Shrinkage Strain Research Articles

Hydraulic barrier properties of soil beneath Egbedi active municipal solid waste dumpsite

This study researches the potential of soil underlying an active municipal solid waste dumpsite as compacted clay liner in municipal solid waste repository structure. Identification of soil samples and their chemical constituents was conducted. Ex-situ tests were conducted in the laboratory to obtain three important hydraulic barrier parameters: coefficient of hydraulic permeability (k), volumetric shrinkage strain (VSS) and shear strength (UCS) of the natural soil samples employing three compaction techniques namely; British Standard Light (BSL), West African Standard (WAS) and British Standard Heavy (BSH). Soil specimens were also prepared with varying moulding moisture contents −2%, +2 and + 4 % of optimum moisture content (OMC). The microstructure of the natural specimen was investigated via scanning electron microscopy. The natural samples were identified as; A-2-7(0), A-2-7(2) and A-7-5(5) for sample A, B and C respectively according to AASHTO classification while all samples are classified as SC (Clayey Sand) according to USCS classification. The moulding moisture content that satisfy the k and VSS conditions of k ≤ 1.0 × 10−7 cm/s and VSS ≤ 4 % falls between 9.63 – 17.68 % and 9.63–12.75 % respectively, but the tested specimens fall short of strength condition. This study revealed that the natural soil samples fail to fulfil the design parameter requirements for strength in its application as liner/cover in the active waste dumpsite, therefore further investigation to ameliorate the strength property of the soil samples using additives or microbial induced calcite precipitation (MICP) technique is recommended.

Effect of Ca on hot tearing susceptibility of WE43 alloy

The effect of Ca on the hot tearing susceptibility (HTS) of WE43 alloy was systematically investigated in this study. The results revealed a significant reduction in HTS with the addition of Ca. The tear volume in WE43-xCa alloys (x = 0, 0.5, 1.0, and 2.0 wt%) was accurately quantified using a Micro-CT system, serving as an indicator for HTS. The lowest HTS was observed in the WE43–2.0Ca alloy, associated with the precipitation of a substantial amount of the Mg2Ca phase. The addition of 2.0 wt% Ca significantly promotes the enrichment of rare-earth eutectic and increases the residual liquid eutectic, resulting in complete healing of the hot tear. The highest HTS was observed in the WE43 alloy due to its low residual liquid eutectic fraction and the inevitable presence of Y2O3 inclusion. Additionally, Ca alloying refined grain size and reduced the susceptible freezing range of the alloys, which can reduce the shrinkage strain acting on the grain boundary per unit at the hot spot. Furthermore, the study investigated the unique morphology of the second phase flat interfaces in the healing region of WE43–2.0Ca alloy. Two possibilities for forming the flattened interface and its effect on HTS are inferred.

Achieving property enhancements in dental resin composites via reduced concentrations of camphorquinone within a ternary initiator system

ObjectivesThe study aimed to assess the impact of diphenyliodonium hexafluorophosphate (DPI) on the physicochemical properties of experimental resin composites (ECRs) featuring reduced concentrations of camphorquinone (CQ)/amine. MethodsFive concentrations of CQ (0.125, 0.25, 0.5, 0.75, and 1 mol%) with dimethylaminoethyl amine benzoate (EDAB) in a 1:2 mol% ratio (CQ:EDAB) were incorporated into a 50:50 mass% monomer blend of bisphenol glycidyl methacrylate (BisGMA) and triethyleneglycol dimethacrylate (TEGDMA). An additional 5 groups with the same CQ:EDAB concentrations had 0.5 mol% DPI added. Each resin group contained 60 wt% of 0.7 µm barium-alumino-silicate glass. Light transmission (n = 3), real-time degree of polymerization (n = 3), temperature change during polymerization (n = 5), polymerization shrinkage strain (n = 3), flexural strength, and modulus (n = 12), as well as water sorption and solubility (n = 5), were evaluated. Data were analyzed using two-way ANOVA and Tukey's post-hoc test (α = 0.05). ResultsLight transmission was reduced in groups containing 0.125 and 0.25 mol% of CQ without DPI. DPI increased temperature, degree and rate of polymerization, despite the reduction in CQ/amine concentration. Additionally, there was an increase in polymerization shrinkage strain, flexural strength and modulus, and a reduction in water sorption and solubility in ECRs with DPI, even with lower concentrations of CQ/EDAB. SignificanceDPI improved the assessed properties of composites across various concentrations of CQ/EDAB, showing the benefit of reducing the quantity of CQ used without compromising the properties and curing of the resin composites.

