By considering the concept of a unified single fluid model, referred to as modified Chaplygin gas (MCG), which amalgamates dark energy and dark matter, we explore the thermodynamic characteristics of charged anti-de Sitter (AdS) black holes existing in an unconventional fluid accompanied by MCG. To accomplish this objective, we derive the equations of state by regarding the charge as a thermodynamic variable. The effects of MCG parameters on the critical thermodynamic quantities ( , , ) are examined, followed by a detailed analysis of the diagram. To provide a clearer explanation of the phase transition, we present an analysis of the Gibbs free energy. It is important to note that if the Hawking temperature exceeds the critical temperature, a distinct pattern is observed known as swallowtail behavior. This indicates that the system undergoes a first-order phase transition from a smaller black hole to a larger one. The critical exponent of the system is found to be in complete agreement with that of the van der Waals fluid system. Furthermore, we investigate the impact of MCG parameters and black hole charge on Joule-Thomson (J-T) expansion in the extended phase space. The J-T coefficient is examined to pinpoint the exact region experiencing cooling or heating, and the observation reveals that the presence of negative heat capacity results in the occurrence of a cooling process. The impact of MCG on the inversion curve of charged black holes exhibits a striking resemblance to that observed in most multi-dimensional black hole systems. In addition, it is worth noting that certain parameters exert a significant influence on the ratio . For specific values of the MCG parameters, the ratio is consistent with the charged AdS black hole. The parameters γ and β have a non-negligible effect on the isenthalpic curve.