Understanding photo-induced charge transfer (PCT) is crucial for optimizing the performance of solar-powered devices like photovoltaic and photoelectrochemical cells, as PCT directly impacts their operation and overall power conversion efficiency. General assessment of PCT has heavily relied on transient absorption techniques to gauge electron transfer between the donor and acceptor. However, there is a pressing need to broaden the methods for comprehensively studying PCT.In this study, we propose an alternative approach utilizing transient photoluminescence to observe PCT dynamics between organic dyes and redox mediators. This approach involves adsorbing various organic dyes onto Al2O3 surfaces along with redox mediators. When excited, the dyes facilitate charge separation from each other, leading to the instantaneous oxidized form of the dye and subsequent electron transfer from the redox mediator. This process results in a decrease in the photoluminescence lifetime of the organic dye. The extent of this decreases correlates with the Gibbs free energy of charge transfer, reflecting the efficiency of electron transfer between the organic dye and the redox mediator. Our findings introduce an alternative avenue for studying PCT, offering insights that are pertinent to various fields including photovoltaics, optoelectronics, and photocatalysis. Figure 1
Read full abstract