Solid Materials Research Articles

Study on the swelling of macromolecular geological organic matter with hydrocarbons and heteroatomic compounds

In this study, we conducted swelling experiments on eleven macromolecular geological organic materials using five types of organic solvents. Our primary objective was to investigate the absorption capacity of different solid organic materials in organic fluids and analyze the influence of their chemical structures. The samples utilized in this research included solid bitumen, kerogen, and coal samples from various basins. The chemical structure of the samples was assessed using solid-state 13C nuclear magnetic resonance (NMR), while X-ray diffraction (XRD) was employed to monitor any detect the structural changes during the swelling process. Our findings reveal that macromolecular geological organic compounds demonstrate a preferential expulsion of saturated hydrocarbons, followed by polycyclic aromatic hydrocarbons, upon interaction with liquid organic matter. The sulfur-containing compounds in solid organic matter demonstrated higher solubility than hydrocarbon compounds, while the solubility of oxygen-containing compounds varied based on the structure of the aliphatic chain and the proportion of oxygen atoms. This research, introduces LA [= Lac × Aac] as a new parameter to assess the combination of aliphatic chain length [Lac] and [Aac] abundance in solid organic matter. Furthermore, XRD testing revealed that the chemical structure unit of heteroatom compounds in solid organic matter consists of amorphous carbon, primarily composed of aliphatic chains. In this study, we evaluated the retention capacity of various macromolecular geological organic matter for both hydrocarbons and heteroatomic compounds. Additionally, the extent of swelling was investigated, providing theoretical support to diverse fields including organic petrology, petroleum geology, coal geology, and organic geochemistry.

Fabricating Ultrathin Imprinting Layer for Fast Capture of Valsartan via a Metal Affinity-Oriented Surface Imprinting Method.

Rapid separation and enrichment of targets in biological matrixes are of significant interest in multiple life sciences disciplines. Molecularly imprinted polymers (MIPs) have vital applications in extraction and sample cleanup owing to their excellent specificity and selectivity. However, the low mass transfer rate, caused by the heterogeneity of imprinted cavities in polymer networks and strong driving forces, significantly limits its application in high-throughput analysis. Herein, one novel metal affinity-oriented surface imprinting method was proposed to fabricate an MIP with an ultrathin imprinting layer. MIPs were prepared by immobilized template molecules on magnetic nanoparticles (NPs) with metal ions as bridges via coordination, and then polymerization was done. Under the optimized conditions, the thickness of the imprinting layer was merely 1 nm, and the adsorption toward VAL well matched the Langmuir model. Moreover, it took just 5 min to achieve adsorption equilibrium significantly faster than other reported MIPs toward VAL. Adsorption capacity still can reach 25.3 mg/g ascribed to the high imprinting efficiency of the method (the imprinting factor was as high as 5). All evidence proved that recognition sites were all external cavities and were evenly distributed on the surface of the NPs. The obtained MIP NPs exhibited excellent selectivity and specificity toward VAL, with good dispersibility and stability. Coupled with high-performance liquid chromatography, it was successfully used as a dispersed solid phase extraction material to determine VAL in serum. Average recoveries are over 90.0% with relative standard deviations less than 2.14% at three spiked levels (n = 3). All evidence testified that the MIPs fabricated with the proposed method showed a fast trans mass rate and a large rebinding capacity. The method can potentially use high-throughput separation and enrichment of target molecules in batch samples to meet practical applications.

Discovering melting temperature prediction models of inorganic solids by combining supervised and unsupervised learning.

The melting temperature is important for materials design because of its relationship with thermal stability, synthesis, and processing conditions. Current empirical and computational melting point estimation techniques are limited in scope, computational feasibility, or interpretability. We report the development of a machine learning methodology for predicting melting temperatures of binary ionic solid materials. We evaluated different machine-learning models trained on a dataset of the melting points of 476 non-metallic crystalline binary compounds using materials embeddings constructed from elemental properties and density-functional theory calculations as model inputs. A direct supervised-learning approach yields a mean absolute error of around 180K but suffers from low interpretability. We find that the fidelity of predictions can further be improved by introducing an additional unsupervised-learning step that first classifies the materials before the melting-point regression. Not only does this two-step model exhibit improved accuracy, but the approach also provides a level of interpretability with insights into feature importance and different types of melting that depend on the specific atomic bonding inside a material. Motivated by this finding, we used a symbolic learning approach to find interpretable physical models for the melting temperature, which recovered the best-performing features from both prior models and provided additional interpretability.

