Small Mode Research Articles

Manipulating the monomers supply of interfacial polymerization towards the ultrathin polyamide composite membrane for CO2 capture

Preparing polyamide (PA) composite membranes with high gas separation performance requires rational control for the interfacial polymerization (IP) process. In this study, the monomer supply of piperazine (PIP) and trimesoyl chloride (TMC) in the IP process was precisely manipulated to generate an ultrathin PA film on the polydimethylsiloxane (PDMS) gutter layer for CO2 separation. Concretely, the PIP supply was regulated from the homogeneous, slow, and excess mode to the inhomogeneous, fast, and small mode by constructing a sodium dodecyl sulfate (SDS) array at the phase interface; subsequently, the TMC supply was increased by elevating the TMC concentration. Therefore, the amine-to-acid chloride concentration ratio in the reaction zone was optimized and, as a consequence, the IP reaction rate was significantly increased. As a result, the thickness of the PA film was reduced from ∼92 nm to ∼37 nm through the optimization of SDS and TMC concentrations, and accordingly, the CO2 permeance was increased from 501 GPU to 1498 GPU under 0.1 MPa without sacrificing selectivity. Moreover, the membrane preparation efficiency was greatly improved with an IP reaction time of less than 30 s. The insights provided could promote the industrial application of interfacial polymerization in the scale-up preparation of high-performance CO2 separation membranes.

Optimizing the quality factor of InP nanobeam cavities using atomic layer deposition

Photonic crystal nanobeam cavities are valued for their small mode volume, CMOS compatibility, and high coupling efficiency-crucial features for various low-power photonic applications and quantum information processing. However, despite their potential, nanobeam cavities often suffer from low quality factors due to fabrication imperfections that create surface states and optical absorption. In this work, we demonstrate InP nanobeam cavities with up to 140% higher quality factors by applying a coating of Al2O3 via atomic layer deposition to terminate dangling bonds and reduce surface absorption. Additionally, changing the deposition thickness allows precise tuning of the cavity mode wavelength without compromising the quality factor. This Al2O3 atomic layer deposition approach holds great promise for optimizing nanobeam cavities that are well-suited for integration with a wide range of photonic applications.

Enhanced Visual Performance for In–Vehicle Reading Task Evaluated by Preferences, Emotions and Sustained Attention

The proliferation of electric and hybrid vehicles has made it possible for people to read and work in a stationary vehicle for extended periods. However, the current commonly used in–vehicle lighting design is still centered around driving and driving safety. Following recommendations from the literature, a neutral white color band (4000 K–5000 K) with 50–100 lx at the vehicle table area is favored. Whether this lighting environment can meet the needs to enhance the reading performance in a modern vehicle was investigated in this presented study. Therefore, in total, 12 lighting settings were designed based on combinations of four illuminance levels (50 lx, 100 lx, 150 lx and 200 lx) and three correlated color temperatures (3000 K, 4000 K and 5000 K); we recruited 19 subjects (12 females, 7 males) and let study participants evaluate each condition based on electronic and paper reading. Next, subjective preferences, positive and negative emotions, feeling of fatigue and sustained attention were tested. We found that higher illuminance and higher CCT (Correlated Color Temperature) can significantly improve the performance of in–vehicle readers in most aspects following Kruithof’s law (p < 0.05). Among them, we recommend the combination of 150 lx and 4000 K as the light parameters for in–vehicle reading as a new development guideline. In addition, we also discovered the inconsistency of people’s lighting preferences between in–vehicle spaces and conventional spaces. For indoor lighting, illuminance values up to 1000 lx are still favored. For an in–vehicle function, starting with 200 lx, the preference level and reading performance already declined. In comparison between electronic and paper reading, both were similarly evaluated. These results show that a neutral white light color should be chosen with a horizontal illuminance of maximal 150 lx for a reading light function independent of the reading device. Interdisciplinarily speaking, our findings can be applied in similar small spaces or transportation modes with gentle acceleration and deceleration such as small space hotel rooms, trains, airplanes or ships.

