Simao Basin Research Articles

K, Sr isotopes, and trace element to constrain potash origin in the Simao Basin, southwestern China, and insight into K isotope geochemical behavior in evaporite

K, Sr isotopes, and trace element to constrain potash origin in the Simao Basin, southwestern China, and insight into K isotope geochemical behavior in evaporite

Cretaceous magnetostratigraphy of the southern Simao Basin, SE Tibetan Plateau, and its paleogeographic implications

Precise stratigraphic chronology is the basis of many studies (e.g., tectonic, paleoclimate, and mineralization) in geoscience. Here, we carried out a detailed youngest detrital zircon U-Pb age-constrained magnetostratigraphic study on the middle-lower parts of a 2309-m-thick Upper Jurassic−Lower Cretaceous sequence from west Jiangcheng in the southern Simao Basin, southeastern Tibetan Plateau. A total of 2262 paleomagnetic samples were collected for magnetostratigraphy, and five siltstone/sandstone samples were collected for detrital zircon U-Pb analyses. Progressive thermal and alternating field demagnetizations isolated 1575 well-defined interpreted primary characteristic remanent magnetization directions, which yielded 25 normal polarity (N7−N31) and 25 reverse polarity (R8−R32) magnetozones. The interpreted maximum depositional ages calculated using the youngest detrital zircon U-Pb dates are 159.0 Ma, 154.0 Ma, 161.0 Ma, 149.3 Ma, and 139.5 Ma for the stratigraphic horizons at 2303 m, 1986 m, 1600 m, 1350 m, and 1110 m, respectively, in the section. Together with the previous magnetostratigraphic results of the upper part of the section, the observed polarity zones are best correlated with chrons C34n−M17r of the geomagnetic polarity timescale (GPTS2012), yielding magnetostratigraphic age estimates of ca. 143.5 Ma to ca. 65.0 Ma for the entire stratigraphic sequence. Paleogeographic analysis shows that the Simao Basin was in a low-latitude offshore environment during the Late Jurassic−earliest Cretaceous (before 142.3 Ma), a dominant fluvial environment during the early−middle Early Cretaceous (142.3−111.5 Ma), with widespread desertification at the end of this period, a saline lake sedimentary environment during the late Early Cretaceous−early Late Cretaceous (111.5−88.7 Ma), and a fluvial environment during the late Late Cretaceous (88.7−65.0 Ma). The changes in depositional environment are consistent with regional/global tectonic and paleoclimate changes, such as the dismission of Pangea, the termination of the megamonsoon, and the closure of the Meso-Tethys Ocean.

Mesozoic evolution of large-scale drainage systems in the Indochina Block: evidence from palaeomagnetic and U–Pb geochronological constraints

The collage of the Indochina Block to the Eurasian continent during the Mesozoic resulted in major changes in source-to-sink systems of East Asia, whilst the sedimentation in the Khorat–Simao Basin of the Indochina Block transited from marine to continental environments. Previous studies uncovered the existence of transcontinental river systems in the East Asia mainland during the Cretaceous to Early Cenozoic, although there have been few studies on pre-Cretaceous drainage systems. To determine the impact on the evolution of palaeo-drainage systems triggered by tectonic movement of the Indochina Block, we performed palaeomagnetic and U–Pb geochronologic analyses on the Late Triassic to Early Cretaceous sedimentary rocks in the Simao Basin. Palaeomagnetic data indicate stable Jurassic tectonic environments between the Indochina and Songpan–Ganzi–South China blocks, following their Late Triassic collision. Based on detrital zircon U–Pb dating, the Late Triassic age spectra consist mainly of Phanerozoic components, while the Jurassic to Cretaceous age spectra display more Precambrian age peaks. The contribution of potential provenance to the Simao Basin changed during the Early Cretaceous, suggesting several sedimentary provenance transitions. Also, we believe that large continental-scale drainage systems flowing through the North Qiangtang, Sichuan, Simao and Khorat Basins were sourced from the Songpan–Ganzi Block since the end of the Late Jurassic. Supplementary material: The findings of a quantitative statistical study (Fig. S1; Table S5), the location of the Late Triassic to Early Cretaceous samples from the Simao Basin (Table S1), palaeomagnetic poles for Eurasia, South China, Indochina, North Qiangtang and Tarim (Table S2), the result of quantitative analysis for the Late Triassic and Middle Jurassic sedimentary rocks from the Simao and Sichuan basins (Table S3), and results of zircon U–Pb dating (Table S4) are available at https://doi.org/10.6084/m9.figshare.c.6862918 Thematic collection: This article is part of the Mesozoic and Cenozoic tectonics, landscape and climate change collection available at: https://www.lyellcollection.org/topic/collections/mesozoic-and-cenozoic-tectonics-landscape-and-climate-change

