Blast Furnace Slag Research Articles

Study on the Chloride–Sulfate Resistance of a Metakaolin-Based Geopolymer Mortar

The chloride–sulfate corrosion environment of concrete is a significant engineering problem. This paper investigates the effect of the complete/semi–immersion mode on the durability of concrete in a chloride–sulfate environment by using different granulated blast furnace slag (GBFS) dosage rates (10–50%) of a metakaolin (MK)-based geopolymer mortar. The chloride–sulfate corrosion environment is discussed by analyzing the apparent morphology, mass change, and mechanical property change in specimens at the age of 120 d of erosion combined with XRD and SEM. The high Ca content in GBFS has an important effect on the strength and erosion resistance of the metakaolin geopolymer (MGP) group mortar; an increase in the GBFS dosage makes the MGP group mortar denser, and the initial strength of the MGP group mortar is positively correlated with the dosage of GBFS. After 120 d of erosion, the GBFS dosage is negatively correlated with erosion resistance, with the high GBFS dosage groups showing more severe damage. Semi-immersion resulted in more severe deterioration at the immersion–evaporation interface zone due to the difference in the ionic concentration and the ‘wick effect’ at the immersion–evaporation interface zone. Compared with the commonly used OPC mortar, the M40 and M50 groups have improved strength and corrosion resistance and are suitable for engineering environments in highly erosive areas.

Effect of desulphurization gypsum on hardening mechanism of the geopolymer produced with steel slag and granulated blast furnace slag

Effect of desulphurization gypsum on hardening mechanism of the geopolymer produced with steel slag and granulated blast furnace slag

Exploration of steel slag by lignin and sodium citrate modification for mechanical properties and stability of steel slag-cement cementitious materials

Steel slag is produced globally in huge annual quantities. How to achieve its large-scale utilization is a question that researchers have been exploring. In this work, sodium citrate (SC) was used as a linker to modify Steel slag (SS) with alkali lignin (AL). And steel slag cement cementitious materials (CSS) were prepared with 10% replacement ratio. The effects of AL and SC on CSS were investigated by X-ray diffractometry (XRD), Fourier Transform Infrared Spectroscopy (FT-IR) and Thermo-gravimetric analysis (TG/DTA) etc. The results indicated that AL successfully loaded on the surface of SS. For CSS, as the degree of modification increased, the standard consistency water consumption of CSS decreased from 27% to 23.5%. During the hydration of CSS, its main hydration product was Ca(OH)2, the suitable amounts of AL and SC can stimulate the activity of SS. In addition, SS modification could improve the stability of CSS. The results of Ray's clamp method showed that the addition of AL and SC made the expansion of CSS reduced from 1.5 to 0. The 3 d and 28 d of CSS maximum flexural strengths were 5.42 MPa and 8.61 MPa and the maximum compressive strengths were 22.96 MPa and 49.15 MPa, respectively. This was an increase of 36.67% and 48.27% respectively. Therefore, the combination of AL and SS can not only effectively solve the problem of AL resource utilization, but also is expected to realize the practical application of SS in cement cementitious materials. It has good social and environmental benefits.

Effect of steam curing on strength, durability and microstructure of concretes with and without mineral admixtures

This research explores the effect of steam curing on the strength, durability and microstructure of concretes with and without mineral admixtures of fly ash (FA) and ground granulated blast-furnace slag powder (SL). Two types of C55 strength grade concretes (one was pure cement concrete, the other was a concrete made by replacing part of the cement with 12% FA and 18% SL) were prepared and their compressive strength, chloride diffusion coefficient and carbonation depth under standard and steam-curing conditions were measured and compared. The phase composition and microstructure of the concretes under the two curing conditions were tested by X-ray diffraction, scanning electron microscopy and mercury intrusion porosimetry. The results showed that, on the one hand, compared with standard curing, steam curing is beneficial to the early strength, but not conducive to the later strength development and chloride permeability resistance of both types of concretes. Furthermore, for the steam-cured concrete, the 28 days carbonation depth of the forming surface is higher than that of the bottom surface. In addition, steam curing can reduce the carbonisation resistance of pure cement concrete and improve the carbonisation resistance of concrete mixed with FA and SL. On the other hand, composite mineral admixtures of FA and SL reduce the early strength and the carbonisation resistance of concrete cured by standard curing, but improve the later strength, the carbonisation resistance and chloride permeability resistance of concrete cured by steam curing. FA and SL are thermally activated under steam curing and can react with the calcium hydroxide formed by cement hydration in the early stage, which produces a larger amount of secondary hydration products to improve the pore structure and interfacial microstructure of the concrete with FA and SL. In this way, the adverse effects of steam curing on later strength and durability of concrete are significantly restrained by composite mineral admixtures of FA and SL.

