Solar Energy Storage Applications Research Articles

Ultrafast Solution-Phase Photophysical and Photochemical Dynamics of Hexaiodobismuthate(III), the Heart of Bismuth Halide Perovskite Solar Cells.

The ultrafast relaxation pathways in a hexaiodide bismuth(III) complex, BiI63-, excited at 530 nm in acetonitrile solution are studied by means of femtosecond transient absorption spectroscopy supported by steady-state absorption/emission measurements and DFT computations. Radiationless relaxation out of the Franck-Condon, largely metal-centered (MC) triply degenerate 3T1u state (46 ± 19 fs), is driven by vibronic coupling due to the Jahn-Teller effect in the excited state. The relaxation populates two lower-energy states: a ligand-to-metal charge transfer (LMCT) excited state of 3π I(5pπ) → Bi(6p) nature and a luminescent "trap" 3A1u(3P0) MC state. Coherent population transfer from the initial 3T1u into the 3π LMCT state occurs in an oscillatory, stepwise manner at ∼190 and ∼550 fs with a population ratio of ∼4:1. The 3π LMCT state decays with a 2.9 ps lifetime, yielding two short-lived reaction intermediates of which the first one reforms the parent ground state with a 15 ps time constant, and the second one decays on a ∼5 ps timescale generating the triplet product species, which persists to the longest 2 ns delay times investigated. This product is identified as the η2 metal-ligated diiodide-bismuth adduct with the intramolecularly formed I-I bond, [(η2-I2)Bi(II)I4]3-, which is the species of interest for solar energy conversion and storage applications. The lifetime of the "trap" 3A1u state is estimated to be 13 ns from the photoluminescence quenching of BiI63-. The findings give insight into the excited-state relaxation dynamics and the photochemical reaction mechanisms in halide complexes of heavy ns2 metal ions.

Fatty Amines Embedded Carbon Membranes with Aligned Nanochannels Network: A Device with Extremely High Photothermal Conversion Efficiency toward Solar Energy Harvesting and Storage

The development of phase change materials (PCMs) composites with high light‐to‐thermal energy conversion efficiency is of great importance for solar energy storage. Herein, the preparation of novel PCMs composites by incorporation of fatty amines (FAs) into the carbon membranes (CMs) with aligned nanochannels network is first reported, which is obtained by employing an anodic alumina oxidation membrane as sacrificing template and using polypyrrole and asphalt as carbon precursor via a simple carbonization treatment. The carbonized membranes possess abundant porosity and aligned nanochannels, which is beneficial to harvest solar light combined with their carbon in nature. In addition, organic PCMs, i.e. 1‐Hexadecanamine (HDA, ΔH = 311.1 kJ/kg) and 1‐Aminoheptadecane (AHD, ΔH = 293.0 kJ/kg) can be spontaneously loaded into the nanochannels of CMs by the capillary action and surface tension. The fabricated FAs/CMs composites present an enhanced thermal conductivity ranging from 0.291 to 0.525 W m−1 K−1. Compared to pure FAs, the thermal conductivities of the PCMs composites are 144.8–357.1% higher than that of the control. Meanwhile, the as‐synthesized FAs/CMs composites also exhibit a remarkable high photothermal energy storage efficiency of up to 93.8%, which is one of the highest values reported to date, making them promising candidates for a broad range of applications in solar energy harvesting, conversion, and storage.

Plasmons: untangling the classical, experimental, and quantum mechanical definitions.

Plasmons have been widely studied over the past several decades because of their ability to strongly absorb light and localize its electric field on the nanoscale, leading to applications in spectroscopy, biosensing, and solar energy storage. In a classical electrodynamics framework, a plasmon is defined as a collective, coherent oscillation of the conduction electrons of the material. In recent years, it has been shown experimentally that noble metal nanoclusters as small as a few nm can support plasmons. This work has led to numerous attempts to identify plasmons from a quantum mechanical perspective, including many overlapping and sometimes conflicting criteria for plasmons. Here, we shed light on the definitions of plasmons. We start with a brief overview of the well-established classical electrodynamics definition of a plasmon. We then turn to the experimental features used to determine whether a particular system is plasmonic, connecting the experimental results to the corresponding features of the classical electrodynamics description. The core of this article explains the many quantum mechanical criteria for plasmons. We explore the common features that these criteria share and explain how these features relate to the classical electrodynamics and experimental definitions. This comparison shows where more work is needed to expand and refine the quantum mechanical definitions of plasmons.

