Similar Density Research Articles

Assessing mammal population densities in response to urbanization using camera trap distance sampling.

Environmental filtering is deemed to play a predominant role in regulating the abundance and distribution of animals during the urbanization process. However, the current knowledge about the effects of urbanization on the population densities of terrestrial mammals is limited. In this study, we compared two invasive mammals (dogs Canis lupus familiaris and cats Felis silvestris) and three indigenous mammals (Siberian weasels Mustela sibirica, Amur hedgehogs Erinaceus amurensis, and Tolai hares Lepus tolai) in response to urbanization using camera trap distance sampling (CTDS) in the rural-urban landscape of Tianjin, China. We used generalized additive mixed models (GAMMs) to test the specific responses of their densities to levels of urbanization. Invasive dogs (2.63 individuals/km2, 95% CI: 0.91-7.62) exhibited similar density estimations to cats (2.15 individuals/km2, 95% CI: 1.31-3.50). Amur hedgehogs were the most abundant species (6.73 individuals/km2, 95% CI: 3.15-14.38), followed by Tolai hares (2.22 individuals/km2, 95% CI: 0.87-5.68) and Siberian weasels (2.15 individuals/km2, 95% CI: 1.06-4.36). The densities of cats, Siberian weasels, and Amur hedgehogs increased with the level of urbanization. The population densities of dogs and cats were only influenced by urban-related variables, while the densities of Siberian weasels and Amur hedgehogs were influenced by both urban-related variables and nature-related variables. Our findings highlight that the CTDS is a suitable and promising method for wildlife surveys in rural-urban landscapes, and urban wildlife management needs to consider the integrated repercussions of urban- and nature-related factors, especially the critical impacts of green space habitats at finer scales.

Power equalization-based disaggregated optical network using switched gain equalization controlled amplifiers.

Optical network disaggregation is an attractive agreement to avoid vendor lock-in in choosing desirable partners based on lead time of delivery and facilitates strong negotiations. Disaggregation of conventional coherent transceivers (XCVRs) with 400G ZR+ technologies (of similar bandwidth density and form factor QSFP-DD) allows operators to enjoy significant cost reduction and substantial power savings in high-capacity IP over a WDM transmission. However, interoperability between low power and high back-to-back required optical signal-to-noise ratio (OSNR) of ZR+ and high power with relatively lower back-to-back required OSNR of conventional coherent XCVRs limits the performance of the latter, which makes disaggregation more complex. This can be avoided by equalizing the power of ZR+ and conventional XCVRs, by wavelength-selective switches (WSSs) in re-configurable optical add/drop multiplexers. However, such power equalization can lead to lower link OSNR, originating from insertion loss and penalty caused by cascaded WSSs. In this Letter, we use a dynamic gain equalizer of a switched gain equalization controlled (SGEC) amplifier at each in-line amplifier site to equalize the powers, without introducing insertion loss or filter penalty. We report a field trial of a low power 400G-ZR+ QSFP-DD-DCO as an alien channel over ten high-power coherent host channels, interoperating with open forward error correction, between two different vendors. We obtain a similar Q-margin in the absence and presence of 400-ZR+ channel, suggesting the equalization by SGEC amplifiers. We further simulate the power and OSNR evolution of channels along the field trial link to verify the equalization. Simulation results are consistent with that of the field trial.

Development of Reproducible and Scalable Culture Conditions for In Vitro Maintenance of Pig Embryonic Stem Cells Using the Sandoz Inbred Swiss Mouse Thioguanine-Resistant Ouabain-Resistant Cell Line as a Feeder Layer.