Detecting single nanoparticles using fiber-tip nanophotonics

Sensing nano-objects, from nanoparticles to molecules, has become a crucial need in environmental monitoring, medical diagnostics, and drug development. Detection of single particles and molecules is highly desirable, as it provides specific information on size, dynamics, and interactions. Current nanophotonic implementations rely on complex optical readout schemes, limiting their application in the field. Here we demonstrate a nanophotonic fiber-tip sensor with a compact sensor footprint and a simple readout scheme. We leverage advanced design methods to simultaneously achieve a small mode volume V m =0.74(λ/n)3, narrow linewidth Δλ=0.4nm, and a large modulation ΔR≈20% in reflection from the fiber. This unique combination of properties opens the way to sensing weak nanoscale perturbations in the vicinity of the fiber tip. In particular, we experimentally demonstrate the real-time detection of single 50 nm nanoparticles. This opens a route towards real-time sensing of single nanoparticles, and potentially single molecules, in environmental monitoring and diagnostics.

Enhancing thermal stability of Nd:GGG WGM microdisk lasers via silica integration

Abstract Whispering gallery mode (WGM) resonators, as an integral component of integrated photonics, have attracted considerable attention due to their high Q factor, small footprint, and small mode volume, making them widely applied as microlasers. In this work, Nd:GGG crystal was prepared into a Nd:GGG film with thickness of 1.8 μm through ion implantation-enhanced etching (IIEE) technique, and subsequently, the Nd:GGG film was partened by focused ion beam (FIB) technology to generate a microdisk with diameter of 20 μm. For high-power microcavity lasers, heat generation during laser operation was inevitable. We placed the microdisk on a silica holder and a silica wafer, respectively. The microdisk placed on the silica holder and silica wafer exhibited laser thresholds of 32 μW and 17 μW, respectively. Moreover, due to different heat dissipation conditions, the microdisk placed on the silica holder exhibited a mode shift of 0.13 nm/mW, while the microdisk placed on the silica wafer showed a more stable laser output state with a mode shift of 0.02626 nm/mW.

Ultra-high Q resonances based on zero group-velocity modes accompanied by bound states in the continuum in 2D photonic crystal slabs

Optical resonators made of 2D photonic crystal (PhC) slabs provide efficient ways to manipulate light at the nanoscale through small group-velocity modes with low radiation losses. The resonant modes in periodic photonic lattices are predominantly limited by nonleaky guided modes at the boundary of the Brillouin zone below the light cone. Here, we propose a mechanism for ultra-high Q resonators based on the bound states in the continuum (BICs) above the light cone that have zero-group velocity (ZGV) at an arbitrary Bloch wavevector. By means of the mode expansion method, the construction and evolution of avoided crossings and Friedrich-Wintgen BICs are theoretically investigated at the same time. By tuning geometric parameters of the PhC slab, the coalescence of eigenfrequencies for a pair of BIC and ZGV modes is achieved, indicating that the waveguide modes are confined longitudinally by small group-velocity propagation and transversely by BICs. Using this mechanism, we engineer ultra-high Q nanoscale resonators that can significantly suppress the radiative losses, despite the operating frequencies above the light cone and the momenta at the generic k point. Our work suggests that the designed devices possess potential applications in low-threshold lasers and enhanced nonlinear effects.

Low noise near-concentric optical cavity design.

Near-concentric cavities are excellent tools for enhancing an atom-light interaction as they combine a small mode volume with a large optical access for atom manipulation. However, they are sensitive to longitudinal and transverse misalignments. To address this sensitivity, we present a compact near-concentric optical cavity system with a residual cavity length variation δLC,rms = 0.36(2) Å. A key part of this system is a cage-like tensegrity mirror support structure that allows us to correct for longitudinal and transverse misalignments. The system is stable enough to allow the use of mirrors with a higher cavity finesse to enhance the atom-light coupling strength in cavity-QED applications.

