Understanding the relationships between electrochemical characteristics and the corresponding parameters of the battery is crucial for optimizing cell design, which creates new ideas for safe management and optimized service life of lithium-ion batteries. Herein, a pseudo two-dimensional (P2D) electrochemical model of 4.35 V prismatically wound LiCoO2 pouch cell is established and optimized to predict its electrochemical behaviors. Based on the significant factors of cell design parameters by analysis of variance, the distribution characteristics of solid and electrolyte-phase Li+ concentration, potential of solid and electrolyte-phase, over-potential and local current density are investigated and verified, which is conducive to provide quantitative guidance for battery design and optimization. Simulation results show that the change of electrolyte-phase Li+ concentration gradient is 14.3% at 1C rate, and the concentration gradient decreases with the increase of the electrolyte phase diffusion coefficient and Li+ transference number. In addition, the particle size shows a positive correlation with the surface lithium ion concentration, while the electrode thickness, solid phase volume fraction and solid phase diffusion coefficient are negatively correlated with the surface lithium ion concentration. The model indicates that the polarization of anode is more than twice as larger as than that of the cathode at 1C discharge. Moreover, simulation results demonstrate that the peak of local current density moved from the separator interface to the current collector interface as discharge proceeded, which further reveal the non-uniform distribution of the electrochemical reaction rate in the cell.
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