Metal sources and fluid pathways of karst-hosted Mississippi Valley-type Zn–Pb deposits in the fold-thrust belt: A case study of the Changdong deposit in the southeastern Himalayan-Tibetan orogen

The metal sources and fluid pathways for Mississippi Valley-type (MVT) Zn–Pb deposits in fold-thrust belts remain open topics of debate. To develop a more comprehensive understanding of these issues, this study presents the sulfide morphology, S and Pb isotopes, and trace element data of the paleokarst-hosted Changdong MVT Zn–Pb deposit in the “Sanjiang” fold-thrust belt. Bulk Pb isotopic ratios for galena were homogenous and indicated potential metal sources. These sources include Triassic to Early Jurassic volcanic rocks at the western margin of the Simao Basin, Cenozoic intrusive rocks at the eastern margin, and Jurassic clastic rocks. The spatial distribution of the in situ Pb isotopic ratios, combined with the spatial relationship between the faults and ore bodies, suggest that the tensile faults acted as vertical pathways for the fluid. The galena grains displayed oscillatory zones of As and Sb elements, indicating that alternating ore-forming fluids with varying chemical compositions entered the local reservoir. The δ34SV-CDT values of sulfides in substage I range from −19.3 to 29.6 ‰, and in substage II, they range from −21.2 to 52.6 ‰. The high fractionation degree (approximately 38.9 ‰) and the presence of microspherulitic morphology suggest that the reduced sulfur originated from a bacterial sulfate reduction. A GGIMFis geothermometer revealed that the precipitation temperatures of substage I sphalerite ranged from 56.68 to 211.58 °C and were higher than substage II. This indicated that the mixing of Zn–Pb-bearing fluid with reduced sulfur was the main controlling factor for sphalerite precipitation, and the temperature decrease represented another important factor. In the fold-thrust system, the complete process of Zn–Pb mineralization was established as follows: the fluid extracted metals from regional rocks and then migrated laterally over long distances. During the regional transition from compression to extension, metal-bearing fluid was injected into the deposit along the normal faults through seismic pumping. The fluid was then mixed with reduced sulfur to precipitate Zn–Pb sulfides. This study provides new insights into the metal sources and fluid pathways of MVT Zn–Pb deposits developed in a fold-thrust belt.

Genesis of Pyrite in Clastic Rocks of Deep Salt-Related Strata in the Simao Basin and Its Implication for Potash Mineralization: A Case Study of the Well MK-3

In depth of the Simao Basin (2390 to 2650 m depth interval), many gray mudstone or carbonate rocks are developed in the red salt-related strata, and pyrite crystals are found in the fissure and matrix. In this study, petrology, mineralogy, element geochemistry, and LA-MC-ICP-MS in situ sulfur isotope analysis were used to constrain the genesis of pyrite, and the influence of relevant geological activities on potash mineralization was discussed. The results show that: (1) In the upper part of the salt layer, particle size of the pyrite ranges from 50 to 300 μm. The crystal morphology is mainly pentagonal-dodecahedral and irregularly granular, with a small amount of cuboidal pyrite. In the interlayer between rock salt, particle size of the pyrite is from 50 to 100 μm, and the crystals are mainly octahedral. (2) The S/Fe value of pentagonal-dodecahedral pyrite is significantly greater than 2; the S/Fe value of octahedral and cubic pyrite is less than 2; and the S/Fe value of irregular granular pyrite is close to 2. (3) The δ34SV-CDT values of pyrite in the upper salt-related strata range from −15.65‰ to 11.81‰, and the average δ34SV-CDT values of all samples range from 0.79‰ to 8.20‰. The δ34SV-CDT values of pyrite interlayer between rock salt range from −15.02‰ to −6.36‰, with an average value of −10.66‰. The above results indicate that the pyrite in the upper part of the rock salt layer was formed in a medium-low temperature hydrothermal environment, and the ore-forming sulfur elements have hydrothermal sources, bacterial sulfate reduction (BSR) sources, and thermochemical sulfate reduction (TSR) contributions. The pyrite between the rock salt layers is of sedimentary origin, and the ore-forming sulfur element comes from BSR. At present, there is no evidence of the influence of hydrothermal activities on deep potash-rich salt bodies, and the influence on the Mengyejing potash deposit has continued since the metallogenic period.