Optimization of the reflection in the optical coupling between high numerical aperture fibers and photonic integrated circuits

The optical coupling in silicon Photonic Integrated Circuits (PICs) remains one of the main topics in the improvement of the performance of these devices. Highly demanding parameter specifications, such as loss, reflection, and bandwidth, drive the continuous search for optimization. The use of High Numerical Aperture Fibers (HNA fibers) to couple light in small diameter mode edge couplers, is one of the existing technologies that address the coupling challenge. We demonstrate, using Eigenmode Expansion (EME) and Transfer Matrix Method (TMM) simulations, that the Optical Return Loss (ORL) of this coupling approach can be made as low as −45 dB for both Transverse Electric (TE) and Transverse Magnetic (TM) polarizations, simultaneously. The results from our TMM model agree well with a commercial solver one and are faster (six orders of magnitude) and more computationally efficient. It is shown that the refractive index in the TMM should be corrected to compensate for the Gouy phase shift in the non-guided sections of the optical coupling. Additionally, the reflection pattern, as a function of the gap between the fiber and the PIC, provides a way to control the distance of the fiber to avoid packaging-related problems.

Assessment of molecular and metabolic traits of a newly isolated Spirulina platensis BERC15 in a low-cost cultivation alternative for its use as functional food

Commercial cultivation of Spirulina relies on expensive chemicals. This study aimed to optimize low-cost cultivation media for upscaling of the Spirulina cultivation for food applications. Here, low-cost nitrogen source resulted in 3 gL−1 of biomass while outdoor pilot-scale cultivation produced 6.5–9.6 g m−2day−1 of biomass. The growth media prepared in underground water (UGW) using commercial-grade chemicals (UGW + CC) was found to be the most suitable low-cost alternative media which produced 2.3 ± 0.28 gL−1 of biomass containing 56 ± 1.22 % proteins, 22 ± 1.88 % carbohydrates, and 12 ± 2.52 % lipids. GC–MS-based metabolomic analysis implied that only four metabolites were either down or upregulated out of 50 detected metabolites. The Hep G2 cancer cell line-based study showed 15-fold higher free radical scavenging activity in UGW + CC grown cells compared to control. This study provides a basis for process optimization towards commercial-scale cultivation of Spirulina using small and medium enterprise mode.

Mode-coupled perturbation growth on the interfaces of cylindrical implosion: A comparison between theory and experiment.

We present a mode-coupled weakly nonlinear model for the evolution of perturbations on cylindrical multilayered shells in a decelerating implosion. We show that nonlinear mode-mode interactions among large wave-number fundamental modes are able to induce the growth of small wave number harmonic modes, i.e., forming inverse cascade channels in the wave-number space. When uniform compression and interfacial coupling are taken into consideration, the amplitude of some perturbation modes exhibits an oscillatory growth pattern, which is beyond the intuition that perturbation amplitudes usually have a fast growth tendency in an implosion dominated by the Bell-Plesset effect. Our model accounts well for the previous experiments of Hsing etal. [Hsing et al., Phys. Rev. Lett. 78, 3876 (1997)0031-900710.1103/PhysRevLett.78.3876 and Phys. Plasmas 4, 1832 (1997)1070-664X10.1063/1.872326], which is among the few experiments of multimode multiinterface perturbation development in a cylindrical implosion. In particular, we find that the inverse cascade of modes is the origin of the excitation and growth of the wave number k=2 harmonic mode on the inner interface. The observed decrease of the fundamental modes on the inner interface is mainly attributed to the decreasing period of the oscillatory growth process. These results may afford further insight into the distortion of hot spots in inertial confined fusion implosion near the final stage, and also help to design multimode perturbation experiments in converging geometry in the coming future.

Asymmetry of the Distribution of Vertical Velocities of the Extratropical Atmosphere in Theory, Models, and Reanalysis

