Abstract In Canada, geochemical reconnaissance using lake and stream sediments and waters has been a cooperative program between federal and provincial geological survey organizations since the 1970's. Similar methods of sampling, analysis and quality control were established to ensure comparable data across the country. As of 1992, 2.5 million km2, or approximately one quarter of Canada's landmass has been covered. The original purpose of this National Geochemical Reconnaissance (NGR) was to assist mineral exploration. However, with time, the relevance of the data to environmental issues has become increasingly apparent. The concentrations of metals in the natural environment vary widely and in some areas unaffected by human activity may reach levels that elsewhere have been considered to have an effect on the ecosystem. Environmental agencies need to incorporate the natural distribution of metals into assessments of ecosystem health and anthropogenic pollution. Sediment quality guidelines, standards or clean-up criteria, are required for the assessment and remediation of contaminated areas under a variety of programs in Canada. These standards need to take into account the natural background of metals in the affected areas. For instance, under the Canadian Environmental Protection Act, a sediment Cd concentration of 0.6 ppm is used to screen ocean dumping permits and yet 20% of the lake and stream sediment samples collected by the NGR exceed this level naturally. We present Canada-wide maps illustrating the regional variability of As, Cd, Cu, Hg, Ni, Pb, Zn and U in sediments, together with more detailed maps for selected areas. Cumulative frequency distribution plots for these elements plus Cr have been constructed based on up to 250,000 samples. At the scale that the maps are presented, anomalies a few km2 or tens of km2 in extent, which may be associated with individual mineral deposits, are not visible. What may be observed are large, regional anomalies hundreds or thousands of km2 in extent. In some cases these may mark important mineral districts, such as U around the Athabasca and Elliot Lake uranium districts and the suite of metals that are enriched in stream sediments from the Selwyn Basin, Yukon that contains a variety of Sedex, Mississippi Valley and intrusion-related mineral deposits.
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