Feeder cells play a crucial role in maintaining the pluripotency of embryonic stem cells (ESCs) by secreting various extrinsic regulators, such as extracellular matrix (ECM) proteins and growth factors. Although primary mouse embryonic fibroblasts (MEFs) are the most widely used feeder cell type for the culture of ESCs, they have inevitable disadvantages such as batch-to-batch variation and labor-intensive isolation processes. Here, we revealed that the Sandoz inbred Swiss Mouse (SIM) thioguanine-resistant ouabain-resistant (STO) cell line, an immortalized cell line established from mouse SIM embryonic fibroblasts, can be used as a feeder layer for in vitro culture of authentic pig ESCs instead of primary MEFs. First, the expression of genes encoding ECM proteins and growth factors was analyzed to compare their secretory functions as feeder cells. Quantitative real-time polymerase chain reaction (qPCR) showed that the gene expression of these pluripotency-associated factors was downregulated in STO cells compared to primary MEFs of similar density. Therefore, subsequent optimization of the culture conditions was attempted using higher STO cell densities. Notably, pig ESCs cultured on STO cell density of 3 × (187,500 cells/cm2) exhibited the most similar pluripotent state to pig ESCs cultured on primary MEF density of 1 × (62,500 cells/cm2), as determined by alkaline phosphatase staining, qPCR, and immunocytochemistry. In addition, pig ESCs cultured on STO cell density of 3 × formed complex teratoma containing multiple types of tissues derived from all three germ layers. Our culture conditions using optimal STO cell density can be applied to fields requiring reproducible and scalable production of pig ESCs, such as preclinical research and cellular agriculture.

A compact model based on the Lambert function for AlGaN/GaN Schottky barrier gated-edge termination

A compact model based on the Lambert function is used to describe I-V-T characteristics of Schottky Barrier Diodes (SBDs) with gated-edge termination (GET) with either SiN or SiO/AlO as GET dielectric. Electrical parameters obtained from this model enable Schottky barrier height (SBH) assessment. It will be shown that fluctuations are about 17% in both cases. Similar interface state density (from ideality factor) is obtained which is consistent with previous work and validates this approach as an interesting method to model these GET-SBDs.

Determination of suitable species combination of two small indigenous fish species (SIS) pabda (Ompok pabda) and gulsha (Mystus cavasius) with rohu (Labeo rohita) in farmers’ pond

An experiment was carried out from May to September, 2018 to determine the suitable species combination of two indigenous fish Pabda (Ompok pabda) and Gulsha (Mystus cavasius) with Rohu in farmer’s pond. Three species combinations (% of total stocking densities) Gulsha: Pabda = 60: 40 at T1, 40: 60 at T2, and 50: 50 at T3 were tested. Stocking of Rohu were similar (2964/ha) for all the treatments. Similar stocking density (200564/ha) was maintained in all the treatments. The production obtained were 7138.30±63, 6977.75±78 and 7037.03±84 kg/ha from T1, T2 and T3 respectively. The highest production was obtained from T1 compared to other treatments. A straightforward economic analysis showed that treatment T1 (BCR -1.94, net profit: Tk.12,94,576/ha/6 months) had the highest benefit-cost ratio (BCR) and net profit, subsequent to treatment T3 (BCR -1.87, net profit: Tk.12,74,685/ha/6 months) and treatment T2 (BCR-1.93, net profit: Tk.12,02,956/ha/6 months). Therefore, it might be concluded that the species combination of pabda, gulsha and rohu followed by T1 may be a better option considering the production and economic benefits to farmer’s ponds in our country. Res. Agric. Livest. Fish. Vol. 10, No. 2, August 2023: 219-228