Study on triaxial compression performance and damage characteristics of fiber-reinforced ecological matrix cementing gangue gypsum fill material.

Polypropylene fiber was equally mixed into alkali-activated slag fly ash geopolymer in order to ensure the filling effect of mine goaf and improve the stability of cemented gangue paste filling material with ecological matrix. Triaxial compression tests were then conducted under various conditions. The mechanical properties and damage characteristics of composite paste filling materials are studied, and the damage evolution model of paste filling materials under triaxial compression is established, based on the deviatoric stress-strain curve generated by the progressive failure behavior of samples. Internal physical and chemical mechanisms of the evolution of structure and characteristics are elucidated and comprehended via the use of SEM-EDS and XRD micro-techniques. The results show that the fiber can effectively improve the ultimate strength and the corresponding effective stress strength index of the sample within the scope of the experimental study. The best strengthening effect is achieved when the amount of NaOH is 3% of the mass of the solid material, the amount of fiber is 5‰ of the mass of the solid material, and the length of the fiber is about 12 mm. The action mode of the fiber in the sample is mainly divided into single-grip anchoring and three-dimensional mesh traction. As the crack initiates and develops, connection occurs in the matrix, where the fiber has an obvious interference and retardation effect on the crack propagation, thereby transforming the brittle failure into a ductile failure and consequently improving the fracture properties of the ecological cementitious coal gangue matrix. The theoretical damage evolution model of a segmented filling body is constructed by taking the initial compaction stage end point as the critical point, and the curve of the damage evolution model of the specimen under different conditions is obtained. The theoretical model is verified by the results from the triaxial compression test. We concluded that the experimental curve is in good agreement with the theoretical curve. Therefore, the established theoretical model has a certain reference value for the analysis and evaluation of the mechanical properties of paste filling materials. The research results can improve the utilization rate of solid waste resources.

DEVELOPMENT OF GEOMETRY MOBILE LEARNING TO ENHANCE STUDENTS' MATHEMATICS LEARNING INTEREST

The development research aims to produce a mobile learning application for geometry to enhance students' interest in learning mathematics. The product encompasses solid geometry materials for 7th-grade junior high school students. The development process follows the ADDIE model: Analyze, Design, Development, Implementation, and Evaluation. The product underwent testing with 7th-grade students at a junior high school in Yogyakarta. Data collection instruments included a questionnaire on students' interest in learning mathematics, a product validation sheet, teacher and student assessment sheets, and an observation sheet on the feasibility of the learning process. These instruments were utilized to measure the validity, effectiveness, and practicality of the developed product. The research findings indicate that: (1) The developed mobile learning application for geometry is presented using Creative Problem Solving syntax, complemented with features such as liveworksheets, Geogebra, instructional videos, Quizizz, and Google Forms, facilitating the enhancement of mathematical creativity. (2) The developed product is declared valid based on the validation results obtained from two media experts and two content experts, with an average Aiken index reaching 0.94 out of the maximum score of 1, categorizing it as "High." The product is assessed as practical based on teacher assessment at 96.55%, student assessment at 71.28%, and an average learning process implementation percentage of 85.83%. The product is also deemed effective due to a significant increase in the variable of students' interest in learning mathematics. Thus, the developed geometry mobile learning application meets the criteria of validity, practicality, and effectiveness.

Effect of Ag content on the friction and wear properties of electrodeposited self-lubricating Ni–Ag coating

Thin film coatings are required to improve the performance of components to resist harsh environments as the modern industry grows. In this study, Ni–Ag coatings with various Ag content were deposited on the Cu surface using an electrodeposition technique. The Ni–Ag coatings were deposited to enhance the tribological properties of the coatings and increase the service life of the friction-sliding components. Ni–6wt%Ag, Ni–8wt%Ag, and Ni–10wt%Ag coatings were deposited. A solid solution of Ni–Ag was formed in the coatings. As the concentration of NiSO4 decreased in the electrolyte, the content of Ag in the coatings increased with the granular morphological characteristics. The increase in Ag content reduces the coefficient of friction (CoF) on comparing the initial running-in period and is stable after some time. The initial decrease was due to the surface roughness. The CoF and wear rate were low for all Ag contents compared to the copper substrate due to the effect of Ag solid lubricant material in prepared coatings.

