Small Gas Research Articles

Coordinated intelligent control strategy and power management for marine gas turbine under pulsed load using optimized neural network

Faced with the challenges of potentially irreversible damage due to instantaneous large pulsed power loads onboard, considering all-electric ship's small power grid capacity and complex gas turbine system, this study proposes a coordinated intelligent control strategy. It utilizes multi-objective optimization neural network to control a validated 20MW ship three-shaft gas turbine, ensuring global optimization tailored to pulsed load variations. Research findings reveal that the gas turbine efficiency at the design point is 32.3%, with a steady-state error within 2.8% and a maximum steady time error of 3.4 seconds, demonstrating acceptable accuracy. Under slope-type pulsed load of 20MW change in 5s, the proposed control strategy effectively manages speed while utilizing the energy storage system to smooth load inputs. It is worth noting that, increasing the fuel flow rate to 1.28 kg/s and inlet guide vane to 5.8 degrees reduces overshoot by 0.7% and rotor steady time by 15.4 seconds. Under transient-type pulsed load of 10MW back and forth change in 5s, the coordinated inlet guide vane control strategy mitigates surge margin and exhaust temperature issues. Adjusting the fuel flow to 1.17 kg/s and inlet guide vane to 9.96 degrees enables the gas turbine to operate within safety boundaries, reducing rotor speed overshoot by 0.4% and steady time by 6.1 seconds. Importantly, the optimized control strategy without energy storage system provides faster and safer dynamic regulation and power transmission for ship acceleration processes under radar load. However, considering only the coordinated strategy of the fuel sub-control loop, it is advisable to avoid compressor surge and over-temperature protection for electromagnetic ejection load scenarios. The research results will lay a valuable technical foundation for the intelligent control and smooth power transfer of the all-electric ship gas turbine power system with pulse loads in the extreme missions of ships in the future.

Core mechanism for the stability preparation of lithium slag-based SOD zeolite: Evolution of trans-crystallization nucleation/growth kinetics of crystals

SOD nano-zeolite has been widely applied in the separation of small gas molecules since these advantages comprise a high-density framework and favorable acid/alkali resistance. Moreover, the bottleneck for the lithium sector can be ameliorated by industrializing the manufacture of SOD zeolite (SLS) from the hazardous waste lithium slag (LS). However, the stability in industrial production is restricted owing to the ambiguous nature of the lattice nucleation/transformation mechanism. Herein, it was discovered that the highest relative crystallinity (98.8 %) of SLS with a layered spherical structure could be achieved under the crystallization condition of heating at 95 °C for 8 h. The nucleation and growth mechanisms of SLS crystals demonstrated a three-dimensional crystal growth pattern characterized by sporadic and transient nucleation, which is essentially consistent with that of crystallization kinetics. Specifically, the activation energies of the induction, transformation and crystallization phases were 41.33, 27.99 and 46.99 kJ·mol−1, respectively, implying that the directional induction of the transition phase is crucial for obtaining SLS with high crystallinity. Two nucleation processes can also be observed in the transformation stage, involving homogeneous nucleation and polymorphic transformation. Our study explored the crystallization and assembly mechanism of SLS crystals, providing a well-defined concept for the regulation of stability preparation.

Carbon‐ and Nitrogen‐Based Complexes as Photocatalysts for Prebiotic and Oxygen Chemistry during Earth Evolution

AbstractSunlight has long served as primary energy source on our planet, shaping the behavior of living organisms. Extensive research has been dedicated to unraveling the evolutionary pathways involved. When the formation of Earth atmosphere, it primarily consisted of small gas molecules, which are considered crucial for the emergence of life. Recent demonstrations have shown that these molecules can also be transformed into semiconductors, with the potential to harness solar energy and catalyze chemical reactions as photocatalysts. Building upon this research, this minireview focuses on the potential revolutionary impact of photocatalysis on Earth. Initially, it examines key reactions, such as the formation of prebiotic molecules and the oxygen evolution reaction via water oxidation. Additionally, various C−N complexes in photocatalysts are explored, showcasing their roles in catalyzing chemical reactions. The conclusion and outlook provide a potential pathway for the evolution of Earth, shedding light on the significance of metal‐free photocatalysts in development of Earth.