The Accuracy Assessment of Lithospheric Density Models

The Earth’s synthetic gravitational and density models can be used to validate numerical procedures applied for global (or large-scale regional) gravimetric forward and inverse modeling. Since the Earth’s lithospheric structure is better constrained by tomographic surveys than a deep mantle, most existing 3D density models describe only a lithospheric density structure, while 1D density models are typically used to describe a deep mantle density structure below the lithosphere-asthenosphere boundary. The accuracy of currently available lithospheric density models is examined in this study. The error analysis is established to assess the accuracy of modeling the sub-lithospheric mantle geoid while focusing on the largest errors (according to our estimates) that are attributed to lithospheric thickness and lithospheric mantle density uncertainties. Since a forward modeling of the sub-lithospheric mantle geoid also comprises numerical procedures of adding and subtracting gravitational contributions of similar density structures, the error propagation is derived for actual rather than random errors (that are described by the Gauss’ error propagation law). Possible systematic errors then either lessen or sum up after applying particular corrections to a geoidal geometry that are attributed to individual lithospheric density structures (such as sediments) or density interfaces (such as a Moho density contrast). The analysis indicates that errors in modeling of the sub-lithospheric mantle geoid attributed to lithospheric thickness and lithospheric mantle density uncertainties could reach several hundreds of meters, particularly at locations with the largest lithospheric thickness under cratonic formations. This numerical finding is important for the calibration and further development of synthetic density models of which mass equals the Earth’s total mass (excluding the atmosphere). Consequently, the (long-to-medium wavelength) gravitational field generated by a synthetic density model should closely agree with the Earth’s gravitational field.

A remarkably stable accretion disc in the Seyfert galaxy MCG-5-23-16

ABSTRACT MCG-5-23-16 is a Seyfert 1.9 galaxy at redshift z = 0.008 49. We analyse here the X-ray spectra obtained with X-ray Multi-Mirror (XMM)-Newton and Nuclear Spectroscopic Telescope Array (NuSTAR) data, which are the first contemporaneous observations with these two X-ray telescopes. Two reflection features, producing a narrow core and a broad component of the Fe Kα, are clearly detected in the data. The analysis of the broad iron line shows evidence of a truncated disc with inner radius $R_{\rm in}=40^{+23}_{-16}$Rg and an inclination of $41^{+9}_{-10}$°. The high quality of the NuSTAR observations allows us to measure a high-energy cut-off at $E_{\rm cut}=131^{+10}_{-9}$ keV. We also analyse the reflection grating spectrometer spectrum, finding that the soft X-ray emission is produced by two photoionized plasma emission regions, with different ionization parameters and similar column densities. Remarkably, the source only shows moderate continuum flux variability, keeping the spectral shape roughly constant in a time-scale of ∼20 yr.

Comparable dark matter and baryon abundances with a heavy dark sector

We propose a scenario that explains the comparable abundances of dark matter (DM) and baryons without any coincidence in the corresponding particle masses. Here, DM corresponds to heavy “dark baryons” in a hidden MSSM-like dark sector, where the supersymmetry breaking scale can be several orders of magnitude larger than in the visible sector. In both sectors a baryon asymmetry is generated via the Affleck-Dine mechanism, and the smaller dark baryon-to-entropy ratio partially compensates the larger dark baryon masses to give similar densities in the two sectors. The large mass hierarchy also naturally results in an asymmetric reheating of these sequestered sectors. Moreover, this scenario predicts uncorrelated DM and baryon isocurvature perturbations.

Analysis of the mechanical behavior of polyurethane thermoset elastomers based on hydrogen bonding between different crosslinking point structures