Preparation and characterization of high temperature shape stable NaNO3/diatomite phase change materials with nanoparticles for solar energy storage applications

In this paper, we presented a simple method of preparation, characterization and thermo physical properties of phase change materials with nanoparticles. The study began with the preparation of NaNO3/diatomite phase change materials (PCMs) and with adding Nano expanded graphite and Nano diamond additives as a thermal conductivity enhancer for high temperature applications. The composite phase change materials are successfully synthesized using a two-step mixing and sintering method for high temperature applications such as concentrated solar powers and solar reactors. In the following, by using the design of experiment (DOE), two responses (phase change temperature and phase change time stability) were investigated in shape stable composite in phase change materials (SS-CPCM) with and without nanoparticles. DSC and IR-Camera results were used as responses and thermal properties of the SS-CPCM. Economical SS-CPCM was prepared, characterized, and optimized by DOE software. Experimental analysis, including 20 runs, has been taken using a design of experiment, and the optimum run has been selected. The optimum SS-CPCM has a latent heat of 87.32 J/g and a melting temperature of 304.64 °C. In the solidification cycle, it requires 87.32 J/g heat dissipation to phase change and solidify at 302.03 °C. A weight loss of 0.00619 g after 50 cycles of phase change for NaNO3/Diatomite/Nano EG SS-PCM shows a reliable SS-CPCM. The same optimum pellet with only a different Nano material of Nano diamond has a latent heat of 91.02 J/g and a melting temperature of 304.98 °C. In the solidification cycle, it requires 90.51 J/g heat dissipation to phase change and solidify at 302.14 °C.

Review on phase change materials for solar energy storage applications.

The energy storage application plays a vital role in the utilization of the solar energy technologies. There are various types of the energy storage applications are available in the todays world. Phase change materials (PCMs) are suitable for various solar energy systems for prolonged heat energy retaining, as solar radiation is sporadic.This literature review presents the application of the PCM in solar thermal power plants, solar desalination, solar cooker, solar air heater, and solar water heater. Even though the availability and cost of PCMs are complex and high, the PCMs are used in most solar energy methods due to their significant technical parameters improvisation. This review's detailed findings paved the way for future recommendations and methods for the investigators to carry work for further system developments.

Optical constants, dispersion parameters and energy loss functions of crystal violet as a potential absorber thin film for solar energy conversion and storage applications

Highly homogenous crystal violet (CV) thin films are grown by spin coating technique. X-ray diffraction (XRD) measurements have been carried out to identify the dominant orientation of the films. The XRD pattern of as-deposited film showed an amorphous structure which turns into nanocrystalline by thermal annealing at 150 °C for 1 h. The spectroscopic characterization of as-deposited and annealed CV films was estimated via spectrophotometric measurements of transmission and reflection in the spectral range 190–2000 nm. Optical constants of CV films were determined. Wemple-DiDomenico model was applied to the normal dispersion region of refractive index spectrum and from which, many dispersion parameters were calculated. The type of most probable transitions and values of optical energy gaps for CV films were estimated by Tauc plot. The dissipation energy and volume & surface loss functions were estimated. The influence of annealing temperature on the spectroscopic properties, dispersion parameters and energy loss functions were investigated which revealed an improvement in the optical properties and decreased values of energy loss functions for the annealed CV films. The obtained results of optical features for CV films reveals that CV films are an excellent potential absorbing material in solar energy conversion and storage devices.

Prepared Pd/MgO/BiVO4 composite for photoreduction of CO2 to CH4

AbstractIn this study, several Pd/MgO/BiVO4 nanocomposites were prepared using the hydrothermal method and their effective photocatalyst activity for the photoreduction of CO2 to CH4 was investigated. The microstructure and photocatalytic behavior of the prepared photocatalysts were studied through X‐ray diffraction, scanning electron microscopy, tunneling electron microscopy, X‐ray photoelectron spectroscopy, ultraviolet–visible spectrophotometry, Fourier‐transform infrared spectroscopy, Brunauer–Emmett–Teller specific surface area, and photoluminescence spectroscopy. CH4 yields of 5.9 and 9.4 μmol g−1 hr−1 were obtained using BiVO4 and 25% MgO/BiVO4 nanocomposites, respectively. The highest production rate of CH4 was measured as 12.8 μmol g−1 hr−1 on overloading 0.3% Pd on 25% MgO/BiVO4. Pd/MgO/BiVO4 exhibited excellent CO2 photoreduction stability with negligible loss after five consecutive cycles. Finally, a possible mechanism of CO2 photoreduction using Pd/MgO/BiVO4 was proposed for understanding the synergistic effects. The results of the experiment revealed that Pd/MgO/BiVO4 can be a promising photocatalyst in solar energy conversion and storage application and can achieve excellent CO2 photoreduction performance.

Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review

Latent heat thermal energy storage systems (LHTES) are useful for solar energy storage and many other applications, but there is an issue with phase change materials (PCMs) having low thermal conductivity. This can be enhanced with fins, metal foam, heat pipes, multiple PCMs, and nanoparticles (NPs). This paper reviews nano-enhanced PCM (NePCM) alone and with additional enhancements. Low, middle, and high temperature PCM are classified, and the achievements and limitations of works are assessed. The review is categorized based upon enhancements: solely NPs, NPs and fins, NPs and heat pipes, NPs with highly conductive porous materials, NPs and multiple PCMs, and nano-encapsulated PCMs. Both experimental and numerical methods are considered, focusing on how well NPs enhanced the system. Generally, NPs have been proven to enhance PCM, with some types more effective than others. Middle and high temperatures are lacking compared to low temperature, as well as combined enhancement studies. Al2O3, copper, and carbon are some of the most studied NP materials, and paraffin PCM is the most common by far. Some studies found NPs to be insignificant in comparison to other enhancements, but many others found them to be beneficial. This article also suggests future work for NePCM and LHTES systems.

Fatty amines/oxidized multi-walled carbon nanotubes phase change composites with enhanced thermal properties

The development of phase change composites with both high latent heat and better thermal conductivity is of great importance for thermal energy or solar energy storage applications. Here, three kinds of oxidized multi-walled carbon nanotubes (p-MWCNTs, a-MWCNTs and c-MWCNTs) prepared though multiple oxidations with different oxygen contents were used as porous support materials for construction of phase change composites, in which two kinds of fatty amines (FAs), e.g. tetradecylamine (TDA) and octadecylamine (ODA), were employed as organic phase change materials (PCMs). The thermal conductivity of FAs/oxidized-MWCNTs phase change composites increased with the increase of the oxygen content of oxidized-MWCNTs. As a kind of novel phase change composites, FAs/c-MWCNTs have excellent thermal stability and energy storage density (latent heat up to 273.8 kJ kg−1 for ODA/3%c-MWCNTs), which can compete or superior to those conventional organic PCMs-based (paraffin, PEG, etc.) composites. Benefiting from the merits mentioned above, the FAs/c-MWCNTs phase change composites may have great potentials for real energy-saving applications.

Ionic Liquids–Cobalt(II) Thermochromic Complexes: How the Structure Tunability Affects “Self-Contained” Systems

With the aim of obtaining thermochromic systems with potential applications in solar energy storage, we evaluated the behavior of some sugar-based ionic liquids (ILs)–Co(NTf2)2 complexes, in IL solution, as a function of temperature. Different structural changes on the cation, the nature of the anion, and the nature of the IL used as the solvent were considered. The analysis of the above factors was carried out through a combined approach of different techniques, that is, variable temperature UV–vis and NMR spectroscopies, conductivity, and thermal gravimetric analysis. The thermochromic systems were analyzed both as solutions and as thin films, and the data collected highlight the defining role played by both the cation structure and the solvent nature in determining their performance. Most of the investigated systems show a chromogenic transition from pink to blue, occurring in a temperature range suitable for practical applications (40–60 °C). Interestingly, when embedded in a polymeric matrix, thin films with high recyclability and long life are also described.

Novel composite phase change materials based on hollow carbon nanospheres supporting fatty amines with high light-to-thermal transition efficiency

The construction of high-performance materials with superior light-to-thermal conversion efficiency is of great importance for harvesting and utilization of solar energy. Hence, we report the creation of novel composite phase change materials (CPCMs) CPCMs by incorporating three kinds of organic phase change materials (PCMs), i.e. 1-Tetradecylamine (TDA), 1-hexadecanamine (HDA) and Octadecylamine (ODA), into hollow carbon nanospheres (HCNS) via a simple impregnation treatment for efficient light-to-thermal transition. Owing to their carbon in nature, the HCNS show better light absorption of higher than 90%. After incorporation of organic PCMs, their light absorption could still attain 62–70%, which can compete with the existing CPCMs. Beneficial from their abundant porosity and high specific surface areas, organic PCMs can be spontaneously diffused and immersed into the porous architecture of HCNS. In this way, the as-resulted CPCMs containing with TDA, HDA and ODA show high phase change enthalpy of 61.23J/g, 119.5J/g and 101.8J/g, respectively. The CPCMs also exhibit better thermal conductivity and excellent thermal stability, e.g., the enthalpy of HAD based CPCMs remains nearly unchanged even after 100 times of melting/freezing cycles. Under 1 sun irradiation, the light-to-thermal conversion efficiency of CPCMs containing with TDA, HDA and ODA were measured to be 73.04%, 74.46% and 71.74%, respectively, Thus showing great potential as a kind of promising photothermal conversion devices for solar or thermal energy storage applications.