Genetic mechanism and exploration progress of global deep alkane gases and small molecule gases (H2, He)

From the perspective of global oil and gas exploration trends, deep to ultra-deep gas exploration has emerged as a focal point in the past decade, shaping the future landscape of fossil energy exploration. Specifically, China has undertaken oil and gas exploration ventures reaching depths of 10,000 m, drawing significant attention to the genesis of gas accumulation at such extreme depths. An analysis of crucial geological factors including basin formation, hydrocarbon generation, storage and accumulation reveals that kerogen cracking gas, crude oil cracking gas, and coal cracking gas served as vital gas sources for ultra-deep paraffin gas in highly over-mature oil-bearing basins, establishing a model for the formation, evolution, and accumulation of natural gas. With the continuous expansion of hydrocarbon genesis theory and the increasing global demand for clean energy, hydrogen, as an important link between inorganic and organic hydrocarbon generation theory, and as a promising clean energy, has gradually aroused extensive attention in the academic community. The genetic types of natural hydrogen are mainly generated from inorganic genetic mechanisms, including earth degassing, water-rock interaction, and water radiolysis. The lithology of the reservoir and the sealing property of the cap layer control the accumulation of natural hydrogen, with the salt-rock cap layer beneficial to the large-scale preservation of natural hydrogen reservoir. Helium, as a constituent resource of natural gas, represents the primary target for exploration among deep small molecule gases. Helium within natural gas reservoirs can be categorized into atmospheric, crust-source and mantle-source varieties based on their origins. Helium source rocks exhibit significant disparities in helium generation capacity attributed to variations in rock types, mineral compositions, and ages, resulting in a relatively complex mechanism governing helium reservoir release, migration and accumulation. Typically, helium-rich gas reservoirs lack optimal cap sealing performance, as excessive sealing inhibits the formation of pressure relief conduits, thereby impeding the supply of helium-rich fluid to the reservoir. Through an analysis of genetic types, formation and evolution models, and reservoir preservation mechanisms pertinent to deep alkane gases and small molecule gases, it is revealed that the large-scale pool-forming geologic units and giant hydrocarbon enrichment zones in ultra-deep strata are key and promising prospects for delivering successive discoveries, and the energy significance and development trend of natural hydrogen and helium in the future were pointed out, in order to provide references for promoting the transition from high carbon to low carbon and carbon-free energy in the energy field.

Unique seismic and eruption precursors to the 1996 and ongoing magmatic eruptions of Popocatépetl: Coupled and fluidized bed events

We describe three unique types of seismicity at Popocatépetl volcano that accompanied the initial vent-clearing eruptive activity in December 1994 through the eruption of the first two domes in 1996. We identify and describe two types of coupled events, 1) spasmodic burst coupled events, a burst of volcano tectonic (VT) events coupled with a large eruptive explosion (21 December 1994 and 5 March 1996), and 2) explosion-couplet coupled events, a pair of events with a deeper first event and whose second event correlates with a small gas emission or explosion. Explosion-couplets occurred with the onset of magmatic ash dominated eruptions and their properties are very useful for forecasting magmatic eruptions at Popocatépetl volcano. Measurable quantities including the time between the first and second phase, daily numbers of events, and the amplitude ratio between the second and first phase systematically changed as the first two domes approached the surface between March and June 1996. Interevent times decreased from many tens of seconds to a few seconds, while amplitude ratios increased from about 2 to 10 or more. Event numbers increased prior to and during initial dome extrusion. These changes were used to forecast the eruption of the first two domes. We also report on another unusual type of low frequency seismicity that accompanied emissions called fluidized bed events. Fluidized bed events occurred following the initial eruption on 21 December 1994, beginning mid-January 1995, when SO2 emissions were initially elevated, and the conduit was open. Fluidized bed events began to wane in late March through the end of May 1995 as did SO2 emissions. Consistent gas, visual and seismic observations by Centro Nacional de Prevención de Desastres (CENAPRED) enabled the direct correlation of the gas, magma, and seismic phenomena.

