Solid Phase Behavior Research Articles

Numerical analysis of solid phase hydrodynamics in a continuous precipitator relevant for plutonium reconversion

The extensive application of solid-liquid flow in various industries, has made it important to comprehend the hydrodynamics inside different process equipment and optimize their operation. In the present work, solid phase hydrodynamics in a continuous precipitator relevant for plutonium (Pu) reconversion has been investigated numerically. Euler-Euler two-fluid simulations were performed to analyse the performance by varying the solid concentration (5, 10, 15, and 20 g/l), impeller speed (500 and 700 rpm) and overflow outlet height (0.65, 0.75 and 0.85 m). The solid phase behaviour in precipitator is analysed by comparing the solid volume fraction and pressure distributions along the height. To enable easy handling of precipitator inside glove-box, the solid mass, volume rate and pressure distributions through overflow outlet at different height is thoroughly investigated. Further, the effect of solid concentration and rotating speed of impeller on radial velocity distribution is analysed. The results show that overflow of solid phase is dependent on dispersed phase concentration and rotating speed of the impeller. Further, the increase in overflow outlet height increases the overflow time. However, the volume fraction of solid remains constant during the steady operation. The study will be helpful to design a glove-box adaptable precipitator for continuous plutonium reconversion.

QUANTAS: a Python software for the analysis of thermodynamics and elastic behavior of solids from ab initio quantum mechanical simulations and experimental data.

Mineralogy, petrology and materials science are fundamental disciplines not only for the basic knowledge and classification of solid phases but also for their technological applications, which are becoming increasingly demanding and challenging. Characterization and design of materials are of utmost importance and usually need knowledge of the thermodynamics and mechanical stability of solids. Alongside well known experimental approaches, in recent years the advances in both quantum mechanical methods and computational power have placed theoretical investigations as a complementary useful and powerful tool in this kind of study. In order to aid both theoreticians and experimentalists, an open-source Python-based software, QUANTAS, has been developed. QUANTAS provides a fast, flexible, easy-to-use and extensible platform for calculating the thermodynamics and elastic behavior of crystalline solid phases, starting from both experimental and ab initio data.

Solid phase behavior of mixture systems based on tripalmitoyl glycerol and monounsaturated triacylglycerols forming a molecular compound.

Differential scanning calorimetry and X-ray diffraction were used to investigate the mixing behavior of triacylglycerol (TAG) mixtures of PPP/PPO (tripalmitoyl glycerol/1,2-dipalmitoyl-3-oleoyl-rac-glycerol) and PPP/MCPOP/PPO (where MCPOP/PPO is the equimolecular blend of 1,3-dipalmitoyl-2-oleoyl-glycerol and PPO forming a molecular compound) under metastable and stable conditions. During cooling and reheating treatments at moderate rates, the eutectic properties of the two systems examined were mainly governed by the crystallization, transformation, and melting behavior of structurally similar β' forms. In addition, steric and kinetic effects determined the formation of solid solutions with up to 10% and 20% of mixed-acid components in PPP/PPO and PPP/MCPOP/PPO mixtures, respectively. These values increased to 30% and 35% when thermodynamically stable β crystalline phases were obtained. In PPP/MCPOP/PPO mixtures, the diffraction data suggested that POP and PPO acted as a single component by dissolving in similar amounts in the solid solution phases and forming molecular compound crystals in eutectic compositions. This fundamental research shows the important role of specific combinations of mixed-acid TAGs and their interaction with high-melting components on the solidification behavior of edible lipids.

Anisotropy and inhomogeneity of permeability and fibrous network response in the pars intermedia of the human lateral meniscus