Flexural cracking behaviour and crack width calculation of steel-plate-reinforced ribbed UHPFRC deck panels

Ribbed ultra-high performance fiber reinforced concrete (UHPFRC) deck panels have been designed and implemented in buildings and bridges due to being increasingly slender, lightweight and tough. To further improve the crack resistance, this paper studies a neotype ribbed UHPFRC deck panel using steel plates and headed studs to reinforce the ribs. Bending tests were conducted to reveal the various crack and strain developments at different specimen parts with an aim to selecting the interesting primary-crack position and spacing. Then, theoretical calculation equations were proposed and verified on the differential strain, crack spacing and crack width for the interesting primary crack. The test results showed that the maximum crack width was invariably located at the rib instead of the top slab, and the primary-crack spacing varied from 52.1 mm to 151.2 mm after the cracks penetrated the whole rib into the top slab. The theoretical study showed that the tensile property of UHPFRC can be taken account by a two-line model, the shrinkage strain of UHPFRC as 556.5 με herein should be amended in the equation of the differential strain between reinforcement and UHPFRC. Besides, the crack spacing before and after the cracks penetrated the whole rib can be predicted by the standard AFNOR: 2016 and the headed-stud spacing, respectively. Finally, the theoretical crack-width calculation method was verified to have a satisfactory accuracy by comparing the calculated and test results with a percentage error within 4.0 %.

Properties of one-part CaO–Na2CO3 activated ground granulated blast furnace slag

In this study, the fresh and hardened performance and durability of one-part ground granulated blast furnace slags (GGBFS) activated by solid CaO and Na2CO3 were discussed, and their hydration process and microstructure development were analyzed accordingly. Results showed that when the water-to-binder ratio was 0.32, the alkali-activated slag (AAS) paste exhibited lower flowability, higher yield stress and plastic viscosity. As the content of CaO and Na2CO3 increased, the yield stress, plastic viscosity, and compressive strength of AAS after hardening all increased. For the durability of the hardened sample, AAS with high content of activator have higher shrinkage strain and chloride ion flux. The microscopic analysis results indicated that AAS containing CaO and Na2CO3 exhibited more intense hydration heat release and rapid microstructure development in the early stage, thereby promoting the improvement of strength. The use of CaO and Na2CO3 to activate GGBFS has enormous application potential in solid waste utilization and carbon emission reduction, which can reasonably replace traditional Portland cement (PC) as a new generation of sustainable cementitious materials.

Preparation of self-consolidating cemented backfill with tailings and alkali activated slurry: Performance evaluation and environmental impact

Development of low-cost and eco-friendly mine backfills is essential for the sustainable mining technology. This study focuses on the design and performance assessment of self-consolidating cemented backfills consisting of iron tailings and alkali-activated slurry (SCBTA). The effects of alkali content, activator modulus, and precursor constituents on SCBTA were clarified by means of investigations including workability and stability at fresh state, mechanical properties, drying shrinkage, and environmental benefits. Moreover, X-ray diffraction (XRD), scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP) were employed to understand the mechanism behind phenomena. The research findings indicate that the alkali activator modulus, alkaline content, and fly ash promote the flowability and stability of fresh SCBTA slurry. When the water-cement ratio is 0.6 and the alkali activator modulus increases from 0 to 1.0, the flow diameter of the fresh SCBTA slurry increases by 40 %. When the alkali activator modulus was 1.0 and the alkali content was 8 %, the addition of fly ash significantly improved the resistance to bleeding and segregation of the slurry. Compared to the alkaline-activated pure slag slurry, the inclusion of fly ash increases these properties by 60 % and 20 %, respectively. However, higher alkaline content and modulus result in a decrease in the resistance to shrinkage strain of hardened slurry. Hardened SCBTA slurry with an alkali activator modulus of 1 and alkaline content of 6 % and 8 % experiences severe shrinkage cracking within 7 days. MIP tests demonstrate that a higher alkali activator modulus promotes structural densification, with gel pores being the primary pore types distributed below 100 nm. Considering the mechanical properties, fluidity, workability, shrinkage, and environmental indicators, the recommended backfill slurry for mining operations is a slag/fly ash mixture with an alkaline content of 6 %, an alkali activator modulus of 0.5, and a water-cement ratio of 0.6.