Effect of granulated blast furnace slag on uniaxial compression fatigue properties of engineered geopolymer composites

Engineered geopolymer composites (EGCs), emerging as a novel eco-friendly cementitious material, exhibit considerable potential in diverse applications. Granulated blast furnace slag (GBFS) is a by-product of the blast furnace ironmaking process. Owing to its exceptional cementing properties, GBFS is frequently incorporated into geopolymer materials to enhance strength and stability, while also achieving slurry solidification at ambient temperature. The study examined the effect of different rates of GBFS replacement on the fatigue behavior of EGCs using uniaxial compression fatigue testing, with a particular focus on the changes in fatigue life and fatigue deformation. The results indicate that the fatigue life of EGC conforms to a Weibull distribution. While a higher GBFS replacement rate can improve the compressive strength of EGC, it has a detrimental effect on the fatigue life. Furthermore, when subjected to fatigue loading, the total strain accumulation, residual strain, and fatigue stiffness of EGC exhibited a three-stage evolutionary pattern, and remained constant during the secondary creep stage. Therefore, the comprehensive effect of adding GBFS to EGC on material strength and fatigue properties should be taken into account. This study uncovers the potential negative impacts of GBFS on the fatigue properties of EGC, contradicting the previous belief that GBFS could enhance the mechanical properties of geopolymers. Therefore, a comprehensive and meticulous assessment is necessary when contemplating the use of GBFS as a reinforcement material for EGC.

Effect of electric furnace steel slag powder on the strength of green low-carbon concrete with high-titanium blast furnace slag

This study explores the application of electric furnace steel slag powder (EFSSP), fly ash (FA), and high-titanium heavy slag (HTHS) from Panzhihua City, China, in producing green low-carbon concrete. The properties of these waste materials were characterized, and the fluidity and hydration activity of the EFSSP-FA composite admixture in cement mortar were tested. Additionally, the strength of HTHSC mixed with EFSSP-FA composite admixture was evaluated at various curing times, and the microstructure of the concrete mortar layer was analyzed. The study shows that the 7-day activity indices of EFSSP and FA are 61 % and 51.96 %, respectively, with fluidity ratios of 92.53 % and 124.58 %. Mixing EFSSP and FA compensates for their individual limitations. At a 1:1 mass ratio, the composite admixture achieved a 69.89 % activity index and 114.46 % fluidity. The pozzolanic reaction within the composite admixture was evident, promoting the continuous formation of C-S-H in HTHSC, the compressive strength after curing periods of 520 days, 300 days, 180 days, and 90 days reached approximately 190 %, 170 %, 150 %, and 130 % of the 28-day strength, respectively. The XRD, SEM, TG, and DSC characterization results for the HTHSC mortar layer at different curing stages were consistent with the observed trends in compressive strength. Since the raw materials used for concrete preparation were industrial waste, this portion was excluded from carbon emissions calculations. The all-industrial waste HTHSC achieved approximately a 30 % reduction in carbon emissions, the carbon emissions per unit of strength at 520 days of curing were approximately 55 % of those at 28 days.

