Saline Snow Research Articles

Snow depth estimation on leadless landfast ice using Cryo2Ice satellite observations

Abstract. Observations of snow on Arctic Sea ice are vitally important for sea ice thickness estimation, bio-physical processes, and human activities. While previous studies have combined CryoSat-2- and ICESat-2-derived freeboards to estimate snow depth over Arctic sea ice, these approaches require leads within the ice pack to estimate the freeboard heights above the sea surface. In regions such as the Canadian Arctic Archipelago (CAA), leads are scarce in winter, posing a significant challenge to estimate snow depth from altimeters. This study is the first assessment of the potential for near-coincident ICESat-2 and Cryosat-2 (Cryo2Ice) snow depth retrievals in a leadless region of the CAA including validation with in situ data. In lieu of sea surface height estimates from leads, snow depths are retrieved using the absolute difference in surface heights (ellipsoidal heights) from ICESat-2 and Cryosat-2 after applying an ocean tide correction based on tidal gauges between satellite passes on 29 April 2022. Both the absolute mean snow depths and distributions retrieved from Cryo2Ice were slightly underestimated (2 to 4 cm) when compared to in situ measurements. All four in situ sites had snow with saline basal layers and different levels of roughness and ridging, which significantly impact the accuracy of the Cryo2Ice snow depth retrievals. Differences between Cryo2Ice and in situ snow depth distributions reflect the varying sampling resolutions of the sensors and the in situ measurements. Cryo2Ice tends to miss snow depths greater than 30 cm, especially around ridges. The results suggest that it might be possible to estimate snow depth over landfast sea ice without leads. However, the observed biases of 2–4 cm likely stem from several factors: (1) discrepancies in sampling resolution between ICESat-2 and CryoSat-2; (2) the CryoSat-2 scattering horizon not aligning with the snow–ice interface due to snow salinity, density, and surface roughness; (3) the choice of retracker; and (4) potential errors in the altimeter's tidal corrections. Further investigation is needed to address these issues. Moreover, the proposed methodology for getting snow depth over leadless landfast sea ice needs to be validated using in situ datasets in other landfast sea ice regions in the Arctic.

Surface snow bromide and nitrate at Eureka, Canada, in early spring and implications for polar boundary layer chemistry

Abstract. This study explores the role of snowpack in polar boundary layer chemistry, especially as a direct source of reactive bromine (BrOx = BrO + Br) and nitrogen (NOx = NO + NO2) in the Arctic springtime. Surface snow samples were collected daily from a Canadian high Arctic location at Eureka, Nunavut (80° N, 86° W) from the end of February to the end of March in 2018 and 2019. The snow was sampled at several sites representing distinct environments: sea ice, inland close to sea level, and a hilltop ∼ 600 m above sea level (a.s.l.). At the inland sites, surface snow salinity has a double-peak distribution with the first and lowest peak at 0.001–0.002 practical salinity unit (psu), which corresponds to the precipitation effect, and the second peak at 0.01–0.04 psu, which is likely related to the salt accumulation effect (due to loss of water vapour by sublimation). Snow salinity on sea ice has a triple-peak distribution; its first and second peaks overlap with the inland peaks, and the third peak at 0.2–0.4 psu is likely due to the sea water effect (a result of upward migration of brine). At all sites, snow sodium and chloride concentrations increase by almost 10-fold from the top 0.2 to ∼ 1.5 cm. Surface snow bromide at sea level is significantly enriched, indicating a net sink of atmospheric bromine. Moreover, surface snow bromide at sea level has an increasing trend over the measurement period, with mean slopes of 0.024 µM d−1 in the 0–0.2 cm layer and 0.016 µM d−1 in the 0.2–0.5 cm layer. Surface snow nitrate at sea level also shows a significant increasing trend, with mean slopes of 0.27, 0.20, and 0.07 µM d−1 in the top 0.2, 0.2–0.5, and 0.5–1.5 cm layers, respectively. Using these trends, an integrated net deposition flux of bromide of (1.01 ± 0.48) × 107 molec.cm-2s-1 and an integrated net deposition flux of nitrate of (2.6 ± 0.37) × 108 molec.cm-2s-1 were derived. In addition, the surface snow nitrate and bromide at inland sites were found to be significantly correlated (R = 0.48–0.76) with the [NO3-]/[Br-] ratio of 4–7 indicating a possible acceleration effect of reactive bromine in atmospheric NOx-to-nitrate conversion. This is the first time such an effect has been seen in snow chemistry data obtained with a sampling frequency as short as 1 d. BrO partial column (0–4 km) data measured by MAX-DOAS show a decreasing trend in early spring, which generally agrees with the derived surface snow bromide deposition flux indicating that bromine in Eureka atmosphere and surface snow did not reach a photochemical equilibrium state. Through mass balance analysis, we conclude that the average release flux of reactive bromine from snow over the campaign period must be smaller than the derived bromide deposition flux of ∼ 1 × 107 molec.cm-2s-1. Note that the net mean fluxes observed do not completely rule out larger bidirectional fluxes over shorter timescales.

