• Thermal property of two unequal flames in a naturally ventilated tunnel is studied. • Temperatures induced by the small plume decay faster than that of the large plume. • A new model for maximum ceiling temperature of two unequal plumes is proposed. • Correlations for ceiling temperature decay profiles of dual plumes are developed. The catastrophic tunnel fire accidents are usually accompanied with multi-source burning. Ceiling gas temperature in tunnel is an important parameter in monitoring the daily operation process and unexpected combustion process. Previous studies are mainly focused on single fire or multiple equal fires in tunnel, while multiple unequal fires burning is common in real tunnel fires. Till now, the law of asymmetrical temperature distribution of multi-source below a ceiling is unknown. This paper aims to experimentally study the thermal performance of two unequal fire sources of propane in a naturally ventilated tunnel. A total of 90 experimental tests were conducted. The side lengths of two burners are fixed at 10 cm and 15 cm. The heat release rate (HRR) of each burner are changed with the HRRs ratio of 1–6. And the spacing between two sources along the longitudinal centerline of tunnel varied from 0–45 cm. Analysis shows that there is only one peak temperature with small spacings, while two peak temperatures appear with large spacings. Then the impingement point position and the maximum ceiling gas temperature of each burner are illustrated. The force analysis is adopted to explain the variation of impingement point position. A parameter α is innovatively introduced to characterize the promoting effect of spacing on maximum temperature at small spacings. Then a new normalized HRR is proposed to establish a unified model for the unequal maximum temperature rises below the ceiling of both sources, which indicates that the maximum temperature rise increases with the normalized HRR and then it maintains at 754 K. By introducing the plume radius, models for asymmetrical temperature decay profiles on both sides of two plumes below the ceiling are proposed, which shows that the temperature in the upstream of the small burner decays faster than that in the downstream of the large burner. The proposed models for maximum temperature and temperature decay profiles can be used to predict the ceiling gas temperatures of two unequal fires in tunnel.