Electromagnetic interference (EMI) shielding is crucial for radio frequency ranges, particularly around 1 GHz, to ensure the functionality and security of electronic devices and wireless communications especially within building materials. The inherent properties of typical metallic materials, such as their heavy weight and high cost, make them less suitable for mass production, particularly in the construction applications. Herein, we present a novel approach to improve EMI shielding efficiency of cement composites by incorporating two types of carbon fibers with distinct lengths as fillers and optimizing the clustering network among these fillers. By precisely controlling the length and proportion of long (mother) and short (anchor) carbon fibers, we demonstrate that a 7:3 ratio of 6 mm mother fibers to 2 mm anchor fibers yields optimal shielding efficiencies, delivering 65.3 dB at a low radio frequency (1 GHz) and 44.5 dB in the high X-band frequency range (8.2 – 12.4 GHz). Significantly, two-dimensional matrix simulations corroborate the geometric modifications occurring between fillers as the length and ratio of carbon fibers are altered, showing excellent agreement with our experimental results. Combined with an intriguing approach to fine-tune the clustered network of carbon fibers, this study highlights the critical role of filler geometry within the matrix in developing high-performance EMI shielding materials, offering new insights for the design of advanced EMI shielding solutions.
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