Global Observations of Tropospheric Bromine Monoxide (BrO) Columns From TROPOMI

AbstractBromine monoxide (BrO) plays an important role in tropospheric chemistry. The state‐of‐the‐science TROPOspheric Monitoring Instrument (TROPOMI) offers the potential to monitor atmospheric composition with a fine spatial resolution of up to 5.5 × 3.5 km2. We present here the retrieval of tropospheric BrO columns from TROPOMI. We implement a stratospheric correction scheme using a climatological approach based on the latest GEOS‐Chem High Performance chemical transport model, and improve the tropospheric air mass factor calculation with TROPOMI surface albedo data accounting for the geometrical dependency. Our product presents a good level of consistency in comparison with measurements from ground‐based zenith‐sky differential optical absorption spectroscopy (r = 0.67), aircrafts (r = 0.46), and satellites (similar spatial distributions of BrO columns). Furthermore, our retrieval captures BrO enhancements in the polar springtime with values up to 7.8 × 1013 molecules cm−2 and identifies small‐scale emission sources such as volcanoes and salt marshes. Based on TROPOMI data, we probe a blowing snow aerosol bromine mechanism in which the snow salinity is reduced to better match simulation and observation. Our TROPOMI tropospheric BrO product contributes high‐resolution global information to studies investigating atmospheric bromine chemistry.

Impact of Changing Arctic Sea Ice Extent, Sea Ice Age, and Snow Depth on Sea Salt Aerosol From Blowing Snow and the Open Ocean for 1980–2017

AbstractWe evaluate the effects of rapidly changing Arctic sea ice conditions on sea salt aerosols (SSA) produced by oceanic wave‐breaking and the sublimation of wind‐lofted salty blowing snow on sea ice. We use the GEOS‐Chem chemical transport model to assess the influence of changing extent of the open ocean, multi‐year sea ice (MYI), first‐year sea ice (FYI), and snow depths on SSA emissions for 1980–2017. We combine snow depths from the Lagrangian snow‐evolution model (SnowModel‐LG) together with an empirically‐derived snow salinity function of snow depth to derive spatially and temporally varying snow surface salinity over Arctic FYI. We find that pan‐Arctic SSA surface mass concentrations have increased by 6%–12% decade−1 during the cold season (November–April) and by 7%–11% decade−1 during the warm season (May–October). The cold season trend is due to increasing blowing snow SSA originating from FYI: as MYI is replaced by FYI with thinning snow depths, snow surface salinity increases by more than 11% decade−1. During the warm season, rapid sea ice loss and thus increasing open ocean SSA are the cause of modeled SSA trends. Observations of SSA mass concentrations at Alert, Canada display positive trends during the cold season (10%–12% decade−1), consistent with our pan‐Arctic simulations. During fall, Alert observations show a negative trend (−18% decade−1), due to locally decreasing wind speeds and thus lower open ocean emissions. These significant changes in SSA concentrations could potentially affect past and future bromine explosions and Arctic climate feedbacks.

Technical note: Sea salt interference with black carbon quantification in snow samples using the single particle soot photometer

Abstract. After aerosol deposition from the atmosphere, black carbon (BC) takes part in the snow albedo feedback contributing to the modification of the Arctic radiative budget. With the initial goal of quantifying the concentration of BC in the Arctic snow and subsequent climatic impacts, snow samples were collected during the research vessel (R/V) Polarstern expedition of PASCAL (Physical Feedbacks of Arctic Boundary Layer, Sea Ice, Cloud and Aerosol; Polarstern cruise 106) in the sea-ice-covered Fram Strait in early summer 2017. The refractory BC (rBC) content was then measured in the laboratory of the Alfred Wegener Institute with the single particle soot photometer (SP2). Based on the strong observational correlations between both rBC concentration and rBC diameter with snow salinity, we hypothesize a salt-induced matrix effect interfering with the SP2 analysis. This paper evaluates the impact of sea salt, based on the measurement of electrical conductivity (κ) in water samples, on rBC measurements made with a SP2 nebulizer technique. Under realistic salinity conditions, laboratory experiments indicated a dramatic six-fold reduction in observed rBC concentration with increasing salinity. In the salinity conditions tested in the present work (salt concentration below 0.4 g L−1) the impact of salt on the nebulization of water droplets might be negligible. However, the SP2 mass detection efficiency systematically decreased with increasing salinity, with the smaller rBC particles being preferentially undetected. The high concentration of suspended salt particles and the formation of thick salt coatings on rBC cores caused problems in the SP2 analog-to-digital conversion of the signal and incandescence quenching, respectively. Changes to the signal acquisition parameters and the laser power of the SP2 improved the mass detection efficiency, which, nonetheless, stayed below unity. The present work provides evidence that a high concentration of sea salt undermines the quantification of rBC in snow performed with the SP2 nebulizer system described here. This interference has not been previously reported and might affect the future such analysis of rBC particles in snow collected, especially over sea ice or coastal regions strongly affected by sea salt deposition.

