Sign Of Charge Research Articles

Modulation of Cosmic-Ray Antiprotons in the Heliosphere: Simulations for a Solar Cycle

The precision measurements of galactic cosmic-ray protons from the Payload for Antimatter Matter Exploration and Light-nuclei Astrophysics and the Alpha Magnetic Spectrometer are reproduced using a well-established three-dimensional numerical model for the period 2006 July–2019 November. The resulting modulation parameters are applied to simulate the modulation for cosmic antiprotons over the same period, which includes the times of minimum modulation before and after 2009, the maximum modulation from 2012 to 2015, including the reversal of the Sun’s magnetic field polarity, and the approach to new minimum modulation in 2020. Apart from their local interstellar spectra, the modulation of protons and antiprotons differ in their charge sign and consequent drift pattern. The lowest proton flux was in 2014 February–March, but the lowest simulated antiproton flux is found to have been in 2015 March–April. These simulated fluxes are used to predict the proton-to-antiproton ratios as a function of rigidity. The trends in these ratios contribute to clarifying, to a large extent, the phenomenon of charge-sign dependence of heliospheric modulation during vastly different phases of the solar activity cycle. This is reiterated and emphasized by displaying so-called hysteresis loops. It is also illustrated how the values of the parallel and perpendicular mean free paths, as well as the drift scale, vary with rigidity over this extensive period. The drift scale is found to be at its lowest level during the polarity reversal period, while the lowest level of the mean free paths is found to be in 2015 March–April.

Measuring the photonic topological charge of power-exponent-phase vortex beam via cross phase

We propose a method for measuring the photonic topological charge of the power-exponent-phase vortex (PEPV) beam with the cross phase. Based on the superimposition of the power-exponent phase and the cross phase, we analyzed the axial diffraction properties of the modulated PEPV beam with different parameters by using the scalar diffraction theory. The simulations demonstrated that dark regions are embedded in the intensity profile of the modulated PEPV beam, and the number of the dark regions is just equal to the photonic topological charge carried by the PEPV beam. Moreover, the sign of the photonic topological charge can be distinguished by the alignment direction of the modulated PEPV light field. The experimental results are consistent with the theoretical ones. The method is promising in the fields of beam shaping and optical trapping.

Dirac Half-Semimetallicity and Antiferromagnetism in Graphene Nanoribbon/Hexagonal Boron Nitride Heterojunctions.

Half-metals have been envisioned as active components in spintronic devices by virtue of their completely spin-polarized electrical currents. Actual materials hosting half-metallic phases, however, remain scarce. Here, we predict that recently fabricated heterojunctions of zigzag nanoribbons embedded in two-dimensional hexagonal boron nitride are half-semimetallic, featuring fully spin-polarized Dirac points at the Fermi level. The half-semimetallicity originates from the transfer of charges from hexagonal boron nitride to the embedded graphene nanoribbon. These charges give rise to opposite energy shifts of the states residing at the two edges, while preserving their intrinsic antiferromagnetic exchange coupling. Upon doping, an antiferromagnetic-to-ferrimagnetic phase transition occurs in these heterojunctions, with the sign of the excess charge controlling the spatial localization of the net magnetic moments. Our findings demonstrate that such heterojunctions realize tunable one-dimensional conducting channels of spin-polarized Dirac fermions seamlessly integrated into a two-dimensional insulator, thus holding promise for the development of carbon-based spintronics.

Does the Sign of Charge Affect the Surface Affinity of Simple Ions?

The role the charge sign of simple ions plays in determining their surface affinity in aqueous solutions is investigated by computer simulation methods. For this purpose, the free surface of aqueous solutions of fictitious salts is simulated at finite concentration both with nonpolarizable point-charge and polarizable Gaussian-charge potential models. The salts consist of monovalent cations and anions that are, apart from the sign of their charge, identical to each other. In particular, we consider the small Na+ and the large I- ions together with their charge-inverted counterparts. In an attempt to avoid the interference even between the behavior of cations and anions, we also simulate systems containing only one of the above ions, and determine the free energy profile of these ions across the liquid-vapor interface of water at infinite dilution by potential of mean force (PMF) calculations. The obtained results reveal that, in the case of small ions, the anion is hydrated considerably stronger than the cation due to the close approach of water H atoms, bearing a positive fractional charge. As a consequence, the surface affinity of a small anion is even smaller than that of its cationic counterpart. However, considering that small ions are effectively repelled from the water surface, the importance of this difference is negligible. Further, a change in the hydration energy trends of the two oppositely charged ions is observed with their increasing size. This change is largely attributed to the fact that, with increasing ion size, the factor of 2 in the magnitude of the fractional charge of the closely approaching water atoms (i.e., O around cations and H around anions) outweighs the closer approach of the H than the O atom in the hydration energy. Thus, for large ions, being already surface active themselves, the surface affinity of the anion is larger than that of its positively charged counterpart. Further, such a difference is seen even in the case when the sign of the surface potential favors the adsorption of cations.