Preparation of Magnetically Recyclable MIL‐101‐immobilized Frustrated Lewis Pairs for the Reduction of Aldehydes and Ketones

Frustrated Lewis pairs (FLPs), composed of spatially hindered Lewis acids and bases, are promising catalysts for the catalytic hydrogenation of unsaturated organic substrates, but the lack of reusability limits their development. The functionalization of solid materials with molecular FLP is a promising method for preparing heterogeneous FLP catalysts. In this work, a magnetically recyclable FLP catalyst was successfully prepared for the reductive carbonyl compounds to the corresponding alcohols. FLP of 2‐Ph2PPhCHO/B(C6F5)3 was grafted into NH2‐MIL‐101@Fe3O4 composite material through an aldehyde‐amine condensation reaction. The as‐prepared FLP‐NH‐MIL‐101@Fe3O4 exhibited remarkable catalytic activity for aldehyde/ketone carbonyl compounds. In addition, FLP‐NH‐MIL‐101@Fe3O4 displays outstanding magnetic recyclability and can be reused 8 times without loss of activity.

Heat Transfer Application of Nanofluids and Testing of Thermal Conductivity

In response to the growing demand for more efficient heat transfer technologies in various industrial processes, the development of nanofluids has emerged as a promising solution. Traditional heat transfer fluids like mineral oil, ethylene glycol, and water have relatively low thermal conductivities compared to solids, limiting the compactness and efficiency of heat exchangers. Nanofluids, which are created by suspending ultrafine metallic or nonmetallic solid powders in base fluids, exhibit enhanced thermal properties due to the superior thermal conductivities of solid materials. This paper reviews the preparation, thermal conductivity measurement, and influencing factors of nanofluids, with a focus on thermal conductivity as the primary driver for improved heat transfer. The preparation of nanofluids involves either a one-step or two-step method, with the two-step method being more commonly used for oxide nanoparticles (NPs) such as Al2O3, ZnO, MgO, TiO2, and SiO2. The study discusses stabilization techniques like ultrasonication and magnetic force agitation to ensure homogeneous suspension and long-term stability of the nanofluids. The thermal conductivity measurements are conducted using short hot wire (SHW) and transient hot wire (THW) techniques, with considerations of the nonsteady-state nature and potential error sources. The research underscores the importance of rigorous experimental design and accurate data analysis to address the complexities and variability in thermal conductivity measurements, ultimately contributing to the advancement of nanofluid technologies for efficient heat transfer solutions.

Blast protection of underwater tunnels with 3D auxetic materials

Abstract In recent years, the risk of blast attacks on underwater tunnels, important transportation routes, has increased due to the growing prevalence of vicious regional conflicts and global terrorist activities. In this work, we investigate the blast impact behavior of underwater tunnels filled with honeycomb core and covered by solid panels. The core is composed of 3D auxetic materials with high energy absorption compared to conventional honeycombs. In order to improve the stiffness of the auxetic structures, a pair of crossed rods is introduce to each cell. The relative densities of 3D auxetic structures are derived theoretically. The coupling effects of the geometrical parameters on the relative density are investigated. Then the deformation patterns of the underwater tunnels at different blast heights are analyzed. The kinetic energy and absorbed energy are discussed for tunnels with 3D auxetic materials and solid materials. Results show that tunnels composed with 3D reinforced auxetic structures can absorb much more energy than solid ones. Moreover, localized damage is observed which means greater chance of survival and smaller repairs after extreme impact. Finally, a stiffness-improved 3D reinforced auxetic structure is presented to enhance the tunnel’s strength and stability further.

Massive, long-lived electrostatic potentials in a rotating mirror plasma

Hot plasma is highly conductive in the direction parallel to a magnetic field. This often means that the electrical potential will be nearly constant along any given field line. When this is the case, the cross-field voltage drops in open-field-line magnetic confinement devices are limited by the tolerances of the solid materials wherever the field lines impinge on the plasma-facing components. To circumvent this voltage limitation, it is proposed to arrange large voltage drops in the interior of a device, but coexist with much smaller drops on the boundaries. To avoid prohibitively large dissipation requires both preventing substantial drift-flow shear within flux surfaces and preventing large parallel electric fields from driving large parallel currents. It is demonstrated here that both requirements can be met simultaneously, which opens up the possibility for magnetized plasma tolerating steady-state voltage drops far larger than what might be tolerated in material media.