Optimization of Velocity String Drainage and Gas Recovery Process for Sour Gas Wells in Jingbian Gas Field

Abstract In view of the gradual attenuation of gas well energy during the development of Jingbian gas field, the liquid carrying effect of some gas wells with small gas production becomes worse, the drainage effect of 60 % gas wells is not ideal, and the H2S content of the lower paleo-sulfur gas wells is high, the salinity is high, there is a certain corrosion, and most of the drainage measures cannot be implemented. The optimization of sulfur-resistant velocity string was carried out from the aspects of velocity string size and pipe material, and the appropriate pipe diameter and pipe material were selected. A new type of broken disc speed string plug was developed, which successfully solved the problem that the existing plug could not be broken or returned after construction. The field application results show that compared with the 27/8 “ string, the liquid carrying flow rate is reduced by 82 %. After 2.5 years of service, the anti-corrosion performance of the pipe is good. The cumulative increase of the well is 445.4 thousand cubic meters, and the effective rate of the measures is 97.45 %. The stable and continuous liquid carrying of the gas well is realized, which has a good application effect. It has certain reference significance for the implementation of the drainage gas recovery technology of the velocity string in the lower ancient sulfur gas well.

A Comparative Study of Sustainable Energy Brayton Cycles in the Oil and Gas Industry. Part 1: Performance

Brayton cycles are open gas turbine cycles extensively used in civil aviation and the petrochemical industry because of their advantageous volume and weight characteristics. With the bulk of engine emissions associated, it is necessary to promote their environmentally-friendliness, including sound technical performance regularly. This research considers high bypass-low specific power plants in aviation and aero-derivative gas turbines combined-heat-and-power generation in the petrochemical industry. The investigation encompasses the comparative assessment of simple and advanced gas turbine cycle options including the component behaviour of the systems. This comprises the performance module. The research has contributed to understanding the technical performances of simple and advanced cycle helicopter engines, and aero-derivative industrial gas turbine cycles at design and off-design conditions. The simple cycles were modified for better fuel burn and thermal efficiency by using some additional components to form the advanced cycles. The helicopter engine investigated was converted to a small-scale aero-derivative industrial engine. Modeling the combined-heat-and-power performance of the small, medium, and large-scale aero-derivative industrial gas turbines was also implemented. The contribution also includes understanding the technical performances of both simple and advanced aero-derivative gas turbines combined heat-and-power at design and off-design A case study underlies the development and deployment of this model. The novelty is the conception of a tool for predicting the most preferred simple and advanced cycle aero-derivative engines combined heat-and-power generation in the petrochemical industry and the derivation of simple and advanced cycle small-scale aero-derivative industrial gas turbines from helicopter engines.

Characteristics of Deterministic and Stochastic Unsteadiness of Trailing Edge Cutback Film Cooling Flows

Abstract Trailing edge cutback film cooling flows are ubiquitous in small and medium gas turbines, but they are difficult to predict accurately due to the inherent deterministic and stochastic unsteadiness that controls the effectiveness of the cooling system. To help develop accurate closure models for such flows, the characteristics of both types of unsteadiness and their effects on the mean flows are analyzed in this research. Zonal detached eddy simulation (ZDES) is performed on a trailing edge cutback flow model, and the numerical results are validated against the measured data. Then, by using spectral proper orthogonal decomposition (SPOD) reconstruction, the original dataset is segregated into deterministic and stochastic unsteadiness. The characteristics of the stress tensor and the heat flux of each type of unsteadiness are analyzed in detail, and notable differences between the two unsteadiness are identified in terms of the stress tensor anisotropy and distribution of unsteady kinetic energy and heat flux. By propagating the unsteadiness through the Reynolds-averaged Navier–Stokes (RANS) equations, the effect of different unsteadiness on the mean flow prediction is quantified. An accurate prediction of the total stress tensor reduces the prediction error in the velocity field by 79% and cooling effectiveness by 55%. An accurate prediction of the total heat flux vector reduces the prediction error in cooling effectiveness further by 37%. These findings provide valuable knowledge for the physical understanding, turbulence modeling, and aerothermal design of cutback trailing edge flows.

