Single Barrier Research Articles

Tunneling conductance regulated by the electrostatic barrier in monolayer black phosphorene

We investigate the tunneling conductance of monolayer black phosphorene through double magnetic barriers modulated by the electrostatic barrier. This magnetic barrier is generated by two ferromagnetic strips deposited on monolayer phosphorene and can form parallel (P) and antiparallel (AP) structures. Applying a voltage to a ferromagnetic strip will create an electrostatic barrier. The transmission of P and AP magnetic structures is calculated using the transfer matrix. Tunneling conductance is given by Landauer–Büttiker theory. Our results show that under double electrostatic barriers modulation, the AP conductance of the system is zero except for sharp peaks, while the P conductance has a certain value, which implies a large tunneling magnetoresistance. However, in the case of single electrostatic barrier modulation, the conductance becomes flat. For the Fermi level in the valence band, the movement of the Fermi level leads to the severe mismatching of transmitted wave vectors in the barrier region, resulting a positive and negative oscillation magnetoresistance. This may be useful for designing memory using a two-dimensional electron gas system.

Influence of neutron transfer channels on fusion dynamics near the Coulomb barrier for 28Si + 116,120,124Sn systems

The phenomenon of enhanced fusion cross-section as compared to the theoretical predictions of 1-D BPM has been extensively studied over the past few decades. However, the unambiguous role of neutron transfer channels on the sub-barrier fusion enhancement is still elusive in most cases. Fusion cross-section measurements ≈ 15% below and above the Coulomb barrier were performed to elucidate the mechanisms responsible for the experimentally observed sub-barrier fusion enhancement. Coupled-channels calculations using CCFULL were used to decipher the reaction dynamics. CC calculations explained the fusion excitation function for 28Si + 116,120Sn systems after the inclusion of inelastic excitations along with a pair transfer. However, the observed behavior for the 28Si + 124Sn system could not be explained. The fusion barrier distribution has been extracted from the experimental data to unveil the various channels coupled in the concerned rection. A single uncoupled barrier was transformed into a distribution of barriers depicting the presence of different channels coupled in the reaction. The results indicate a significant effect from multi-neutron transfer channels on the fusion dynamics.

Implementation of energy barrier layers for 1550 nm high-power laser diodes

The influence of a thin AlInAs energy barrier on the efficiency of 1550 nm high-power semiconductor lasers efficiency has been experimentally studied. It was shown that the position and number of barriers in an asymmetric laser heterostructure based on a 1.8–1.9 μm thick waveguide has a significant effect on the output optical power. It is shown that in a barrierless structure, the main reason for radiative efficiency decrease is internal quantum yield drop due to the absence of an energy barrier for the type-II heterojunction at the waveguide-p-cladding interface and electron leakage to the p-emitter layer. It is demonstrated that the implementation of single AlInAs energy barrier layer on waveguide-p-cladding heterojunction allows significantly increase laser diode maximum output power. 2 W maximum CW optical power has been achieved from 40 μm aperture laser diode at heatsink temperature 25 °C.

A local ATR-dependent checkpoint pathway is activated by a site-specific replication fork block in human cells.

When replication forks encounter DNA lesions that cause polymerase stalling, a checkpoint pathway is activated. The ATR-dependent intra-S checkpoint pathway mediates detection and processing of sites of replication fork stalling to maintain genomic integrity. Several factors involved in the global checkpoint pathway have been identified, but the response to a single replication fork barrier (RFB) is poorly understood. We utilized the Escherichia coli-based Tus-Ter system in human MCF7 cells and showed that the Tus protein binding to TerB sequences creates an efficient site-specific RFB. The single fork RFB was sufficient to activate a local, but not global, ATR-dependent checkpoint response that leads to phosphorylation and accumulation of DNA damage sensor protein γH2AX, confined locally to within a kilobase of the site of stalling. These data support a model of local management of fork stalling, which allows global replication at sites other than the RFB to continue to progress without delay.