Simulated Ka- and Ku-band radar altimeter height and freeboard estimation on snow-covered Arctic sea ice

Abstract. Owing to differing and complex snow geophysical properties, radar waves of different wavelengths undergo variable penetration through snow-covered sea ice. However, the mechanisms influencing radar altimeter backscatter from snow-covered sea ice, especially at Ka- and Ku-band frequencies, and the impact on the Ka- and Ku-band radar scattering horizon or the “track point” (i.e. the scattering layer depth detected by the radar re-tracker) are not well understood. In this study, we evaluate the Ka- and Ku-band radar scattering horizon with respect to radar penetration and ice floe buoyancy using a first-order scattering model and the Archimedes principle. The scattering model is forced with snow depth data from the European Space Agency (ESA) climate change initiative (CCI) round-robin data package, in which NASA's Operation IceBridge (OIB) data and climatology are included, and detailed snow geophysical property profiles from the Canadian Arctic. Our simulations demonstrate that the Ka- and Ku-band track point difference is a function of snow depth; however, the simulated track point difference is much smaller than what is reported in the literature from the Ku-band CryoSat-2 and Ka-band SARAL/AltiKa satellite radar altimeter observations. We argue that this discrepancy in the Ka- and Ku-band track point differences is sensitive to ice type and snow depth and its associated geophysical properties. Snow salinity is first increasing the Ka- and Ku-band track point difference when the snow is thin and then decreasing the difference when the snow is thick (>0.1 m). A relationship between the Ku-band radar scattering horizon and snow depth is found. This relationship has implications for (1) the use of snow climatology in the conversion of radar freeboard into sea ice thickness and (2) the impact of variability in measured snow depth on the derived ice thickness. For both (1) and (2), the impact of using a snow climatology versus the actual snow depth is relatively small on the radar freeboard, only raising the radar freeboard by 0.03 times the climatological snow depth plus 0.03 times the real snow depth. The radar freeboard is a function of both radar scattering and floe buoyancy. This study serves to enhance our understanding of microwave interactions towards improved accuracy of snow depth and sea ice thickness retrievals via the combination of the currently operational and ESA's forthcoming Ka- and Ku-band dual-frequency CRISTAL radar altimeter missions.

Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O<sub>3</sub> in the Arctic

Abstract. We use the GEOS-Chem chemical transport model to examine the influence of bromine release from blowing-snow sea salt aerosol (SSA) on springtime bromine activation and O3 depletion events (ODEs) in the Arctic lower troposphere. We evaluate our simulation against observations of tropospheric BrO vertical column densities (VCDtropo) from the GOME-2 (second Global Ozone Monitoring Experiment) and Ozone Monitoring Instrument (OMI) spaceborne instruments for 3 years (2007–2009), as well as against surface observations of O3. We conduct a simulation with blowing-snow SSA emissions from first-year sea ice (FYI; with a surface snow salinity of 0.1 psu) and multi-year sea ice (MYI; with a surface snow salinity of 0.05 psu), assuming a factor of 5 bromide enrichment of surface snow relative to seawater. This simulation captures the magnitude of observed March–April GOME-2 and OMI VCDtropo to within 17 %, as well as their spatiotemporal variability (r=0.76–0.85). Many of the large-scale bromine explosions are successfully reproduced, with the exception of events in May, which are absent or systematically underpredicted in the model. If we assume a lower salinity on MYI (0.01 psu), some of the bromine explosions events observed over MYI are not captured, suggesting that blowing snow over MYI is an important source of bromine activation. We find that the modeled atmospheric deposition onto snow-covered sea ice becomes highly enriched in bromide, increasing from enrichment factors of ∼5 in September–February to 10–60 in May, consistent with composition observations of freshly fallen snow. We propose that this progressive enrichment in deposition could enable blowing-snow-induced halogen activation to propagate into May and might explain our late-spring underestimate in VCDtropo. We estimate that the atmospheric deposition of SSA could increase snow salinity by up to 0.04 psu between February and April, which could be an important source of salinity for surface snow on MYI as well as FYI covered by deep snowpack. Inclusion of halogen release from blowing-snow SSA in our simulations decreases monthly mean Arctic surface O3 by 4–8 ppbv (15 %–30 %) in March and 8–14 ppbv (30 %–40 %) in April. We reproduce a transport event of depleted O3 Arctic air down to 40∘ N observed at many sub-Arctic surface sites in early April 2007. While our simulation captures 25 %–40 % of the ODEs observed at coastal Arctic surface sites, it underestimates the magnitude of many of these events and entirely misses 60 %–75 % of ODEs. This difficulty in reproducing observed surface ODEs could be related to the coarse horizontal resolution of the model, the known biases in simulating Arctic boundary layer exchange processes, the lack of detailed chlorine chemistry, and/or the fact that we did not include direct halogen activation by snowpack chemistry.