Numerical Simulation Analysis of Force on 50m³ Small Liquefied Gas Spherical Tank

Numerical Simulation Analysis of Force on 50m³ Small Liquefied Gas Spherical Tank

Study on the cracking process of epoxy resin under oxygen and water atmosphere based on ReaxFF force field

Amino-cured epoxy resins are widely used in the electrical and electronic industry for their excellent properties. To investigate the mechanism of the effect of O2 and H2O on the pyrolysis behavior of epoxy resin, in this paper, the cross-linked structure of bisphenol A type epoxy resin cured by adducts of diethylenetriamine and butyl glycidyl ether is modeled based on the ReaxFF force field, and the thermal decomposition processes at different temperatures and gas atmospheres were simulated and the pathways of the small molecule products were clarified. The results show that epoxy resin will produce small molecule gas products, such as H2, CO, H2O, OH, CH2O, and free radicals, in the process of pyrolysis; the presence of amino groups also generates nitrogen-containing radicals, such as CN, CH2N, and C2H4N; as the reaction temperature increases, the rate of pyrolysis reaction will be accelerated. The same temperature in oxygen and water atmospheres can accelerate the breakage of epoxy resin main chain by promoting the breakage of carbon and oxygen bonds and, at the same time, promote the generation of small molecule gases, such as H2 and CO.

Gas hydrate technological applications: From energy recovery to carbon capture and storage

Hydrates are crystalline structures that trap small gas molecules inside hydrogen-bonded water cages. These structures form at high pressure and low temperature. In recent years, there has been a growing interest in gas hydrates for technological applications, specifically in energy recovery, as well as carbon dioxide capture and storage. In the CO2/CH4 exchange using gas hydrates, researchers have reported a large amount of natural gas trapped in the form of gas hydrates under the ocean seafloor and permafrost regions. This large amount of natural gas trapped inside hydrate cages in oceanic and permafrost deposits has driven interest in the energy sector to investigate the possibility of safely harvesting gas hydrates as one of energy resources. However, there are still unanswered fundamental questions including the mechanism of natural gas recovery from gas hydrates. Another gas hydrate-based technology that has a growing interest is the use of gas hydrates for separation including carbon dioxide capture and storage. Carbon dioxide molecules have been shown to be preferentially trapped in the hydrate phase, demonstrating the possibility of the usage for carbon capture technology. Similarly, there are still underlying concerns of these applications, such as thermodynamics and stability of gas hydrates in porous materials, and the crystallization kinetics and mechanism of hydrate formation. This paper provides an overview of laboratory investigations conducted to understand the mechanism and evaluate the feasibility of energy recovery as well as discussion on recent advances in laboratory investigations on gas hydrate-based technology.

The effect of adsorbent shaping on the equilibrium and kinetic CO2 adsorption properties of ZIF-8

To be used at scale, adsorbents must be shaped into macroscopic objects, e.g. pellets, granules, and monoliths. Shaping may involve various processing steps and additives that collectively contribute to the final equilibrium and kinetic sorption properties of the adsorbent. Understanding the fundamental links between these processing steps and the resulting sorption performance is needed to rationalise the design of shaped adsorbents. Our study aims to advance the state of knowledge in this area. By focusing on ZIF-8, a prototypical metal organic framework (MOF), and CO2, a common small gas adsorbate, we compared a commercial binderless ZIF-8 extrudate and two purpose-made ZIF-8 pellets shaped with a blend of binders. We used analytical, spectroscopic, and imaging techniques to characterise the samples’ chemical, textural, and morphological properties. In addition, we collected equilibrium and kinetic CO2 adsorption data at 283, 293, and 303 K and up to 1 bar. The binderless ZIF-8 extrudate exhibited a homogeneous structure with BET area, micro- and meso-porosity only slightly reduced compared to ZIF-8 powder. The ZIF-8 pellets also maintained the overall BET area of the ZIF-8 powder, but displayed enhanced macroporosity and skeletal density as well as reduced microporosity – features that likely result from the pressure-induced strains of pelletisation. The extrudates are much less mechanically robust than the pellets. All samples displayed CO2 adsorption capacity in line with the CO2 uptake of their respective components. The CO2 kinetics measurements reveal clear distinctions between binderless ZIF-8 extrudate and ZIF-8 pellets, the latter indicating a behaviour associated with the additional presence of macropores. Our study presents quantifiable evidence for the effect of adsorbent shaping on gas adsorption equilibria and kinetics, providing a valuable resource for preliminary process design.