Three-Dimensional Thermo-Chemo-Mechanical Coupled Curing Analysis for the Filament Wound Composite Shell.

Carbon fiber resin-based composite materials are widely employed in the manufacturing of composite shells. During the curing process, the temperature gradients and cure degree gradients make it easy to generate thermal strains in both carbon fibers and resin, with the resin experiencing cure shrinkage strain due to the curing reaction, ultimately leading to residual stresses and strains. In this paper, a three-dimensional thermo-chemo-mechanical coupled curing model of the composite shell was established based on a resin test, and the changes of temperature, curing degree, residual stress, and strain during the solidification of the composite shell were investigated. First, the curing property parameters and elastic modulus of HCM-2184 resin were obtained through a curing dynamic test and a tensile test. Then, considering the heat release and shrinkage reaction of solidification, a coupled thermo-chemo-mechanical curing model was developed with the CHILE (α) elastic model, and the curing process of the composite shell was simulated numerically. The results show that the resin used in the test belongs to the autocatalytic reaction. For thin composite shells, the heat accumulation inside the shell during curing is not obvious. During the curing process, the curing shrinkage behavior of the resin is an important factor for the generation of residual stress and residual strain.

Performance of capsules in self-healing early-age concrete due to restrained shrinkage

Performance of capsules in concrete was evaluated numerically using a simulated ASTM C1581 restrained shrinkage test and experimentally measured concrete shrinkage strain data to determine their effectiveness in healing cracks in early-age concrete. The model accounts for the concrete’s time-dependent mechanical properties, and the capsule’s geometrical and mechanical properties, and depth. A finite element model was developed to simulate the concrete volume change due to autogenous and drying shrinkage and the corresponding state of stress, and fracture mechanics to trace crack initiation and propagation in a restrained shrinkage ring. The performance of capsules in self-healing early-age concrete was found to depend on the capsules’ geometry, the stiffness ratio of concrete-to-capsule, and bond strength-to-rupture strength ratio of concrete-to-capsule. Results reveal that corresponding ratios of concrete effective stiffness and bond strength at 28 days to the stiffness and rupture strength of the capsules provide a threshold limit after which capsules debond in self-healing early-age concrete.

Tailoring high ductility cementitious composite incorporating recycled fine aggregate based on shrinkage and mechanical properties

High ductility cementitious composite (HDCC) is recognized as an ideal structural bonding and repair material due to multiple steady-state cracking and strain-hardening properties. However， higher shrinkage strains and low economic and environmental friendliness limit its wide application. To promote the application of HDCC, recycled high ductility cementitious composite (R-HDCC) was prepared by using recycled fine aggregate (RFA) to replace natural fine aggregate (NFA), and the effects of RFA substitution rate and fly ash content on the mechanical and shrinkage properties of R-HDCC were thoroughly investigated. The results showed that the compressive strength of R-HDCC gradually decreased with the increase of RFA substitution, but its tensile strain was enhanced. R-HDCC, with 100 % RFA substitution, still maintained a tensile strength of 2.66 MPa and a tensile strain capacity of 2.46 %. The high fly ash content improved the matrix ductility, resulting in a 54.19 % increase in tensile strain over natural HDCC. In addition, the incorporation of RFA and fly ash reduced the autogenous shrinkage of R-HDCC due to the internal curing effect, but the total drying shrinkage of the matrix increased with increasing RFA substitution rate. R100-70 showed optimal environmental benefits and engineering application value through environmental impact assessment and economic analysis. Finally, this paper is expected to guide the design of ecological, economical, and high-performance R-HDCC.