Investigating the microstructure of alkali activated fly ash, ground granulated blast furnace slag (GGBS), or their mixtures by depth sensing nanoindentation and structure dependence of their composition by Magic Angle Spinning (MAS) NMR

Investigating the microstructure of alkali activated fly ash, ground granulated blast furnace slag (GGBS), or their mixtures by depth sensing nanoindentation and structure dependence of their composition by Magic Angle Spinning (MAS) NMR

Exploring machine learning to study and predict the chloride threshold level for carbon steel reinforcement

Chloride-induced corrosion of steel reinforcing bar (rebar) is the primary cause of deterioration in reinforced concrete structures, posing a significant infrastructure challenge. The chloride threshold level (CTL) of rebar, which represents the critical amount of chloride needed to initiate active corrosion, is crucial in corrosion and service life prediction models. However, substantial uncertainties and a multitude of influencing factors, along with the absence of a universally accepted testing framework, hinder the achievement of a consistent CTL range for service life models and complicate comparisons of published values. This study addresses these challenges by developing multiple machine learning models to predict CTL, considering 21 carefully selected features. A comprehensive database of 423 data points was compiled from an exhaustive literature review. Seven machine learning models—linear regression, decision tree, random forest, K-nearest neighbors, support vector machine, artificial neural network, and an ensemble model—were developed and optimized. The ensemble model achieved superior prediction performance, with a mean absolute error of 0.218 % by weight of binder, root mean square error of 0.321 %, and a coefficient of determination of 0.751 on unseen CTL data. Partial dependence plots generated using the support vector machine model quantified the effect of each feature on CTL. The random forest model identified SiO₂ binder content and exposed rebar area to chlorides as the most influential factors. The study also examined the impact of supplementary cementitious materials (SCMs), finding that only blast furnace slag positively affected CTL.

Limestone impact on properties, microstructure and CO2 emissions of waste glass-activated blast furnace slag cements

Limestone impact on properties, microstructure and CO2 emissions of waste glass-activated blast furnace slag cements

Stress-Strain Behavior and Strength Development of High-Amount Phosphogypsum-Based Sustainable Cementitious Materials.

Phosphogypsum is a common industrial solid waste that faces the challenges of high stockpiling and low utilization rates. This study focuses on the mechanical properties and internal characteristics of cementitious materials with a high phosphogypsum content. Specifically, we examined the effects of varying amounts of ground granulated blast furnace slag (5-28%), fly ash (5-20%), and hydrated lime (0.5-2%) on the stress-strain curve, unconfined uniaxial compressive strength, and elastic modulus (E50) of these materials. The test results indicate that increasing the ground granulated blast furnace slag content can significantly enhance the mechanical properties of phosphogypsum-based cementitious materials. Additionally, increasing the fly ash content can have a similar beneficial effect with an appropriate amount of hydrated lime. Furthermore, microscopic analysis of the cementitious materials using a scanning electron microscope revealed that the high sulfate content in phosphogypsum leads to the formation of calcium aluminate as the main product. Concurrently, a continuous reaction of the raw materials contributes to the strength development of the cementitious materials over time. The results could provide a novel method for improving the reusing phosphogypsum amount in civil engineering materials.

Proposing Optimized Random Forest Models for Predicting Compressive Strength of Geopolymer Composites

This paper explores advanced machine learning approaches to enhance the prediction accuracy of compressive strength (CoS) in geopolymer composites (GePC). Geopolymers, as sustainable alternatives to Ordinary Portland Cement (OPC), offer significant environmental benefits by utilizing industrial by-products such as fly ash and ground granulated blast furnace slag (GGBS). The accurate prediction of their compressive strength is crucial for optimizing their mix design and reducing experimental efforts. We present a comparative analysis of two hybrid models, Harris Hawks Optimization with Random Forest (HHO-RF) and Sine Cosine Algorithm with Random Forest (SCA-RF), against traditional regression methods and classical models like the Extreme Learning Machine (ELM), General Regression Neural Network (GRNN), and Radial Basis Function (RBF). Using a comprehensive dataset derived from various scientific publications, we focus on key input variables including the fine aggregate, GGBS, fly ash, sodium hydroxide (NaOH) molarity, and others. Our results indicate that the SCA-RF model achieved a superior performance with a root mean square error (RMSE) of 1.562 and a coefficient of determination (R2) of 0.987, compared to the HHO-RF model, which obtained an RMSE of 1.742 and an R2 of 0.982. Both hybrid models significantly outperformed traditional methods, demonstrating their higher accuracy and reliability in predicting the compressive strength of GePC. This research underscores the potential of hybrid machine learning models in advancing sustainable construction materials through precise predictive modeling, paving the way for more environmentally friendly and efficient construction practices.