Charge–Sign Dependence of Cosmic Ray Modulation from the PAMELA Experiment

Charge–Sign Dependence of Cosmic Ray Modulation from the PAMELA Experiment

Unusual Aspects of Charge Regulation in Flexible Weak Polyelectrolytes.

This article reviews the state of the art of the studies on charge regulation (CR) effects in flexible weak polyelectrolytes (FWPE). The characteristic of FWPE is the strong coupling of ionization and conformational degrees of freedom. After introducing the necessary fundamental concepts, some unconventional aspects of the the physical chemistry of FWPE are discussed. These aspects are: (i) the extension of statistical mechanics techniques to include ionization equilibria and, in particular, the use of the recently proposed Site Binding-Rotational Isomeric State (SBRIS) model, which allows the calculation of ionization and conformational properties on the same foot; (ii) the recent progresses in the inclusion of proton equilibria in computer simulations; (iii) the possibility of mechanically induced CR in the stretching of FWPE; (iv) the non-trivial adsorption of FWPE on ionized surfaces with the same charge sign as the PE (the so-called "wrong side" of the isoelectric point); (v) the influence of macromolecular crowding on CR.

Comparative Studies of Selenium Nanoparticles Stabilized with Polyelectrolytes of Different Signs

Selenium (Se0) nanoparticles are stabilized with water-soluble polymers containing ionogenic groups of the different signs, namely, poly(N,N,N-trimethylammonium)ethyl methacrylate iodide (polycation) and sodium polystyrenesulfonate (polyanion). A comprehensive comparative study of the resulting selenium-containing nanodispersions by the UV–visible spectroscopy, atomic force and transmission electron microscopy, and dynamic and electrophoretic light-scattering methods is conducted. The effect of the charge sign of the polymer stabilizer on the structural–morphological, dimensional, electrochemical, and spectral characteristics of selenium-containing nanodispersions is shown.

The application of a new “interstitial” model for the Interfacial freezing potential of pure water (Workman-Reynolds Potential) to aqueous solutions

A new model of pure water freezing potential (Workman-Reynolds potential), published in Journal of Molecular Liquids 359 (2022) 119278, explained the positive electric charge of ice relative to water during crystallization by the fact that protons were captured faster than hydroxide ions by numerous charge traps in ice - interstitials. In the present article, additions have been made to this model to extend the application of the model from pure water to aqueous solutions with an impurity concentration in the parent solution of 10-4 M or more. The additions take into account the ability of impurity anions and cations to act as acceptors for protons and hydroxide ions in ice. As a result of capture by acceptors, the equilibrium concentrations of protons and hydroxide ions can shift significantly in favor of the former or the latter. This will radically affect the kinetics of filling the charge traps (interstitials) with protons or hydroxide ions and the sign of the electric charge of ice with respect to the solution. In particular, the model explains the negative ice charge during crystallization of 10-4 M KCl solutions.

Predicting Interfacial Tension and Adsorption at Fluid-Fluid Interfaces for Mixtures of PFAS and/or Hydrocarbon Surfactants.