Study on the Effect of Interfacial Modification on the Properties of Super Standard Mica Sand Cement-Based Materials

Mica is a harmful substance in sand and occurs frequently. The application of super standard mica sand is a difficult problem in large-scale engineering. In this work, the effects of an interface modifier, mineral admixture, and a curing system on the properties of cement-based materials with super standard mica sand were studied. The strength of cement-based materials linearly decreases with the mica content in sand. When the mica content in sand exceeds 6%, the compressive strength of mortar and concrete at 28 d decreases by more than 22.3% and 33.5%, respectively. By adding the silane coupling agent (SCA) of 50% mica mass and curing in natural conditions, the compressive strength of mortar increases by 10.9%. The cement-based materials with the SCA are more suitable for curing in natural conditions, and the performance of the SCA will not be affected by adding appropriate amounts of mineral admixture. The drying shrinkage strain of the concrete, with the sand containing high mica content modified by SCA, is reduced by 10.5%, and the diffusion of chloride ions in concrete is reduced. The XRD results show that the addition of the interfacial agent does not change the hydration products. The MIP and SEM results show that the SCA can form a bridge structure between the hydration products and the mica, improve the bonding strength of the interface zone, and reduce the number of harmful pores.

High-Performance Materials Improve the Early Shrinkage, Early Cracking, Strength, Impermeability, and Microstructure of Manufactured Sand Concrete

The poor early shrinkage and cracking performances of manufactured sand concrete, waste powder concrete, and recycled aggregate concrete are the main difficulties in engineering applications. To solve these problems, early shrinkage and cracking, strength, and impermeability tests were performed on high-volume stone powder manufactured sand concrete mixed with fly ash and slag powder (FS), a shrinkage-reducing agent (SRA), polyvinyl alcohol (PVA) fibers, and a superabsorbent polymer (SAP). Furthermore, the microstructures and pore structures of these concretes were revealed using nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM). The results showed that the mixture of FS, SRA, PVA fibers, and SAP could effectively inhibit the shrinkage strain and cracking area of the concrete. The effect of the SAP on reducing the early shrinkage of the concrete is the greatest, and the shrinkage strain can be reduced by 76.49%. The PVA fibers had the most obvious effect on inhibiting the early cracking of the concrete, and the total cracking area was reduced by 66.91%. Significantly, the incorporation of the FS can improve the particle gradation and the pore structure and improve its compactness. The PVA fibers not only provide good carriers for cement-based materials but also enhance the bonding force between the particles inside the concrete, filling the pores inside the concrete, inhibiting the loss of water, and reducing the generation of internal microcracks. The FS and PVA can reduce the shrinkage and cracking risk and improve the strength and impermeability of the concrete. Although the SRA and SAP can reduce the shrinkage and cracking risks, it will lead to a significant decrease in the later strength and impermeability. The main reason is that the SRA leads to an increase in micropores in the matrix and microcracks near the aggregate, which are not conducive to the development of the strength and penetration resistance of the MS. Similarly, the SAP can promote the rapid formation of ettringite (Aft) at an early age and improve the early shrinkage, early cracking, and early strength of the concrete. However, with an increase in age, the residual pores, after SAP dehydration, will cause the deterioration of the concrete pore structure, resulting in the deterioration of the strength and impermeability.

Subsidence associated with dewatering and gas extraction from coal seams: Contribution of desorption-induced coal shrinkage

Several coal seams are contained within the formations of Great Artesian Basin (GAB), the largest natural underground water reservoir in Australia and the world. The extraction of coal seam gas (CSG) and its associated water from thousands of wells within the coal measures of the GAB has led to tens of millimetres of subsidence in CSG development areas. Since highly developed farming systems located in these areas rely on very low slope landforms, even this scale of subsidence has caused significant community concern about the potential for CSG extraction to impair farming operations and productivity through changes in land slope and drainage. Coal seam compaction associated with dewatering and gas extraction has two key components: poromechanical compaction and desorption-induced bulk shrinkage. The former results from pore pressure depletion (due to dewatering and gas extraction) and an increase of vertical effective stress, while the latter is induced by gas desorption from the coal matrix, leading to further deformation. While poromechanical compaction of fluid-bearing formations has been extensively addressed in the literature, relatively little research has been conducted on the role of coal shrinkage in CSG-induced subsidence. This paper introduces an innovative practical modelling approach for assessing CSG-induced subsidence at a subregional/regional scale. The approach utilises an analytical model for CSG-induced subsidence derived from constitutive stress–strain relations for poroelastic-sorptive media. This is a novel approach in the context of CSG-induced subsidence which considers both poromechanical compaction and desorption-induced shrinkage. A further distinction to previous work is the integration of the geomechanical-sorptive subsidence model with a numerical groundwater model. Based on this approach, this paper examines the effect of coal shrinkage on subsidence, and its proportions with respect to total compaction for one of the major coal measures in the Surat Basin. Input data are derived from three-dimensional geological, geomechanical, and groundwater models, as well as methane adsorption and desorption reports. Results show that (a) the impact of coal shrinkage on CSG-induced subsidence is likely to be significant in the study area and (b) the contribution of coal shrinkage to CSG-induced subsidence depends on gas content, Langmuir isotherm, shrinkage strain parameters, and the saturation state of coal. This study provides important insights into CSG-induced subsidence and lays the foundation for the development of robust, efficient, and localised predictive models to support environmental impact assessment and management.

