Sodium Silicate Solution Research Articles

Sustainability and durability performance evaluation of geopolymer concrete with industrial effluent as alternative to conventional river sand

Due to infrastructural development activities, the need for the construction materials increases, because of which most of the naturally available natural resources are over exploited and the cost of construction materials are increased. Therefore, the present study focuses on the use of industrial by-products for the development of concrete and examines the physical, mechanical, durability and sustainable performances. Fly ash (FA) and ground granulated blast furnace slag (GGBS) were employed as binder medium and the industrial effluent sodium silicate waste was used to replace the conventional river sand in the geopolymer concrete (GPC). GGBS was employed as source material for the production of concrete to increase the polymerization reaction process and further, the developed concrete was cured in the ambient condition of temperature range 27 ± 2 °C, in the laboratory. The concentration of the sodium hydroxide (NaOH) in the present study was 12M, and the alkaline solution ratio was 1:1.5. During the production process of sodium silicate solution in the factory, the residue left at the bottom of the boiling hopper were dumped as waste in the open land. GPC gains its strength based on the alumina and silica in the source material and alkaline activator solution, therefore, this industrial waste residue was identified as potential alternative to conventional river sand. The concrete with and without effluent was subjected to two types of acid (Sulfuric acid (H2SO4) and Hydrochloric acid (HCl)) and further to examine the performance of concrete under marine condition, two types of salt solutions, namely, magnesium sulfate (MgSO4) and Sodium Chloride (NaCl) were used, the concentration of acids employed in the present study is 2% and the marine solution is 3.5%. Increase in the proportion of effluent from 0% to 100% decreases the slump value of the concrete. Contrastingly, increasing the proportion of effluent increases the strength of GPC after 28-d of room temperature curing. To examine the performance of the concrete under acidic and marine conditions, average of three concrete specimens were employed and the duration of exposure was considered in the present study starts from 28-d and continues till 360-d. After exposing to acidic environment, mass loss, strength loss and surface modification were examined; the loss in mass was found to be 1.5–3% and the strength loss was found to be 35%–45%. In the case of salt solution exposure, the loss in mass was seen to be 1–2% and whereas in the case of strength, the loss was found to be 30%–42%, respectively. Further, the sustainability aspects of the concrete with industrial effluents were examined in detail; focusing on economic value of the concrete, carbon emission and energy demand during the production of concrete.

Sustainable Ecological Non-Sintered Ceramsite (SENC) with Alkali Activators: Performance Regulation and Microstructure

The development of novel materials made from waste is one of the main measures to achieve sustainable materials development. In this study, ash of mushroom and corn straw (MCA) and furnace slag (FS) were used as raw materials to prepare alkali-activated biomass ash-slag material (AABS) and sustainable ecological non-sintered ceramsite (SENC). In this paper, the effects of quicklime powder (QL), NaOH, and sodium silicate solution (SS) on AABS were analyzed using single factor and orthogonal tests, and the preferred ratio of the composite alkali activator configuration was established. SENC was prepared based on the composite alkali activator, and the microstructure and phase composition of SENC were explored using XRD and SEM–EDS. The results showed that 3 wt% QL enhanced the early age compressive strength of AABS. The composite alkali activator was best configured when the additions of QL, NaOH, and SS were 3%, 2%, and 15%, respectively. At this configuration, the 28 d compressive strength of AABS was 47.4 MPa, and most of the internal pores were less than 0.4 μm; the 28 d numerical tube pressure of the SENC reached 12.2 MPa with a softening coefficient of 0.96. According to the results of XRD and SEM–EDS, SENC contained various hydration products such as C-A-S-H, calcium hemicarboaluminate, hydrotalcite, portlandite, and vaterite. The largest proportion of hydration products was C-A-S-H, which contributed to the pore refinement and structural densification. SENC has the potential to be used as coarse aggregate in sustainable lightweight concrete.

Design of Alkali-Activated Materials and Geopolymer for Deep Soilmixing: Interactions with Model Soils.

