinoids, their metabolites, and related pesticides in water

Neonicotinoid insecticides (NEOs) such as clothianidin, imidacloprid, and thiamethoxam are used worldwide. The occurrence of their degradates, for instance, clothianidin-n-desmethyl (CLO-N-DES), clothianidin-urea (CLOU), imidacloprid urea (IMIU) and olefin (IMIO), as well as thiamethoxam urea (THXU), have seldom been documented in water due to the lack of a sensitive analytical method. In this study, a method only requiring 12 mL of water sample was developed and validated to quantify 8 NEOs, 13 metabolites, and 3 related insecticides using solid phase extraction (SPE) coupled with HPLC-MS/MS. The method demonstrated good linearity (r2 > 0.99), with limits of detection (LOD) ranging from 0.16 to 1.21 ng/L and limits of quantification (LOQ) from 0.54 to 4.03 ng/L in water samples. Validation showed accuracy between 70 and 130 % and precision below 15 % for most analytes. The method's performance was comparable to, or better than, existing methods, with the advantage of requiring much smaller sample volumes. Using this method, we monitored the occurrence and seasonal variability of NEOs and their metabolites in various surface water and groundwaters matrices from across Iowa. For example, analysis of water samples from private wells across three Iowa counties detected several NEOs, with notable findings including the first detection of flupyradifurone (FLU) in Iowa well water. Surface water analysis from five locations revealed frequent detection of NEOs and their metabolites, with some concentrations exceeding U.S. EPA chronic toxicity benchmarks for freshwater invertebrates. In addition, this is the first study to demonstrate the occurrence of CLO-N-DES, CLOU, and THX-U in US surface water. The study helps advance analytical methods for NEOs and their metabolites while also highlighting their widespread occurrence in Iowa waters and associated ecological risks, emphasizing the need for more comprehensive monitoring of these compounds.

Experimental study of solid-liquid two-phase flow field in a centrifugal pump volute under multiple working conditions

In order to study the variation law of the solid-liquid two-phase flow field in the volute of centrifugal pump and the distribution law of the solid particles in the volute, based on PIV technology, the dynamic and static interference flow field of the volute under different flow conditions (30 m3/h, 40 m3/h, 50 m3/h, 60 m3/h, 70 m3/h) and different solid phase volume fractions (1 %, 1.5 %, 2 %) is studied. It is found that with the increase of the solid phase volume fraction, the head and efficiency of the centrifugal pump gradually decrease, and the addition of the solid phase has little effect on the pump head when the solid phase volume fraction is small under the condition of the large flow. The high turbulent kinetic energy area in the volute is mainly concentrated near the outer wall of the volute and the area where the tongue is located. Under the same solid phase volume fraction, the turbulent kinetic energy in the volute increases with the increase of the flow rate. The turbulent kinetic energy in the volute decreases with the increase of the solid phase volume fraction. The absolute velocity component of the flow field in the volute is significantly affected by the flow condition.

Effect of inorganic salt composition on strength, microstructure and leaching toxicity of coal-based solid waste backfill materials

This study explores the potential of coal-fired slag, desulfurized gypsum and modified magnesium slag as cementing agents for coal-based solid waste backfill materials. Inorganic salts like CaCl2, Na2SO4 and Na2SiO3 were used as excitants to investigate their combined impact on the mechanical properties, microstructure and leaching risk of hazardous elements from the coal-based solid waste backfill materials. The findings show that the addition of inorganic salt boosts the alkalinity within the liquid-phase reaction system. This disrupted the hydration-blocking membrane, accelerating the dissolution and reaction rate of the silica-alumina mineral components within the cementitious material. Concurrently, the inorganic salt ions consumed the early alkaline hydration products, destroying the hydration reaction equilibrium and facilitating the formation of hydration products like AFt, C-S-H gel, C-A-S-H gel, and Friedel's salt. This increase in the solid-phase volume content and microscopic densities in the reaction system improved the early mechanical properties of the coal-based solid waste backfill materials. Additionally, after a 28-day curing period, the leaching concentration of deleterious elements in the coal-based solid waste backfill material containing inorganic salt components was below the permissible concentration limit of the Class III groundwater quality standard. This eco-friendly backfill material is promising for mine backfilling, a potential substitute for traditional cement-based backfill material.