Within the human tibiofemoral joint, meniscus plays a key role due to its peculiar time-dependent mechanical characteristics, inhomogeneous structure and compositional features. To better understand the pathophysiological mechanisms underlying this essential component, it is mandatory to analyze in depth the relationship between its structure and the function it performs in the joint. Accordingly, the aim of this study was to evaluate the behavior of both solid and fluid phases of human meniscus in response to compressive loads, by integrating mechanical assessment and histological analysis. Cubic specimens were harvested from seven knee lateral menisci, specifically from anterior horn, pars intermedia and posterior horn; unconfined compressive tests were then performed according to three main loading directions (i.e., radial, circumferential and vertical). Fibril modulus, matrix modulus and hydraulic permeability of the tissue were thence estimated through a fibril-network-reinforced biphasic model. Tissue porosity and collagen fibers arrangement were assessed through histology for each region and related to the loading directions adopted during mechanical tests. Regional and strain-dependent constitutive parameters were finally proposed for the human lateral meniscus, suggesting an isotropic behavior of both the horns, and a transversely isotropic response of the pars intermedia. Furthermore, the histological findings supported the evidences highlighted by the compressive tests. Indeed, this study provided novel insights concerning the functional behavior of human menisci by integrating mechanical and histological characterizations and thus highlighting the key role of this component in knee contact mechanics and presenting fundamental information that can be used in the development of tissue-engineered substitutes. Statement of significanceThis work presents an integration to the approaches currently used to model the mechanical behavior of the meniscal tissue. This study assessed in detail the regional and directional contributions of both the meniscal solid and fluid phases during compressive response, providing also complementary histological evidence. Within this updated perspective, both knee computational modeling and meniscal tissue engineering can be improved to have an effective impact on the clinical practice.

Improving efficiency and feasibility of subcritical water debromination of printed circuit boards E-waste via potassium carbonate adding

Waste printed circuit boards (WCBs) were debrominated under hydrothermal treatment, using potassium carbonate as an alkaline additive to improve debromination efficiency (DE). Two different high-pressure reactors were used: a 1-L stirred reactor, where the evolution of the DE was followed over time at a low CO32−/Br− ratio (1:25), and an elementary 0.1-L non-stirred reactor, used to find the optimal parameters and to simplify the hydrothermal debromination (HTD) process. Considering both reactors, experiments were conducted changing the temperature (200 °C, 225 °C, 250 °C, 275 °C), and also the CO32−/Br− anionic ratio (1:50, 1:25, 1:10, 1:5, 1:2.5, 1:1, 2:1, 4:1) and the solid/liquid ratio (1:10, 1:5, 1:2) in the case of the 0.1-L reactor. No metallic catalyst was required.A maximum DE of about 98.9 wt % was reached in the agitated vessel at 275 °C after 4 h, with an additive/bromine ratio of 1:25. Similar DE (99.6 wt %) was also achieved in the non-stirred reactor at only 225 °C and after 2 h, using an additive/bromine ratio of 4:1 and a solid/liquid ratio of only 1:2. Concerning the solid phase behaviour during debromination, only 5 % of the net calorific value (NCV) was lost after a complete HTD treatment of WCB.

Tracking the Amide I and αCOO- Terminal ν(C=O) Raman Bands in a Family of l-Glutamic Acid-Containing Peptide Fragments: A Raman and DFT Study.

The E-hook of β-tubulin plays instrumental roles in cytoskeletal regulation and function. The last six C-terminal residues of the βII isotype, a peptide of amino acid sequence EGEDEA, extend from the microtubule surface and have eluded characterization with classic X-ray crystallographic techniques. The band position of the characteristic amide I vibration of small peptide fragments is heavily dependent on the length of the peptide chain, the extent of intramolecular hydrogen bonding, and the overall polarity of the fragment. The dependence of the E residue’s amide I ν(C=O) and the αCOO− terminal ν(C=O) bands on the neighboring side chain, the length of the peptide fragment, and the extent of intramolecular hydrogen bonding in the structure are investigated here via the EGEDEA peptide. The hexapeptide is broken down into fragments increasing in size from dipeptides to hexapeptides, including EG, ED, EA, EGE, EDE, DEA, EGED, EDEA, EGEDE, GEDEA, and, finally, EGEDEA, which are investigated with experimental Raman spectroscopy and density functional theory (DFT) computations to model the zwitterionic crystalline solids (in vacuo). The molecular geometries and Boltzmann sum of the simulated Raman spectra for a set of energetic minima corresponding to each peptide fragment are computed with full geometry optimizations and corresponding harmonic vibrational frequency computations at the B3LYP/6-311++G(2df,2pd) level of theory. In absence of the crystal structure, geometry sampling is performed to approximate solid phase behavior. Natural bond order (NBO) analyses are performed on each energetic minimum to quantify the magnitude of the intramolecular hydrogen bonds. The extent of the intramolecular charge transfer is dependent on the overall polarity of the fragment considered, with larger and more polar fragments exhibiting the greatest extent of intramolecular charge transfer. A steady blue shift arises when considering the amide I band position moving linearly from ED to EDE to EDEA to GEDEA and, finally, to EGEDEA. However, little variation is observed in the αCOO− ν(C=O) band position in this family of fragments.