This study focuses on the use of alkali-activated materials and geopolymer grouts in deep soilmixing. Three types of grouts, incorporating metakaolin and/or slag and activated with sodium silicate solution, were characterized at different scales to understand the development of their local structure and macroscopic properties. The performance of the soilmix was assessed by using combinations of the grouts and model soils with different clay contents. Feret's approach was used to understand the development of compressive strength at different water-to-solid ratios ranging from 0.65 to 1. The results suggested that incorporating calcium reduced the water sensitivity of the materials, which is crucial in soilmixing. Adding soils to grouts resulted in improved mechanical properties, due to the influence of the granular skeleton. Based on strength results, binary soilmix mixtures containing 75% of metakaolin and 25% of slag, with H2O/Na2O ratios ranging from 28 to 42 demonstrated potential use for soilmixing due to the synergistic reactivity of metakaolin and slag. The optimization of compositions is necessary for achieving the desired properties of soil mixtures with higher H2O/Na2O ratios.

Aluminosilicate-based material fabricated from fly ash for energy harvesting application

A triboelectric nanogenerator (TENG) is an emerging energy harvesting technology that utilizes the combination of triboelectrification and electrostatic induction to collect wasted mechanical energy and convert it into electricity. In this work, an aluminosilicate (AS)-based composite, considered as a potential alternative to cement material, has been developed for the fabrication of TENGs. Herein, the AS material is synthesized through the alkali activation of fly ash using a mixture of sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) solutions as activating agents. The electrical output of AS TENGs can be optimized by tuning the liquid-to-solid powder (L/S) ratio during the fabrication of AS composites. The AS composites fabricated at different L/S ratios exhibit the variations in dielectric properties, surface morphology and microstructure. It is found that a high dielectric constant is not the only requirement for achieving optimal TENG output performance. The contribution of dielectric properties and microstructures of the AS composites on TENG performance is discussed. The AS composite with an optimal L/S ratio of 0.5 results in the highest TENG power output density of 2.78 W/m2. Additionally, the versatility of AS TENG to harvest mechanical energy and its application as a power source for portable electronic device are demonstrated. This research has proposed the promising aspect of AS composites as alternative construction materials capable of harvesting mechanical energy, which is essential for the development of green and sustainable power sources.

Metallic aluminium in municipal solid waste incineration fly ash as a blowing agent for porous alkali-activated granules.

Porous alkali-activated materials are synthetic aluminosilicates that should be often produced as granules for practical applications. In the present study, municipal solid waste incineration fly ash with ~1.2 wt% of metallic aluminium was used as a novel blowing agent for metakaolin (their ratio ranged from 0% to 100%) with an aqueous sodium silicate solution as the alkali-activator and granulation fluid in high-shear granulation. The compressive strength of all granules was sufficient (≥2 MPa). Water absorption indicated an increase in porosity as the fly ash content increased. However, X-ray microtomography imaging showed no clear correlation between the fly ash content and porosity. The granules exceeded the leaching limits for earth construction materials for antimony, vanadium, chloride and sulphate. Of those, antimony, chloride and sulphate could be controlled by decreasing the ash content, but the source of vanadium was identified as metakaolin. The increase in the fly ash content decreased the cation exchange capacity of the granules. In conclusion, the recommended fly ash content is equivalent to 0.3 wt% of Al0 and the developed granules could be best suited as light-weight artificial aggregates in concrete where the additional binder would provide stabilization to decrease the leaching.

Effect of rice husk morphology on the ability to synthesize silicon carbide by pyrolysis method

Silicon carbide (SiC) is a mineral with good technical properties and high economic value. However, the synthesis of SiC is expensive because it is synthesized at a high-temperature environment (above 1500oC). The synthesis of SiC from biomass can significantly reduce the synthesis temperature. One commonly used biomass material for synthesizing SiC is rice husk. However, the ability to synthesize SiC depends on the shape of the rice husk. The influence of the morphology of rice husk on the ability to synthesize SiC was studied in this study. Experimental results showed that the original rice husk would give better SiC formation capacity than the rice husk powder. The amount of SiC formed using the original rice husk when impregnated by sodium silicate solution and pyrolysis at 1200oC is 18.3% (wt%.). With rice husk powder, it is 15.12% (wt%.). The results of analysis of the mineral composition, functional groups, and morphologies by X-ray diffraction (XRD), Fourier Infrared Transform Method (FT-IR), and Scanning Electron Microscopy (SEM) found that the polymorphy of SiC is α-SiC and β-SiC. These minerals are the basis for SiC from rice husks, which can be applied as wear-resistant materials.