The underestimated role of tectonics in the mid-Late Cretaceous desertification in SE Asia

The relative roles of tectonics and climate change in global and regional desertification are not well constrained. Previous studies have emphasized the role played by climate change as a dominant cause of southeastern (SE) Asia desertification during the mid-Late Cretaceous. The effect of early uplift of the Tibetan Plateau prior to the collision between Eurasia and India on regional desertification remains poorly understood. We present a comprehensive set of provenance data on two aeolian sequences deposited in the Simao Basin and Khorat Plateau desert environments adjacent to southeast Tibet. Our provenance results suggest that the aeolian sandstones of the Pashahe Formation in the Simao Basin were largely recycled from exposed sedimentary rocks of the Songpan-Garze terrane, Southern Qiangtang terranes, and northern Yangtze Block with minor contributions from the magmatic rocks of the Tengchong and Southern Qiangtang terranes. Combined with other evidence, provenance results indicate the source areas started to grow and to be rapidly unroofed and determined the birth of the transcontinental southerly flowing paleo-river, which carried the sand to be stored. In contrast, the Phu Thok aeolian sandstones in the Khorat Plateau were predominantly sourced from the exposed Sibumasu igneous rocks together with recycled detritus in the Sukhothai Arc terrane, which was possibly transported by a local river. Hence, our thesis is that elevated topography caused by the closure of the Bangong-Nujiang Mesotethys profoundly affected the atmospheric circulation and drainage development, leading to mid-Late Cretaceous desertification across SE Asia.

Origin of Halite in the Lanping–Simao Basin, Southeastern Tibetan Plateau, China: Evidence from Sr and Cl Isotopes

AbstractThe Lanping–Simao Basin is located on the southeastern Tibetan Plateau, China, and contains massive evaporites. The origin of evaporites in the basin has been hotly debated because of the strong transformation by tectonic movement. Forty halite samples from borehole MK‐3 in the Mengyejing area of the basin were collected and analyzed using XRD, Cl‐Sr isotopes and chemical compositions to trace the origin of the evaporites in the basin. The Br × 103/Cl ratios of the halite samples are between 0 and 0.55, most of which are synchronized with the law of seawater evaporation and at the stage of halite precipitation from seawater, indicating that the evaporites are mainly of marine origin. The 87Sr/86Sr ratios range from 0.707489 to 0.711279; after correction, the 87Sr/86Sr 145 Ma ratios range from 0.704721 to 0.707611, equivalent with the 87Sr/86Sr ratios of seawater at 145 Ma, indicating a marine origin. The decay of 87Rb in the evaporite during deposition, change of the depositional environment and the unsealed environment at a later period resulted in the present 87Sr/86Sr ratios of some samples being high. The δ37Cl value compositions range from –0.38‰ to 0.83‰, which is consistent with the δ37Cl value composition of the world marine halite (–0.6‰ to 0.4‰), further confirming that seawater is the main origin. In addition, the high δ37Cl value of some samples at the boundary of the upper and lower evaporite layers might be related to the influence of δ37Cl‐rich brine and the incomplete dissolution of the halite.

