Foam materials have been widely used in various industrial applications, where higher and higher heat and mass transfer performances are pursued. However, the mechanism of many factors on the heat transfer performances is still unclear. The main purpose of this article is to investigate how the porous properties, porosity, cell size and the sample thickness affect the volumetric convective heat transfer. In this study, the single-blow method is used to determine the volumetric heat transfer coefficient of ceramics foam in the temperature range from 283 K to 323 K. In particular, sensitivity analysis of the foam porosity, cell size, velocity and the sample thickness on the volumetric heat transfer coefficient within the ceramics foam were all conducted. The results indicate that the sample thickness has a significant effect on the volumetric heat transfer coefficient which decreases with the sample thickness. In addition, the local thermal equilibrium phenomenon is verified and its influence on the volumetric heat transfer coefficient discussed. Based on the experimental data, a new correlation is proposed that includes sample thickness, porosity, superficial velocity and fluid properties. This study is crucial to the theory of the convective heat transfer inside the porous media, and can be used to guide the design and optimization of volumetric solar air receivers, compact heat exchangers, heat sinks, heat regenerators, packed bed reactors and so on.