First direct observation of sea salt aerosol production from blowing snow above sea ice

Abstract. Two consecutive cruises in the Weddell Sea, Antarctica, in winter 2013 provided the first direct observations of sea salt aerosol (SSA) production from blowing snow above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in the Antarctic. Blowing or drifting snow often leads to increases in SSA during and after storms. For the first time it is shown that snow on sea ice is depleted in sulfate relative to sodium with respect to seawater. Similar depletion in bulk aerosol sized ∼0.3–6 µm above sea ice provided the evidence that most sea salt originated from snow on sea ice and not the open ocean or leads, e.g. >90 % during the 8 June to 12 August 2013 period. A temporally very close association of snow and aerosol particle dynamics together with the long distance to the nearest open ocean further supports SSA originating from a local source. A mass budget estimate shows that snow on sea ice contains even at low salinity (<0.1 psu) more than enough sea salt to account for observed increases in atmospheric SSA during storms if released by sublimation. Furthermore, snow on sea ice and blowing snow showed no or small depletion of bromide relative to sodium with respect to seawater, whereas aerosol was enriched at 2 m and depleted at 29 m, suggesting that significant bromine loss takes place in the aerosol phase further aloft and that SSA from blowing snow is a source of atmospheric reactive bromine, an important ozone sink, even during winter darkness. The relative increase in aerosol concentrations with wind speed was much larger above sea ice than above the open ocean, highlighting the importance of a sea ice source in winter and early spring for the aerosol burden above sea ice. Comparison of absolute increases in aerosol concentrations during storms suggests that to a first order corresponding aerosol fluxes above sea ice can rival those above the open ocean depending on particle size. Evaluation of the current model for SSA production from blowing snow showed that the parameterizations used can generally be applied to snow on sea ice. Snow salinity, a sensitive model parameter, depends to a first order on snowpack depth and therefore was higher above first-year sea ice (FYI) than above multi-year sea ice (MYI). Shifts in the ratio of FYI and MYI over time are therefore expected to change the seasonal SSA source flux and contribute to the variability of SSA in ice cores, which represents both an opportunity and a challenge for the quantitative interpretation of sea salt in ice cores as a proxy for sea ice.

Snow Property Controls on Modeled Ku-Band Altimeter Estimates of First-Year Sea Ice Thickness: Case Studies From the Canadian and Norwegian Arctic

Uncertainty in snow properties impacts the accuracy of Arctic sea ice thickness estimates from radar altimetry. On first-year sea ice (FYI), spatiotemporal variations in snow properties can cause the Ku-band main radar scattering horizon to appear above the snow/sea ice interface. This can increase the estimated sea ice freeboard by several centimeters, leading to FYI thickness overestimations. This article examines the expected changes in Ku-band main scattering horizon and its impact on FYI thickness estimates, with variations in snow temperature, salinity, and density derived from ten naturally occurring Arctic FYI Cases encompassing saline/nonsaline, warm/cold, simple/complexly layered snow (4–45 cm) overlying FYI (48–170 cm). Using a semi-empirical modeling approach, snow properties from these Cases are used to derive layer-wise brine volume and dielectric constant estimates, to simulate the Ku-band main scattering horizon and delays in radar propagation speed. Differences between modeled and observed FYI thickness are calculated to assess sources of error. Under both cold and warm conditions, saline snow covers are shown to shift the main scattering horizon above from the snow/sea ice interface, causing thickness retrieval errors. Overestimates in FYI thicknesses of up to 65% are found for warm, saline snow overlaying thin sea ice. Our simulations exhibited a distinct shift in the main scattering horizon when the snow layer densities became greater than 440 kg/m3, especially under warmer snow conditions. Our simulations suggest a mean Ku-band propagation delay for snow of 39%, which is higher than 25%, suggested in previous studies.