Immiscibility in N2–H2O solids up to 140 GPa

Nitrogen and water are very abundant in nature; however, the way they chemically react at extreme pressure-temperature conditions is unknown. Below 6GPa, they have been reported to form clathrate compounds. Here, we present Raman spectroscopy and x-ray diffraction studies in the H2O-N2 system at high pressures up to 140GPa. We find that clathrates, which form locally in our diamond cell experiments above 0.3GPa, transform into a fine grained state above 6GPa, while there is no sign of formation of mixed compounds. We point out size effects in fine grained crystallites, which result in peculiar Raman spectra in the molecular regime, but x-ray diffraction shows no additional phase or deviation from the bulk behavior of familiar solid phases. Moreover, we find no sign of ice doping by nitrogen, even in the regimes of stability of nonmolecular nitrogen.

Synthesis, characterization and thermal behaviour of solid phases in the quasi-ternary system Mg(SCN)2-H2O-THF.

Mg(SCN)2·4H2O can be converted into previously unknown compounds Mg(SCN)2·(4 - x) H2O·xTHF with x = 0, 2 and 4 by multiple recrystallization in tetrahydrofuran (THF). The phases were characterized by infrared spectroscopy (IR), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), and their crystal structures were solved from X-ray powder diffraction (XRPD) data. In the crystal structures isolated Mg(NCS)2(H2O)4-x(THF)x units form layered motifs. The thermal behavior of Mg(SCN)2·4H2O and Mg(SCN)2·4THF was investigated by temperature dependent in situ XRPD, where Mg(SCN)2·4THF was found to acquire a room temperature (α-form) and high temperature modification (β-form). The phase transformation is associated with an order-disorder transition of the THF molecules and with a reversion of the stacking order of the layered motifs. Further heating eventually leads to the formation of Mg(SCN)2·2THF. There thiocyanate related sulfur atoms fill the voids in the coordination sphere of magnesium, which leads to the formation of one dimensional electroneutral ∞[Mg(NCS)2/2(SCN)2/2(THF)2] chains. All investigated Mg(SCN)2·(4 - x) H2O·xTHF phases exhibit a remarkable anisotropic thermal expansion, and Mg(SCN)2·4H2O and Mg(SCN)2·2THF were found to show both positive and negative thermal expansion coefficients.

Effect of different derivatives of paraffin waxes on crystallization of eutectic mixture of cocoa butter-coconut oil

Paraffin wax is a mixture of numerous unbranched hydrocarbons used frequently for various purposes: to improve the shelf life of products containing lipid system and develop more shiny products. However, because of its complex nature, the effect of such molecular structure on the solid phase behavior of lipids is hardly unstated. Hence in our study, we focus on understanding the impact of derivatives of paraffin wax on the lipid system. In the current work, three unbranched derivatives of paraffin wax: Eicosane C (20), Pentacosane C (25) and Triacontane C (30) were selected as additives. These n-alkanes are specifically added to the eutectic mixture of cocoa butter (CB) and coconut oil (CO) (ECB-CO) to observe the effect on thermal, morphological, rheological properties and crystallization kinetics with respect to the carbon chain length. Results from our study illustrate that melting and crystallization temperature, storage modulus and solid fat content (SFC) increases after the addition of 1 wt% of C (20), C (25). In contrast, there is a phase separation for 1 wt% C (30). Further similar study with addition of n-alkanes to pure CB and CO reveals that the interaction of n-alkanes with ECB-CO is dominated by the interaction of n-alkanes with CO instead of CB. Therefore, our findings provide insight into the effect of addition of n-alkanes having different carbon chain length and their respective concentration on crystallization process of CB and CO. This will definitely help to design the processes for products containing such model systems.

On the quantification of solid phases in hydrated cement paste by 1H nuclear magnetic resonance relaxometry

Different solid phases, important to cement paste hydration, are investigated with low-field benchtop 1H nuclear magnetic resonance (NMR). A combination of the well-established quadrature echo pulse sequence with variable pulse gap together with a T1 saturation recovery quadrature echo pulse sequence is used. The results illustrate the diversity in the 1H NMR relaxation behaviour of solid phases that prospects the differentiation in more complex materials. We propose a procedure to obtain quantified values of the solid compounds using these unique relaxation responses of solids, called finger print, and apply this technique to well-hydrated white and ordinary Portland cement paste. Based on the results, needs and ways for future improvements are discussed.