Many per- and polyfluoroalkyl substances (PFAS) are surface-active and adsorb at fluid-fluid interfaces. The interfacial adsorption controls PFAS transport in multiple environmental systems, including leaching through soils, accumulation in aerosols, and treatment methods such as foam fractionation. Most PFAS contamination sites comprise mixtures of PFAS as well as hydrocarbon surfactants, which complicates their adsorption behaviors. We present a mathematical model for predicting interfacial tension and adsorption at fluid-fluid interfaces for multicomponent PFAS and hydrocarbon surfactants. The model is derived from simplifying a prior advanced thermodynamic-based model and applies to nonionic and ionic mixtures of the same charge sign with swamping electrolytes. The only required model inputs are the single-component Szyszkowski parameters obtained for the individual components. We validate the model using literature interfacial tension data of air-water and NAPL (non-aqueous phase liquid)-water interfaces covering a wide range of multicomponent PFAS and hydrocarbon surfactants. Application of the model to representative porewater PFAS concentrations in the vadose zone suggests competitive adsorption can significantly reduce PFAS retention (up to 7 times) at some highly contaminated sites. The multicomponent model can be readily incorporated into transport models to simulate the migration of mixtures of PFAS and/or hydrocarbon surfactants in the environment.

Electrokinetic comparison of CaF2 and AgCl from a MDS perspective

CaF2 has limited electrokinetic sensitivity to fluoride ions in solution and the positive CaF2 surface charge is not reversed at high fluoride ion concentration. Similar insensitivity of surface charge to high fluoride ion concentration has been observed for other alkali and alkaline earth fluoride salts. On the contrary, chloride ions act as potential determining ions for AgCl and reverse the surface charge, as expected. FTIR-IRS results indicate that the AgCl/water interface has a water structure-breaking tendency, whereas the CaF2/water interface has a structure-making tendency. It is speculated that the strong hydrogen bonding between fluoride ions and water prevents the accommodation of excess fluoride ions at surface lattice sites of fluorite, and therefore explains the low sensitivity of the fluorite surface charge sign and magnitude to fluoride ion concentration. However, this speculation has not been examined at the molecular level and is evaluated by molecular dynamics simulations (MDS) in the research presented in this paper. Higher hydrogen bond density at the CaF2 mineral/water interface confirms that the water structure has stronger hydrogen bonding at both the CaF2 mineral surface and with the F− ion in solution. In this way, the interaction of the F− ion with the CaF2 surface is inhibited.

Prospects for ultra-high-energy particle acceleration at relativistic shocks

ABSTRACT We study the acceleration of charged particles by ultra-relativistic shocks using test-particle Monte Carlo simulations. Two field configurations are considered: (i) shocks with uniform upstream magnetic field in the plane of the shock, and (ii) shocks in which the upstream magnetic field has a cylindrical geometry. Particles are assumed to diffuse in angle due to frequent non-resonant scattering on small-scale fields. The steady-state distribution of particles’ Lorentz factors is shown to approximately satisfy dN/dγ ∝ γ−2.2 provided the particle motion is scattering dominated on at least one side of the shock. For scattering dominated transport, the acceleration rate scales as tacc ∝ t1/2, though recovers Bohm scaling tacc ∝ t if particles become magnetized on one side of the shock. For uniform field configurations, a limiting energy is reached when particles are magnetized on both sides of the shock. For the cylindrical field configuration, this limit does not apply, and particles of one sign of charge will experience a curvature drift that redirects particles upstream. For the non-resonant scattering model considered, these particles preferentially escape only when they reach the confinement limit determined by the finite system size, and the distribution approaches the escapeless limit dN/dγ ∝ γ−1. The cylindrical field configuration resembles that expected for jets launched by the Blandford & Znajek mechanism, the luminous jets of active galactic nuclei and gamma-ray bursts thus provide favourable sites for the production of ultra-high-energy cosmic rays.

Generation and measurement of irregular polygonal perfect vortex optical beam based on all-dielectric geometric metasurface.

The perfect optical vortex (POV) beam carrying orbital angular momentum with topological charge-independent radial intensity distribution possesses ubiquitous applications in optical communication, particle manipulation, and quantum optics. But the mode distribution of conventional POV beam is relatively single, limiting the modulation of the particles. Here, we originally introduce the high-order cross-phase (HOCP) and ellipticity γ into the POV beam and construct all-dielectric geometric metasurfaces to generate irregular polygonal perfect optical vortex (IPPOV) beams following the trend of miniaturization and integration of optical systems. By controlling the order of the HOCP, conversion rate u, and ellipticity factor γ, various shapes of IPPOV beams with different electric field intensity distributions can be realized. In addition, we analyze the propagation characteristics of IPPOV beams in free-space, and the number and rotation direction of bright spots at the focal plane give the magnitude and sign of the topological charge carried by the beam. The method does not require cumbersome devices or complex calculation process, and provides a simple and effective method for simultaneous polygon shaping and topological charge measurement. This work further improves the beam manipulation ability while maintaining the characteristics of the POV beam, enriches the mode distribution of the POV beam, and provides more possibilities for particle manipulation.