Sea salt aerosol production via sublimating wind-blown saline snow particles over sea ice: parameterizations and relevant microphysical mechanisms

Abstract. Blowing snow over sea ice has been proposed as a significant source of sea salt aerosol (SSA) (Yang et al., 2008). In this study, using snow salinity data and blowing snow and aerosol particle measurements collected in the Weddell Sea sea ice zone (SIZ) during a winter cruise, we perform a comprehensive model–data comparison with the aim of validating proposed parameterizations. Additionally, we investigate possible physical mechanisms involved in SSA production from blowing snow. A global chemical transport model, p-TOMCAT, is used to examine the model sensitivity to key parameters involved, namely blowing-snow size distribution, snow salinity, sublimation function, surface wind speed, relative humidity, air temperature and ratio of SSA formed per snow particle. As proposed in the parameterizations of Yang et al. (2008), the SSA mass flux is proportional to the bulk sublimation flux of blowing snow and snow salinity. To convert the bulk sublimation flux to SSA size distribution requires (1) sublimation function for snow particles, (2) blowing-snow size distribution, (3) snow salinity and (4) ratio of SSA formed per snow particle. The optimum model–cruise aerosol data agreement (in diameter range of 0.4–12 µm) indicates two possible microphysical processes that could be associated with SSA production from blowing snow. The first one assumes that one SSA is formed per snow particle after sublimation, and snow particle sublimation is controlled by the curvature effect or the so-called “air ventilation” effect. The second mechanism allows multiple SSAs to form per snow particle and assumes snow particle sublimation is controlled by the moisture gradient between the surface of the particle and the ambient air (moisture diffusion effect). With this latter mechanism the model reproduces the observations assuming that one snow particle produces ∼10 SSA during the sublimation process. Although both mechanisms generate very consistent results with respect to observed aerosol number densities, they correspond to completely different microphysical processes and show quite different SSA size spectra, mainly in ultra-fine and coarse size modes. However, due to the lack of relevant data, we could not, so far, conclude confidently which one is more realistic, highlighting the necessity of further investigation.

Sources and selection of snow-specific microbial communities in a Greenlandic sea ice snow cover

Sea ice and its snow cover are critical for global processes including climate regulation and biogeochemical cycles. Despite an increase in studies focused on snow microorganisms, the ecology of snow inhabitants remains unclear. In this study, we investigated sources and selection of a snowpack-specific microbial community by comparing metagenomes from samples collected in a Greenlandic fjord within a vertical profile including atmosphere, snowpack with four distinct layers of snow, sea ice brine and seawater. Microbial communities in all snow layers derived from mixed sources, both marine and terrestrial, and were more similar to atmospheric communities than to sea ice or seawater communities. The surface snow metagenomes were characterized by the occurrence of genes involved in photochemical stress resistance, primary production and metabolism of diverse carbon sources. The basal saline snow layer that was in direct contact with the sea ice surface harbored a higher abundance of cells than the overlying snow layers, with a predominance of Alteromonadales and a higher relative abundance of marine representatives. However, the overall taxonomic structure of the saline layer was more similar to that of other snow layers and the atmosphere than to underlying sea ice and seawater. The expulsion of relatively nutrient-rich sea ice brine into basal snow might have stimulated the growth of copiotrophic psychro- and halotolerant snow members. Our study indicates that the size, composition and function of snowpack microbial communities over sea ice were influenced primarily by atmospheric deposition and inflow of sea ice brine and that they form a snow-specific assemblage reflecting the particular environmental conditions of the snowpack habitat.

Using CALIOP to constrain blowing snow emissions of sea salt aerosols over Arctic and Antarctic sea ice

Abstract. Sea salt aerosols (SSA) produced on sea ice surfaces by blowing snow events or the lifting of frost flower crystals have been suggested as important sources of SSA during winter over polar regions. The magnitude and relative contribution of blowing snow and frost flower SSA sources, however, remain uncertain. In this study, we use 2007–2009 aerosol extinction coefficients from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) instrument onboard the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite and the GEOS-Chem global chemical transport model to constrain sources of SSA over Arctic and Antarctic sea ice. CALIOP retrievals show elevated levels of aerosol extinction coefficients (10–20 Mm−1) in the lower troposphere (0–2 km) over polar regions during cold months. The standard GEOS-Chem model underestimates the CALIOP extinction coefficients by 50 %–70 %. Adding frost flower emissions of SSA fails to explain the CALIOP observations. With blowing snow SSA emissions, the model captures the overall spatial and seasonal variation of CALIOP aerosol extinction coefficients over the polar regions but underestimates aerosol extinction over Arctic sea ice in fall to early winter and overestimates winter-to-spring extinction over Antarctic sea ice. We infer the monthly surface snow salinity on first-year sea ice required to minimize the discrepancy between CALIOP extinction coefficients and the GEOS-Chem simulation. The empirically derived snow salinity shows a decreasing trend between fall and spring. The optimized blowing snow model with inferred snow salinities generally agrees with CALIOP extinction coefficients to within 10 % over sea ice but underestimates them over the regions where frost flowers are expected to have a large influence. Frost flowers could thus contribute indirectly to SSA production by increasing the local surface snow salinity and, therefore, the SSA production from blowing snow. We carry out a case study of an Arctic blowing snow SSA feature predicted by GEOS-Chem and sampled by CALIOP. Using back trajectories, we link this feature to a blowing snow event that occurred 2 days earlier over first-year sea ice and was also detected by CALIOP.