Green slag cement with nano copper oxide and nano silica: Enhanced antimicrobial and structural properties

The global construction industry is facing challenges related to sustainability, environmental impact, and the demand for innovative materials with multifunctional properties. A major concern is the durability of cement structures, which is often compromised by harmful bacteria and algae. These microorganisms accelerate the deterioration of structures, increase maintenance costs, and pose safety risks. Addressing these issues is essential to prolong the life of cement-based structures and reduce their environmental and carbon footprint. Cement in moist environments is particularly vulnerable to microbial growth, leading to structural weaknesses and degradation. This degradation necessitates costly repairs, shortens the lifespan of infrastructure, creates a threat to human lives, and contributes to increased carbon emissions. To tackle these challenges, researchers have tried to develop low-carbon cement ((green cement) with antimicrobial properties. Nanomaterials like nano-copper oxide (nCuO) and nano-silica (nSiO₂) have shown great potential in enhancing both the structural performance and microbial resistance of green cement. When nanomaterials, nCuO is incorporated into Portland slag cement (PSC), which already has a lower carbon footprint compared to traditional cement, enhances antibacterial and antialgal properties but adversely impacts the mechanical performance and to counter the adverse effect of nCuO, nSiO2 added to improve the mechanic performance. PSC is known for its ability to reduce industrial waste and CO₂ emissions, and the addition of nCuO and nSiO₂ makes it an even higher-performance material. Effects of nCuO and nSiO₂ on PSC have been studied by using isothermal calorimetry to assess hydration kinetics, X-ray diffraction to observe composition changes during hydration, scanning electron microscopy (SEM) to analyze microstructural changes, and mechanical testing to evaluate the strength of the material. The effectiveness of antimicrobial properties is studied in lab and field experiments. The results revealed improved compressive strength and significant resistance to bacterial and algal growth. The combination of nCuO's antimicrobial properties and nSiO₂'s ability to enhance the cement's strength created a synergistic effect that optimizes both performance and durability. Additionally, the study proposed a model to better understand the interaction between these nanomaterials, offering valuable insights into the mechanisms of hydration and microbial inhibition.

Fluidized solidified soil using construction slurry improved by fly ash and slag: Preparation, mechanical property, and microstructure

Abstract Fluidized solidified soil (FSS) is a cement-based engineering matergood working performance and mechanical properties. Based on fixed cement and desulphurisation gypsum (DG), fly ash (FA) and ground granulated blast furnace slag (GGBS) were added as admixtures to the construction slurry to prepare three types of FSS: namely cement-GGBS-DG FSS (CGD-FSS), cement-FA-GGBS-DG FSS (CFGD-FSS), and cement-FA-DG FSS (CFD-FSS). Considering 7 d, 14 d, and 28 d three curing times, compressive, flexural, scanning electron microscopy (SEM), and X-Ray diffraction (XRD) analyses were conducted to explore the time-dependent mechanical properties and microscopic characterisation of FSS. The mechanical test showed that CFGD-FSS doped with FA and GGBS had better fluidity, compressive strength, and flexural strength than CGD-FSS doped with FA alone and CFD-FSS doped with GGBS. The CFGD-FSS specimen with a cement:FA:GGBS:DG ratio of 30: 10: 40: 20 in the curing agent had the best mechanical properties, i.e., the CFGD01 specimens. It has fluidity of 189 mm, compressive strength of 671 kPa, and flexural strength of 221 kPa with a 28d curing time, which can meet the working requirements of FSS for filling narrow engineering spaces. And compared with other specimens, it has the shortest setting time, which can effectively shorten the construction period. Microscopic analysis showed that a large number of hydration products, such as calcium silicate hydrate, calcium aluminate hydrate, and ettringite (Aft), were well-formed in the FSS, resulting in good mechanical properties, especially for the CFGD-01 specimens. Finally, two empirical models were established to describe the compressive strength–porosity and flexural strength–porosity relationships. Moreover, the investigated data agreed well with the modelling results.