Dimensional reduction and the generalized pion in a magnetic field within the NJL model

In this work, the mass of the neutral pion is investigated in the presence of background magnetic fields in the framework of the Nambu-Jona-Lasinio model. Taking into account the anisotropic four-fermion interactions, a tensor current arises in the magnetized QCD system, which forms an anomalous magnetic moment (AMM) coupling in the Dirac equation for the quarks. By solving the gap equations, we find that the sign of the dynamically generated AMM is opposite to the sign of the quark's charge and its magnitude is definitely smaller than the constituent mass. We construct two generalized Nambu-Goldstone pions, which emerge as combinations of the quantum fluctuations around the conventional scalar and the emergent tensor chiral condensates. We analytically demonstrate that the Goldstone nature has been spoiled by the dimensional reduction in the two-particle state and the corresponding decreasing mass of the lighter generalized pionic mode is a remnant of the infrared dynamics.

Selective Separation of Singly Charged Chloride and Dihydrogen Phosphate Anions by Electrobaromembrane Method with Nanoporous Membranes.

The entrance of even a small amount of phosphorus compounds into natural waters leads to global problems that require the use of modern purification technologies. This paper presents the results of testing a hybrid electrobaromembrane (EBM) method for the selective separation of Cl- (always present in phosphorus-containing waters) and H2PO4- anions. Separated ions of the same charge sign move in an electric field through the pores of a nanoporous membrane to the corresponding electrode, while a commensurate counter-convective flow in the pores is created by a pressure drop across the membrane. It has been shown that EBM technology provides high fluxes of ions being separated across the membrane as well as a high selectivity coefficient compared to other membrane methods. During the processing of solution containing 0.05 M NaCl and 0.05 M NaH2PO4, the flux of phosphates through a track-etched membrane can reach 0.29 mol/(m2×h). Another possibility for separation is the EBM extraction of chlorides from the solution. Its flux can reach 0.40 mol/(m2×h) through the track-etched membrane and 0.33 mol/(m2×h) through a porous aluminum membrane. The separation efficiency can be very high by using both the porous anodic alumina membrane with positive fixed charges and the track-etched membrane with negative fixed charges due to the possibility of directing the fluxes of separated ions in opposite sides.

Temporal Structures in Electron Spectra and Charge Sign Effects in Galactic Cosmic Rays.

We present the precision measurements of 11years of daily cosmic electron fluxes in the rigidity interval from 1.00 to 41.9GV based on 2.0×10^{8} electrons collected with the Alpha Magnetic Spectrometer (AMS) aboard the International Space Station. The electron fluxes exhibit variations on multiple timescales. Recurrent electron flux variations with periods of 27days, 13.5days, and 9days are observed. We find that the electron fluxes show distinctly different time variations from the proton fluxes. Remarkably, a hysteresis between the electron flux and the proton flux is observed with a significance of greater than 6σ at rigidities below 8.5GV. Furthermore, significant structures in the electron-proton hysteresis are observed corresponding to sharp structures in both fluxes. This continuous daily electron data provide unique input to the understanding of the charge sign dependence of cosmic rays over an 11-year solar cycle.

Synchrotron radiation by slowly rotating fermions

We study the synchrotron radiation emitted by a charged fermion, rotating as a part of a larger system, in a constant magnetic field $B$ parallel to the axis of rotation. The rotation is classical and independent of the magnetic field. The angular velocity of rotation $\mathrm{\ensuremath{\Omega}}$ is assumed to be much smaller than the inverse magnetic length $\sqrt{qB}$, which allows us to ignore the boundary effects at $r=1/\mathrm{\ensuremath{\Omega}}$. We refer to such rotation as slow, even though in absolute value it may be an extremely rapid rotation. Using the exact solution of the Dirac equation, we derived the intensity of electromagnetic radiation, its spectrum, and its chirality. We demonstrate by explicit numerical calculation that the effect of rotation on the radiation intensity increases with the particle energy. Depending on the relative orientation of the vectors $\mathbf{\ensuremath{\Omega}}$ and $\mathbit{B}$ and the sign of the electric charge, the rotation can either strongly enhance or strongly suppress the radiation.