Effect of gas components on the degradation mechanism of o-dichlorobenzene by non-thermal plasma technology with single dielectric barrier discharge

In this paper, the degradation of o-DCB under different gas-phase parameter conditions was investigated using the SDBD-NTP system. The results showed that the increase in initial and oxygen concentrations had opposite effects on the degradation of o-DCB. Among them, the increase of oxygen concentration promoted the degradation of o-DCB. Relative humidity promoted and then inhibited the degradation of o-DCB. The highest degradation efficiency of o-DCB was achieved at RH = 15%, reaching 91% at 29W. In the study of by-products, it was found that O3 and NOx were the main inorganic by-products, and that different oxygen levels and relative humidity conditions had a large effect on the production of O3 and NOx. In all of them, the concentration of O3 decreased with the increase of input power. NOx increased with increasing oxygen concentration, but the increase in relative humidity inhibited the production of NO and N2O and promoted the conversion of NO2. A study of organic by-products revealed this. In the absence of oxygen, a higher number of benzene products appeared. Whereas, with the addition of oxygen, only in the by-products under conditions where no relative humidity was introduced, benzene ring products were predominantly present in the by-products. However, when RH was added, n-hexane was found to be present in the by-products. This may be because the introduction of OH• favors the destruction of the benzene ring. Finally, the possible reaction pathways and reaction mechanisms of o-DCB under different gas-phase parameters are given. It provides a reference for future related scientific research as well as scientific problems in practical applications.

Greatly enhanced tunneling electroresistance in ferroelectric tunnel junctions with a double barrier design

We propose that the double barrier effect is expected to enhance the tunneling electroresistance (TER) in the ferroelectric tunnel junctions (FTJs). To demonstrate the feasibility of this mechanism, we design a model structure of Pt/BaTiO3/LaAlO3/Pt/BaTiO3/LaAlO3/Pt double barrier ferroelectric tunnel junction (DB-FTJ), which can be considered as two identical Pt/BaTiO3/LaAlO3/Pt single barrier ferroelectric tunnel junctions (SB-FTJs) connected in series. Based on density functional calculation, we obtain the giant TER ratio of 2.210 × 108% in the DB-FTJ, which is at least three orders of magnitude larger than that of the SB-FTJs of Pt/BaTiO3/LaAlO3/Pt, together with an ultra-low resistance area product (0.093 KΩμm2) in the high conductance state of the DB-FTJ. Moreover, it is possible to control the direction of polarization of the two single ferroelectric barriers separately and thus four resistance states can be achieved, making DB-FTJs promising as multi-state memory devices.

WR1065 conjugated to thiol-PEG polymers as novel anticancer prodrugs: broad spectrum efficacy, synergism, and drug resistance reversal.

The lack of anticancer agents that overcome innate/acquired drug resistance is the single biggest barrier to achieving a durable complete response to cancer therapy. To address this issue, a new drug family was developed for intracellular delivery of the bioactive aminothiol WR1065 by conjugating it to discrete thiol-PEG polymers: 4-star-PEG-S-S-WR1065 (4SP65) delivers four WR1065s/molecule and m-PEG6-S-S-WR1065 (1LP65) delivers one. Infrequently, WR1065 has exhibited anticancer effects when delivered via the FDA-approved cytoprotectant amifostine, which provides one WR1065/molecule extracellularly. The relative anticancer effectiveness of 4SP65, 1LP65, and amifostine was evaluated in a panel of 15 human cancer cell lines derived from seven tissues. Additional experiments assessed the capacity of 4SP65 co-treatments to potentiate the anticancer effectiveness and overcome drug resistance to cisplatin, a chemotherapeutic, or gefitinib, a tyrosine kinase inhibitor (TKI) targeting oncogenic EGFR mutations. The CyQUANT®-NF proliferation assay was used to assess cell viability after 48-h drug treatments, with the National Cancer Institute COMPARE methodology employed to characterize dose-response metrics. In normal human epithelial cells, 4SP65 or 1LP65 enhanced or inhibited cell growth but was not cytotoxic. In cancer cell lines, 4SP65 and 1LP65 induced dose-dependent cytostasis and cytolysis achieving 99% cell death at drug concentrations of 11.2 ± 1.2 µM and 126 ± 15.8 µM, respectively. Amifostine had limited cytostatic effects in 11/14 cancer cell lines and no cytolytic effects. Binary pairs of 4SP65 plus cisplatin or gefitinib increased the efficacy of each partner drug and surmounted resistance to cytolysis by cisplatin and gefitinib in relevant cancer cell lines. 4SP65 and 1LP65 were significantly more effective against TP53-mutant than TP53-wild-type cell lines, consistent with WR1065-mediated reactivation of mutant p53. Thus, 4SP65 and 1LP65 represent a unique prodrug family for innovative applications as broad-spectrum anticancer agents that target p53 and synergize with a chemotherapeutic and an EGFR-TKI to prevent or overcome drug resistance.