A tuff interlayer in deep potash-bearing salt rocks and its implication for potash mineralization in the Simao Basin, southwestern China

The lithology and genesis of a dark grey clastic interlayer first encountered within the deepest potassium-rich salt body in the Simao Basin, southwestern China, were analysed. Analyses of the petrography, mineralogy, and element geochemistry of the layer revealed that (1) the layer contains quartz crystals with gulf corrosion edges and explosion cracks and angular volcanic ash-sized glasses; (2) the main mineral components of the crystal fragments are chlorite, illite, biotite, quartz, anhydrite, gypsum, magnesite, pyrite, molybdenite, clinopyroxene, and zircon; (3) the rare earth element patterns, Zr/TiO2 and Nb/Y diagrams as well as boron content all indicate a volcanic origin for the layer. Based on these observations, the layer is suggested to be an altered tuff associated with various volcanic fragments dominated by chlorite and formed after alteration of a parent tuff in an alkaline, salty, and low-temperature water body. Discovery of the layer indicates that the potash-bearing salt rocks could have taken in volcanic materials during these volcanic activities and provides the possibility of reliable zircon U‒Pb dating to determine the absolute age of the host rock, which is fundamental in studying the genetic mechanism of this deeply buried salt body.

Age of the Mengyejing potash deposit in the Simao Basin, southwest China: Constraints from detrital zircon U-Pb ages

The age of the Mengyejing potash deposit (MPD) in the Simao Basin, the only pre-Quaternary economically exploitable solid potash occurrence in China, has been the subject of debate for decades. It has been established that the ore-hosting Mengyejing Formation formed during the mid-Cretaceous based on radioactive and magnetic dating. The age discrepancy between the primary mid-Cretaceous and the squeezing of the Middle Jurassic is related to the lack of direct previous dating of the MPD itself. In this study, detrital zircon U-Pb dating of four clastic rock samples interbedded with the potash layers yielded the youngest zircon ages of 104.8, 106.5, 107.8, and 110 Ma. Taking into account the relatively large proportion of the youngest Cretaceous zircons and the Hf isotopic analysis, we propose that most of the Cretaceous zircons were derived from the contemporaneous volcanic activity that produced the tuff beds within the potash deposit and elsewhere in the Mengyejing Formation, while only a small fraction of the Cretaceous zircons were found to be of detrital origin and have derived from the Bomi-Chayu and Dianxi-Burma batholiths. Consequently, the maximum age of the potash deposit of 110 to 105 Ma is the true depositional age of the strata and potash deposit.

Genetic Model of Mud-Clast Conglomerates in Salt Rocks and Their Significance for Salt Mineralization in Mohei Area, Simao Basin, China: A Case Study of Well L-2.

The Simao Basin is one of the most important Mesozoic salt basins in China, and the salt rocks generally contain mud-clast conglomerates. The characteristics of mud-clast conglomerates can provide effective information indicating the evolution process of the salt deposits. A combined analysis of trace elements and clay minerals was performed to characterize the genetic model of mud-clast conglomerates in the salt rocks. The results show that the sedimentary materials are felsic rocks from the Upper Crust. Ternary plot diagrams show that the tectonic settings are between the continental margin and the continental island arc. The clay minerals in the samples mainly contain illite and illite–smectite mixed layers. A dry and hot climate prevailed during the deposition of the Mengyejing Formation, and the warm-humid climate that also occurred is interspersed in some periods. Evaporation makes the water bodies shallower, and the concentrated brine starts to precipitate salt under the arid and hot climate conditions. Redox proxies indicate that most of the samples were deposited in relatively oxic conditions. The Sr/Ba ratios (average of 0.5) and paleosalinity (average of ∼35‰) during the depositional period indicate an increase in terrigenous freshwater input and carry of clasts into the evaporation basin. Furthermore, the freshwater supply enhances the hydrodynamics; as a result, the detritus that deposited in the early stage is broken into mud-clast conglomerates and co-deposited with the salt rocks. The results provide a geochemical basis for further study of mud-clast conglomerates in the Simao Basin and supply recommendations for the origin of salt deposits in similar basins around the world.