Magnetic skyrmion dynamics induced by surface acoustic waves

Magnetic skyrmions are promising information carriers for high-density memories. The dynamical motion of magnetic skyrmions have been extensively investigated in the development of magnetic racetracks. In this study, a surface acoustic wave (SAW) is theoretically investigated to drive skyrmions by using micromagnetic simulations. The in-plane type and out-of-plane particle displacement components of SAWs generate different magnetoelastic effective fields. The shear horizontal (SH) wave mode SAW drives skyrmions flow movement by the magnetoelastic coupling effect. Increasing the acoustic wave amplitude and magnetoelastic coupling constants, as well as a reduced wavelength, are beneficial for an enhanced skyrmion motion velocity. The skyrmion motion trajectory can be controlled by designing the geometry of magnetic films. Interestingly, in a circular magnetic film, the skyrmions driven by SH waves show clockwise or counterclockwise movement trajectories depending on the sign of topological charges. Our results provide an energy efficient approach to drive skyrmion dynamics including rotational motion, thus paving the way for low-power spintronics.

Charge-driven arrested phase-separation of polyelectrolyte-gold nanoparticle assemblies leading to plasmonic oligomers

Aggregates of charged metal particles obtained by electrostatic coupling with a compound of opposite charge in the vicinity of the net zero charge ratio are of interest in the field of plasmonics because the inter-particle distance is minimal, which favours plasmonic coupling. However, these structures present a low colloidal stability limiting the development of applications. In this article we show that globally neutral aggregates formed by electrostatic complexation of citrate-stabilized gold particles and a quaternized chitosan (i.e., polycation) around the net zero charge ratio could be stabilized at a nanometric size by the subsequent addition of polyelectrolyte chains. Furthermore, the sign of the charge carried by the stabilizing chains determines the sign of the global charge carried by the stabilized complexes. The stabilization is demonstrated in saline environment on a broad pH range as well as in a cell culture media over periods of several days. Contrarily to stabilization by charged particles, our stabilized complexes are found to retain their initial characteristics (i.e. shape, size, internal structure and optical properties) after stabilization. Hence, the plasmonic coupling allows to maximize the optical absorption around the 800nm wavelength at which the lasers used for thermoplasmonic and surface enhanced Raman scattering analysis operate.

Current rectification by nanoparticles in bipolar nanopores

Charged nanoparticles can significantly increase rectification in bipolar nanopores but this effect is largely dependent on the pore's geometry, its charge distribution, and the sign of the nanoparticles' charge.

Impact of polyelectrolyte adsorption on the rheology of concentrated poly(N-isopropylacrylamide) microgel suspensions.

We explore the impact of three water-soluble polyelectrolytes (PEs) on the flow of concentrated suspensions of poly(N-isopropylacrylamide) (PNIPAm) microgels with thermoresponsive anionic charge density. By progressively adding the PEs to a jammed suspension of swollen microgels, we show that the rheology of the mixtures is remarkably influenced by the sign of the PE charge, PE concentration and hydrophobicity only when the temperature is increased above the microgel volume phase transition temperature Tc, namely when microgels collapse, they are partially hydrophobic and form a volume-spanning colloidal gel. We find that the original gel is strengthened close to the isoelectric point, attained when microgels are mixed with cationic PEs, while PE hydrophobicity rules the gel strengthening at very high PE concentrations. Surprisingly, we find that polyelectrolyte adsorption or partial embedding of PE chains inside the microgel periphery occurs also when anionic polymers of polystyrene sulfonate with a high degree of sulfonation are added. This gives rise to colloidal stabilization and to the melting of the original gel network above Tc. Contrastingly, the presence of polyelectrolytes in suspensions of swollen, jammed microgels results in a weak softening of the original repulsive glass, even when an apparent isoelectric condition is met. Our study puts forward the crucial role of electrostatics in thermosensitive microgels, unveiling an exciting new way to tailor the flow of these soft colloids and highlighting a largely unexplored path to engineer soft colloidal mixtures.