To reveal the effect of polyurethane crosslinking point structures on the mechanical properties of polyurethane thermoset elastomers, using amorphous prepolymer poly (azide glycidyl ether) (GAP) as a binder, polyisocyanate cross-linker N100 and hexamethylene diisocyanate (HDI) as curing agents, trimethylolpropane (TMP) as a crosslinking agent, two GAP polyurethane thermoset elastomers that have similar chemical crosslinking network density, elastomer S0 prepared from GAP and N100 and elastomer S4 prepared from GAP and HDI/TMP, were selected to study in detail. DSC and XRD analysis indicated that two GAP polyurethane thermoset elastomers both exhibit stable amorphous aggregation structure below 80 °C. Mechanical properties test showed that thermoset elastomer S0 gives higher tensile modulus, lower tensile strength and elongation rate, while thermoset elastomer S4 gives lower tensile modulus, higher tensile strength and elongation rate. In-situ FTIR and low field nuclear magnetic resonance (LF-NMR) analysis suggested that there exists stronger urea carbonyl hydrogen bonding structure within thermoset elastomer S0, while weaker urethane carbonyl hydrogen bonding structure within thermoset elastomer S4. The different strength of the hydrogen bonding between crosslinking points imparts different segment mobility to S0 and S4. Dynamic thermodynamic analysis (DMA) indicated that, stronger urea carbonyl hydrogen bonding has suppressed segments mobility and thermoset elastomer S0 present lower loss modulus and loss factor, while thermoset elastomer S4 present higher loss modulus and loss factor because there just exist weaker urethane carbonyl hydrogen bonding interaction between crosslinking points.

Comparative analysis of process-induced strain glass states in austenitic and martensitic NiTi shape memory alloy plates

Strain glass alloys (SGAs) are metallic alloys with glassy martensitic nanodomains within a crystalline material that occur from compositionally or processing-induced strain. SGAs originate from shape memory alloys (SMAs) and exhibit similar shape memory properties and high actuation densities. The transition from SMA to SGA is relatively unexplored, and although there are similarities to amorphous SMAs and cold-worked SMAs, SGAs should be distinguished as a separate grouping. The transition occurs by interrupting the long-range martensitic order, which in turn disrupts the martensitic transformation, resulting in short-range martensitic order. A glassy martensitic phase is produced that exhibits enhanced structural and load-bearing abilities, functional stresses, and recoverability. In this study, the transformation from SMA to SGA is explored in two common commercially available SMAs, Ni49.5Ti50.5 and Ni50.8Ti49.2 (at. %), to compare martensitic versus austenitic SGAs, respectively. SMA plates were cold worked in 5% increments until a strain glass transition occurred. Characterizations of the samples at various stages of cold work were examined via differential scanning calorimetry (DSC), Vickers hardness, transmission electron microscopy (TEM), and synchrotron radiation X-ray diffraction (SR-XRD). Some prominent characteristics between the two plates, such as enthalpy peaks, twin size reduction, and crystallographic structure, were examined and compared to improve the understanding of the SMA to SGA transition.

Multi‐Energy X‐Ray Linear‐Array Detector Enabled by the Side‐Illuminated Metal Halide Scintillator

AbstractConventional scintillator‐based X‐ray imaging typically captures the full spectral of X‐ray photons without distinguishing their energy. However, the absence of X‐ray spectral information often results in insufficient image contrast, particularly for substances possessing similar atomic numbers and densities. In this study, an innovative multi‐energy X‐ray linear‐array detector is presented that leverages side‐illuminated X‐ray scintillation using the emerging metal halide Cs3Cu2I5. The negligible self‐absorption characteristic not only improves the scintillation output but is also beneficial for improving the energy resolution for the side‐illuminated scintillation scenarios. By exploiting Beer's law, which governs the absorption of X‐ray photons with different energies, the incident X‐ray spectral can be reconstructed by analyzing the distribution of scintillation intensity when the scintillator is illuminated from the side. The relative error between the reconstructed and measured X‐ray spectral is < 5.63%. This method offers an additional energy‐resolving capability for X‐ray linear‐array detectors commonly used in computed tomography (CT) imaging setups, surpassing the capabilities of conventional energy‐integration approaches, all without requiring extra hardware components. A proof‐of‐concept multi‐energy CT imaging system featuring eight energy channels is successfully implemented. This study presents a simple and efficient strategy for achieving multi‐energy X‐ray detection and CT imaging based on emerging metal halides.