Alkali-Silica Reaction and Residual Mechanical Properties of High-Strength Mortar Containing Waste Glass Fine Aggregate and Supplementary Cementitious Materials

This paper presents the influence of supplementary cementitious materials (SCMs), such as fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GGBS), and waste glass fine aggregate (GA), on the alkali-silica reaction (ASR) in high-strength and normal-strength mortar using an accelerated mortar bar test (AMBT). Residual mechanical properties and scanning electron micrographs were used to assess the changes in the matrix. GA reduced the mechanical properties of both normal-strength (NGA_OPC) and high-strength mortars (HGA_OPC), contributing to a decline in overall performance. This phenomenon was a result of the slipping of the GA from the matrix owing to its smooth surface. However, the inclusion of reactive SF and GGBS in the HGA improved the slip phenomenon of the GA, leading to a significant enhancement in its mechanical properties. Following the ASR expansion measurement, HGA_OPC demonstrated an ASR expansion rate approximately three times higher than that of NGA_OPC. This was attributed to the dense structure of HGA_OPC, which resulted in greater expansion than that of NGA_OPC. However, with the incorporation of SCMs into both HGA and NGA, a significant reduction in ASR expansion was observed. This was attributed to the delayed ASR of GA due to alkali activation or the pozzolanic reaction of the SCMs. Continuous exposure to the AMBT environment can lead to the destruction of GA. This was caused by the inner ASR that originated from the surface crack of the GA, which resulted in a reduction in the flexural strength of the mortar. The HGA with SF exhibited the highest resistance to ASR expansion and residual mechanical properties’ degradation. Therefore, various durability and long-term performance-monitoring studies on ultra-high-performance concrete or high-strength cementitious composites with very high SF contents and GA can be conducted.

Workability and Environmental Evaluation of Using Sunflower Stalk Ash as an Alkali Activator with Blast Furnace Slag and Black Rice Hull Ash to Prepare Geopolymer Grouts

Workability and Environmental Evaluation of Using Sunflower Stalk Ash as an Alkali Activator with Blast Furnace Slag and Black Rice Hull Ash to Prepare Geopolymer Grouts

Preparation of Glass–Ceramics Using Low-Pressure Sintering Method for High-Value Utilization of Blast Furnace Slag

Preparation of Glass–Ceramics Using Low-Pressure Sintering Method for High-Value Utilization of Blast Furnace Slag

Sustainable quaternary binders made from metallurgical wastes of northeast Mexico: strength, hydration products, and durability.

In this research, four industrial wastes were used for up to 80% as supplementary cementitious materials (SCMs) in cement mortar systems: ground granulated blast furnace slag, electric arc furnace slag, basic oxygen furnace slag, and waste limestone powder. Quaternary cementitious blends were prepared and studied for up to 120days. Workability, compressive strength, durability, microstructures, and sustainability studies were performed and compared with Portland cement references. Results showed that more than 30MPa in compressive strength can be achieved by > 50% replacement with SCMs; only 9% below the reference. Neither H2SO4 nor MgSO4 attacks resulted in critical damages; nevertheless, curing under NaCl solution showed detrimental behavior. C-S-H with a low Ca/Si ratio was identified in the mortars as the main hydration product, possibly intermixed with stratlingite, C-A-S-H and/or hydrotalcite. Environmental impact for the blended cements was determined as the CO2eq. factor from a simple life cycle assessment. The embodied greenhouse gasses varied in 260.2-541.4kg CO2eq./ton of binder depending on the formulation. This was 40-70% less than Portland cement (922.6kg CO2eq./ton). The production of the raw materials dominated the polluting emissions, while freight, grinding, and sieving had little environmental impact.