Effect of Recycled Asphalt Mixture and Solid Waste-Based Solidification Materials on Performance of Cold-Regenerated Asphalt Mixture

In this study, an aging asphalt mixture was regenerated by a waste-based rejuvenator and cemented by solid waste-based solidification materials (SSMs). A splitting test, wheel tracking test, and three-point bending test were conducted to evaluate the properties of the regenerated asphalt mixture (RAM). The results reveal that the properties of the asphalt mixture were not diminished or were moderately enhanced by the 30% substitution of RAP. With the substitution of RAP to 100%, the splitting tensile strength, dynamic stability, and splitting strength ratio were decreased by 13%, 15%, and 5%, respectively. With the 100% substitution of SSMs for cement, the compressive strength, dynamic stability, flexural strain, and splitting strength ratios of the RAM were increased by 40%, 32%%, 14%, and 8%, respectively. The lightweight components can be supplemented, and low-temperature deformation and interlayer flowability can be improved by the incorporation of the rejuvenator. The generation of hydrated calcium silicate and ettringite for SSMs is greater than those of cement. The massive generation of ettringite has been observed to increase the solid phase volume by 120%, which may facilitate a more complete filling of the remaining pores in the RAM due to water evaporation. The regeneration and cement on green and the high performance of the rejuvenator and the SSM markedly enhanced RAM performance.

Mechanism of the impact of sediment particles on energy loss in mixed-flow pumps

Numerical simulations were performed on the fluid domain of the mixed-flow pump with different solid-phase volume fractions to examine the influence of the sediment particles on internal energy dissipation. The energy properties of the mixed-flow pump were analyzed using the entropy production theory, considering the various flow rates and the solid particle conditions. The research examined the impact of the proportion of the solid particles in the flow on the performance and effectiveness, uncovering the complexities of the energy dissipation in the channel. The results showed that incorporating solid particle media resulted in the decrease in both the performance and effectiveness of the mixed-flow pump compared to water conditions. The mixed-flow pump's head decreased by 0.56 % and its efficiency declined by 2.74 % due to the change in particle volume fraction (Cv) from 5 % to 7.5 %. Upon transitioning from Cv = 7.5 % to Cv = 10 %, the head exhibited a 2.54 % decrease, coupled with a 7.22 % efficiency reduction, signifying pronounced energy loss. The findings highlight that the increase in the quantity of the solid particles enhances the pump's energy dissipation. Solid particles tend to be mainly concentrated in the impeller inlet, blade outer edge, guide vane inlet, and guide vane outer edge regions at varying solid-phase volume fractions. The main dissipation in the fluid region of the mixed flow pump mainly occurs in the impeller and the guide vane, the total energy loss in the guide vane is more than 500 W under the three volume fractions, the total energy loss in the impeller is also about 500 W, and the inlet and outlet losses are small. These research outcomes lay the groundwork for further enhancements in the energy characteristics of mixed-flow pumps.

Numerical Simulation of Solid-Liquid Two-Phase Flow in Pump

Abstract This paper is based on EDEM-FLUENT coupling calculation, the solid-liquid two-phase flow at pump is analyzed. Three kinds of solid phase volume concentration and three solid phase particle diameters are given respectively, and the solid-liquid two-phase flow numerical simulation of the internal flow field of the pump is carried out. The position distribution of solid particles in the flow field and the change of particle average velocity with time and the distribution of particle velocity are analyzed. The results show that the inlet of the runner and the pressure surface of the blade are the concentrated distribution areas of particles. With the increase in particle concentration, the particle distribution at the outlet of the volute is more uniform. The average velocity of particles at different particle concentrations varies similarly with time, but the average velocity of particles increases with the increase of concentration. With the increase in particle size, the average velocity of particles decreases, but the velocity value with the largest proportion of particles becomes larger.

Two-Fluid and Discrete Population Balance Model for Simulation of Batch Sedimentation Relevant to Plutonium Reconversion

There are widespread occurrence and application of solid-liquid sedimentation processes among different industries. Therefore, it becomes important to understand the hydrodynamic inside the process equipment and particle agglomeration characteristics. In the present work, solid-liquid sedimentation is analyzed, which will be helpful for the design of continuous process equipment in plutonium (Pu) reconversion. Experiments were carried out in a batch settler to understand solid sedimentation in suspension in terms of varying the overall solid fractions. Euler-Euler two-fluid simulations were performed to investigate the local and overall solid phase volume fraction distributions, position of the active interface (AI) (settling curve), axial solid phase velocity, and pressure distributions during settling, and selected data were compared with the measured data. Further, the discrete population balance model (PBM) with different agglomeration kernels was used with the two-fluid computational fluid dynamics (CFD) model to understand and further improve predictions in terms of the AI position. The variation in number density of the different particles in the settler with time was investigated. The predicted results show that agglomeration is dominant during the sedimentation process and application of the discrete PBM with the CFD model enhances the predictive capability in comparison with the predictions obtained from only the two-fluid model. The results reported using CFD+PBM will aid in the design of continuous process equipment (thickener/precipitator) for Pu reconversion.