Experiment and Analysis of Variance for Stabilizing Fine-Grained Soils with Cement and Sawdust Ash as Liner Materials.

Due to volume change and low strength, fine-grained soils are problematic in construction. Stabilization with cement and sawdust ash (SDA) by-products can improve engineering properties. This study aimed to investigate the effectiveness of cement and sawdust ash (SDA) in stabilizing fine-grained soils for liner applications. Varying proportions of cement (0-9%) and SDA (0-10%) were added to soil samples (n = 24). Specimens were tested for unconfined compressive strength (UCS), hydraulic conductivity (HC), and volumetric shrinkage strain (VSS). Two-way ANOVA analyzed stabilization effects. Optimal stabilization occurred with 6% cement and 6% SDA, resulting in significant increases in UCS (51 to 375 kN/m2) and decreases in HC (1.7 × 10-8 to 4.7 × 10-10 m/s) and VSS (12.8 to 3.51%) compared to untreated soil. ANOVA indicated that both cement and SDA had statistically significant (p < 0.05) effects on improving all three engineering properties. The addition of 6% cement and 6% SDA significantly improved the expansive soil's strength, hydraulic conductivity, and volume change properties. ANOVA confirmed the quantitative improvements and the significance of both stabilizers. Stabilization using the by-product SDA has the potential to be a sustainable soil improvement method.

Long-Term Drying Shrinkage Strain of Engineered Cementitious Composite Concrete Contains Polymeric Fibers

The lack of concrete tensile stress endurance led to the invention of engineered cementitious composite. However, the absence of gravel from the mixture in addition to the high binder content may lead to high shrinkage strain. Therefore, a radical solution to this problem is worth to be anticipated. The importance of this research lies in investigating the long-term drying shrinkage strain of the engineered cementitious composite since there is a lack of information regarding this behavior. Mixes of 30 and 60 MPa strengths were produced with polyvinyl alcohol fibers PVA-ECC and polypropylene fibers PP-ECC. The drying shrinkage strain of PVA-ECC mixes has been compared to PP-ECC mixes for both short term (0–28 days) and long term (0–360 days). Results indicated that all PVA-ECC mixes exhibited lower drying shrinkage strains than PP-ECC mixes. The ultimate drying shrinkage strain was recorded to be 1200 microstrain at 28 days. The increment in drying shrinkage strain after 28 days was 5.6% in PVA-ECC mixes when compared to that in PP-ECC mixes which was 6.77%. For high strength levels, the drying shrinkage strain at the age of 360 days declared a reduction of 3.5% for PVA-ECC compared to PP-ECC mixes. Also, it was lower for mixes with 60 MPa (6.3%) than for mixes with 30 MPa (7.6%). Therefore, despite the higher cement content for mixes with 60 MPa strength, the higher fiber volume fraction and the higher PVA solution percentage restricted the drying shrinkage strain increment. The research also addresses some mechanical tests of engineered cementitious composite concrete such as compressive strength, flexural strength, and strain capacity that may provide a strong relation to the drying shrinkage behavior of the different mixes. The scanning electron microscope images were involved in this research to declare the impact of fiber types on the microstructure of the ECC mixes.

Assessment of flexural response of RC beams and unrestrained shrinkage of fiber-reinforced high-volume fly ash-based no-aggregate concrete and self-compacting concrete