High-energy and light-actuated phase change composite for solar energy storage and heat release

Phase change materials (PCMs) show great potential for solar thermal energy application due to the large latent heat and high efficiency. However, it is difficult to implement long-term storage because of the sensitive phase-transition to environment temperature. Here, we report a high-energy organic phase change composite (PCC) by introducing long-chain azobenzene molecule (AZO) into low-cost tetradecyl alcohol (TA) for light-regulated solar energy storage and release. The photo-switch azobenzene can install a new energy barrier and form a supercooling in liquid-phase charged PCC via molecular photo-isomerization and enhanced intermolecular interactions. Moreover, the charged PCC reveals a large latent heat of 239 J g−1 and a high power density of 594 W kg−1 with a suitable degree of supercooling (3.33–7.67 °C) for energy storage near room temperature. It is noted that the optically-controlled energy release by blue light and excellent cycling stability can be obtained. This kind of PCC is a promising candidate for smart and convenient solar energy storage application.

Flexible textiles with polypyrrole deposited phase change microcapsules for efficient photothermal energy conversion and storage

The design of flexible phase change textiles with photothermal conversion/storage performance provides a new direction for their potential applications in advanced solar energy storage. Herein, photothermal phase change microcapsules (microPCMs) were facilely prepared via surface modification of microPCMs with photothermal converter polypyrrole (PPy). A flexible photothermal phase change textile was further fabricated together with polyurethane (PU). The microPCMs coated with merely 1.91 wt% PPy exhibited high photothermal storage efficiency (up to 94.03%) under 1 solar irradiation and high melting enthalpy (231.6 J/g). Meanwhile, the microPCMs/PU composite fiber remained highly elastic (365% elongation) at a loading of 79.45 wt% microPCMs. Additionally, the photothermal phase change textile showed high cycling durability with essentially unchanged performance after 100 heating-cooling cycles. These favorable features of the composite textile grant it great potential for solar energy-related applications.

A new optimized control system architecture for solar photovoltaic energy storage application

A new optimized control system architecture for solar photovoltaic energy storage application

Theoretical study of the influence of doped niobium on the electronic properties of CsPbBr3.

In the family of inorganic perovskite solar cells (PSCs), CsPbBr3 has attracted widespread attention due to its excellent stability under high humidity and high temperature conditions. However, power conversion efficiency (PCE) improvement of CsPbBr3-based PSCs is markedly limited by the large optical absorption loss coming from the wide band gap and serious charge recombination at interfaces and/or within the perovskite film. In this work, using density functional theory calculations, we systemically studied the electronic properties of niobium (Nb)-doped CsPbBr3 with different concentration ratios. As a result, it is found that doped CsPbBr3 compounds are metallic at high Nb doping concentration but semiconducting at low Nb doping concentration. The calculated electronic density of states shows that the conduction band is predominantly constructed of doped Nb. These characteristics make them very suitable for solar cell and energy storage applications.

Modeling PCM Phase Change Temperature and Hysteresis in Ventilation Cooling and Heating Applications

Applying phase change material (PCM) for latent heat storage in sustainable building systems has gained increasing attention. However, the nonlinear thermal properties of the material and the hysteresis between the two-phase change processes make the modelling of PCM challenging. Moreover, the influences of the PCM phase transition and hysteresis on the building thermal and energy performance have not been fully understood. This paper reviews the most commonly used modelling methods for PCM from the literature and discusses their advantages and disadvantages. A case study is carried out to examine the accuracy of those models in building simulation tools, including four methods to model the melting and freezing process of a PCM heat exchanger. These results are compared to experimental data of the heat transfer process in a PCM heat exchanger. That showed that the four modelling methods are all accurate for representing the thermal behavior of the PCM heat exchanger. The model with the DSC Cp method with hysteresis performs the best at predicting the heat transfer process in PCM in this case. The impacts of PCM phase change temperature and hysteresis on the building energy-saving potential and thermal comfort are analyzed in another case study, based on one modelling method from the first case study. The building in question is a three-room apartment with PCM-enhanced ventilated windows in Denmark. The study showed that the PCM hysteresis has a larger influence on the building energy consumption than the phase change temperature for both summer night cooling applications and for winter energy storage. However, it does not have a strong impact on the yearly total energy usage. For both summer and winter transition seasons, the PCM hysteresis has a larger influence on the predicted percentage of dissatisfied (PPD) than the phase change temperature, but not a strong impact on the transition season average PPD. It is therefore advised to choose the PCM hysteresis according to whether it is for a summer night cooling or a winter solar energy storage application, as this has a significant impact on the system’s overall efficiency.