Study on corrosion characteristics of reinforcing bars in concrete under industrial SO2 environment

Sulfur dioxide (SO2) is the primary pollutant in industrial atmospheres, leading to significant damage to industrial buildings. The corrosion caused by SO2 in concrete, including neutralization and solid phase volume expansion, poses particular concerns. However, there is a lack of research on the electrochemical behaviour and corrosion mechanisms of reinforcing bars embedded in concrete. This study conducted indoor simulations of reinforced concrete specimens exposed to industrial SO2 corrosion utilizing an SO2 testing chamber. The corrosion behavior of the reinforcing bars was monitored through half-cell potential, weak polarization, and electrochemical impedance spectroscopy (EIS). Additionally, the corrosion mechanisms of the reinforcing bars under SO2 exposure were investigated using scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS), X-ray diffraction (XRD), and Raman spectra. The results demonstrated a consistent correlation between variations in corrosion potential (Ecorr) and corrosion current density (icorr) of steel rebars in different types of concrete. The corrosion rates of the reinforcing steel in C1 (w/b=0.57), C2 (w/b=0.47), and C3 (w/b=0.37) concrete exceeds 0.1 μA/cm2 after 42, 72, and 90 days of SO2 corrosion, respectively. At this time, the ratio of the depth of neutralization to the thickness of the protective layer is 0.51–0.65. The rust exhibits a layered structure with a presence of S elements adsorbed and deposited on the surface of the rust layer. Moreover, the research has identified the accumulation of S elements within corrosion pits, which can be attributed to localized acidification reactions. The rust products identified include iron hydroxide (FeOOH), and iron oxide (Fe2O3), rozenite (FeSO4·4 H2O). The formation of FeSO4·4 H2O in corrosion pits suggests that significant localized corrosion on the surface of reinforcing bars in concrete under the impact of SO2.

Ni agglomeration and performance degradation of solid oxide fuel cell: A model-based quantitative study and microstructure optimization

Nickel agglomeration poses a noteworthy impediment to the commercialization of SOFCs. A comprehensive coupled degradation model is established, encompassing a Ni-particle coarsening model, microstructural parameters, effective mesoscopic parameters, and various transport processes (mass/momentum/heat/charge/multi-species transports), and chemical/electrochemical reactions. The initial anode microstructural parameters are optimized by the comprehensive model and response surface method (RSM). Single-factor analysis shows that within the initial Ni-particle diameter (dNi(t=0)) range of 0.6–0.9 μm, a particle size ratio (R) of 1.0–1.5 between YSZ-particle and Ni-particle, and a solid-phase volume fraction of Ni-particle (ψNi) ranging from 0.35 to 0.55, SOFC demonstrates high power density and a reduced degradation rate. Using the single-factor results, RSM is employed for -anode microstructure optimization, specifying: dNi(t=0) = 0.7 μm, R = 1.0, and ψNi = 0.49. Correspondingly, the average power density at 0.6 V (PD‾0.6V) reaches 2828.5 W/m2, with a degradation rate (Vde) off 0.441 %/1000 h. In comparison to original microstructure parameters (dNi(t=0) = 0.6 μm, R = 1.0, ψNi = 0.4), the optimal SOFC exhibits a remarkable enhancement in electrical performance and durability, with an 11.9 % increase in PD‾0.6V and a 69 % reduction in Vde. The integration of the comprehensive model and RSM presents a promising strategy for predicting performance, refining operation condition, and optimizing electrode microstructure for long-term operating SOFC.