Enhanced corrosion resistance, antibacterial properties and osteogenesis by Cu ion optimized MgAl-layered double hydroxide on Mg alloy

Magnesium (Mg) and its alloys have similar densities and elastic moduli to natural bone, making them an excellent choice for orthopedic implants. However, Mg alloys are prone to electrochemical corrosion, which often leads to implant failure and hinders the further development of Mg alloys due to bacterial infection around the implant. This work aims to enhance the corrosion resistance of Mg alloys, and provide theoretical guidance for solving the problem that Mg-based orthopedic implants are susceptible to bacterial infection and, thus, implant failure. In order to solve the corrosion problem, the Mg alloy AZ91D was used as the substrate, and a compact and uniform MgAlCu-layered double hydroxide (Mg(Cu)-LDH) was prepared on its surface using a hydrothermal method. The Mg(Cu)-LDH provides a barrier between the AZ91D and corrosive liquid, which effectively protects the Mg substrate from being corroded. The Mg(Cu)-LDH shows great cell viability for MC3T3-E1 cells. The Cu2+ and Mg2+ in the coating also endow the Mg(Cu)-LDH/AZ91D with antibacterial properties, showing strong antibacterial effects on both E. coli and S. aureus with antibacterial rates over 85%. Finally, in vivo results indicated that a LDH-coated implant had no systemic effects on the hearts, livers, spleens, lungs or kidneys. It was shown that 4 weeks after surgery the ratio of bone volume to tissue volume (BV/TV) of the LDH implant was 24%, which was 1.7 times that observed for AZ91D.

What must be considered in winter strawberry production under LEDs in Iceland?

ABSTRACT Supplementary lighting is essential to maintain year-round production in Iceland due to the extremely low natural light level in winter. In this research, the effects of high-pressure vapour sodium lamps (HPS) are compared to light emitting diodes (LED), both with similar photosynthetic photon flux density (PPFD). Strawberries (Fragaria x ananassa cv. ‘Sonata' and cv. ‘Magnum') were grown either under HPS lights or LEDs and 16°C/8°C (day/night). However, in the second winter, the day temperature was increased to 19°C under LEDs. The results showed that under the same temperature set points, the development of the flowers and the harvest was delayed by two weeks under LEDs due to a lower leaf, substrate and air temperature. However, when temperature set points were adapted, no delay under LEDs was observed. LEDs did not lead to higher yield, but to a higher energy use efficiency, while light use efficiency behaved contrary. Economic calculations clearly demonstrate that it is not justified to switch from HPS lights to LEDs. Instead, it is rather recommended to emphasise a high-yielding variety like Sonata in winter-growing of strawberries.

Plasma sputtering of biased electrodes in an oblique magnetic field

The surface erosion of biased electrodes immersed in a radio frequency (RF) plasma was investigated in oblique magnetic fields ranging from 0.1 T to 3.5 T. The plasma potential and density in the vicinity of the biased electrode have been measured using an RF-compensated cylindrical Langmuir probe moved by a three-dimensional motorised arm in the ALINE facility at 0.1 T. The erosion profiles were determined for different gases (argon and helium), magnetic field strength and plasma volume for the same electrode surface area at an angle of 5∘ with the magnetic field in three different experimental geometries. The radial electric field (perpendicular to the magnetic field) in the plasma column has been deduced from plasma potential measurements. This radial field makes the ions converge to the core of the plasma column at grazing angles (30∘) and is reversed at larger angles. The ion flux on the sample increases with the magnetic field magnitude leading to a strong erosion inhomogeneity. At lower plasma volume, the erosion rate is sensitively enhanced. Local redeposition was identified using x-ray photoelectron spectroscopy on the surfaces exhibiting preferential deposition directions. Finally, the asymmetric erosion patterns obtained from a molybdenum layer etching are explained by the similar asymmetric density maps obtained with the probe and by the drift and the local sheath acceleration.