Hydrogeochemistry of Hot Springs and the 2018 Mojiang M 5.9 Earthquake-Related Chemical Changes in the Simao Basin, China

The Simao Basin is characterized by strong tectonic activity and frequent seismicity. This study investigated the hydrochemical characteristics of 21 thermal springs in the Simao Basin from 2018 to 2020. In this study period, the 2018 Mojiang M5.9 earthquake caused several hydrochemical changes. The results indicate that the Simao Basin contained saline spring waters, HCO3−-rich spring waters, and SO42−-rich spring waters. In the study area, the water chemistry types were controlled by stratum lithology. Saline springs flowed through red beds and dissolved large amounts of halite, which is a rich source of Cl−and Na+ ions. In the hot spring waters, Ca2+ (Mg2+) and HCO3− were mainly derived from the dissolution of carbonate minerals, gypsum, and anhydrite of Triassic rocks. The higher SO42- content in the hot spring waters was caused by the pyrite present in Ailaoshan metamorphic rocks. The reservoir temperatures (121–289 °C) in the Simao Basin were estimated by the silica-enthalpy mixing model equation and the silica-enthalpy diagram. The hot springs had higher reservoir temperatures (>250 °C) and were mainly located at the edges of the basin. Metamorphic rocks exposed in the region had low permeabilities and these springs was close to nearby deep faults that provided deep heat. In most springs, the concentrations of Ca2+ and HCO3− ions increased obviously before the 2018 Mojiang M5.9 earthquake; however, the concentrations of these ions decreased after the earthquake. The hydrogeochemical variations might be attributed to the vigorous water-rock interactions and the mixing of secondary fluids. The entry of cold shallow groundwater caused changes in the reservoir temperatures of some spring samples.

Two Mechanisms of Earthquake-Induced Hydrochemical Variations in an Observation Well

Due to frequent large earthquakes in the Lanping-Simao fault basin—located in China’s Yunnan Province—the Simao observation well has observed groundwater discharge, as well as Ca2+, Mg2+, and HCO3− concentrations every day between 2001–2018. Over 18 years of observations, M ≥ 5.6 earthquakes within a radius of 380 km from the well were seen to cause hydrochemical variations. In this study, we investigated CO2 release and groundwater mixing as possible causes of regional earthquake precursors, which were caused by the characteristics of the regional structure, lithology, water-rock reactions, and a GPS velocity field. Precursory signals due to CO2 injection are normally short-term changes that take two months. However, groundwater mixing linked to earthquakes was found to take, at the earliest, 15 months. The proportion of shallow water that contributes to mixing was found to significantly increase gradually with the stronger regional strain. These finding delineate the two mechanisms of earthquake-induced hydrochemical variations in an observation well, and would contribute to a better understanding of chemical changes before events in the Simao basin.

Geochemistry of evaporitic deposits from the Cenomanian (Upper Cretaceous) Maha Sarakham Formation in the Khorat Basin, northeastern Thailand

The Cenomanian (Upper Cretaceous) Maha Sarakham Formation of the Khorat Basin, northeastern Thailand consists of three evaporite units (Lower, Middle and Upper Salt) interbedded with clastic sediments and exhibits abundant deposits of potash. Although numerous studies have been carried out on the Khorat potash deposit, results are still equivocal with regard to the origin of the rock salt, whether it was marine or non-marine (hydrothermal and/or mixed fluids). The purpose of this study is to examine the origin of rock salt based on elemental compositions and boron isotope analyses in the southwestern part of the Khorat Basin. A stratigraphic correlation of five boreholes (K-201– 205) located in Bamnet Narong and Chaturat districts, Chaiyaphum province, Thailand, revealed a salt dome structure. The elemental composition and δ11B values in the longest borehole K-203 indicate a precipitation of halite and carnallite from seawater. Rare earth elements (REE) of claystone and siltstone from five boreholes (K-201– 205) are comparable to the REE of sandstone from the Simao Basin in China, which suggest a similar provenance. Stratigraphic comparisons and geochemical signatures are important for a better understanding of the recharge models of paleoseawater. In agreement with some previous studies, we conclude that the Cenomanian evaporites within the Khorat Basin are marine deposits.