Bio-based boards made of hazelnut shell and A. donax for indoor applications - A solution with good performance in case of fire

The present study investigated the reaction to fire of bio-based boards for indoor applications made of A. donax and hazelnut shells as aggregates. A sodium silicate solution was employed as the adhesive due to its several advantages. Among others, the possibility of moderating some of the main drawbacks of bio-based building composites, such as the resistance to fire. The considered materials were analysed both individually, to test their inherent properties, and when integrated into the composites, ensuring considerations about materials' influence on the final products’ properties. Two different test methods, using a cone calorimeter, were considered and performed. The results showed that the sodium silicate solution avoided flaming and smoking, in case of a constant heat application with and without an igniter (spark), demonstrating the benefit of its use in this type of bio-based composites. Overall, the particleboards demonstrated their ability to comply with fire behaviour consistent with the Class A1 requirements, while the bio-components on themselves were characterized by an intermediate fire risk propensity. Thus, the present study provided an effective solution to avoid one of the main drawbacks of bio-based composites. It demonstrated the feasibility of employing the proposed bio-based boards as indoor coating, with no risk to human life in case of fire.

Phase identification and micromechanical properties of non-traditional and natural pozzolan based alkali-activated materials

Four groups of non-traditional and natural pozzolan (NNP) based (aluminosilicate-based) materials, calcined clays, ground bottom ashes, volcanic ashes, and fluidized bed combustion ashes, were alkali activated using a hybrid solution of sodium silicate and sodium hydroxide. The microhardness and reduced modulus of the phases present in eleven alkali-activated pastes were measured using nanoindentation. At least 800 data points were collected from 28-day old ambiently cured paste samples. Unsupervised machine learning techniques i.e., k-means clustering and Gaussian mixture modeling (GMM) were used for the classification of the micromechanical properties supplemented by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The clustering of micromechanical and EDS data revealed five distinct phases in these hardened pastes. The alkali-activated gels identified had reduced modulus values ranging from 12 to 34 GPa. The remnant phases were partly reacted grains and unreacted minerals exhibiting reduced modulus values ranging from 35 to 105 GPa. Micromechanical property contour plots and SEM image pixel count plots were used to validate the phase assemblage. Additionally, the identification capabilities and advantages of the method are assessed by direct comparison with experimental results for different alkali-activated gels.

Effect of Expanded Glass Lightweight Aggregate on the Performance of Geopolymer Mortar at Elevated Temperatures

AbstractThe greenhouse gas emissions associated with conventional concrete as a result of the cement industry have prompted scientists to search for eco-friendly alternatives. Among these promising alternatives is geopolymer concrete or mortar. This work studies the impact of using polyvinyl alcohol (PVA) fibers and lightweight expanded glass (EG) aggregate on the mechanical behaviour of lightweight geopolymer mortar (LWGM) at various temperatures (room temperature, 250 °C, and 500 °C). EG was utilized to partially replace the sand by 10 and 20%. Limited studies dealt with geopolymer mortar based on such composition at high temperatures. The geopolymer mortar was created using slag as the main precursor activated by a mixed solution of sodium hydroxide and sodium silicate. Various combinations were produced, and their behaviour was observed at room and high temperatures. Several tests such as workability, compressive and flexural strengths, density, stress-strain relationship, load-displacement behaviour, and uniaxial tensile strength were performed. The findings of the study indicate that the density and compressive strength of geopolymer mortar reduced with increasing the replacement level by the EG. However, the utilization of 10% EG can produce a lightweight mortar with a compressive strength of 17.9 at 28 days. Moreover, the use of 1% PVA significantly improves the mechanical performance. Furthermore, the mechanical characteristics of the materials were considerably altered when subjected to extreme temperatures of 500 °C as observed from experimental data.

Effects of elevated temperature on mechanical properties and microstructures of alkali-activated mortar made from low calcium fly ash-calcium carbide residue mixture