Radiative cooling effects on reverse shocks formed by magnetized supersonic plasma flows

We study the structure of reverse shocks formed by the collision of supersonic, magnetized plasma flows driven by an inverse (or exploding) wire array with a planar conducting obstacle. We observe that the structure of these reverse shocks varies dramatically with wire material, despite the similar upstream flow velocities and mass densities. For aluminum wire arrays, the shock is sharp and well-defined, consistent with magneto-hydrodynamic theory. In contrast, we do not observe a well-defined shock using tungsten wires, and instead we see a broad region dominated by density fluctuations on a wide range of spatial scales. We diagnose these two very different interactions using interferometry, Thomson scattering, shadowgraphy, and a newly developed imaging refractometer that is sensitive to small deflections of the probing laser corresponding to small-scale density perturbations. We conclude that the differences in shock structure are most likely due to radiative cooling instabilities, which create small-scale density perturbations elongated along magnetic field lines in the tungsten plasma. These instabilities grow more slowly and are smoothed by thermal conduction in the aluminum plasma.

Localized Corrosion Behavior and the Relationship to the Second Phases in Biodegradable ZX21 Mg Alloy in Hanks' Balanced Salt Solution

Mg alloys are considered promising biodegradable implant materials owing to their high activity, which makes Mg alloys degradable in the human body and can avoid second removal surgeries. Also, compared with other biodegradable implant materials, Mg alloy has a similar density and Young’s modulus to human bones, which minimizes the stress shielding effect. ZX series Mg alloys, which contain Zn and Ca, are designed to increase the alloy strength but maintain biocompatibility. However, even with all the advantages, the high degradation rate limits the clinical applications of ZX series Mg alloys. With fast degradation, not only the mechanical properties are affected, but also a large amount of hydrogen gas and hydroxide ions would accumulate around the implant in the patient. Therefore, it is essential to investigate the corrosion mechanism of the ZX series Mg alloys to mitigate the degradation rates.Localized corrosion is one of the noticeable features in the corrosion process of ZX series Mg alloys, which is the main reason for the low corrosion resistance and high degradation rate of the alloy. However, the origin and detailed mechanism of the initiation and propagation of localized corrosion on ZX series Mg alloys are still unclear. The second phases, which contain Zn and Ca, play complex roles in the corrosion process owing to the inhomogeneous elemental distribution and different electrochemical potentials with respect to the Mg alloy matrix. Thus, this study aims to investigate the microstructure of the localized corrosion sites and the galvanic effects around the second phases in a ZX series Mg alloy.In this study, an Mg-2 wt%Zn-1 wt%Ca (ZX21) alloy was prepared, and the localized corrosion behavior was investigated in a Hanks’ balanced salt solution (HBSS) at 37°C. By scanning electron microscope (SEM)/focused ion beam (FIB) cross-sectional observations, two kinds of second phases were identified in the ZX21 Mg alloy, one is enriched with Zn and the other is not. After immersion in HBSS, galvanic corrosion sites were found in the Mg alloy matrix next to the second phase enriched with Zn, while the Mg alloy matrix next to the second phase with lower Zn concentration was intact. Furthermore, the second phases in the ZX21 Mg alloy were found to hinder the propagation of localized corrosion. The complex roles of the second phases in the ZX21 Mg alloy on the localized corrosion behavior will be discussed based on electrochemical measurements and microstructure characterizations. Figure 1

Silvicultural canopy gaps improve health and growth of eastern hemlocks infested with Adelges tsugae in the southern Appalachian Mountains