Effect of fly ash and gypsum on drying shrinkage and mechanical properties of one‐part alkali‐activated slag mortar

AbstractOne‐part alkali‐activated materials can be processed into semi‐finished products by mixing a solid activator with the powder. They only require the addition of water, which greatly improves their commercial feasibility. So, we used one‐part alkali‐activated slag mortar to investigate the effects of the dosages of the activator (sodium metasilicate), fly ash (FA), and gypsum on its fluidity, flexural strength, compressive strength, and drying shrinkage. The microscopic mechanisms of the mortar were analyzed using scanning electron microscopy and x‐ray diffraction. The below conclusions were drawn. First, the drying shrinkage and compressive strength of the mortar gradually increased with the increase of the activator dosage. Second, the drying shrinkage of the mortar initially decreased and then increased as increasing FA substitution, while the compressive strength decreased gradually in the early stage and then increased and decreased in the later stage. Lastly, by increasing the gypsum dosage, the drying shrinkage of the mortar was significantly reduced. However, the compressive strength gradually decreased. Besides, when adding 20% of FA and 2.4% of gypsum, it was found that ettringite, which underwent expansion, formed in the system. This not only reduced the drying shrinkage by 25.3% but also increased the compressive strength by 1.3%. Furthermore, our investigation has led to the development of a low‐shrinkage one‐part alkali‐activated slag and FA mortar, which not only facilitates the recycling of solid waste materials but also presents commendable environmental and economic advantages.

Data‐driven nonlocal model for fragmentation in the crushing of solids

AbstractA technique is proposed for reproducing particle size distributions in three‐dimensional simulations of the crushing and comminution of solid materials. The method is designed to produce realistic distributions over a wide range of loading conditions, especially for small fragments. In contrast to most existing methods, the new model does not explicitly treat the small‐scale process of fracture. Instead, it uses measured fragment distributions from laboratory tests as the basic material property that is incorporated into the algorithm, providing a data‐driven approach. The algorithm is implemented within a nonlocal peridynamic solver, which simulates the underlying continuum mechanics and contact interactions between fragments after they are formed. The technique is illustrated in reproducing fragmentation data from drop weight testing on sandstone samples.

The structurally‐controlled polyphase Au mineralization in the southern Youjiang Basin: Insights from magnetotelluric imaging

The Youjiang Basin, located on the southwestern margin of the Yangtze Craton, hosts significant Upper Triassic and Lower Cretaceous gold (Au) deposits. Isotope studies suggest that the polyphase Au mineralization in the Youjiang Basin is derived from Indosinian and Yanshanian magmatic events, but the structural plumbing system beneath the basin remains poorly understood. We collected 32 magnetotelluric (MT) stations extending from the southern margin of the Youjiang Basin which hosts the Zhesang, Badu, and Jinya Au deposits at the western margin of the Jiangnan Orogenic (JNO) belt. The full impedance tensor of MT data is utilized to generate a high-precision lithospheric resistivity model by three-dimensional (3-D) inversion. Importantly, our MT data reveals several crustal conductors (<30 Ω·m) underlying major structures in the northwestern part of the study area. These crustal conductive anomalies spatially overlap with high-magnetic anomalies and polymetallic Au-Sn deposits. We interpret these anomalies as solid conductive materials such as graphite and/or sulfides related to the structurally controlled Mesozoic Au mineralization. Additionally, we interpret these conductive anomalies beneath the known Au deposits as the conduits of magmas and solidified paleo-magma chambers that were emplaced along deep-seated northwestern faults and likely documenting the genetic relationship between Au mineralization and Mesozoic magmatism. The synthesis of the electrical resistivity structure and metallogenic considerations is presented in a schematic sketch model illustrating that the deep-seated northwest-trending structures likely acted as a plumbing system controlling both the migration and emplacement of magmas and related oxidizing fluids that subsequently precipitated the polyphase Au deposits.

