Cu–Al alloys are widely used in electronics, new energy, and other fields due to the combination of th excellent corrosion resistance and electrical conductivity of Cu and the light weight of Al. In this paper, the powder metallurgy and equal-channel angular pressing compound technology was used to fabricate a Cu–Al alloy joint, which can be used to replace armor. Devices such as an optical microscope, electron scanning microscope, and microhardness scale were used to characterize the microstructure and mechanical properties of the Cu–Al alloys. The finite element analysis software Abaqus was used to analyze stress distribution during equal-channel angular pressing. The results indicated that the microstructure and properties of Cu–Al alloys were closely related to the volume ratio of Cu–Al. The microhardness and tensile strength were significantly increased by increasing the volume ratio of Cu–Al. As the volume ratio of Cu–Al varied from 1:2 to 2:1, the ultimate tensile strength of the Cu–Al alloys increased from 79.9 MPa to 164.9 MPa at room temperature and the microhardness increased from 60 HV to 101 HV. However, the elongation of the Cu–Al alloys hardly changed; this was about 4.4%. Crack initiation occurred at the Cu–Al interface and spread along the bonding surface of the Cu–Al alloys during the tensile process.