The hemlock woolly adelgid (HWA, Adelges tsugae Annand) is an invasive forest insect threatening the sustainability of eastern hemlock (Tsuga canadensis (L.) Carrière) in eastern North America. In this study, cutting small gaps in the forest canopy above understory eastern hemlocks was evaluated as a potential tool for use in the integrated pest management of HWA. Two gap sizes and two gap creation methods (felling vs. girdling trees) were assessed for effects on HWA density, hemlock crown health, hemlock growth, and regeneration of competing tree species, at three different latitude groups in the southern Appalachian Mountains. In all three latitude groups, the treatment that removed the most canopy competition (Large Fell) increased the production of new hemlock shoots, reduced the percentage of dead shoots, and increased basal area increment of target hemlocks relative to unreleased trees. Smaller gaps and those that removed fewer competing live trees (Girdle treatments) also improved hemlock health in the southernmost latitude group. Positive effects of canopy gaps on hemlock crown condition and growth occurred despite similar or higher HWA densities on gap-released vs. unreleased trees. In regression analysis, more than half the variability in crown transparency change and basal area growth post-treatment was explained by the competition index of live trees remaining, average HWA density index, and tree size (dominant tree height and hemlock dbh). In the southernmost latitude group, the regeneration density of deciduous species increased significantly in the three years following gap creation and were highest in the Large Fell treatment. Results support the hypothesis that the increased availability of sunlight (and possibly other limited resources) resulting from canopy gaps (radius approximately ¼ to ½ dominant tree height) improves the physiological tolerance of eastern hemlock to HWA infestation and could complement biological control by providing a more stable source of new shoots with adelgid prey for predatory insects.

(Digital Presentation) The Utilization of Platinum Catalysts Deposited on Carbon Support Synthesized from Coffee Grounds in a Polymer Electrolyte Membrane Fuel Cell

Exploring alternative sources for platinum catalyst carbon support material is vital for the further development of polymer electrolyte membrane fuel cells (PEMFC).1 The support material and the method of depositing Pt nanoparticles are crucial for defining the catalytic properties of the catalyst. In this study, carbon support material, derived from coffee grounds was used in the preparation of Pt catalysts for PEMFC application. The carbon material was synthesized using ZnCl2 activated pyrolysis method2 and the Pt nanoparticles were deposited onto carbon support by two methods: using ethylene glycol3 or hydrogen4 as a reducing agent.The physical properties of the support material, as well as catalysts were analysed through thermogravimetric analysis (TGA), dynamic light scattering, X-ray diffraction (XRD), N2 sorption analysis and high-resolution scanning electron microscopy (HR-SEM) methods. The electrochemical activity, as well as the electrochemically active surface area (ECSA) of the catalysts were determined in a completed PEMFC. The properties and performance of catalysts synthesised were compared with the catalyst which was deposited onto commercial carbon (Ketjenblack, EC-300J).TGA displayed that carbon derived from coffee grounds contained 6.9 % of impurities by mass in the form of metal oxides and that the coffee carbon Pt catalyst contained 60 wt% of Pt. The Pt crystallite size was determined through XRD and it was 1.4 nm. HR-SEM analysis displayed that the average particle size of Pt nanoparticles on the coffee carbon catalyst was 4.7±2.5 nm. Results from N2 sorption analysis showed that all materials were micro-mesoporous, with coffee ground carbon having a specific surface area of 590 m2 g-1. The coffee carbon Pt catalyst produced smaller results of 370 m2 g-1 compared to the carbon support, due to the Pt nanoparticles depositing in the micropores, however still had a larger specific surface area than the commercial carbon catalyst with a specific surface area of 300 m2 g-1.Catalysts deposited on coffee ground carbon produced comparable electrochemical results to catalysts deposited on commercially available carbon. The coffee carbon catalyst produced a higher ECSA of 64 mPt 2 gPt -1, compared to the commercial carbon catalyst with an ECSA of 51 mPt 2 gPt -1. The current density of the Pt catalyst deposited onto coffee carbon was 0.68 A cm-2 at 670 mV, whilst in the same conditions commercial carbon peaked at 0.70 A cm-2. Both coffee and commercial carbon Pt catalysts produced similar power density maximums with the coffee Pt catalyst producing 0.56 W cm-2 and the commercial Pt catalyst producing 0.60 W cm-2.Physical and electrochemical characterizations displayed that higher ECSA values were strongly correlated to smaller Pt crystallite size. Other techniques to increase fuel cell performance were also experimented with, such as covering the gas diffusion layer with catalyst instead of Nafion membrane and adding additional Nafion layers, with both methods producing promising results.This study displays that there is a lot of potential in improving the catalytic performance of Pt catalysts by depositing on support materials derived from alternative sources. The methods of boosting PEMFC performance could be further investigated for catalysts deposited on different carbon supports. Acknowledgements This work was supported by the EU through the European Regional Development Fund TK141 “Advanced materials and high-technology devices for energy recuperation systems” (2014-2020.4.01.15-0011), Personal Research Grant PRG676 and by private limited company AuVe Tech LLTKT20148 “Production of Polymer Electrolyte Membrane Fuel Cells”. The SEM measurements were conducted using the NAMUR+ core facility funded by the Estonian Research Council (TT 13). References S. Shahgaldi and J. Hamelin, Carbon, 94, 705-728 (2015). M. Härmas, PhD thesis, University of Tartu, Tartu, Estonia (2020). Y. Shao, S. Zhang, R. Kou, X. Wang, C. Wang, S. Dai, V. Viswanathan, J. Liu, Y. Wang, Y. Lin, J. Power Sources 195, 1805-1811 (2010). Y. Zheng, Z. Dou, Y. Fang, M. Li, X. Wu, J. Zeng, Z. Hou, S. Liao, J. Power Sources, 306, 448-453 (2015).