Expansion Control of Alkali-Activated Materials Using Waste Glass Cullet from Photovoltaic Panels as Fine Aggregates

Glass cullet (GC) generated from the disposal of photovoltaic (PV) panels are typically landfilled, and effective GC utilization methods must be established for PV generation. In this study, alkali-activated material (AAM) mortars were prepared from the paste of fine blast-furnace slag powder, fly ash, and sodium orthosilicate (SO) and mixed with crushed sand and GC to investigate the potential use of GC as a fine aggregate in AAM. The replacement of crushed sand with GC did not considerably affect the flowability of the mortar, whereas the compressive strength decreased with the increasing GC replacement rates. Although expansion due to the alkali–silica reaction (ASR) was observed in mortars wherein GC replaced crushed sand, the expansion can be controlled by reducing the amount of mixed SO, autoclaving the GC, performing preleaching to remove the Si that causes the ASR, and replacing the blast-furnace slag with fly ash. By enforcing measures against the expansion, the possibility of using GC as fine aggregate is enhanced considerably, thus increasing the feasibility of continuous PV production.

Life cycle assessment of green binder for organic soil stabilization

Increasing construction on soils with low bearing capacity is a geotechnical challenge currently faced in several parts of the world. Highly compressible organic soils require intervention to improve their mechanical behavior. In this case, mass stabilization with binder is an applicable technique, however the commercial cement used (Ordinary Portland Cement) generates environmental impacts that can be minimized with its replacement by environmentally friendly binders. Blended binders can use secondary materials from the industry (waste or by-products) and promote environmental gains. In this case, this research proposes the use of carbide lime and granulated blast furnace slag with the complement of Portland cement for the stabilization of an organic soil. A comparison of the strength obtained with the blended binder versus Portland cement is analyzed in soil stabilization. A Life Cycle Assessment is performed to verify if the proposed blended binder has environmental benefits in replacing conventional cement. Results show that the blended binder has similar capacity to stabilize the organic clay soil compared to commercial cement. The life cycle analysis showed that the use of secondary materials from industry in the composition of blended binder promotes a significant reduction in environmental impacts assessed.

Transforming industrial byproduct to eco-friendly functional material: Ground-granulated blast furnace slag reinforced paper for renewable energy storage

This study pioneered an eco-friendly approach for reutilizing Ground-granulated blast furnace slag (GGBFS) in paper production. This investigation is the first study focusing on the usage of paper production that presents both a new usage area of GGBFS and also a new sight. So, it can contribute to save the trees. Also, GGBFS gains economical value in paper production. 15–25 % integrated slag led to markedly enhanced brightness, density and smoothness accompanied by only minor mechanical strength decreases versus pure pulp. Significantly, the electrical analysis revealed a higher conductivity at higher frequency region reaching almost S value near to 1 which might be a good choice for electromagnetic shielding, thus; higher conductivity with increasing slag contents from pure paper's 10−11 S/cm up to 10−6 S/cm for 25 % addition which confirms the modified paper's usefulness as conductive slag agent. Although the higher addition of GGBFS has led to rising in relaxation time basically from 1.77e−4 to 2.95e−3 and based on Debye relaxation, the rising time in relaxation which was observed after the addition of GGBFS reveals better polarizability values 0.29–0.35 compared to control sample 0.26 by which both longer relaxation time and higher polarizability contribute to the ability of energy storage of modified papers. The conductive characteristics and improved qualities demonstrate these recyclable slag-modified papers present unique opportunities for emerging flexible, eco-friendly electronics, capacitors, electromagnetic shielding, and renewable energy storage applications. Overall, novel integration and characterization of slag waste for enhanced sustainable paper products pioneers an unexplored territory.