Experimental and Numerical Simulation Research on Different Shapes of Flame-Stabilizing Baffles in the Furnace

The use of fully premixed combustion in small gas boilers can improve denitrification efficiency. On the basis of fully premixed combustion, adding flame stabilizers inside the boiler can further reduce production of oxides of nitrogen. Four types of flame-stabilizing baffles were added at a certain position inside the furnace after the fully premixed burner. Experiments were conducted separately on the Noporous baffle, and numerical calculations were performed for 36 operating conditions of the four baffles. The experimental results and numerical calculations indicate that under experimental conditions, NOx emissions were all below 40 mg/m3, and the net heat efficiency of the boiler was above 80%. Under a maximum firing rate, CO emissions are below 20 ppm, and the minimum error between the calculated and experimental values is 2.2%. The calculation error of CO emissions under various working conditions does not exceed 6.8%, indicating that the impact of different-shaped baffles on CO emissions is relatively small. When installing a Nonporous baffle, the error between the experimental and calculated exhaust temperature values under minimum firing rates is 6.6%, the error between the calculated and measured values under middle firing conditions is 2.9%, and the error between the calculated and measured values under maximum firing rate conditions is 3.0%. Among the four different partition conditions, the exhaust temperature of the Nonporous baffle is the lowest. Under the same excess air coefficient, the pressure in the furnace for the middle and maximum firing rate is higher than that of the minimum firing rate, and the experimental values are in good agreement with the calculated values. When installing the Strip baffle, the calculated CO2 emission is the lowest. The experimental results show that the NOx in the flue gas inside the furnace is mainly NO, and the NO content exceeds 75%, reaching a maximum of 85%. The experimental results show that the minimum NOx emission value is 26.9 mg/m3. The error between the measured and calculated NOx values when installing a Nonporous baffle is 20.4%. All of the above indicate that installing a flame-stabilizing baffle at an appropriate position in the furnace can further reduce NOx emissions, and the optimization amplitude is related to the shape of the baffle.

Visual detection of aldehyde gases using a silver-loaded paper-based colorimetric sensor array

The small molecule aldehydes are volatile organic compounds (VOCs), possessing cytotoxicity and carcinogenicity. Long-term exposure can pose a serious threat to human health. Based on an in-situ reduction colorimetric method to generate silver nanoparticles and induce colorimetric response, we proposed a silver-loaded paper-based colorimetric sensor array for visually detecting and differentiating five relatively common trace small molecule aldehyde gases. The silver ions are immobilized onto a porous filter paper and stabilized by complexing agents of branched polyethyleneimine, ethylenediamine, and 1,6-diaminohexane, respectively. The as-fabricated sensor array expresses remarkable stability and capacity to resist humidity. The qualitative analysis reveals that the sensor array has excellent selectivity for aldehyde gases and displays remarkable anti-interference ability. The quantitative analysis indicates that the sensor array exhibits superior sensitivity for five aldehyde gases, with limits of detection (LODs) of 9.0 ppb for formaldehyde (FA), 3.1 ppm for acetaldehyde (AA), 3.5 ppm for propionaldehyde (PA), 23.8 ppb for glutaric dialdehyde (GD), and 71.5 ppb for hydroxy formaldehyde (HF), respectively. Importantly, these LODs are all comfortably below their respective permissible exposure limits. A unique colorimetric response fingerprint is observed for each analyte. Standard chemometric methods illustrate that the sensor array has excellent clustering capability for these aldehyde gases. Additionally, the sensor array's response is irreversible and possesses outstanding performance for cumulative monitoring. This colorimetric sensor array based on silver ions reduced to silver nanoparticles offers a novel detection method for the continuous, ultrasensitive, and visual detection of trace airborne pollutants.