Preparation and Hydration Properties of Sodium Silicate-Activated Municipal Solid Waste Incineration Bottom Ash Composite Ground-Granulated Blast Furnace Slag Cementitious Materials.

The production of municipal solid waste incineration bottom ash (MSWIBA) is substantial and has the potential to replace cement, despite challenges such as complex composition, uneven particle size distribution, and low reactivity. This paper employs sodium silicate activation of MSWIBA composite Ground-granulated Blast Furnace slag (GGBS) to improve the reactivity in preparing composite cementitious materials. It explores the hydration performance of the composite cementitious materials using isothermal calorimetric analysis, Fourier-transform infrared (FTIR) spectroscopy, XRD physical diffraction analysis, and SEM tests. SEM tests were used to explore the hydration properties of the composite gelling. The results show that with an increase in MSWIBA doping, the porosity between the materials increased, the degree of hydration decreased, and the compressive strength decreased. When the sodium silicate concentration increased from 25% to 35%, excessive alkaline material occurred, impacting the alkaline effect. This inhibited particle hydration, leading to a decrease in the degree of hydration and, consequently, the compressive strength. The exothermic process of hydration can be divided into five main stages; quartz and calcite did not fully participate in the hydration reaction, while aluminum did. The vibrational peaks of Si-O-Ti (T = Si and Al) were present in the material. The vibrational peaks of XRD, FTIR, and SEM all indicate the presence of alumosilicate network structures in the hydration products, mainly N-A-S-H and C-A-S-H gels.

A Comprehensive Parametric CFD Investigation on Packed Bed Thermal Energy Storage System with Encapsulated Solid–Solid Phase Change Materials in Discharging Mode

A Comprehensive Parametric CFD Investigation on Packed Bed Thermal Energy Storage System with Encapsulated Solid–Solid Phase Change Materials in Discharging Mode

Recycling the electric arc furnace waste after geopolymerization in bitumen: experimental analyses and LCA study

The conversion of solid waste materials into cleaner products for road paving. applications appears to be a promising and sustainable option. However, there is still a lack of attention given to quantifying the potential environmental benefits of recycling solid wastes in asphalt pavements, regarding the impact on asphalt performance. To address this gap, the present study investigates the effects of recycling electric arc waste based geopolymers on asphalt binder and mixture characteristics, as well as environmental outputs. For this purpose, geopolymers were incorporated into both neat and SBS-modified binders. A comprehensive rheological investigation was conducted using cutting-edge multiple stress creep recovery (MSCR) and linear amplitude sweep (LAS) analyses. Stability, Marshall quotient, and flow values, as well as dry and wetconditioned tensile strength were considered, to determine asphalt mixture properties. In the Life Cycle Assessment (LCA), greenhouse gases resulting from fuel and energy consumption in each inventory phase were determined. The varying service lifetimes, maintenance and rehabilitation plans, and production and construction requirements of the different asphalt schemes were taken into account. Subsequently, the environmental impacts of the asphalt mixtures, including global warming potential, acidification, eutrophication, and smog formation potential, along with the total energy demand, were calculated across different stages of the LCA. The results show that the geopolymerization process results in important contributions in terms of both environmental savings and pavement performance.

Dry-Wet Cycles Durability of Solid Waste Based Cementing Materials Solidifying Different Characteristic Soils

Abstract A comparative study of the durability of multi-source solid waste-based soil solidification materials in solidifying different soil types has not yet been conducted. Therefore, the properties of multi-source solid waste-based solidification materials (SBM) solidifying clay soil (CS), sandy soil (SS) and organic soil (OS) subjected to dry-wet cycles of damage were studied in this work. The unconfined compressive strength (UCS) of the SBM solidified soil was tested to evaluate the mechanical properties of the solidified soil. Scanning electron microscopy (SEM) and mercury injection porosimetry (MIP) tests were conducted in order to study the micro-action mechanism. The results demonstrated that the SBM showed wide applicability and good long-term performance. The rate of strength increase of the SBM solidified soil during the long-term curing period was found to be dependent on soil characteristics. All the types of SBM solidified soils exhibited increased UCS during the first 10 cycles of the D-W. As the number of D-W cycles increased from 10 to 50, the UCS loss rate for CS reached 78%, with OS experiencing the least at 58%. The structure of SBM solidified soil exhibited softening and weakened resistance to deformation with each additional D-W cycle. The types of hydration products were consistent across all three soil types. The quantity of hydration products was influenced by the characteristics of the soil, which also contributed to the deterioration of damage resistance in D-W cycles. The number of pores within the SBM solidified soil increased with the number of D-W cycles (&gt;10 cycles), resulting in a deterioration of the compact structure.