Abstract The vertical velocity distribution in the atmosphere is asymmetric with stronger upward than downward motion. This asymmetry is important for the distribution of precipitation and its extremes and for an effective static stability that has been used to represent the effects of latent heating on extratropical eddies. Idealized GCM simulations show that the asymmetry increases as the climate warms, but current moist dynamical theories based around small-amplitude modes greatly overestimate the increase in asymmetry with warming found in the simulations. Here, we first analyze the changes in asymmetry with warming using numerical inversions of a moist quasigeostrophic omega equation applied to output from the idealized GCM. The inversions show that increases in the asymmetry with warming in the GCM simulations are primarily related to decreases in moist static stability on the left-hand side of the moist omega equation, whereas the dynamical forcing on the right-hand side of the omega equation is unskewed and contributes little to the asymmetry of the vertical velocity distribution. By contrast, increases in asymmetry with warming for small-amplitude modes are related to changes in both moist static stability and dynamical forcing leading to enhanced asymmetry in warm climates. We distill these insights into a toy model of the moist omega equation that is solved for a given moist static stability and wavenumber of the dynamical forcing. In comparison to modal theory, the toy model better reproduces the slow increase of the asymmetry with climate warming in the idealized GCM simulations and over the seasonal cycle from winter to summer in reanalysis. Significance Statement Upward velocities are stronger than downward velocities in the atmosphere, and this asymmetry is important for the distribution of precipitation because precipitation is linked to upward motion. An important and open question is what sets this asymmetry and how much it increases as the climate warms. Past work has shown that current theories greatly overestimate the increase in asymmetry with warming in idealized simulations. In this work, we develop a more complete theory and show that it is able to better reproduce the slow increase of the asymmetry with warming that is found over the seasonal cycle from winter to summer and in idealized simulations of warming climates.

Visible–Telecom Photon Pair Source Based on a Photonic-Crystal Fiber under Continuous-Wave Pumping

The generation of interband photon pairs with wavelengths near 0.5 and 1.6 μm in a photonic-crystal fiber under low-power cw optical pumping by a diode laser with a central wavelength of 0.8 μm has been experimentally demonstrated. It has been found that the generation rate of entangled photons under cw pumping is comparable with values obtained with pulsed pumping by a femtosecond Ti:sapphire laser if the average cw pump power is an order of magnitude higher than the average pulsed pump power. The reached rates of photon generation are ensured by the used photonic-crystal fiber with a small effective mode area and a special dispersion profile. The reached low noise in the output signal is ensured by the separation of carrier frequencies of generated photons into different spectral bands.

Indefinite metacavities coupled to a mirror: bound states in the continuum with anomalous resonance scaling

Indefinite metacavities (IMCs) made of hyperbolic metamaterials show great advantages in terms of extremely small mode volume due to large wave vectors endowed by the unique hyperbolic dispersion. However, quality (Q) factors of IMCs are limited by Ohmic loss of metals and radiative loss of leaked waves. Despite the fact that Ohmic loss of metals is inevitable in IMCs, the radiative loss can be further suppressed by leakage engineering. Here we propose a mirror coupled IMC structure which is able to operate at Fabry–Pérot bound states in the continuum (BICs) while the hyperbolic nature of IMCs is retained. At the BIC point, the radiative loss of magnetic dipolar cavity modes in IMCs is completely absent, resulting in a considerably increased Q factor (>90). Deviating from the BIC point, perfect absorption bands (>0.99) along with a strong near-field intensity enhancement (>1.8×104) appear when the condition of critical coupling is almost fulfilled. The proposed BICs are robust to the geometry and material composition of IMCs and anomalous scaling law of resonance is verified during the tuning of optical responses. We also demonstrate that the Purcell effect of the structure can be significantly improved under BIC and quasi-BIC regimes due to the further enhanced Q factor to mode volume ratio. Our results provide a new train of thought to design ultra-small optical nanocavities that may find many applications benefitting from strong light–matter interactions.

Low-Threshold Anti-Stokes Raman Microlaser on Thin-Film Lithium Niobate Chip.