Paleogeographic Characteristics of the Mengyejing Formation in the Simao Basin during Its Depositional Period and Its Indication of Potash Mineralization: A Case Study of MZK-3 Well

In China, pre-Quaternary solid potash deposit has only been discovered in the Simao Basin, and the Lower Cretaceous Mengyejing (MYJ) Formation (Fm.) is the productive layer of potash deposit. In this study, we investigated the clay conglomerates which are distributed in upper and lower members of the potash-bearing salt rock layer. We analyzed the relative contents of major elements (Al2O3, Fe2O3T, MgO, CaO, Na2O, K2O) and trace elements (B, Ba, Co, Cr, Cu, Ga, Mn, Ni, Rb, Sr, V, Zn, Zr) in the samples. The results show that MgO and CaO in the major elements are rich relative to Post Archean Australian Shale (PAAS), whose average enrichment factor values of the MgO (EFMgO) is 2.61 and CaO (EFCaO) is 4.57, and the others major elements are relatively minor; trace elements (B, Ga, Mn, Zr) are rich relative to PAAS, and the others trace elements are minor relative to PAAS. The study of paleogeographic conditions using various parameters shows that the paleoclimate is generally dry and hot during the period of clay conglomerate deposition, but it was warm and humid in certain periods; the main sedimentary environment is weak oxidation condition with strong oxidation conditions in individual periods; the average value of paleosalinity is ~21‰, and the highest is no more than ~92‰. The significance of the paleogeographic characteristics of MYJ Fm. to potash mineralization are as follows: (1) they indicates that the clay conglomerates of MYJ Fm. are not clastic sediments in brine formed by seawater, because the paleosalinity of clay conglomerates deposition period is obviously lower than that of seawater; (2) MYJ potassic salt ore is not formed by evaporation and concentration of seawater in clay conglomerates in the sedimentary basin, because there is no carbonate rock and sulfate rock of corresponding scale after the deposition of clay conglomerates in the basin; (3) clay conglomerates of MYJ Fm. were deposited in continental shallow water basin; (4) the matter source of potash minerals is deep marine strata; (5) in the MYJ Fm. sedimentation period, deep source salt moved to the surface under the background of extensional structure, and the subsequent sedimentary clastic rock formed a protective layer of potash-bearing rock, thus completing the “deep source and shallow mineralization” metallogenic process.

The Middle to Late Cretaceous marine incursion of the Proto-Paratethys Sea and Asian aridification: A case study from the Simao-Khorat salt giant, Southeast Asia

Asian aridification during the Cenozoic was strongly related to moisture flux modulated by sea incursion and the retreat fluctuations of the proto-Paratethys Sea via the Westerlies. However, the extents of the sea incursions are poorly constrained, and there is a lack of sedimentary records beyond the Central Asian basins. The Middle to Late Cretaceous Simao Basin and the Khorat Plateau in Southeast Asia contain thick continental sequences of red beds, evaporites, and aeolian deposits, but whether the depositional environment of the evaporites was marine or continental has been hotly debated. In this study, we compiled multiple sedimentology proxies, biomarkers, element geochemistry, and isotopic geochemistry of the fine-grained sediments of the Mohan section in the Simao Basin. Sedimentological analyses show that this section is composed of subtidal flat fine-grained siliciclastic and carbonate rocks and supratidal flat conglomerates and evaporites. The paleosalinity proxies show that the B concentration and B/Ga and Srcorrected/Ba ratios range from 30.3 to 81.7 ppm, 2.4 to 5.0, and 0.05 to 0.60, respectively, which indicate brackish conditions. The two typical increases in these proxies are consistent with the stratigraphic horizons of the diagnostic marine biomarkers 24-n-propyl- and 24-iso-propylcholestanes, which suggests seawater recharge. The carbonate δ13C and δ18O values (−4.84‰ to −1.75‰ and −8.25‰ to −3.69‰, respectively) and the bulk δ13Corg values (−26.5‰ to −23.22‰) also indicate the influence of seawater. We propose that the seawater likely originated from the proto-Paratethys Sea during a marine incursion. We propose for the first time that the proto-Paratethys seawater incursions extended into the Simao Basin and the Khorat Plateau. These results provide a novel paleogeographic configuration for East Asia during the Middle to Late Cretaceous. The retreat of the proto-Paratethys Sea, the northeast Trade Winds, and the tectonic uplift dramatically decreased the moisture and intensified the extreme aridification in the Simao Basin and the Khorat Plateau.