A Numerical Study on Effects of Electrolyte Dry-out in Separators of Lithium-Ion Batteries

A variety of strategies to deal with the Lithium-ion batteries (LIBs) reaching the end-of-life (EOL) is being proposed, one of which is the secondary use applications such as the grid distribution system or the off-grid system. [1] It is reported that within the EOL range, the capacity fade generally represents linear dependence on charge throughput and that SEI layer growth is the dominant factor. After prolonged cycling, however, the transition point to the nonlinearity of aging is observed and the LIBs capacity dropped suddenly, indicating that some other aging mechanisms. [2] This rapid capacity drop phenomenon has been reported by experimental tests of other groups. [3-5] Among many phenomena related to the rapid drops, electrolyte dry-out including decomposition of additives has been considered as one of the major factors.In this work, we employ an electrochemical physical model for 20Ah NCM pouch-type cell, which describes both solid and liquid phase behavior through a concentrated solution and porous electrodes. A pseudo-two-dimensional (P2D) electrochemical physical model calculates lithium concentrations and electric potentials in the electrolyte and the active materials and allows them to expand to additional physical phenomena. Saturation in the porous media is defined to account for the dry-out of the electrolyte. Because electrodes have higher wettability than separators, if the decreases of saturation occur in the LIBs, the problem area is more likely to be a porous separator than a composite electrode. [6] For this reason, we assumed that saturation reduction occurs only at separators as the electrolytes are decreased in the cell. Reduced saturation in a separator can be followed by a block of ionic transport through separator pores, and result in the sudden death of LIBs battery.The P2D model cannot solve non-uniform phenomena appearing along the electrode area because of a one-dimensional calculation in the electrode thickness direction. Therefore, an expanded pseudo-three-dimensional (P3D) model was used to examine how dry-out in the separator affects the physics of the LIBs quantitatively. The P3D model is possible to simulate the imbalance in LIBs cells as well as the end-of-life of LIBs. Also, parametric studies about area and saturation of the dry-out we conducted by the model. The model results show that there is a critical saturation of the dry-out leading a sharp performance drop. This model can account for the sudden degradation of LIBs and the loss of ionic path and the internal imbalance caused by electrolyte dry-out.

Transmission electron microscopy analysis of multiblock ethylene/1-octene copolymers

The crystalline morphology of ethylene/1-octene (EO-BC) statistical multiblock copolymers is investigated by transmission electron microscopy (TEM). EO-BCs are an important class of thermoplastic elastomers characterized by alternating crystalline, octene-poor, hard blocks and amorphous, octene-rich, soft blocks and statistical distribution of block length (BL) and number of blocks/chain (NB). Adopting similar crystallization conditions, samples with only subtle differences in the chain microstructure, are shown to display different solid-state morphology as probed by TEM and different melt rheology. In particular, the homogeneous or heterogeneous lamellar morphology which develops in the solid state reflects the tendency of the samples to show homogeneous or heterogeneous melt-rheology, respectively. As EO-BCs are a reactor blend of non-uniform chains, it is argued that the solid state and melt phase behavior of EO-BCs is controlled by differences in the relative abundance of chains including a prevalence of hard blocks of short and/or high length.

Excess enthalpy of mixing of mineral solid solutions derived from density-functional calculations

Calculations using the density-functional theory (DFT) in combination with the single defect method were carried out to determine the heat of mixing behaviour of mineral solid solution phases. The accuracy of this method was tested on the halite–sylvite (NaCl–KCl) binary, pyrope–grossular garnets (Mg3Al2Si3O12–Ca3Al2Si3O12), MgO–CaO (halite structure) binary, and on Al/Si ordered alkali feldspars (NaAlSi3O8–KAlSi3O8); as members for coupled substitutions, the diopside–jadeite pyroxenes (CaMgSi2O6–NaAlSi2O6) and diopside–CaTs pyroxenes (CaMgSi2O6–CaAlAlSiO6) were chosen for testing and, as an application, the heat of mixing of the tremolite–glaucophane amphiboles (Ca2Mg5Si8O22(OH)2–Na2Mg3Al2Si8O22(OH)2) was computed. Six of these binaries were selected because of their experimentally well-known thermodynamic mixing behaviours. The comparison of the calculated heat of mixing data with calorimetric data showed good agreement for halite–sylvite, pyrope–grossular, and diopside–jadeite binaries and small differences for the Al/Si ordered alkali feldspar solid solution. In the case of the diopside–CaTs binary, the situation is more complex because CaTs is an endmember with disordered cation distributions. Good agreement with the experimental data could be, however, achieved assuming a reasonable disordered state. The calculated data for the Al/Si ordered alkali feldspars were applied to phase equilibrium calculations, i.e. calculating the Al/Si ordered alkali feldspar solvus. This solvus was then compared to the experimentally determined solvus finding good agreement. The solvus of the MgO–CaO binary was also constructed from DFT-based data and compared to the experimentally determined solvus, and the two were also in good agreement. Another application was the determination of the solvus in tremolite–glaucophane amphiboles (Ca2Mg5Si8O22(OH)2–Na2Mg3Al2Si8O22(OH)2). It was compared to solvi based on coexisting amphiboles found in eclogites and phase equilibrium experiments.