A pore-level 3D lattice Boltzmann simulation of mass transport and reaction in catalytic particles used for methane synthesis

Three-dimensional lattice Boltzmann (LB) simulations were carried out to investigate the mass transport and reaction inside and around catalytic porous particles used in fluidized beds for the synthesis of methane from biogas (H2/CO mixtures). The 3D internal porous structure of a real particle with a size ∼200 μm was assessed with Synchrotron-based X-ray tomography (XTM). Pore-resolved simulations with a suitable LB model for catalytic reactions in microflows revealed that the preferential diffusion of H2 and the resulting inability of CO to penetrate deep inside the pores led to segregated distributions of the two species, hindering reaction in the downstream parts of the particle and rendering CO the deficient reactant. The implications for practical fluidized beds are that, for specific bed zones with a high dense-phase (solid-phase) volume fraction and a predominant flow direction, CO starvation may occur and may thus limit the methane yields. Subsequent parametric studies of spherical particles with a diameter 2R=150 μm and an artificially generated porosity allowed comparisons of LB results with radially symmetric analytical continuum-model solutions. The LB simulations revealed appreciable angular variations in the CO concentration at the external surface (r=R) and the outer layers of particle, especially at the higher investigated Damköhler numbers, which were however diminished as the core of the particle (r→0) was approached. The large angular variations, in conjunction with the skewed CO distributions towards their lower values, led to LB-computed particle effectiveness factors ∼30% lower than the corresponding analytical solutions.

Study on flow and heat transfer characteristics of salt solution ice slurry

As a phase change material, ice slurry allows the storage of thermal energy in the form of latent heat. This has great advantages in terms of reducing energy consumption and environmental protection, and is being widely used. In this study, based on the Eulerian-Eulerian CFD model and the Population Balance Model (PBM), the flow and heat transfer characteristic of salt solution ice slurry was simulation studied, which included the pressure drop, friction coefficient, volume fraction, distribution of ice crystals and local heat transfer coefficient during the flow and solidification of salt solution ice slurry in different conditions. And the experimental system is set up to verify the results of the model and analyze the variation rules of these parameters. The results showed that in salt solutions with different concentrations, when the flow rate and solid phase volume fraction increase, the pressure drop and local heat transfer coefficient of the ice slurry will increase. The surface heat transfer coefficient reached to 2.5 × 103 W m-2 K-1, 2.9 × 103 W m-2 K-1, and 3.2 × 103 W m-2 K-1 when ice crystal volume fraction was 5 %, 10 %, and 15 %, respectively. The study will contribute to understanding of the changes in basic characteristics of salt solution slurry during the flow and phase transition processes.

Strategies to improve the thermal performance of solar collectors

Abstract The paper evaluates a passive method for heat transfer improvement in heat exchangers, which implies the use of nanofluids. All calculations were carried out with a constant volumetric flow rate. The study examines three fluids with 0–4 % volume concentrations of CuO, MgO, and Al2O3 particles. The results indicate an increase in the heat transfer coefficient with increasing temperature. An Al2O3 nanofluid (4 % concentration) contributed to the best thermal performance. The incorporation of a 4 % content of MgO yielded an augmentation in heat transfer ranging from 15 % to 22 %, whereas an analogous concentration of CuO led to a more substantial enhancement of 25 %. Notably, the introduction of nanoparticles of Al2O3 produces a remarkable augmentation in heat transfer performance, with potential improvements of up to 36 %. The Nusselt number increases with increasing particle volume fraction and Reynolds number, according to results obtained for several nanoparticles (Al2O3, CuO, SiO2, and ZnO) with volume percentages in the range of 1–4 % and nanoparticle diameters of 25–70 nm. For all nanofluids, the time-averaged Nusselt number rises with a solid phase volume fraction increase of less than 5 %.

Strategies to improve the thermal performance of solar collectors

Abstract The paper evaluates a passive method for heat transfer improvement in heat exchangers, which implies the use of nanofluids. All calculations were carried out with a constant volumetric flow rate. The study examines three fluids with 0–4 % volume concentrations of CuO, MgO, and Al2O3 particles. The results indicate an increase in the heat transfer coefficient with increasing temperature. An Al2O3 nanofluid (4 % concentration) contributed to the best thermal performance. The incorporation of a 4 % content of MgO yielded an augmentation in heat transfer ranging from 15 % to 22 %, whereas an analogous concentration of CuO led to a more substantial enhancement of 25 %. Notably, the introduction of nanoparticles of Al2O3 produces a remarkable augmentation in heat transfer performance, with potential improvements of up to 36 %. The Nusselt number increases with increasing particle volume fraction and Reynolds number, according to results obtained for several nanoparticles (Al2O3, CuO, SiO2, and ZnO) with volume percentages in the range of 1–4 % and nanoparticle diameters of 25–70 nm. For all nanofluids, the time-averaged Nusselt number rises with a solid phase volume fraction increase of less than 5 %.