Sr, S, and O Isotope Compositions of Evaporites in the Lanping–Simao Basin, China

Evaporites are widely distributed within continental “red beds” in the Lanping–Simao Basin, west Yunnan, China. Sr (Strontium), S (Sulfur), and O (Oxygen) isotope compositions have been measured on 54 sulfate or/and sulfate-bearing samples collected from Lanping, Nuodeng, Jinggu, Mengyejing, Baozang throughout the Lanping–Simao Basin. The 87Sr/86Sr ratios of all samples (0.708081 to 0.710049) are higher than those of contemporaneous seawater, indicating a significant continental contribution to the drainage basin. Sulfates in the Lanping Basin have higher 87Sr/86Sr ratios (0.709406 to 0.710049) than those (0.708081 to 0.709548) in the Simao Basin. Nevertheless, the δ34S values of gypsums (13.4‰ to 17.6‰) in Lanping and Baozang fall within the range of Cretaceous seawater. Gypsums from a single section in Baozang have trends of decreasing δ34S values and increasing 87Sr/86Sr ratios from base to top, indicating continental input played an increasingly significant role with the evaporation of brines. High δ34S values (20.5‰ to 20.7‰) of celestites in Lanping are probably caused by bacterial sulfate reduction (BSR) process in which 34S were enriched in residual sulfates and/or recycling of Triassic evaporites. The reduced δ34S values of gypsums (9.5‰ to 10.4‰) in Nuodeng could have been caused by oxidation of sulfides weathered from Jinding Pb-Zn deposit. The complex O isotope compositions indicate that sulfates in the Lanping–Simao Basin had undergone sulfate reduction, re-oxidation, reservoir effects, etc. In conclusion, the formation of continental evaporites was likely derived from seawater due to marine transgression during the Cretaceous period. Meanwhile, non-marine inflows have contributed to the basin significantly.

New insights on the age of the Mengyejing Formation in the Simao Basin, SE Tethyan domain and its geological implications

Knowledge on the origin and mechanism of the large potash formation in the southeast Tethyan tectonic domain are still under debate, one of which mainly due to the controversial ages of the potash-bearing strata. Here we present a detailed detrital zircon U-Pb geochronologic-magnetostratigraphic study of the potash-bearing Mengyejing (MYJ) Formation (Fm) from the Simao Basin. 948 paleomagnetic cores and 4 detrital zircon U-Pb samples were collected from a 932-m thick Jiangcheng section. Thermal demagnetization isolated 857 primary characteristic remnant magnetization (ChRM) directions, indicated by positive reversals and fold tests and petrologic examinations. Seven normal and seven reversed polarity zones were identified and correlated well with chrons C27r to C34n of the geomagnetic polarity timescale (GPTS2012), yielding the first known age sequence of >112 to ∼63 Ma for the MYJ Fm. The ages for the potash bearing strata in the Simao commenced ∼20 Ma earlier than those in the adjacent Khorat basins, opposite to the traditional viewpoint that the former would rather correspond to the middle and lower parts of the latter. Given the paleogeographic reconstruction of likely a pan-Simao-Khorat basin during the Cretaceous, ∼85 Ma would be another important potential period for future potash exploration in the Simao Basin.

Geochemistry of rare earth elements in the hot springs in the Simao Basin in southwestern China