Biomolecular Mechanisms and Case Series Study of Socket Preservation with Tooth Grafts.

Twenty patients requiring tooth extraction underwent socket preservation utilizing the extracted tooth as the grafting material. After a 4-month healing period, the defects were significantly filled with newly formed hard tissue. Subsequently, bone biopsies were performed during dental implant placement to evaluate histological outcomes. The tissue exhibited a similar density to medium-density bone, displaying a homogeneous and uniform appearance without any visible signs of inflammation. The post-operative healing phase was free from infective complications or indications of graft particles within the regenerated bone structure. The histomorphometric analyses revealed the following results: bone total volume, BV% 52.6 ± 13.09, vital bone VB% 40.39 ± 15.86, residual graft % 12.20 ± 12.34. The study demonstrated positive bony healing in guided regenerative surgery procedures using autologous tooth grafts. However, further research with an extended follow-up period is necessary to thoroughly assess the potential of demineralized dentin autografts.

Two-Step Flux Synthesis of Ultrapure Transition-Metal Dichalcogenides.

Two-dimensional transition-metal dichalcogenides (TMDs) have attracted tremendous interest due to the unusual electronic and optoelectronic properties of isolated monolayers and the ability to assemble diverse monolayers into complex heterostructures. To understand the intrinsic properties of TMDs and fully realize their potential in applications and fundamental studies, high-purity materials are required. Here, we describe the synthesis of TMD crystals using a two-step flux growth method that eliminates a major potential source of contamination. Detailed characterization of TMDs grown by this two-step method reveals charged and isovalent defects with densities an order of magnitude lower than those in TMDs grown by a single-step flux technique. For WSe2, we show that increasing the Se/W ratio during growth reduces point defect density, with crystals grown at 100:1 ratio achieving charged and isovalent defect densities below 1010 and 1011 cm-2, respectively. Initial temperature-dependent electrical transport measurements of monolayer WSe2 yield room-temperature hole mobility above 840 cm2/(V s) and low-temperature disorder-limited mobility above 44,000 cm2/(V s). Electrical transport measurements of graphene-WSe2 heterostructures fabricated from the two-step flux grown WSe2 also show superior performance: higher graphene mobility, lower charged impurity density, and well-resolved integer quantum Hall states. Finally, we demonstrate that the two-step flux technique can be used to synthesize other TMDs with similar defect densities, including semiconducting 2H-MoSe2 and 2H-MoTe2 and semimetallic Td-WTe2 and 1T'-MoTe2.