Gas tightness around salt cavern gas storage in bedded salt formations

Underground salt cavern storage has become the preferred medium for storing gas energy and strategic substances. Salt caverns are suitable for storing small molecular gases due to the low porosity and permeability of salt rocks. This paper comprehensively analyzes the physical properties of four gases - hydrogen, helium, methane, and carbon dioxide - under subsurface temperature and pressure conditions. It categorizes the flow regimes of these gases in salt rocks under geological pressure conditions based on the Knudsen number. In a typical 1000 m salt cavern, the predominant permeation flow regime of four gases in the surrounding rock is Klinkenberg flow, with helium potentially undergoing transitional flow at low operation pressures. A 3D numerical model is established for an actual salt cavern to compare the permeation and leakage characteristics of these gases within salt rock formations. Results indicate that, under identical operation conditions, the permeation range of the gases decreases in the following order: hydrogen > methane > helium > carbon dioxide. Under the cyclic operation pressures, the cumulative leakage amount of hydrogen, helium, and methane increases over time, while that of carbon dioxide initially rises and then decreases. This behavior is attributed to the fact that the reverse-permeation rate of carbon dioxide at low pressures exceeds its permeation rate at high pressures. Over 30 years cyclic operation, the leakage ratios of the gases are as follows: hydrogen (13.29 %), methane (9.34 %), helium (7.47 %), and carbon dioxide (0.93 %), with hydrogen exhibiting the highest and carbon dioxide the lowest leakage ratios. Larger permeability results in a larger permeation range, while larger porosity leads to a smaller permeation range. When the permeability of salt layer is greater than 1e-20 m2, the permeation range of hydrogen significantly increases. Gas leakage ratios increase with permeability nonlinearly and increase with porosity linearly. The impact of salt layer permeability on leakage ratios is greater than that of porosity. This study provides crucial guidance for the selection of geological formations for storing hydrogen, helium, methane, and carbon dioxide in salt caverns, as well as the investigation of gas permeation characteristics in salt layers.

Single-Layer Graphene Incorporation in PEMFCs for Enhancing Membrane Durability and Its Impact on Catalyst Layer Properties

In the realm of heavy-duty vehicle (HDV) applications, the primary technological hurdle facing Proton Exchange Membrane Fuel Cells (PEMFCs) is durability. HDVs necessitate an exceptional lifespan of 1 million miles, 6.5 times longer than their light-duty vehicle (LDV) counterparts1. Two pivotal components, the polymer electrolyte membrane and the catalyst layer, have been identified as crucial for achieving durability.Chemical degradation of perfluorinated polymer electrolyte membranes, e.g., Nafion, is attributed to the small but finite H2 and O2 gas crossover through the polymer electrolyte from the anode and cathode, respectively. These crossover gases generate active oxygen radical species, such as -OH and -OOH, which attack the polymer backbone or side chains. Additionally, Pt particles have been observed migrating into the membrane, creating another site for radical formation2. This process results in pinhole formation, membrane thinning, carbon support, and platinum catalyst degradation3. Analyzing effluent water for fluoride ion release rate is the primary method for evaluating the membrane degradation rate.Recent approaches involve the utilization of cerium and manganese additives to mitigate radical formation and chemical degradation induced by radicals. However, a limitation associated with metal and metal oxide additives is their propensity for migration and agglomeration, causing alterations in membrane morphology and subsequently affecting proton conductivity. As an alternative to metal oxide additives, defect-free monolayer graphene, which is chemically stable, has been explored. It has been discovered that defect-free monolayer graphene is impermeable to all atoms and molecules but permeable to protons4. The incorporation of monolayer graphene with small defects may significantly reduce gas crossover while allowing the transport of water and protons. We also hypothesize that the graphene layer will serve as a barrier to catalyst ion transport (Pt2+ or Co2+) into the membrane, which can have an interesting impact on catalyst electrochemically active surface area (ECSA) and catalyst layer ionic resistance.In this study, we showcase the enhanced chemical durability of the Nafion membrane by introducing an atomically thin chemical vapour deposition (CVD) single graphene layer onto the PEM. Accelerated stress tests (AST), such as open circuit voltage (OCV) in H2 /Air at 30 %RH and 80oC, are used to evaluate the chemical durability of membranes within a relatively short time. Water collected from both the anode and cathode side were analyzed for fluoride emission rate and sulphate content. Catalyst layer ECSA, H2 crossover, membrane and catalyst layer ionic resistance were monitored every 24-28 hours. The insights gained from these results will be invaluable in assessing the promise and the challenges of employing 2D-material-modified PEM for HDV applications. Reference: (1) Cullen, D. A.; Neyerlin, K. C.; Ahluwalia, R. K.; Mukundan, R.; More, K. L.; Borup, R. L.; Weber, A. Z.; Myers, D. J.; Kusoglu, A. New Roads and Challenges for Fuel Cells in Heavy-Duty Transportation. Nat. Energy 2021, 6 (5), 462–474. https://doi.org/10.1038/s41560-021-00775-z.(2) Kim, T.; Lee, H.; Sim, W.; Lee, J.; Kim, S.; Lim, T.; Park, K. Degradation of Proton Exchange Membrane by Pt Dissolved/Deposited in Fuel Cells. Korean J. Chem. Eng. 2009, 26 (5), 1265–1271. https://doi.org/10.1007/s11814-009-0212-9.(3) Inaba, M.; Kinumoto, T.; Kiriake, M.; Umebayashi, R.; Tasaka, A.; Ogumi, Z. Gas Crossover and Membrane Degradation in Polymer Electrolyte Fuel Cells. Electrochim. Acta 2006, 51 (26), 5746–5753. https://doi.org/10.1016/j.electacta.2006.03.008.(4) Hu, S.; Lozada-Hidalgo, M.; Wang, F. C.; Mishchenko, A.; Schedin, F.; Nair, R. R.; Hill, E. W.; Boukhvalov, D. W.; Katsnelson, M. I.; Dryfe, R. A. W.; Grigorieva, I. V.; Wu, H. A.; Geim, A. K. Proton Transport through One-Atom-Thick Crystals. Nature 2014, 516 (7530), 227–230. https://doi.org/10.1038/nature14015.