Raman microlasers form on-chip versatile light sources by optical pumping, enabling numerical applications ranging from telecommunications to biological detection. Stimulated Raman scattering (SRS) lasing has been demonstrated in optical microresonators, leveraging high Q factors and small mode volume to generate downconverted photons based on the interaction of light with the Stokes vibrational mode. Unlike redshifted SRS, stimulated anti-Stokes Raman scattering (SARS) further involves the interplay between the pump photon and the SRS photon to generate an upconverted photon, depending on a highly efficient SRS signal as an essential prerequisite. Therefore, achieving SARS in microresonators is challenging due to the low lasing efficiencies of integrated Raman lasers caused by intrinsically low Raman gain. In this work, high-Q whispering gallery microresonators were fabricated by femtosecond laser photolithography assisted chemo-mechanical etching on thin-film lithium niobate (TFLN), which is a strong Raman-gain photonic platform. The high Q factor reached 4.42 × 106, which dramatically increased the circulating light intensity within a small volume. And a strong Stokes vibrational frequency of 264 cm-1 of lithium niobate was selectively excited, leading to a highly efficient SRS lasing signal with a conversion efficiency of 40.6%. And the threshold for SRS was only 0.33 mW, which is about half the best record previously reported on a TFLN platform. The combination of high Q factors, a small cavity size of 120 μm, and the excitation of a strong Raman mode allowed the formation of SARS lasing with only a 0.46 mW pump threshold.

High-resolution single-pixel imaging based on a probe of single-mode fiber and hybrid multimode fiber

In single-pixel imaging, the combination of random speckles generated by the multimode fiber (MMF) as projection patterns and the compressed sensing theory is beneficial for improving imaging performance and expanding application scenarios. However, the image reconstruction quality using the MMF is usually unsatisfactory, which is helpless for retrieving objects with detailed information or multi-resolution objects. The reason lies in the limited number and compromised spatial resolution of low-correlated speckle patterns provided by the MMF in practical circumstances like long operating time or bending disturbances. Here, we propose a novel concept of hybrid multimode fibers (HMMF) for single-pixel imaging resolution enhancement. Based on the bending insensitivity property of single-mode fiber (SMF) and the compatibility property of small bending radius and high mode density of HMMF, the wavelength-modulated SMF-HMMF probe is designed to significantly improve the number and spatial resolution of speckle patterns while ensuring the robustness of the imaging system. The experimental results demonstrate that the spatial resolution of the speckle patterns has been improved by approximately 3 times (from 20.35 pixels to 7.24 pixels) compared to the non-HMMF probe. The correlation of the speckle patterns holds as low as about 0.1, even when the tuning wavelength interval is reduced to 5 pm. The maximum deviation of the repeatability of the speckle pattern was 0.044 for the 120-min interval tested, and the consistent output of the speckle pattern under various bending configurations demonstrates the strong robustness of the imaging system. High-quality imaging of multi-resolution target objects has been achieved even at a remarkably low sampling rate (SR) of 5 %. This study has the potential to expand the application of single-pixel imaging systems in flexible and long-distance detection imaging scenarios.

Effect of hyper-resistivity on ballooning modes with resonant magnetic perturbations

The impact of hyper-resistivity on non-ideal ballooning modes (BMs) is studied in the presence of resonant magnetic perturbation (RMP) through considering the hyper-resistivity, resistivity and diamagnetic effect in the BM model with an equilibrium distorted by RMP, which is stable for ideal BMs. Similar to the resistivity, the hyper-resistivity is also destabilizing for the BMs, but RMPs make the mode spectrum of the BMs destabilized by the hyper-resistivity move towards the low toroidal mode number side on the flux surface with a safety factor slightly larger than the RMP resonance safety factor, where the growth rates of the BMs destabilized by the resistivity decrease due to RMP. When both the hyper-resistivity and the resistivity are considered, there is a sort of competitive relationship between them in determining the properties of BMs. If either of the hyper-resistivity term and the resistivity term is much larger than the other one, the instability of BMs is mainly determined by the larger one, and the effect of the smaller one is masked. The destabilizing mechanisms of the hyper-resistivity and the resistivity on BMs are similar, namely, the diffusion and dissipation of current and magnetic field weaken the stabilizing effect of magnetic field line bending. The research results may be important for understanding the enhancement of plasma transport and the mechanism of small edge localized mode (ELM) during ELM control with RMP.