Fluctuation analysis and spatial distribution model of particle concentration in a lab-scale scrubbing-cooling chamber

The motion and distribution of ash from coal gasification during the scrubbing and cooling process are crucial for revealing the fluid flow pattern and improving the efficiency of multiphase separation. Experimental measurements of the local solid holdup (εs) in the liquid pool of a laboratory-scale gas-liquid-solid three-phase scrubbing-cooling chamber were carried out using an optical fiber probe. The fluctuations of εs in time and frequency domains under different operating conditions were discussed. The axial and radial distribution of εs was quantitatively analyzed. The results showed that inter-particle collision and particle-fluid interaction are the key factors leading to a fluctuation in particle concentration. Axial uniformity of particle concentration can be quantified by solid-phase volume fraction, particle Reynolds number, Archimedes number, and Morton number; εs in different regions is expressed according to the degree of influence of bubble wake as a correlation equation consisting only of cross-sectional average solid holdup and dimensionless radial position; a dimensionless expression for εs concerning operating conditions was established.

Development and assessment of an onsite large volume solid phase extraction (LV-SPE) device for the determination of pharmaceuticals and personal care products (PPCPs) in water

It is essential to determine the occurrence of emerging organic contaminants (EOCs), such as pharmaceuticals and personal care products (PPCPs), in the ambient environment to address growing public concerns. However, such analysis is quite challenging due to the low trace level of such contaminants in water, which therefore requires several litres of water samples. In this study, a large volume solid phase extraction (LV-SPE) device was developed and evaluated for its performance in monitoring PPCPs as an example. Relatively good recoveries and reproducibility were obtained under specific operating conditions: a water sample volume of no more than 20 L, a flow rate not exceeding 120 mL/min, and a methanol elution volume of at least 30 mL. In addition, the results from the onsite enrichment approach using LV-SPE were compared with those from the conventional approach using a standard SPE device in the laboratory for real groundwater samples. Among the eight selected PPCPs (nalidixic acid, carbamazepine, bezafibrate, clofibric acid, sulfadiazine, sulfamethoxypyridazine, sulfamethazine and sulfamonomethoxine), LV-SPE approach detected more target compounds. While the detected concentrations were generally comparable, slightly higher concentrations were observed for carbamazepine, clofibric acid, sulfadiazine and sulfamethazine using the LV-SPE method. The developed LV-SPE device provides an alternative approach for trace analysis of PPCPs and may also be applicable for other emerging organic contaminants.

Research on the thermo-electrochemical behavior during the electrodeposition process of lithium metal battery

Lithium metal batteries (LMBs) are promising renewable energy storage device with higher energy density. During charging/discharging, the electrodeposition or dendrite growth on surface of Li electrode and temperature influence thermo-electrochemical behaviors in LMBs greatly. Coupling electrochemical reaction kinetic equations and thermal relations in electrode, as well as diffusion migrating equations of Li+ ion in electrolyte is employed to investigate the effects of temperature, charging current density, volume fraction of active solid and Li concentration in positive electrode, as well as salt concentration in electrolyte on the entropy production relating to power consumption and Joule heat, as well as cell voltage and overpotential in positive electrode and negative electrode with protrusion surface during charging. More polarization reactions together with larger heat generation take place, and cause more entropy generation in area of protrusion. The voltage efficiency is defined to evaluate thermo-electrochemical behaviors in LMBs, and the higher voltage efficiency occurs with the decrease in charging current density. The 93.6% voltage efficiency can be obtained in the case with solid-phase volume fraction of 0.518 in positive electrode under charging current density of 43.608A/m2. All results from investigation will be beneficial to obtain better thermo-electrochemical behavior in Li metal batteries.

Exploring the potential of hybrid nanofluids for enhanced heat transfer in a duct: A comprehensive study utilizing a phases-interaction driven multiphase mixture model