Absorptive Dissolution Testing: An Improved Approach to Study the Impact of Residual Crystallinity on the Performance of Amorphous Formulations

Amorphous solid dispersions typically improve the oral bioavailability of poorly soluble drugs. However, residual crystallinity is always a concern, in terms of potential impact on the product stability and performance. Consequently, in vitro tools that allow biorelevant assessment of residual crystallinity are of interest. The goal of the present study was to use absorptive dissolution testing to evaluate the impact of different levels of crystallinity in an amorphous formulation on membrane mass transport kinetics and supersaturation-time profiles. Partial crystallinity was induced in commercially available tacrolimus formulations by exposure to moderate temperature and high relative humidity. A hollow fiber membrane was coupled to a dissolution vessel to create an absorptive dissolution testing apparatus, and concentration-time profiles were simultaneously monitored during dissolution (donor compartment) and after absorption across the membrane (receiver compartment). The coupled dissolution-absorption measurements indicated that residual crystallinity impacted the absorption profiles in a manner that depended on the volume of fluid used for the dissolution measurement. A high percentage of residual crystallinity hampered the drug release from the formulation. Higher supersaturation in nonsink dissolution conditions improved mass transfer rates; however, the presence of seed crystals led to rapid desupersaturation. Further systematic studies to delineate the interplay between the rate of absorption and desupersaturation revealed that for a given dissolution rate, the crystallization rate would supersede the absorption rate only at high supersaturations. Thus, seeds have a lower impact on absorption when the overall supersaturation generated is lower. This study underscores the importance of considering competing physical processes when evaluating amorphous formulations. A further consideration highlighted is that different fluid volumes may impact the absorption profile for supersaturating dosage forms. Absorptive dissolution testing appears to be a potentially valuable tool to mechanistically investigate amorphous solid dispersion formulation release and phase behavior under more biorelevant conditions.

Dechlorination of polyvinyl chloride electric wires by hydrothermal treatment using K2CO3 in subcritical water

Polyvinyl chloride (PVC) waste generation has significantly increased in recent years and their disposal is considered a major environmental concern. Removal techniques of chlorine from PVC waste are being studied to minimize a negative environmental impact. In this work, the use of K2CO3 as an alkaline additive to improve the dechlorination efficiency (DE) in the hydrothermal degradation of PVC wires was studied. Different experiments were carried out varying both temperature (175, 200, 225, 235 and 250 °C) and K2CO3 concentration (0.025, 0.050 and 0.125 M), using a solid/liquid ratio of 1:5 in order to determine the evolution of the dechlorination efficiency with time. About 4.66, 21.1, 24.4, 45.7 and 92.6 wt% of chlorine in PVC wire was removed during hydrothermal dechlorination (HTD) with an additive/chlorine ratio of 1:25 (K2CO3 solution of 0.050 M) at 175, 200, 225, 235 and 250 °C, respectively. Optimal additive/chlorine ratio decreased to 1:50 (K2CO3 solution of 0.025 M) at 250 °C, obtaining a dechlorination degree of 99.1% after 4 h without the need of metallic catalysts. Concerning the solid phase behavior during dechlorination, a linear correlation between the DE reached and the weight loss of PVC was found.