This research investigated the high-temperature resistance of alkali-activated mortar (AAM) using Class F fly ash (FA) blended with calcium carbide residue (CR) as a binder. The FA was blended with CR at 15 %, 30 %, and 45 % by weight. Sodium hydroxide (NaOH) and sodium silicate solution (Na2SiO3) was used as activator in the ratio of 2:1 by weight. The sodium hydroxide solution concentrations were 6, 8, and 10 M, the liquid-to-binder ratio was 0.85, and the binder-to-fine aggregate ratio was 1:2.75 by weight. The study assessed physical characteristics, compressive strength, weight loss, and microstructural analysis, subsequent to being subjected to 2-hour heating at 400, 600, and 800 °C. According to the findings, the highest compressive strength (prior heating) was recorded as 41.3 MPa after 28 days and this was observed in samples where 30 % of CR was combined with 70 % of FA. Meanwhile, when exposed to elevated temperatures, the compressive strength of all samples was decreased. The decomposition of Ca(OH)2, C-S-H, and C-A-S-H gel in the matrix as indicated by the microstructure result was conformed to the result of compressive strength loss. Nonetheless, when the samples were sintered at 800 °C, a new crystalline phase was formed, resulting in a slightly increase in compressive strength compared to samples sintered at 600 °C.

Effect of curing condition on mechanical properties and durability of alkali-activated slag mortar

While alkali-activated slag (AAS) has emerged as a promising alternative binder in construction engineering, a consensus on the optimal curing condition for this material has not been reached yet. It is well known that AAS can harden at ambient temperatures, but the influence of humidity on its properties remains poorly understood. Herein, we considered five curing conditions with different relative humidities (RH), including ambient/dry condition (RH=55 %), sealed condition (RH=80–95 %), fog condition (RH>95 %), water immersion condition (RH=100 %), and saturated limewater immersion condition (RH=100 %). Various properties have been examined, including flexural and compressive strengths, elastic modulus, shrinkage, pore structure, carbonation resistance, and freeze-thaw resistance of AAS mortars (AASM). Two types of activators, sodium hydroxide and sodium silicate (modulus at 1) solutions were used. The experimental results indicate that drying at early ages is detrimental to almost all the properties investigated. Sealed curing can deliver desirable mechanical properties and durability, but considerable shrinkage. Fog and water curings are highly effective at mitigating early shrinkage in AASM, but the problem of leaching adversely affects its long-term properties. Generally, limewater curing offers limited benefits compared to other high-humidity curing methods.

NON-FIRED LATERITE SOIL BRICKS WITH NA-BASED STABILIZER ADDITION FOR SUSTAINABLE DEVELOPMENT

Fired bricks are widely used, but they are energy-intensive and non-eco-friendly. Non-fired bricks with chemical stabilisers can be the alternative solution, which is a low-energy-intensive and environmentally friendly manufacturing product. Laterite soil can be the raw material for the synthesis of non-fired clay brick in sodium hydroxide solution and sodium silicate solution. However, it may have been mixed with other laterite soils with different optimum moisture contents and grain sizes during extraction. Thus, the mixing ratio of laterite soil, Na-based stabilisers, and water for non-fired brick production is determined. Besides, two types of laterite soil, LAT 1 and LAT 2, from different locations were prepared, and another type of laterite soil, LAT 3, was prepared by mixing LAT 1 and LAT 2. Both three are compared primarily in terms of compressive strength and water absorption, which are mixed with the Na2SiO3/NaOH ratio. As a result, the new mixing ratio with increased water content was determined based on the optimum moisture content of the soil. Besides, the optimum mixing ratio of each type of brick was determined. Overall, based on the Malaysian standard, all types of brick samples from each ratio could be used as load-bearing class 1 and internal wall bricks. Additionally, LAT 2 and LAT 3-based bricks with a ratio of 1.5 Na2SiO3/NaOH ratio can be used as load-bearing brick class 2.

Synthesis of Silica Nanoparticles from Sodium Silicate and Carbon Dioxide as Reactants

In this study, Taylor-vortex reactor was adopted to synthesize silica nanoparticles from sodium silicate solution and carbon dioxide. The outstanding advantages of the reactor have been demonstrated by comparing the synthesis results of silica nanoparticles by Erlenmeyer reactor. The results showed that silica particles synthesized from Taylor-vortex reactor are smaller in size than silica particles synthesized from the Erlenmeyer reactor. SEM images and histogram of particle size distribution obtained from experiments clearly exhibited that the concentration of SiO2 in the solution, reaction temperature, and rotation speed of the cylinder significantly affected morphology as well as size of the silica particles.