Resonant Tunneling Effects on the Double‐Barrier Electron Blocking Layer of a Nitride Deep‐UV Light‐Emitting Diode

The multi‐quantum‐barrier electron blocking layer (EBL) is reported to significantly improve efficiency by nearly 3 times over a single barrier in deep‐UV AlGaN light‐emitting diodes to deal with electron leakage. The improvement is usually attributed to the enhanced effective barrier height, and this article aims to explore the benefits of the tunneling effect by calculating the tunneling currents of electrons and holes through an Al0.6Ga0.4N/AlyGa1−yN double‐barrier EBL under external bias from opposite directions. The results show that the tunneling current for holes Jh is several orders of magnitude higher than that of the electrons Je as the barriers are with Al mole fraction y greater than 0.75 and thickness larger than 2 nm, which promises effective hole injection by tunneling without much electron leakage. Tunneling mechanism works better in EBL with higher and thicker barriers because the tunneling coefficients of light hole drop much slower than electrons due to its small effective mass. A proper distance between the barriers is needed to avoid electron leakage while holes tunnel through the EBL. Built‐in electric fields tilt the band to enlarge the peak‐to‐valley ratio. This work indicates that the tunneling effect substantially facilitates a multibarrier EBL to enhance carrier‐injection efficiency.

Class A Prediction Symposium on Debris Flow Impact Forces on Single and Dual Barriers

Over recent years, significant advances have been made in the modelling of the impact dynamics between debris flows and single and dual rigid and flexible barriers. Numerical tools and analytical formulations have been proposed to predict the impact force, runup height, barrier deformation, and overflow and landing dynamics. However, there remains a dearth of well-recognised tools that can be used in routine engineering design practice because their reliability is unclear. On 8 and 9 May 2022, a virtual Class A Prediction Symposium on Debris Flow Impact Forces on Single and Dual Barriers was held to evaluate the reliability of existing design tools and identify areas for improvement to advance the current state of barrier design. The symposium was organised by The Hong Kong University of Science and Technology, Norwegian University of Science and Technology, Institute of Mountain Hazards and Environment of the Chinese Academy of Sciences, and the Geotechnical Engineering Office of the Civil Engineering and Development Department of the HKSAR Government. This paper summarises the existing research on flow-barrier interaction, and details of the symposium, including the prediction cases and results, roundtable discussion, and future research directions.

Systematic study of the isotopic dependence of heavy-ion fusion cross sections at below- and above-barrier energies

The present work provides a systematic study on the role of nuclear surface tension in the isotopic dependence of the fusion cross sections at below- and above-barrier energies over wide range of neutron content (0.5 < N/Z < 1.7). To realize our goal, we select three different versions of proximity-based potential, involving proximity potential 1977, 1988, and 2010, in order to calculate the nucleus-nucleus potential and ultimately the fusion barrier parameters. It is shown that the barrier positions, heights, and curvatures follow a (second-order) non-linear isotopic behavior with addition of neutrons which are dependent on the effect of variation in the nuclear surface tension. Our findings reveal that the sensitivity of isotopic dependence of the fusion barrier characteristics to the effect of surface energy coefficients γ increases by increasing the asymmetry of the colliding pair. In addition, we demonstrate the sensitivity toward the coefficient γ is seen more clearly from the more neutron-rich nuclei compared to the neutron-deficient ones. We discuss the isotopic dependence of the fusion cross sections at below- and above-barrier energies within the framework of the Wong model for a single potential barrier. For above-barrier energies, it is shown that the fusion cross sections follow an increasing (second-order) non-linear trend due to the addition of neutrons. While a decreasing (second-order) non-linear trend exists for the variation in the fusion cross sections at below-barrier energies. Simultaneous comparison the results obtained by the 3 versions of proximity potential for the isotopic dependence of fusion cross sections in the mentioned energy regions reveal the importance of the quantum tunneling and also nuclear structure effects.