Cyclone-induced surface ozone and HDO depletion in the Arctic

Abstract. Ground-based, satellite, and reanalysis datasets were used to identify two similar cyclone-induced surface ozone depletion events at Eureka, Canada (80.1° N, 86.4° W), in March 2007 and April 2011. These two events were coincident with observations of hydrogen deuterium oxide (HDO) depletion, indicating that condensation and sublimation occurred during the transport of the ozone-depleted air masses. Ice clouds (vapour and crystals) and aerosols were detected by lidar and radar when the ozone- and HDO-depleted air masses arrived over Eureka. For the 2007 event, an ice cloud layer was coincident with an aloft ozone depletion layer at 870 m altitude on 2–3 March, indicating this ice cloud layer contained bromine-enriched blowing-snow particles. Over the following 3 days, a shallow surface ozone depletion event (ODE) was observed at Eureka after the precipitation of bromine-enriched particles onto the local snowpack. A chemistry–climate model (UKCA) and a chemical transport model (pTOMCAT) were used to simulate the surface ozone depletion events. Incorporating the latest surface snow salinity data obtained for the Weddell Sea into the models resulted in improved agreement between the modelled and measured BrO concentrations above Eureka. MERRA-2 global reanalysis data and the FLEXPART particle dispersion model were used to study the link between the ozone and HDO depletion. In general, the modelled ozone and BrO showed good agreement with the ground-based observations; however, the modelled BrO and ozone in the near-surface layer are quite sensitive to the snow salinity. HDO depletion observed during these two blowing-snow ODEs was found to be weaker than pure Rayleigh fractionation. This work provides evidence of a blowing-snow sublimation process, which is a key step in producing bromine-enriched sea-salt aerosol.

Effect of Snow Salinity on CryoSat‐2 Arctic First‐Year Sea Ice Freeboard Measurements

AbstractThe European Space Agency's CryoSat‐2 satellite mission provides radar altimeter data that are used to derive estimates of sea ice thickness and volume. These data are crucial to understanding recent variability and changes in Arctic sea ice. Sea ice thickness retrievals at the CryoSat‐2 frequency require accurate measurements of sea ice freeboard, assumed to be attainable when the main radar scattering horizon is at the snow/sea ice interface. Using an extensive snow thermophysical property dataset from late winter conditions in the Canadian Arctic, we examine the role of saline snow on first‐year sea ice (FYI), with respect to its effect on the location of the main radar scattering horizon, its ability to decrease radar penetration depth, and its impact on FYI thickness estimates. Based on the dielectric properties of saline snow commonly found on FYI, we quantify the vertical shift in the main scattering horizon. This is found to be approximately 0.07 m. We propose a thickness‐dependent snow salinity correction factor for FYI freeboard estimates. This significantly reduces CryoSat‐2 FYI retrieval error. Relative error reductions of ~11% are found for an ice thickness of 0.95 m and ~25% for 0.7 m. Our method also helps to close the uncertainty gap between SMOS and CryoSat‐2 thin ice thickness retrievals. Our results indicate that snow salinity should be considered for FYI freeboard estimates.

Ku-, X- and C-Band Microwave Backscatter Indices from Saline Snow Covers on Arctic First-Year Sea Ice

In this study, we inter-compared observed Ku-, X- and C-band microwave backscatter from saline 14 cm, 8 cm, and 4 cm snow covers on smooth first-year sea ice. A Ku-, X- and C-band surface-borne polarimetric microwave scatterometer system was used to measure fully-polarimetric backscatter from the three snow covers, near-coincident with corresponding in situ snow thermophysical measurements. The study investigated differences in co-polarized backscatter observations from the scatterometer system for all three frequencies, modeled penetration depths, utilized co-pol ratios, and introduced dual-frequency ratios to discriminate dominant polarization-dependent frequencies from these snow covers. Results demonstrate that the measured co-polarized backscatter magnitude increased with decreasing snow thickness for all three frequencies, owing to stronger gradients in snow salinity within thinner snow covers. The innovative dual-frequency ratios suggest greater sensitivity of Ku-band microwaves to snow grain size as snow thickness increases and X-band microwaves to snow salinity changes as snow thickness decreases. C-band demonstrated minimal sensitivity to changes in snow salinities. Our results demonstrate the influence of salinity associated dielectric loss, throughout all layers of the three snow covers, as the governing factor affecting microwave backscatter and penetration from all three frequencies. Our “plot-scale” observations using co-polarized backscatter, co-pol ratios and dual-frequency ratios suggest the future potential to up-scale our multi-frequency approach to a “satellite-scale” approach, towards effective development of snow geophysical and thermodynamic retrieval algorithms on smooth first-year sea ice.