Preparation and thermal properties of zeolite/MgSO4 composite sorption material for heat storage

Thermochemical sorption heat storage based on salt hydrates offers the potential advantages such as high energy density, negligible heat loss, small volume change and flexible working modes. Magnesium sulphate (MgSO4) is a high energy density hydrated salt available for the thermochemical sorption heat storage. In this work, different types of zeolites (including 3A, 5A and 13X zeolites) have been selected as mass-transfer-enhancing and structural stabilizing materials, and a series of zeolite/MgSO4 composites have been fabricated. To investigate the thermal energy storage performance of zeolite/MgSO4 composites, the properties of the composites, such as micro-morphology, pore structure, chemical composition and sorption-desorption behavior, have been characterized and analyzed. Results indicated that the mass transfer performance of the composite materials is significantly better than that of the pure zeolites. As the mass fraction of MgSO4 in the composite sorbents increases, the specific surface area and porosity of the composite sorbent decreases, and the sorption performance has been enhanced. Compared with 3A zeolite-based and 5A zeolite-based composites, 13X zeolite/MgSO4 composite materials show the best heat storage performance. At the condition of 25 °C and 60% RH, the 13XM20 has the highest sorption capacity of 0.21 g/g, which is 24% higher than that of pure zeolite 13X. Accordingly, the maximum heat storage density is 438.4 kJ/kg, which exhibits the superior heat storage performance among of the hydrated salt sorbents. The potential of 13X zeolite/MgSO4 as sorption heat storage material in efficient utilization of solar heat and low-grade industrial waste heat has been revealed.

Silicon photonics-based high-energy passively Q-switched laser

Chip-scale, high-energy optical pulse generation is becoming increasingly important as integrated optics expands into space and medical applications where miniaturization is needed. Q-switching of the laser cavity was historically the first technique to generate high-energy pulses, and typically such systems are in the realm of large bench-top solid-state lasers and fibre lasers, especially in the long wavelength range >1.8 µm, thanks to their large energy storage capacity. However, in integrated photonics, the very property of tight mode confinement that enables a small form factor becomes an impediment to high-energy applications owing to small optical mode cross-sections. Here we demonstrate a high-energy silicon photonics-based passively Q-switched laser with a compact footprint using a rare-earth gain-based large-mode-area waveguide. We demonstrate high on-chip output pulse energies of >150 nJ and 250 ns pulse duration in a single transverse fundamental mode in the retina-safe spectral region (1.9 µm), with a slope efficiency of ~40% in a footprint of ~9 mm2. The high-energy pulse generation demonstrated in this work is comparable to or in many cases exceeds that of Q-switched fibre lasers. This bodes well for field applications in medicine and space.

Large mode volume microresonator with a gradient refractive index

Whispering gallery mode microcavities have been widely explored because of high Q factors and small mode volumes. Although small mode volumes are beneficial in sensors and nonlinear applications, recent studies suggest that large mode volumes are required for noise reduction in advanced applications. To enhance the mode volume, one possible method is to utilize the material inside the cavity. Herein, a radial gradient refractive index (GRIN) microresonator has an internal potential well and allows the mode field to shift inward. The GRIN resonator is formed by changing the radial refractive index n(r), and can be produced by the mature ion-exchange process. By adjusting the process parameters, the internal potential well can be widened to generate large mode volumes. However, it takes a lot of time to optimize the process parameters of wide potential well resonators using commercial software. Therefore, in this paper, we propose a fast algorithm for radial GRIN microcavities. Using this algorithm, we optimize the diffusion and annealing times of the GRIN resonator to increase the mode volume to more than four times that of the WGM microcavity. COMSOL simulations also support the conclusion with no additional loss in the Q factor.

Brillouin lasing in microspheres coupled with silicon subwavelength grating waveguides

Brillouin lasing has been widely applied to microwave oscillators, optical gyroscopes, optical sensors, and other fields owing to its strong and flexible dynamics. Microspheres with ultrahigh quality factors and small mode volume are very suitable for generating Brillouin lasing, but it is difficult to integrate them on a chip. Here, we utilize subwavelength grating waveguide as a photonic coupler to connect the silica microsphere with a silicon chip and realize on-chip backward Brillouin lasing. It is experimentally indicated that when the on-chip pump power reaches 24.8 mW, the backward Brillouin lasing with an on-chip slope efficiency of 5% will be excited. Our method makes it easier to realize on-chip Brillouin acousto-optic interaction and greatly expands the application range of microspheres.