Alcohol policy development in Sierra Leone: An assessment of the role of civil society

Objective: To assess the value addition of civil society collaboration with Government in the development of Sierra Leone’s National Alcohol Policy (NAP). Policy Development Process: We reviewed the entire process of lobby, advocacy, and support for the development of the NAP from 2015 when the Siera Leone Alcohol Policy Alliance (SLAPA) was formed to the launch of the NAP in 2023. It also assesses the level of collaboration between FoRUT, SLAPA and Ministry of Health of Health and Sanitation (MoHS). The MoHS coordinated the policy formulation process with substantive technical support from civil society. Results: The quality of the NAP was rated high as it reflected appropriate policy areas and interventions from the Global Strategy to Reduce the Harmful Use of Alcohol, the WHO SAFER initiative, and the Global Action Plan for Alcohol Control (202-2030). The NAP is a solid reference material for the development of a new alcohol bill. MoHS recognized FoRUT and SLAPA as the national champions for alcohol control in the country. FoRUT, directly and through SLAPA influenced the process of developing the NAP and its quality through advocacy, collaboration and technical and financial support. Conclusions: The development of the NAP in Sierra Leone truly reflects civil society-government collaboration, built on mutual trust and a common health and development agenda. Connecting national level lobby and advocacy with regional global advocacy actions to prioritize, influence, support, and monitor the alcohol control agenda is a critical catalyst for civil society to advancing the development of NAPs.

Synthesis and characterization of hydroxyapatite nanoparticles from calcium hydroxide fouled with gases evolved from smokestack of glass industry

In glass industry, the evolved gases and fumes from burning the gas fuel absorbed in calcium hydroxide to minimize the pollution of environment. After a period of time, the calcium hydroxide fouled with sulphate and carbonate as action of the absorbed SO3 and CO2 gases. Based on our interest to treatment the solid waste materials, this study intended to convert the obtained waste of calcium hydroxide fouled with gases to valuable products. Firstly, this waste was treated with water, caustic soda and acids. The results confirmed the conversion of waste to pure calcium sulfate by treatment with 6 v/v% sulfuric acid. Secondly, the obtained calcium sulfate was reacted with ammonium dihydrogen phosphate solution for preparation of calcium hydroxyapatite (HAp) nanoparticles. The produced HAp sample was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), thermal gravimetric analysis (TGA) and N2 adsorption measurements. The obtained findings confirmed that the HAp can be produced after calcination at 700 °C, nanorods-like of sizes ranged from 11 to 15 nm and with main surface functional groups of hydroxyapatite. TGA and DTA data indicated that HAp is thermally stable up to 700 °C. Also, the obtained HAp has Ca/P molar ratio of 1.60 and exhibited high total surface area of 146 m2/g with mesoporous structure which make this material can be used in medical and water purification applications.

A Unified Thermo-Fluid–Solid Formulation for FSI and Phase Change Problems Based on the Particle Finite Element Method

The modeling of industrial processes that involve phase change (e.g., casting, welding or additive manufacturing) is challenging due to their multiscale and multiphysics nature. The coupling of the fluid and solid mechanics is difficult due to the unknown and evolving fluid–solid interface. To deal with the difficulty of the coupling, a unified approach has been developed where fluid and solid regions are represented in the same computational domain and solved by a single solver. The interaction of fluid and solid regions is therefore automatically captured and the material can locally undergo phase transition. This allows to capture the flow in the melt and the thermal stresses in the solid. The solid material model is currently limited to linear elasticity, but it opens the path to more complex material models with plasticity modeling, which already exist in the literature. The proposed method is based on the Particle Finite Element Method (PFEM), which has been shown to accurately handle both fluid and solid mechanics. In this work, we present the key aspects of this novel unified formulation and the treatment of the fluid–solid interface in the PFEM context. The methodology is presented and verified using a set of tests. A laser spot welding example test case demonstrates the potential of combining the unified formulation with the interface treatment and the phase change capabilities and is used for the validation of the present technique.