Visual detection of aldehyde gases using a silver-loaded paper-based colorimetric sensor array

Abstract

The small molecule aldehydes are volatile organic compounds (VOCs), possessing cytotoxicity and carcinogenicity. Long-term exposure can pose a serious threat to human health. Based on an in-situ reduction colorimetric method to generate silver nanoparticles and induce colorimetric response, we proposed a silver-loaded paper-based colorimetric sensor array for visually detecting and differentiating five relatively common trace small molecule aldehyde gases. The silver ions are immobilized onto a porous filter paper and stabilized by complexing agents of branched polyethyleneimine, ethylenediamine, and 1,6-diaminohexane, respectively. The as-fabricated sensor array expresses remarkable stability and capacity to resist humidity. The qualitative analysis reveals that the sensor array has excellent selectivity for aldehyde gases and displays remarkable anti-interference ability. The quantitative analysis indicates that the sensor array exhibits superior sensitivity for five aldehyde gases, with limits of detection (LODs) of 9.0 ppb for formaldehyde (FA), 3.1 ppm for acetaldehyde (AA), 3.5 ppm for propionaldehyde (PA), 23.8 ppb for glutaric dialdehyde (GD), and 71.5 ppb for hydroxy formaldehyde (HF), respectively. Importantly, these LODs are all comfortably below their respective permissible exposure limits. A unique colorimetric response fingerprint is observed for each analyte. Standard chemometric methods illustrate that the sensor array has excellent clustering capability for these aldehyde gases. Additionally, the sensor array's response is irreversible and possesses outstanding performance for cumulative monitoring. This colorimetric sensor array based on silver ions reduced to silver nanoparticles offers a novel detection method for the continuous, ultrasensitive, and visual detection of trace airborne pollutants.