A Capacitor‐type Faradaic Junction for Direct Solar Energy Conversion and Storage

AbstractTwo‐electrode solar rechargeable devices trigger intense attention due to their potential applications in solar energy conversion and storage. However, interface energy barriers lead to severe loss of output voltage and negligible dark discharge current. Therefore, external biases are required for dark discharge in these devices, limiting their practical applications. Herein, we report a new two‐electrode device of Si/WO3/H2SO4(aq)/C that can work without bias. The device has the highest dark output power among all of the two‐electrode solar rechargeable devices. The device based on a Si/WO3 junction indicates photoinduced adjustable interface barrier height during charge transfer, which can overcome the energy barrier and realize dark discharge without bias. Owing to the interface characteristics, the Si/WO3 is designated as a capacitor‐type Faradaic junction.

A Capacitor-type Faradaic Junction for Direct Solar Energy Conversion and Storage.

Two-electrode solar rechargeable devices trigger intense attention due to their potential applications in solar energy conversion and storage. However, interface energy barriers lead to severe loss of output voltage and negligible dark discharge current. Therefore, external biases are required for dark discharge in these devices, limiting their practical applications. Herein, we report a new two-electrode device of Si/WO3 /H2 SO4(aq) /C that can work without bias. The device has the highest dark output power among all of the two-electrode solar rechargeable devices. The device based on a Si/WO3 junction indicates photoinduced adjustable interface barrier height during charge transfer, which can overcome the energy barrier and realize dark discharge without bias. Owing to the interface characteristics, the Si/WO3 is designated as a capacitor-type Faradaic junction.

Phase-Changing Microcapsules Incorporated with Black Phosphorus for Efficient Solar Energy Storage.

A new solar energy storage system is designed and synthesized based on phase‐changing microcapsules incorporated with black phosphorus sheets (BPs). BPs are 2D materials with broad light absorption and high photothermal performance, which are synthesized and covalently modified with poly(methyl methacrylate) (PMMA) to produce the PMMA‐modified BPs (mBPs). With the aid of PMMA, the mBPs and phase‐changing materials (PCM, eicosane) are encapsulated together to form microcapsules. The microencapsulated eicosane and mBPs (mBPs‐MPCM) composites exhibit a high latent heat of over 180 kJ kg−1, good thermal reliability, as well as excellent photothermal characteristics inherited from BPs. Owing to the direct contact in the integrated mBPs‐MPCM composites, the thermal energy generated by mBPs is transferred to eicosane immediately giving rise to three times higher efficiency in solar energy storage compared to microcapsules with mBPs on the surface. The mBPs‐MPCM composites have great potential in solar energy storage applications and the concept of integrating photothermal materials and PCMs as the core provides insights into the design of high‐efficiency solar energy storage materials.

Significance of Nanomaterials in solar energy storage applications

In the present decade, energy demand is one of the most challenging issues being faced throughout the world. To overcome the problems in the high energy production, the recent advances in nanotechnology, with a huge range of nanostructured materials have become all the rage for energy storage applications. A great number of devices have been developed in recent decades with the advancement of nanoscience. In the concept of renewable energy resources, Solar Energy can be referred to as the “elixir of power production” throughout the world. Extensive research is being carried out for distinguished Nanomaterials on energy storage applications by researchers and scientists to produce an efficient power absorption and storage material with high thermal conductivity and high corrosion resistance. In this paper, reviewing the concepts of nanotechnology in solar energy applications is made excessively focussing on PCM, Nano fluids, and Nanocomposites. Also by considering several other important factors in energy storage applications a statistical/graphical approach is presented for a better understanding by taking different research and review articles. This paper extensively would give researchers ease in the selection of material for energy storage applications.