Bio-regeneration for Sodium Silicate Used Sands and its Unattended Monitoring System

Sodium silicate, known for its low cost and non-toxicity, has been considered as a promising option for green foundry in terms of mould sands. However, the utilization of used sodium silicate sands has posed significant challenges. To address the issues of high energy consumption and secondary pollution associated with wet and dry regeneration of sodium silicate used sands, this paper proposes a novel unattended biological regeneration system. The system involves culturing diatoms in an incubator with a solution of sodium silicate used sands. The incubator is equipped with built-in sensors that continuously monitor temperature, illuminance, pH, and water level. The monitoring data is transmitted in real-time to the Yeelink Internet of Things platform via the controller using the TCP/IP protocol. By logging onto the corresponding web page, the experimenter can remotely observe the monitoring data. The results of the experiment indicate that diatoms bloomed five times, and the water pH decreased from 10.2 to 8.2 after 40 days of cultivation. Additionally, the film removal rate of the used sands reached 90.26%.

Hybrid alkali-activated fly ash-Portland cement binders with modified polymer as patch repair

The alternative patch repair derived from hybrid alkali-activated binders (HAAB) were investigated in this paper. The HAAB mortar was produced with fly ash (FA), Portland cement (PC), and polymer-modified material (PMM). The additives (PC and PMMs) were used to replace FA at the dosage of 30 % by weight of binder. The proportions of PC-to-PMM at 30:0, 20:10, 10:20, and 0:30 were investigated. Sodium silicate (NS) and sodium hydroxide (NH) solutions were used as the alkaline activators. Constant NS-to-NH ratio of 2.0 and liquid/solid binder ratio of 0.60 were used for all mixtures. Experimental results showed that the setting time, compressive and shear bond strengths of the HAAB mortars met the requirement for repair material as specified by ASTM standard. The 7-day bond strength increased with increasing PMM replacement up to an optimum level; thereafter, it started to decline. A combination of PC and PMM in FA-based HAAB enhanced the adhesion at contact zone. Moreover, the HAAB mortars showed greater durability compared to conventional PMMs after immersion in sulfate and acid solutions, as evidenced by its relatively low strength loss. The increased formation of ettringite might be the main factor for the substantial reduction in the strength of PMM mixes. Therefore, the HAAB mortar is an attractive choice for patch repair material in terms of excellent durability, high bond strength, cost-effectiveness, and low carbon footprint compared to conventional PMM.

Investigation of different deposition methods for synthesized gold nanoparticles on a South African sugarcane leaves derived silica xerogel support

Value added materials made from agricultural residues are very attractive since they contribute in reducing environmental waste and enhancing economic sustainability. Two deposition methods were investigated where silica xerogel from sugarcane leaves (a waste from sugarcane industry) was used as a support for the synthesized gold nanoparticles. Biogenic silica was refluxed with sodium hydroxide at 80 °C to form sodium silicate solution. The gold nanoparticles were either synthesized in the sodium silicate solution or separately to form silica/Au nanoparticles through a sol-gel method. Ultraviolet (UV)-visible spectroscopy, x-ray powder diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray fluorescence spectroscopy (XRF), energy dispersive x-ray (EDX) and nitrogen adsorption-desorption were used to characterize the produced Si/Au nanoparticles. The two investigated methods resulted in distinctive deposition of gold nanoparticles on a silica xerogel support and also significantly different textural properties. The produced silica/gold nanoparticles had a Brunauer-Emmett-Teller (BET) surface area of up to 619 m2/g, pore diameter of 8.3 nm and pore volume of 1.28 cm3.g−1.

Optimization using central composite design for continuous absorption of CO2 gas with green sodium silicate in a packed bed column

If absolutely nothing is taken to reduce carbon dioxide (CO2) emissions, atmospheric concentrations of carbon dioxide will rise to 550 parts per million by 2050, which will have disastrous effects on the world's climate and food production. An apparatus has been designed and setup to convert CO2 into a useful and vital product which was silica. The effect of different experimental factors on the compositions by weight percent of SiO2 and Na2CO3 were studied including the CO2 gas flow rate (1.037, 1.648 and 2.26 L/min), initial concentration of sodium silicate (Na2SiO3) solution (5, 7.5 and 10 %wt) and the packing size (15.95, 20.175, and 24.4 mm). An optimization process was performed using the Design Expert software program to achieve the optimum experimental conditions at which the maximum weight percent of SiO2 (main product), the minimum weight percent of (Na2CO3) (side product) and the minimum reaction time were determined. From the optimization process, the maximum weight percent of SiO2 (25.63 %), the minimum weight percent of (Na2CO3) (9.62 %) and the minimum reaction time (7.59 min) were achieved at the following optimum experimental conditions of CO2 gas flow rate = 1.648 L/min, packing size = 24.4 mm and initial concentration of sodium silicate solution = 10 %wt.