Transfer matrix in 1D Dirac-like problems

The transfer matrix method is considered to obtain the fundamental properties of 1D Dirac-like problems. The case of 1D problems in monolayer graphene is addressed. The main characteristics of the transfer matrix are analyzed, contrasting them with the ones corresponding to 1D Schrödinger-like problems. Analytic expressions for the transmission coefficient and bound states are obtained. The continuity between bound states and states of perfect transmission is demonstrated in general, and in particular showed for the case of single electrostatic barriers. These findings in principle can be extended to 2D materials with Hamiltonian similar to monolayer graphene such as silicene and transition metal dichalcogenides.

Long-term effects of soft rock amendment on changes of soil aggregate cementing agents of sandy soil by SEM-EDS

Soil aggregates are a crucial constituent of soil and have a significant function in regulating water, nutrients, air, and heat within the soil. The development of soil aggregates is influenced by various factors, including the soil’s parent material and human activities. Understanding the formation and the mechanism of stabilization of soil aggregates is of great significance in the study of soil development, in regulating and managing organic carbon pools in soils, and in promoting soil fertility. In this study, aeolian sandy soil with a low degree of soil development and compound soil formed by combining soft rock and aeolian sandy soil were selected as the research objects. We selected three time points from 0 to 9 years after amendment by soft rock in order to investigate the changes of soil aggregate cementing agents. The shape of soil aggregates in both types of soils was analyzed by environmental scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), which were also used to assess the appearance of soil aggregates and quantify the composition of mineral elements on a cross section of the aggregate. The results show that when the soft rock and the aeolian sandy soil are compounded and mixed, the clay minerals in the soft rock change the microstructure of the original aeolian sandy soil from a single granular barrier to one characterized by a cumulative porous structure, indicating that clay minerals promote soil development and form aggregates with good structural properties. The cementing agents in the compounded soil aggregates are mainly clay minerals, aluminum, iron, and calcium. In comparison to aeolian sandy soils, the presence of iron and calcium in compounded soils is notably elevated. The iron oxides present in compounded soils serve a similar function to “bolts” in the formation of soil aggregates. These findings establish a theoretical foundation for investigating the process of soil aggregate formation and the mechanisms by which cementing agents contribute to their stabilization.

Atomistic determination of Peierls barriers of dislocation glide in nickel

The Peierls barrier measures the lattice resistance to dislocation glide in crystalline solids. We use the nudged elastic band (NEB) method to calculate the Peierls barriers for screw and edge dislocation glide in a face-centered cubic (FCC) metal of Ni. The minimum energy paths (MEPs) across single or sequential Peierls barriers are determined under shear loading. The NEB results show the decreasing Peierls barrier with increasing shear stress, giving the Peierls stress at which the Peierls barrier vanishes. The effects of boundary condition and system size on Peierls barriers are studied by comparing strain- and stress-controlled NEB results. Furthermore, the free-end NEB methods are applied to determine MEPs with improved computational efficiency. The NEB results are also used to evaluate the energetic driving force of dislocation glide, which is consistent with that determined from the Peach-Koehler force. The accuracy of the present NEB results based on an empirical interatomic potential is assessed by comparison with a machine-learning potential. This work demonstrates the robust and efficient quantification of Peierls barriers to dislocation glide in an FCC metal, and it lays a solid foundation for the atomistic determination of Peierls barriers in compositionally complex alloys with the FCC structure in future studies.

Calculating InN/GaN Transmission Coefficient from Single Barrier to Five Barriers with Propagation Matrix and Transfer Matrix Methods

In this study, the value of transmission coefficient on InN/GaN semiconductor from a single barrier to five barriers was determined by using the propagation matrix method and the transfer matrix method. This study aims to see the effect of adding a barrier to the number of resonance tunneling that occurs, to see the difference in transmission coefficient values which was obtained with the two methods, and to determine the effectiveness of the program execution process time from the propagation matrix and transfer matrix methods using Matlab programming. The results obtained indicated that the value of the transmission coefficient obtained from the two methods was the same. As the number of barriers increases, the number of resonance tunneling that occurs will increase. These two matrix methods had differences in terms of the effectiveness of the program execution process time and calculation process. The propagation matrix method was considered more effective than the transfer matrix method.