Little is known about the REEs characteristics and distribution in groundwater in the Simao Basin in southwest China. In this study, hydrochemical analyses and models are used to examine the REE inorganic speciation, characteristics and controls of REE concentrations, and fractionation of spring waters in different types of rocks in the basin. REE contents in the spring waters are relatively low, which are positively correlated with TDS. Relatively high concentrations of REEs are observed in the spring waters in the red beds rather than in the carbonate rocks. Speciation calculations indicate that dissolved REEs mainly composed of LnCO3+ and Ln(CO3)2− complexes (the sum ranging from 30.8 to 98.2%). The carbonate complexes account for a larger proportion in the spring waters in the carbonate rocks than in the red beds. LnSO4+ also accounts for a certain proportion up to 67.5% in the spring waters in the red beds. Relatively low pH and Eh values and high concentration of HCO3 contribute to the REEs enrichment in the groundwater. Carbonate complexation and preferential adsorption may result in the enrichment of MREEs and HREEs. The positive Eu anomalies in the spring waters are related to the interaction of groundwater with the carbonate rocks, because Eu can exist in the Ca site of certain calcium-rich minerals (especially carbonate rocks). The negative Ce anomalies are related to redox conditions. Under the oxidation conditions, Ce3+ is oxidized to Ce4+ and coprecipitates with oxides of iron and manganese in the form of CeO2 or Ce(OH)4.

Characterization of a saline hot spring depositing travertine in the red beds in the Simao Basin of China

The Mangka saline hot springs, in the Simao Basin in southwest China, are unique in having relatively large discharge (>10 L/s) from the red beds (relatively poor permeability) and travertine deposition from Cl-Na type hot water with high content of total dissolved solids (10 g/L). The stable hydrogen and oxygen isotopes indicate that the Mangka spring waters are meteoric in origin and the average altitude of the recharge area is estimated as 1,750 m above sea level. The high temperature of the spring water is derived from geothermal heating. The estimated geothermal reservoir temperature range is 86–91 °C and the circulation depths of the spring waters are 2,318–2,454 m. Incongruent dissolution of salt-bearing formations contributes to the mineralization of the Mangka saline hot springs, including dissolution of halite, gypsum, carbonate and sylvite. Some suitable hydrochemical factors provide beneficial conditions for travertine deposition such as a higher CO2 partial pressure of 10–1.94–10–0.9, γCa/γHCO3 (the milliequivalent ratio of Ca and HCO3) ranging from 5.76 to 6.67, and saturation indices for both calcite and aragonite over or equal to zero. There is also a favorable hydrodynamic condition for the spring water flowing down steep slopes and forming fast-flowing shallow channels with a relatively large surface area. The formation of the Mangka saline hot springs is summarized as follows: the groundwater receives recharge of infiltration from precipitation, undergoes deep circulation in the salt-bearing strata, receives heat from the geothermal heat flow, and ascends to the land surface along the permeable fault.

Hydrogeochemistry, Geothermometry, and Genesis of the Hot Springs in the Simao Basin in Southwestern China

In the Simao Basin in southwest China widely occur red beds of poor permeability. Nevertheless, more than 100 springs exist in the basin, some of which are hot springs with varying temperature. Hot springs contain abundant information on hydrogeochemical processes and groundwater circulation. In this study, hydrochemical and isotopic analyses and mixed models are used to examine the sources of recharge, heat, and solutes of the hot springs to better understand the subsurface processes and formation mechanisms of different hot springs in the basin. Three types of springs are found in the Simao Basin: springs of HCO3-Na type occur in the metamorphic rocks, springs of HCO3-Ca(Mg) and Cl-HCO3-Na-Ca types in the carbonate rocks, and springs of Cl(SO4)-SO4(Cl)-HCO3-Na(Ca) type in the red beds. Data of δ2H and δ18O indicate that the hot springs in the Simao Basin are meteoric in origin. Incongruent dissolution is the dominant process affecting the chemical compositions of the spring waters. The hydrochemical constituents of the hot springs in the metamorphic rocks, carbonate rocks, and red beds are influenced by the weathering of albite and the dissolution of carbonate, gypsum, anhydrite, and halite. The geothermal waters are mixed with shallow cold waters in their ascending processes, and the mixing ratios of cold water range from 58% to 94%. Due to the effect of mixing, the reservoir temperatures (51°C-127°C) calculated with the quartz geothermometer are regarded as the minimum reservoir temperatures. More reliable reservoir temperatures (91°C-132°C) are estimated with the fixed-Al method. The following mechanisms contribute to the formation of hot springs in the Simao Basin: the groundwater receives recharge from infiltration of precipitation and undergoes deep circulation, during which groundwater is heated by heat flow and incongruently dissolves the subsurface minerals and emerges in the form of hot springs along the permeable fracture or fault zones.