Long-term durability of discarded cork-based composites obtained by geopolymerization

Geopolymers are amorphous aluminosilicate inorganic polymers synthesized by alkaline activation characterized by a lower carbon footprint, greater durability, and excellent mechanical properties compared to traditional concrete, making them promising building materials for sustainable construction. To develop sustainable lightweight geopolymer-based building materials useful as fire resistant thermal insulation materials, we added 5 and 10 wt% of discarded cork dust, a readily available industrial by-product, to metakaolin before and after the alkaline activation with sodium hydroxide 8 M and sodium silicate solutions. We followed the chemical, microstructural, antibacterial, and physical properties of the resulting composites for up to 90 days in order to monitor their long-term durability. The presence of cork does not interfere with the geopolymerization process and in fact reduces the density of the composites to values around 2.5 g/cm3, especially when added after alkaline activation. The composites resulted in chemically stable matrices (less than 10 ppm of cations release) and filler (no hazardous compounds released) with a bacterial viability of around 80%. This study provides valuable insights into the tailoring of discarded cork-based composites obtained by geopolymerization with a porosity between 32 and 48% and a mechanical resistance to compression from 15 to 5 MPa, respectively, suggesting their potential as durable interior panels with low environmental impact and desirable performance.

Synthesis of Chitosan Silica Membrane from Petung Bamboo (<i>Dendrocalamus asper</i>) Leaves and Its Application as Pb(II) Metallic Adsorbent

Membrane synthesis through a phase inversion method using chitosan and sodium silicate solutions has been conducted. This research aims to characterize the silica chitosan membrane (SCM) of petung bamboo leaves and determine the synthesized product's adsorption capacity for Pb(II) ions. The XRF characterization showed the silica content of petung bamboo leaves with a percentage of 78.03%. SEM analysis before adsorption is around 13.0 μm, and the pore diameter after adsorption is around 9.7 μm. The results of adsorption analysis of Pb(II) metal using AAS showed that the SCM variation A at an initial concentration of 10.0000 ppm Pb(II) metal adsorbed was 9.8101 ppm, and at an initial concentration of 25.0000 ppm Pb(II) metal was 22.3421 ppm. The variation B at an initial concentration of 10.0000 ppm Pb(II) metal adsorbed was 9.8870 ppm and at an initial concentration of 25.0000 ppm Pb(II) metal adsorbed was 23.5806 ppm. The variation C at an initial concentration of 10.0000 ppm Pb(II) metal adsorbed was 9.9639 ppm, and at an initial concentration of 25.0000 ppm Pb(II) metal was 24.1855 ppm. The results of this research conclude that the highest SCM adsorption power is variation C (2%:22.95%) with a percentage of 99.63%.

Strength evolution and microstructure of alkali-activated ultra-fine slag in low-temperature environments

At low temperatures, the hydration rate of Portland cement significantly slows down, resulting in a decrease in its strength. Additionally, the pore solution freezes easily. As a kind of low-carbon cementitious material, alkali-activated slag (AAS) material has a short setting time at room temperature and a high early strength, meanwhile the alkali solution does not freeze at low temperatures. This study investigates the evolution mechanism of the strength and microstructure of AAS pastes cured at 0℃. Slag with different fineness was activated by a sodium silicate solution with different moduli, whose strength was compared with that of an AAS paste cured at 20 °C. The setting time, compressive strength, hydration process, pore structure, freezing point, and microstructure of the AAS paste were studied, whose results showed that the setting time of the AAS paste was obviously prolonged, and the compressive strength decreased under low-temperature curing. After the activation of slag ground, the early compressive strength of the AAS paste was significantly improved, whose reason was that the hydration degree of the paste was improved after slag ground, and that a dense pore structure was formed. The freezing point of the AAS paste was approximately −26 °C, which, remarkably, even at −40 °C, was still capable of undergoing a weak chemical reaction, producing an exothermic enthalpy. This characteristic makes alkali-activated ultrafine slag a highiy-promising cementitious material for curing at low temperatures.