Lagrangian method to simultaneously characterize transport behaviour of liquid and solid phases: a feasibility study in a confined vortex ring

Lagrangian method to simultaneously characterize transport behaviour of liquid and solid phases: a feasibility study in a confined vortex ring

The Ternary Solid State Phase Behavior of Triclinic POP, POS, and SOS and Its Relationship to CB and CBE Properties

The ternary phase behavior between 1,3-dipalmitoyl-2-oleoyl-glycerol (POP), 1-palmitoyl-2-oleoyl-3-stearoyl-glycerol (POS), and 1,3-distearoyl-2-oleoyl-glycerol (SOS) in their triclinic crystal polymorphic forms was determined. The phase behavior was studied for samples crystallized from acetone and from the melt in the β2 polymorphic form. The melting point, enthalpy of fusion, crystal structure, and solid fat content (SFC) were determined for different proportions of POP:POS:SOS and compared to cocoa butter (CB) and three enzymatically synthesized cocoa butter equivalents (CBEs). A dramatic reduction in the melting point of ternary mixtures was observed with increasing POP content. The eutectic behavior between POP:POS and POP:SOS caused melting drop with increasing POP content. A eutectic region for POP:POS was also identified at 50:50:0 (w/w/w) POP:POS:SOS, while a novel specific composition of higher melting point was identified at 40:40:20 (w/w/w) POP:POS:SOS. The polymorphism of the CBEs and CB see...

Computational modelling of water flow inside laboratory Knelson concentrator bowl

ABSTRACTEnhanced gravity concentrators such as Knelson concentrator (KC) are extensively used in the mineral processing industry. The complexities of KC bowl geometry and variation of feed characteristics have forced process engineers to design empirically new units using laboratory and pilot-scale Knelson concentrators. However, numerical modelling methods such as computational fluid dynamics (CFD) and discrete element method (DEM) provide a better insight of flow behaviour of fluid and particulate solid phases inside these processing units. This article reports findings of CFD simulations for single-phase water flow inside the laboratory KC. An available standard 7.5-cm laboratory KC bowl was numerically simulated using realisable k-ε turbulence model to resolve the turbulence dispersion of existing transitional flow regime. The effects of relative centrifugal force (RCF) intensity and bed fluidisation water flow rate on the water velocity and pressure distributions were studied. Simulations confirmed the swirling flow pattern governing inside the bowl. The results revealed that the impact of RCF intensity on the water field values is greater than that of bed fluidisation water flow rate. Both velocity and pressure variations inside the bowl rings followed a linear trend.

Solid Phase Behavior, Polymorphism, and Crystal Structure Features of Chiral Drug Metaxalone

In addition to the previously known A-rac and B-rac polymorphs of the chiral drug metaxalone 1, an enantiopure A-(S)-form was obtained and studied. According to X-ray analysis, the crystalline organization of this form is close to the A-rac-1 polymorph. Crystallization of metaxalone melts is accompanied by the formation of a previously unknown metastable C-phase, which in the case of both racemic and enantiomeric samples are transformed into A-rac-1 or A-(S)-1. Analysis of the PXRD and IR spectra of crystalline samples revealed a similarity of the internal structure for the A-(S)-1, A-rac-1, C-(S)-1, and C-rac-1 crystalline forms and the essential difference of all of these phases from the B-rac-1 phase. According to the thermochemical data, the dependences of the change in the Gibbs free energy for all the phases studied are plotted in the interval from the melting point to 20 °C. Under standard conditions, the crystalline modifications of metaxalone, relative to ΔG0, form such a series: B-rac-1 < A-(S)-...

Strain-rate controlled Gleeble experiments to determine the stress-strain behavior of HSLA steel S960QL

Abstract In order to generate a material data base for computational welding mechanics, temperature and strain-rate dependent stress-strain experiments were performed by using a Gleeble® 3500 testing system. The object of the investigation was HSLA transformable steel S960QL and related solid phases as bainite, martensite and austenite. For the production of these solid phases, the base material was heat treated according to an average weld temperature cycle which was extracted within the heat affected zone of a thermal numerical weld simulation of a GMA weld. The hot tensile tests were carried out via cost-saving flat specimen geometries. Two experimental series with different strain-rates were conducted, where the longitudinal strain-rate was controlled by specification of the transversal strain-rate applying Poisson's-ratio. Subsequently, the resulting stress-strain curves were approximated in accordance with the Ramberg-Osgood-materials law. Consequently, it is shown that the temperature and strain-rate dependent stress-strain behavior of metals can be successfully characterized by means of a Gleeble®-system. However, this requires a control of the longitudinal strain-rate by specification of the transversal strain-rate. The related experimental procedure and the method of evaluation are explained in detail. With regard to all tested solid phases, a significant strain-rate dependency can only be observed upwards from temperatures of 400 °C. Based on experimental results, Ramberg-Osgood-parameters will be presented to describe the stress-strain behavior of steel S960QL and related solid phases for temperatures between 25 °C and 1200 °C. Furthermore, the use of cost-saving flat specimen-geometry appears reasonable.