This study investigates the influence of phases interactions in hybrid nanofluids using a multiphase mixture model. Neglecting phase interaction for Al2O3-Cu leads to Nusselt number difference of 0.05 (volume fraction 0.1%), increasing to 0.6 at volume fraction 2%. Among investigated nanofluids (Al2O3-Au NPs, Al2O3-CuO, Al2O3-TiO2, CuO-Au NPs, CuO-TiO2, TiO2-Au NPs), those with gold nanoparticles exhibit exceptional heat transfer enhancements: Al2O3-Au NPs (63.85%), CuO-Au NPs (64.65%), and TiO2-Au NPs (62.10%) at 3% total solid phase volume fraction. CuO-Au NPs perform best, except at ∼5% volume fraction where Al2O3-Au NPs excel. Optimization shows increasing gold particle volume fractions benefit particularly at higher Reynolds numbers. For CuO-Au NPs, highest average Nusselt numbers are obtained at gold volume fractions of 10%, 20%, 40%, and 60% of total solid phases volume fractions for Reynolds numbers 300, 500, 1000, and 2000, respectively. Moreover, the investigation showed that the performance index generally increases with volume fraction up to 5%, except for hybrid nanofluids with gold particles. Notably, in the presence of gold particles, the performance index rises distinctly up to a volume fraction of 3%, followed by a subsequent decline.

Target Screening of Chemicals of Emerging Concern (CECs) in Surface Waters of the Swedish West Coast

The aquatic environment faces increasing threats from a variety of unregulated organic chemicals originating from human activities, collectively known as chemicals of emerging concern (CECs). These include pharmaceuticals, personal-care products, pesticides, surfactants, industrial chemicals, and their transformation products. CECs enter aquatic environments through various sources, including effluents from wastewater treatment plants, industrial facilities, runoff from agricultural and residential areas, as well as accidental spills. Data on the occurrence of CECs in the marine environment are scarce, and more information is needed to assess the chemical and ecological status of water bodies, and to prioritize toxic chemicals for further studies or risk assessment. In this study, we describe a monitoring campaign targeting CECs in surface waters at the Swedish west coast using, for the first time, an on-site large volume solid phase extraction (LVSPE) device. We detected up to 80 and 227 CECs in marine sites and the wastewater treatment plant (WWTP) effluent, respectively. The dataset will contribute to defining pollution fingerprints and assessing the chemical status of marine and freshwater systems affected by industrial hubs, agricultural areas, and the discharge of urban wastewater.

Two-particle method for liquid–solid two-phase mixed flow

Liquid–solid two-phase flows are a very important class of multiphase flow problems widely existing in industry and nature. This paper establishes a two-phase model for liquid–solid two-phase flows considering multiphase states of granular media. The volume fraction is defined by the solid phase, determining the material properties of the two phases, and momentum is exchanged between the phases by drag and pressure gradient forces. On this basis, a two-particle method for simulating the liquid–solid two-phase flow is proposed by coupling smoothed particle hydrodynamics with smoothed discrete particle hydrodynamics. The coupling framework for the two-particle method is constructed, and the coupling between the algorithms is realized through interphase momentum exchange, volume fraction constraint, and field variable sharing. The liquid phase density changes are divided into two types. One is caused by weak compressibility, and the other is caused by changes in the solid phase volume fraction. The former is used to calculate the liquid-phase flow field, and the latter is used to calculate the two-phase coupling to solve the problem of sudden bulk density changes in the liquid phase caused by changes in particle volume fractions. The two-particle method maintains the dual advantages of the particle method for free interface tracking and material point tracking for particles. The new method is validated using a series of fundamental test cases, and comparison with experimental results shows that the new method is suitable for resolving liquid–solid two-phase flow problems and has significant practical value for future simulations of mudflow motions, coastal breakwaters, and landslide surges.

TPMS metamaterial structures based on shape memory polymers: Mechanical, thermal and thermomechanical assessment

Triply periodic minimal surfaces (TPMS) are a type of metamaterial that get their unusual properties from the topology of microstructure elements, but they provide non-controllable properties. Utilizing shape memory polymer as a base material, it is possible to control the properties of these structures and create significant and reversible changes in the stiffness, geometry, and performance of metamaterials which could be applicable in many application fields. In this work, the thermal, mechanical, and shape memory behavior of 8 SMP-based TPMS structures has been studied in a wide range of the solid phase volume fractions (i.e., 35–65%). In the thermomechanical analysis, we consider the shape recovery%, the force recovery%, and the shape fixity% as the shape memory properties. For this purpose, the structures were simulated using thermo-visco-hyperelastic constitutive equations. Also, the temperature rate and elastic modulus are considered as the representative thermal and mechanical properties, respectively. Results of this study indicate that the best shape memory and mechanical behaviors belong to the Primitive structure at all different Volume fractions. And the best overall performance for different 8 TPMS structures including the best thermal, mechanical, and thermomechanical behavior accrues at VF = 40% and is sorted as FKS > FRD > Diamond > Diamond-type 2 > Gyroid > IWP > Primitive > Neovious.