The use of industrial byproducts as a substitute for cement in concrete production to improve its properties is becoming a widespread practice in producing sustainable concrete. Although research around the world emphasizes higher substitution levels of fly ash (FA) to accrue the benefits from the microstructure refinement, no attempt has been made to study the deflection behavior and drying shrinkage of concrete that is devoid of aggregates while supplementing 80% of cement with class F fly ash (F-FA). Two types of concrete are used to cast full-scale reinforced concrete (RC) beams of size 150×300×2200 mm. The first type is a novel no aggregate concrete (NAC) made up of 80% F-FA and 20% ordinary Portland cement (OPC). The second type is high-volume fly ash self-compacting concrete (HVFASCC), which has 60% F-FA as a cement supplement and is equivalent in compressive strength to NAC. The NAC is reinforced with polypropylene fibers (PF) in three varying volume fractions: 0.6%, 0.8%, and 1.0%. All the beams are tested under a simply supported four-point loading condition. The drying shrinkage strain and mass loss are measured for prisms of size 75×75×300 mm up to 220 days exposed at 20% relative humidity (RH) and 50 ºC temperature in a humidity oven for all the mixes. The mechanical properties are also assessed along with the water absorption (sorptivity). The results indicate that adding PF to the beams with NAC delays the formation of the first crack and improves the peak load, the ultimate load, and the ductility of the NAC beam. Additionally, the beams with PF exhibit lower mid-span deflection and ductile failure mode, improving the overall structural performance. Regarding drying shrinkage, the HVFASCC prisms record the lowest shrinkage strains of all mixes. Adding PF to NAC increases the initial and ultimate drying shrinkage strains. However, adding PF to NAC inhibits the rate of shrinkage strain over the test duration. This research enhances understanding of how PF affects no-aggregate concrete behavior, paving the way for more comprehensive construction materials.

Study on the evolutionary mechanism of shrinkage stress-strain behavior of EVA-modified cement mortar at an early age

Understanding the early deformation characteristics is important to predict early cracks in cementitious materials and to serve structural engineering. Incorporation of polyethylene-vinyl acetate (EVA) dispersible polymer powder can improve the early cracking of cementitious materials. In this paper, the homogeneity, shrinkage stress-strain behavior and the evolutionary mechanism of EVA-modified cement mortar (EMCM) with different polymer-to-cement ratios (p/c) were investigated at an early age. The homogeneity and shrinkage stress-strain behavior of EMCM were characterized by a self-designed test setup. Isothermal calorimetric analysis, scanning electron microscopy and X-ray diffraction were used for the evolutionary mechanism analysis. The results show that the homogeneity of shrinkage of EMCM can be improved by adding EVA and prolonging the mixing time. The shrinkage stress of EMCM can be reduced by 83 % when p/c is 10 % and 15 %. Meanwhile, the elastic modulus of mortar can be reduced by 45 % when the EVA content is 15 %. Isothermal calorimetric analysis and characterization of microscopic properties show that EVA can inhibit both the generation and conversion of C4AH13, as well as the generation of AFt and CH, and retard the hydration of cement mortar. Within 3 h of hydration, the change in shrinkage stress of EMCM is only affected by the amount of AFt generated, while the change in shrinkage strain is affected by both CH and AFt generation, and the correlation with CH is greater. Finally, the interpenetrating network structure between the EVA and the cementitious matrix increases the interaction and bond between them, giving good deformability and thus reducing shrinkage. Therefore, the reduction in shrinkage stress-strain of EMCM is a result of the combined effect of the polymer on delaying cement hydration and increasing internal interaction and bonding.

On-line cure monitoring of phenol formaldehyde resin using embedded fiber Bragg grating sensor

On-line cure monitoring techniques have shown advantages for identifying the stages of curing and can lead to smart curing process of resin system and its composites. In this study, an on-line measuring technique with fiber Bragg grating (FBG) sensors was used to gain clear understanding of the curing stages of phenolic resin, as well as to determine its chemical shrinkage level. The FBG sensors were embedded in phenolic resin and worked under temperature raising and isothermal conditions. Through the interface between FBG sensor and resin, curing shrinkage strain was transferred to the grating, changing the central wavelength of FBG and producing strain. The feasibility of FBG sensors for monitoring chemical shrinkage during curing was verified by employing epoxy and benzoxazine resins that exhibits low chemical shrinkage. For cure monitoring of phenolic resin, the results show that the strain signal can be corresponded to various responses, such as solvent volatilization, hydroxylation and dehydration condensation reactions during temperature raising curing process. Through these strain characteristics, the curing state of phenolic resin can be obtained, which degree of cure ranges from 0.05 to 0.9. In isothermal curing process of phenolic resin, an exponential correlation between chemical shrinkage induced compressive strain and degree of cure of resin was identified, indicating that the real-time compressive strain is proportional to the degree of cure of phenolic resin. By evaluating real-time curing shrinkage levels, the estimation of curing degree of phenolic resin can be achieved utilizing exponential correlation of curing degree and curing shrinkage level.

