Characterisation and Performance of Nigerian Kaolin and Metakaolin in Geopolymer Synthesis

Abstract

This study is aimed at characterising and understanding the mechanical and microstructural behaviour of natural and calcined kaolin clay for geopolymer applications. The clay samples obtained from Kaduna State, Northern area of Nigeria, were calcined within the temperature range of 700 and 900oC and are represented by MK7, MK8 and MK9. The raw kaolin and metakaolin were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF) and scanning electron microscopy (SEM). To produce geopolymer binders, the precursors were reacted with a 1:1 combination of sodium hydroxide and sodium silicate solution and a precursor to activator ratio of 1.2 was suitable for preparation. The compressive strength of the samples was determined at three testing age of 7, 14 and 28 days. From the results obtained, the kaolin-based geopolymer generally had a long setting time and testing was impossible at the 7-day testing age. The compressive strength of other samples however, increased with increase in the calcination temperature. The values obtained at the maximum testing age of 28 days for all samples fall between 5.1 -14.9 MPa. The scanning electron microscope morphology of the produced binder, show the presence of air trapped in the paste which may have reduced the strength value. Vibrating samples before setting can improve the performance of the geopolymer binders by removing most of the trapped air. Geopolymers produced from this study based on strength obtained, can be used in less critical areas of the construction industry.