Random magnetic anisotropy driven transitions in the layered perovskite LaSrCoO4

Attempts to unravel the nature of magnetic ordering in LaSrCoO$_4$ (Co$^{3+}$), a compound intermediate between antiferromagnetic (AFM) La$_2$CoO$_4$ (Co$^{2+}$) and ferromagnetic (FM) Sr$_2$CoO$_4$ (Co$^{4+}$), have met with a limited success so far. In this report, the results of a thorough investigation of dc magnetization and ac susceptibility (ACS) in single-phase LaSrCoO$_4$ provide clinching evidence for a thermodynamic paramagnetic (PM) - ferromagnetic (FM) phase transition at T$_{c}$ = 220.5 K, followed at lower temperature (T$_{g}$ = 7.7 K) by a transition to the cluster spin glass (CSG) state. Analysis of the low-field Arrott plot isotherms, in the critical region near T$_{c}$, in terms of the Aharony-Pytte scaling equation of state clearly establishes that the PM-FM transition is basically driven by random magnetic anisotropy (RMA). For temperatures below $\approx$ 30 K, large enough RMA destroys long-range FM order by breaking up the infinite FM network into FM clusters of finite size and leads to the formation of a CSG state at temperatures T $\lesssim$ 8 K by promoting freezing of finite FM clusters in random orientations. Increasing strength of the single-ion magnetocrystalline anisotropy (and hence RMA) with decreasing temperature is taken to reflect an increase in the number of low-spin (LS) Co$^{3+}$ ions at the expense of that of high-spin (HS) Co$^{3+}$ ions. At intermediate temperatures (30 K $\lesssim T \lesssim$ 180 K), spin dynamics has contributions from the infinite FM network (fast relaxation governed by a single anisotropy energy barrier) and finite FM clusters (extremely slow stretched exponential relaxation due to hierarchical energy barriers).

Numerical study on the effect of complex structural barrier walls on high-pressure hydrogen horizontal jet flames

Hydrogen has the potential to produce energy with no emissions, and therefore offers a strategic opportunity for rapid development of renewable energy storage. However, jet flames caused by the leakage of high-pressure hydrogen may cause casualties and damage equipment, so the safety issues associated with hydrogen incidents are a key issue restricting its development. Barrier walls can be an important mitigative action to reduce the hazard of hydrogen jet flames. Previous studies have evaluated the protective effect of different vertical or inclined arrangements of a single barrier wall in the vertical direction. However, in the vertical direction, a single barrier wall is not sufficient to reduce the hazards associated with high-pressure hydrogen jet flames. In this paper, a two-dimensional CFD model of high-pressure hydrogen jet flames are established. A simplified form of the hydrogen real gas equation of state is used to describe the complex behavior of high-pressure hydrogen. This CFD study employs the standard k-ε turbulence model, the eddy dissipation concept (EDC) model, and the discrete ordinate (DO) radiation model. The results display good agreement with the experimentally obtained flame shape and thermal radiation values, which confirms the applicability of the model. Based on this model, the characteristics of high-pressure jet flames are systematically studied under different forms of barrier walls and different pressures of hydrogen storage. Compared with the vertical barrier wall, barrier walls with complex structures can block the flames in front of the wall more effectively. This is proven through a remarkable decline in the vertical flame length and a reduction in the high temperature area. Comparing the five barrier wall patterns for their combined flame shape and flame temperature, it is more preferred to choose 60° Plate. The results of this study will help to better analyze the consequences of hydrogen jet flames and provide guidance for better design of barrier walls for mitigation.

Interaction mediated electron transport within the many-body tunnelling Hamiltonian

For a non-superconducting system and in the spirit of the transfer or tunnelling Hamiltonian formalism, an expression for the electronic tunnelling current through an insulating barrier is calculated, explicitly taking into account the effects of electron-electron interactions that can persist across the barrier. In the presence of a single tunnelling barrier, the exact Hamiltonian is projected onto the subspaces of the ‘left’ and ‘right’ conducting leads. In the weak-tunnelling limit, the well-known tunnelling Hamiltonian is recovered, along with an additional term. This additional term originates from the projection of the electron-electron interaction onto each subspace and corresponds to a correlated or interaction-mediated tunnelling. It is shown that the tunnelling current in this approximation is related to—in addition to the single-particle density of states—the two-particle spin-spin and density-density susceptibilities. The signatures of these terms have been observed in scanning tunnelling microscope experiments on atomic spin chains.