Geophysical and atmospheric controls on Ku-, X- and C-band backscatter evolution from a saline snow cover on first-year sea ice from late-winter to pre-early melt

This study investigates changes in Ku-, X- and C-band microwave backscatter, co-polarized ratio and dual-frequency ratios, to changes in in-situ measured snow thermophysical properties, driven by surface radiation measurements, during a 7-day transition from late winter to pre-early melt on a highly saline snow cover on smooth first-year ice. A surface-based Ku-, X- and C-band microwave scatterometer system is used near coincident with in-situ thermophysical snow measurements. A frequency-dependent penetration depth model is utilized to simulate diverse variations in Ku-, X- and C-band penetration during fluctuating snow thermophysical and atmospheric conditions. These results helped improve the interpretation of observed changes in Ku-, X- and C-band backscatter. Overall, dielectric loss associated with presence of brine throughout the snow volume, is observed to be the governing factor affecting microwave penetration. Our results indicate significant differences in observed microwave backscatter and derived co-polarized ratio and dual-frequency ratios, for all three frequencies during the transition from cold late winter phase to warm pre-early melt onset phase. C-band demonstrates the greatest increase in backscatter and co-pol ratios, followed by X- and Ku-bands. The dual-frequency ratio combinations clearly demonstrate their ability to separate sensitivities in frequencies by characterizing changes in backscatter during the 7-day transition. Our results indicate strong direct influence of downwelling shortwave and longwave radiation on snow brine volume and dielectric properties, which drives changes to Ku-, X- and C-band microwave backscatter and its associated co-polarized ratio and dual-frequency ratios. Our results demonstrate the ability of an observational multi-frequency active microwave approach to illustrate frequency-, polarization- and incidence angle-dependent changes in microwave backscatter from snow covers on first-year ice, at varying atmospheric and snow thermophysical conditions.

Diurnal Scale Controls on C-Band Microwave Backscatter From Snow-Covered First-Year Sea Ice During the Transition From Late Winter to Early Melt

Diurnal observations of coincident in situ physical-, electrical-, and surface-based C-band microwave scattering properties of a 16-cm saline snow cover on smooth, moderately saline, first-year sea ice are presented for the transition period between late winter and early melt. Statistical regression analysis and backscatter modeling are employed to explore the scattering mechanisms within the snowpack and to assess associations between backscatter and snow properties for both periods. Our results demonstrate substantial variation in both measured snow properties and C-band microwave backscatter over the diurnal cycle during the late winter period when the difference between maximum and minimum air and snow surface temperature was approximately 5 °C. No such variation in snow properties and backscatter occurred for the early melt period when our case study exhibited a small diurnal variation (~1°C) in air and snow surface temperature. Statistical and modeled results show significant association between the microwave backscatter and snow properties for the top 8 cm of the snowpack. Basal snow properties do not contribute toward total backscatter in either case. As a result, we are certain that the sea ice surface was a negligible scattering interface during both cases. Correlations between backscatter and snow properties are incidence angle dependent, demonstrating the highest association at 50°. Diurnal backscatter from RADARSAT-2 synthetic aperture radar acquisitions support the influence of varying diurnal snow properties on C-band backscatter, showing a difference of ~4 dB for ${ \sigma }_{\vphantom {R_{j}}{\text {hh}}}^{o}$ and ${ \sigma }_{{\text {vv}}}^{o}$ during the late winter period. This difference is reduced to <1 dB for the early melt period.