Experimental Study of Fuel-Air Mixing and Dilution Jets on Outlet Temperature Distribution in a Small Gas Turbine Combustor

Experimental Study of Fuel-Air Mixing and Dilution Jets on Outlet Temperature Distribution in a Small Gas Turbine Combustor

Investigating the adsorption performance of agricultural greenhouses hazardous gases on Rh doped HfX2 (X=S, Se) monolayers through DFT for potential gas sensor applications

This study uses density functional theory to study the adsorption performance of agricultural greenhouses hazardous gases on Rh doped HfX2 (X=S, Se) monolayers. After multiple geometric optimizations, the most stable adsorption configuration was found. The results indicate that the adsorption energy of Rh doped HfX2 monolayers is very stable for adsorbing small molecule gases. The change in the total density of states of the adsorption system reveals the transfer and recombination of electrons during the adsorption process, and the partial density of states helps to understand the interactions between bonding atoms. Molecular orbital analysis shows that LUMO is mainly concentrated near Hf atoms, while HOMO is mainly concentrated near X atoms, Rh atom, and gases. By calculating the work function, the interaction strength and electron transfer mechanism between the adsorbent and the metal surface are revealed. In addition, the recovery time indicates that HfX2 and Rh-HfSe2 are excellent adsorbents for these four gases at room temperature, but when HfS2 operates at 473 K, it will be an efficient and excellent gas sensor for the four gases. Thus, Rh-HfS2 can be a feasible resistance sensing material for Cl2 and SO2. This DFT results provide a theoretical basis for potential gas sensor applications of Rh doped HfX2 (X=S, Se) monolayers, leading to the design and development of more efficient greenhouse gas identification sensor devices.

Simulation study on optimization design of small gas water heat exchangers

Simulation study on optimization design of small gas water heat exchangers

Regulation of MOF-74 nanosheet channels for precise H2 purification

Mixed matrix membranes (MMMs), composed of functional fillers and a polymer matrix, are considered effective demonstrations for overcoming the trade-off limitation of polymeric membrane-based gas separations. MOF-74, with its high density of open metal sites and one-dimensional straight honeycomb channels, is an extremely attractive filler material. However, the intrinsically large pore aperture and micron-sized, spindle-shaped grain morphology hinder the use of high-performance, interfacial defect-free MMMs for small gas separations. Herein, we report novel mixed matrix membranes integrated with dual-metallic MOF-74 nanosheets and poly(vinylamine) for precise molecular sieving for H2 purification applications. The nanosheets of parallel orientation within the membrane maximize the exposure of channels for polymeric chain penetration. The amino side groups anchored on the polymeric chains coordinate with the open metal sites on the channel walls of MOF-74 nanosheets, exposing the hydrophobic alkyl backbones to shrink the originally large channel apertures and simultaneously enhancing the interfacial compatibility between MOF-74 and the polymer matrix. Benefiting from the merits of these elegant channel regulations, MMMs exhibit superior H2/CH4 and H2/CO2 separation performances toward binary, ternary and even quaternary feedstocks, along with remarkable long-term separation stability. This MMM is expected to constitute a new membrane paradigm that holds great promise for practical H2 purification and separation.