Global Distribution and Morphodynamic Patterns of Paired Spits Developed at the Mouths of Interdistributary Bays of Deltas and within Coastal Channels

Previously, paired spits have been described at the mouths of bays, estuaries, and deltas. This study analyzed the worldwide distribution and morphodynamic patterns of paired spits located at the mouths of interdistributary bays of deltas (three systems) and within coastal channels (24 systems). The methodology was based on the detailed analysis of satellite images, nautical charts, and tidal-range databases. The paired spits found were mainly located on microtidal coasts at high or mid latitudes. Waves were the main factor controlling convergent progradation and breaching of the spits, while the hydraulic blockage for the development of these paired spits was mainly due to tide-induced currents, as well as minor fluvial outlets in the interdistributary bays. Three morphodynamic patterns were identified: (i) stable, with low progradation rates, generally without breaching or degradation of any of the spits; (ii) stationary, with high progradation rates, alternating degradation or breaching of any of the spits with the formation of new spits or closure of the breaches; and (iii) instable or ephemeral, which included three subtypes, the severe erosion of one or both spits, the joining of the head of the two spits forming a single barrier, and the merging of each with its channel margin.

A Cross-sectional Survey to Assess Awareness of Syndromic Surveillance by Clinicians Practicing Emergency Medicine: An Opportunity for Education and Collaboration.

Syndromic surveillance (SyS) is an important public health tool using de-identified healthcare discharge data from emergency department (ED) and urgent care settings to rapidly identify new health threats and provide insight into current community well-being. While SyS is directly fed by clinical documentation such as chief complaint or discharge diagnosis, the degree to which clinicians are aware their documentation directly influences public health investigations is unknown. The primary objective of this study was to evaluate the degree to which clinicians practicing in Kansas EDs or urgent care settings were aware that certain de-identified aspects of their documentation are used in public health surveillance and to identify barriers to improved data representation. We distributed an anonymous survey August-November 2021 to clinicians practicing at least part time in emergency or urgent care settings in Kansas. We then compared responses from emergency medicine (EM)-trained physicians to non-EM trained physicians. Descriptive statistics were used for analysis. A total of 189 respondents across 41 Kansas counties responded to the survey. Of those surveyed, 132 (83%) were unaware of SyS. Knowledge did not differ significantly by specialty, practice setting, urban region, age, nor by experience level. Respondents were unaware of which aspects of their documentation were visible to public health entities, or how quickly records were retrievable. When asked about improving documentation for SyS, lack of clinician awareness (71.5%) was perceived as a greater barrier than electronic health record platform usability or time available to document (61% and 59%, respectively). This survey suggests that most practitioners in EM have not heard of SyS and are unaware of the invaluable role certain aspects of their documentation play in public health. Critical information that would be captured and coded into a key syndrome is often missing, but clinicians are unaware of what types of information may be most useful in their documentation, and where to document that information. Lack of knowledge or awareness was identified by clinicians as the single greatest barrier to enhancing surveillance data quality. Increased awareness of this important tool may lead to enhanced utility for timely and impactful surveillance through improved data quality and collaboration between EM practitioners and public health.

Numerical Simulation of the Interaction between Solitary Waves and Underwater Barriers Using a VPM–THINC/QQ-Coupled Model

The interaction between solitary waves and underwater barriers is investigated using our in-house code, entitled VPM (volume-average/point-value multi-moment)–THINC/QQ (THINC method with quadratic surface representation and Gaussian quadrature)-coupled model. The stability and accuracy of the proposed model are validated by comparing the numerical results with those of the well established two-phase flow solver interFoam. All the results indicate that the presented coupled model has the advantage of high fidelity in simulating solitary wave propagation. Subsequently, solitary waves passing over a single underwater barrier are simulated by the present model. Numerical results are compared with experimental results in terms of the free surface elevation, velocity profile, vorticity field, and wave forces. Great agreements are obtained. In the end, the interactions between solitary waves and double underwater barriers are investigated numerically. The results reveal that the reflection coefficient increases first, and then decreases, with the increasing space between the two barriers. For cases with different wave heights, the transmission coefficient decreases monotonically, and the dissipation coefficient is opposed to the transmission coefficient.