Globally, the adverse climate effects caused by greenhouse gas emissions are becoming increasingly apparent, and solutions to increase the use of eco-friendly transportation methods are urgently needed. Introducing solar-powered vehicles (SPVs), which are cars integrated with solar panels capable of generating power, presents a promising solution to reduce urban carbon footprints. However, the low adoption rate of SPVs implies that the benefits—such as environmental friendliness and ability to charge while driving—need to be more palpably experienced by consumers. To address this aspect, in this study, we aimed to develop a navigation system algorithm that guides users along routes that optimize energy consumption and solar energy production from the starting point to the destination. This was done with the objective of providing more tangible benefits from using SPVs. The study focused on the high-traffic urban center of Seoul, where determining solar power availability for a moving SPV is challenging, given the presence of shadows cast by roadside features such as buildings and trees. To achieve this, panoramic images from Google Street View were collected at 10 m intervals from all roads within the research area. From these images, sky and non-sky elements were separated. Subsequently, a hemispherical map was constructed and superimposed with the sun's path. The presence of shadows was determined by assessing whether the sun's path was obstructed by non-sky elements; if the path was unimpeded in the sky, no shadow was recorded. The shadow data obtained at each spot were efficiently stored in a database for quick retrieval and application based on specific locations and departure times. Using this shadow information, the navigation algorithm calculates power generation along a given route and considers the energy consumption of the SPV. Analysis led to the identification of an energy-saving route, which enabled the achievement of energy conservation and CO2 reduction benefits. Furthermore, a comprehensive sensitivity analysis was conducted to examine the impact of four critical parameters—module efficiency, solar panel area, vehicle speed, and departure time—on route selection and net energy consumption. The energy-saving path planning algorithm enhances the economic feasibility of solar charging for SPVs during travel; thus, this study can contribute significantly to the widespread adoption of SPVs, which play a definitive role in reducing transportation's carbon footprint.