Multifrequency Microwave Backscatter From a Highly Saline Snow Cover on Smooth First-Year Sea Ice: First-Order Theoretical Modeling

A theoretical understanding of a multifrequency microwave approach to understand complex microwave interactions from a highly saline snow cover on a relatively smooth first-year sea ice is presented. We examine the sensitivity of Ku-, X-, and C-band ${\sigma }_{{\text {VV}}}^{0}$ and ${\sigma }_{{\text {HH}}}^{0}$ to variability in snow geophysical properties such as salinity, density, temperature, and snow grain radius, sampled from a highly saline snow cover on first-year sea ice. A first-order multilayer snow and ice backscatter model is used to calculate ${\sigma }_{{\text {VV}}}^{0}$ and ${\sigma }_{{\text {HH}}}^{0}$ by taking into account the surface and volume scattering contributions within each snow layer of the snow pack. Penetration depth models are used to calculate the potential penetration of all three frequencies, at initial and perturbed snow property conditions. Sensitivity analyses suggest that variability in salinity and snow grain radius have the greatest effect, followed by density and temperature. This phenomenon is observed for all three frequencies, influencing microwave penetration and backscatter. Dielectric loss associated with highly saline snow covers and substantial changes in scattering contributions from snow grain radius perturbations were found to be the dominant factors affecting microwave penetration and backscatter. Results from this paper demonstrate the potential of using a multifrequency theoretical approach to correlate with active microwave observations to determine the geophysical and electrical state of snow/sea ice system. The paper also represents an evolution in a theoretical understanding on how an active microwave approach using multiple frequencies can be further utilized toward the development of snow thickness and/or snow water equivalent algorithm on smooth FYI.

Wintertime enhancements of sea salt aerosol in polar regions consistent with a sea ice source from blowing snow

Abstract. Sea salt aerosols (SSA) are generated via air bubbles bursting at the ocean surface as well as by wind mobilization of saline snow and frost flowers over sea-ice-covered areas. The relative magnitude of these sources remains poorly constrained over polar regions, affecting our ability to predict their impact on halogen chemistry, cloud formation, and climate. We implement a blowing snow and a frost flower emission scheme in the GEOS-Chem global chemical transport model, which we validate against multiyear (2001–2008) in situ observations of SSA mass concentrations at three sites in the Arctic, two sites in coastal Antarctica, and from the 2008 ICEALOT cruise in the Arctic. A simulation including only open ocean emissions underestimates SSA mass concentrations by factors of 2–10 during winter–spring for all ground-based and ship-based observations. When blowing snow emissions are added, the model is able to reproduce observed wintertime SSA concentrations, with the model bias decreasing from a range of −80 to −34 % for the open ocean simulation to −2 to +9 % for the simulation with blowing snow emissions. We find that the frost flower parameterization cannot fully explain the high wintertime concentrations and displays a seasonal cycle decreasing too rapidly in early spring. Furthermore, the high day-to-day variability of observed SSA is better reproduced by the blowing snow parameterization. Over the Arctic (&gt; 60° N) (Antarctic, &gt; 60° S), we calculate that submicron SSA emissions from blowing snow account for 1.0 Tg yr−1 (2.5 Tg yr−1), while frost flower emissions lead to 0.21 Tg yr−1 (0.25 Tg yr−1) compared to 0.78 Tg yr−1 (1.0 Tg yr−1) from the open ocean. Blowing snow emissions are largest in regions where persistent strong winds occur over sea ice (east of Greenland, over the central Arctic, Beaufort Sea, and the Ross and Weddell seas). In contrast, frost flower emissions are largest where cold air temperatures and open leads are co-located (over the Canadian Arctic Archipelago, coastal regions of Siberia, and off the Ross and Ronne ice shelves). Overall, in situ observations of mass concentrations of SSA suggest that blowing snow is likely to be the dominant SSA source during winter, with frost flowers playing a much smaller role.

Ku-, X- and C-band measured and modeled microwave backscatter from a highly saline snow cover on first-year sea ice

Abstract In this study, we inter-compare observed and modeled Ku-, X- and C-band microwave backscatter for two snow temperature conditions for a highly saline snow cover on smooth first-year sea ice. A new surface-based multi-frequency (Ku-, X- and C-bands) microwave scatterometer system is used quasi-coincident with in situ geophysical snow measurements. A multilayer snow and ice backscatter model is used to calculate the total co-polarized backscatter coefficient for two snow temperature conditions. The model provides the surface and volume scattering contributions for each snow layer, as well as the frequency-dependent penetration depth. These results aid interpretation of observed backscatter. Joint use of Ku-, X- and C-band microwaves provide an enhanced understanding of diverse variations in geophysical, thermodynamic and electrical state of snow/sea ice system. Our results indicate that the effect of dielectric loss associated with highly saline snow covers is the dominant factor affecting microwave penetration and backscatter from all three frequencies. The observed and modeled C-band backscatter shows good agreement, followed by X- and Ku-bands, at both snow temperature conditions. Microwave backscatter shows greater sensitivity to variations in plot-scale surface roughness, for all three frequencies. Additionally, Ku-band wavelength exhibits greater sensitivity to snow grain radius, over X-, and C-bands. Our results demonstrate the future potential of a multi-frequency approach towards the development of snow thickness and snow water equivalent algorithms on first-year sea ice.