Study on the performance and synergistic mechanism of cement mortar reinforced with combined superabsorbent polymers and basalt fibers admixture

This study addresses the need for cement-based materials with high mechanical properties and reduced autogenous shrinkage by investigating the effectiveness of incorporating superabsorbent polymers (SAP) and basalt fibers (BF) to enhance the volumetric stability of cement mortar. The effects of individual and combined additions of SAP and BF on mortar were systematically evaluated through autogenous shrinkage tests, mechanical properties tests, and workability assessments, culminating in an optimized mixture. The synergy between SAP and BF was further examined by using Scanning Electron Microscopy (SEM) to observe changes in the surface microstructure of the cement matrix. The findings demonstrate that (1) the optimal proportions of SAP and BF are 0.25% each, leading to cement mortar with superior mechanical properties and improved volumetric stability; (2) SAP significantly reduces shrinkage strain by water absorption and subsequent water release, promoting hydration, while BF contributes to the stress distribution capacity of the matrix, particularly increasing tensile and flexural strength and reducing crack propagation; and (3) the synergistic interaction between SAP and BF enhances the interfacial microstructure and bonding, as well as reduces porosity following SAP-induced water release, thereby improving the mechanical properties and crack resistance of the cement mortar.

Effect of Public Fillers on Cement-Stabilized Recycled Mixes of Road Performance: Mechanical Properties, Microstructure, and Durability.

In order to address the challenges of resource utilization posed by construction waste, the substitution of natural aggregate (NA) with public fill (PF) contents was investigated for load reclamation and road grassroots applications. A comprehensive assessment of road performance for the recycled mixture was conducted, focusing on parameters such as unconfined compressive strength, splitting strength, compressive resilience modulus, dry shrinkage, and frost resistance. Additionally, the impact of incorporating PF at various types and replacement ratios on the microstructure of cement-stabilized aggregate (CSA) was analyzed. The results indicated that the unconfined compressive strength of cement-stabilized recycled mixture with varying PF contents meets the base strength requirements for heavy, medium, and light traffic pavement on secondary and sub-secondary roads in China. Notably, the unconfined compressive strength and resilience modulus follow a similar pattern, reaching their peak at a 25% PF content. Microscopic examination reveals that an appropriate PF content leads to the predominant formation of C(N)-A-S-H, hydrotalcite, Ca(OH)2, and CaCO3 as paste reaction products. As the replacement of public fill increases from 0% to 25%, there is a gradual stacking of gel products, which enhances the compactness of the microstructure by cementing together unreacted particles. Consequently, this process reduces dry shrinkage strain and effectively mitigates the formation of reflection cracks. Applying large quantities of public fill to road construction can effectively deal with various waste accumulation problems and produce a novel road material with significant social, economic, and environmental benefits.

Creep and Shrinkage Properties of Nano-SiO2-Modified Recycled Aggregate Concrete.

The poor performance of recycled concrete aggregate (RCA) leads to greater creep in recycled aggregate concrete (RAC) compared to natural aggregate concrete (NAC). To enhance the quality of RCA, this paper utilizes a 2% concentration of a nano-SiO2 (NS) solution for pre-soaking RCA. This study aims to replace natural aggregate (NA) with NS-modified recycled aggregate (SRCA) and investigate the creep and shrinkage properties of NS-modified recycled aggregate concrete (SRAC) at various SRCA replacement rates. Subsequently, the creep and shrinkage strains of NAC, SRAC, and RAC are simulated using the finite element method. Finally, a comparative analysis is conducted with the predicted creep and shrinkage strains from CEB-FIP, ACI, B3, and GL2000 models. The experimental results indicate that the creep and shrinkage deformation of SRAC increases with the SRCA replacement rate. Compared to NAC, the creep and shrinkage deformation of SRAC at replacement rates of 30%, 50%, 70%, and 100% increased by 2%, 7%, 13%, and 30%, respectively. However, when 100% of the natural aggregate is replaced with SRCA, the creep and shrinkage deformation decreases by 7% compared to RAC. Moreover, the CEB-FIP and ACI models can predict the creep and shrinkage deformation of concrete reasonably well.