Sewage Sludge Management Research Articles

Environmental sustainability opportunity and socio-economic cost analyses of phosphorus recovery from sewage sludge

Although phosphorus (P) recovery and management from sewage sludge are practiced in North America and Europe, such practices are not yet to be implemented in China. Here, we evaluated the environmental sustainability opportunity and socio-economic costs of recovering P from sewage sludge by replacing the current-day treatments (CT; sludge treatment and landfill) and P chemical fertilizer application (CF) in China using life cycle assessment and life cycle costing methods. Three potential P recovery scenarios (PR1‒PR3: struvite, vivianite, and treated sludge) and corresponding current-day scenarios (CT1‒CT3 and CF) were considered. Results indicated that PR1 and PR2 have smaller environmental impacts than the current-day scenarios, whereas PR3 has larger impacts in most categories. PR3 has the lowest net costs (sum of internal costs and benefits, 39.1–54.7 CNY per kg P), whereas PR2 has the lowest external costs (366.8 CNY per kg P). Societal costs for production and land use of 1 kg P by P recovery from sewage sludge (e.g., ∼527 CNY for PR1) are much higher than those of P chemical fertilizers (∼20 CNY for CF). However, considering the costs in the current-day treatments (e.g., ∼524 CNY for CT1), societal costs of P recovery scenarios are close to or slightly lower than those of current-day scenarios. Among the three P recovery scenarios, we found that recovering struvite as P fertilizer has the highest societal feasibility. This study will provide valuable information for improved sewage sludge management and will help promote the sustainable supply of P in China.

Carbon Footprint Analysis of Sewage Sludge Thermochemical Conversion Technologies

Thermochemical conversion technology for sewage sludge (SS) management has obvious advantages compared to traditional technologies, such as considerable volume reduction, effective pathogen elimination, and potential fuel production. However, few researchers conducted comparative research on the greenhouse gas (GHG) emission performances of these technologies. This paper evaluates the lifecycle carbon footprints of three SS thermochemical conversion technologies, including hydrothermal liquefaction (HTL) (Case 1), pyrolysis (Case 2), and incineration (Case 3) with software OpenLCA and Ecoinvent database. The results show that Case 1 has the smallest carbon footprint (172.50 kg CO2eq/t SS), which indicates the HTL process has the best GHG emission reduction potential compared to other SS disposal routes. The biggest contributor to the carbon footprint of SS thermochemical conversion technologies is indirect emissions related to energy consumption. So the energy consumption ratio (ECR) of the three cases is calculated to assess the energy consumption performances. From the perspective of energy conversion, Case 1 shows the best performance with an ECR of 0.34. In addition, element balance analysis is carried out to deeply evaluate the carbon reduction performance of the three cases. This study fills the knowledge gap regarding the carbon footprints for SS thermochemical conversion technologies and provides a reference for future technology selection and policymaking against climate change in the SS management sector.

Full-Scale Sewage Sludge Reduction Technologies: A Review with a Focus on Energy Consumption

In recent years, increasing attention has been paid to the problem of sewage sludge management and the relevant energy consumption, which represent the main cost items in wastewater treatment plants. Therefore, implementation of technologies that can reduce sludge production and ensure a positive impact on the energy of the entire sewage treatment plant has gained considerable importance in the scientific and technical community. The objective of this study was thus to screen full-scale sludge reduction technologies integrated into both the water line and the sludge line of a municipal sewage treatment plant with a sustainable impact on the overall balance of the plant. The results showed that, within the water line, ultrasound in the recirculation line of the activated sludge allowed for greater reductions in sludge production than the Cannibal and UTN systems, despite the higher energy consumption. CAMBITM, BioThelysTM, ExelysTM and TurboTec® enabled the greatest reductions in sludge production among the technologies integrated into the sludge line, and although they required a large amount of energy, this was partially offset by energy recovery in terms of additional biogas production.

Sustainability assessment of alternative waste-to-energy technologies for the management of sewage sludge

The management of sewage sludge still represents a challenge in the EU sustainability plan for biowaste. Although there are consolidated alternatives for the valorization of sewage sludge (incineration, pyrolysis and gasification), technical issues related to heavy metals and other pollutants are not sufficiently understood considering the whole waste-to-energy process. In addition, societal-economic and environmental aspects are usually not included in the evaluation of these conversion technologies. In this study, we propose an integrated assessment from a sustainability perspective to evaluate the valorization of sewage sludge by thermal conversion, comparing different alternatives based on existing Waste-to-energy (WtE) technologies. The results provide an insightful vision on the challenges to manage the sewage sludge disposal and to transform the obtained waste into new raw materials with added value. In addition, the evaluation of the WtE alternatives shows that they face important challenges preventing their application, being the gasification the best performing technology according to the sustainability assessment. Finally, a decentralized scheme based on sewage sludge gasification is further evaluated using real data from wastewater treatment plants in Andalusia.

Characteristics of Solidified Carbon Dioxide and Perspectives for Its Sustainable Application in Sewage Sludge Management.

Appropriate management is necessary to mitigate the environmental impacts of wastewater sludge. One lesser-known technology concerns the use of solidified CO2 for dewatering, sanitization, and digestion improvement. Solidified CO2 is a normal byproduct of natural gas treatment processes and can also be produced by dedicated biogas upgrading technologies. The way solidified CO2 is sourced is fully in line with the principles of the circular economy and carbon dioxide mitigation. The aim of this review is to summarize the current state of knowledge on the production and application of solid CO2 in the pretreatment and management of sewage sludge. Using solidified CO2 for sludge conditioning causes effective lysis of microbial cells, which destroys activated sludge flocs, promotes biomass fragmentation, facilitates efficient dispersion of molecular associations, modifies cell morphology, and denatures macromolecules. Solidified CO2 can be used as an attractive tool to sanitize and dewater sludge and as a pretreatment technology to improve methane digestion and fermentative hydrogen production. Furthermore, it can also be incorporated into a closed CO2 cycle of biogas production-biogas upgrading-solidified CO2 production-sludge disintegration-digestion-biogas production. This feature not only bolsters the technology's capacity to improve the performance and cost-effectiveness of digestion processes, but can also help reduce atmospheric CO2 emissions, a crucial advantage in terms of environment protection. This new approach to solidified CO2 generation and application largely counteracts previous limitations, which are mainly related to the low cost-effectiveness of the production process.

РОССИЙСКИЕ И ЗАРУБЕЖНЫЕ ПРАКТИКИ ОБРАЩЕНИЯ С ОСАДКОМ СТОЧНЫХ ВОД

Purpose: to analyze the best practices for sewage sludge management both in our country and abroad. Discussion. The qualitative composition of sewage sludge varies depending on the wastewater composition, the characteristics of treatment facilities and the treatment methods used. The choice of sludge disposal method depends primarily on environmental and social factors. The environmental factor is determined primarily by the presence of pathogenic microorganisms and helminths, heavy metals and biogenic substances. The problem with helminths and pathogenic microorganisms is solved by disinfection and stabilization of sewage sludge. The problem with heavy metals is solved by their immobilization. The biogenic composition of sewage sludge, and primarily the nitrogen and phosphorus content, predetermines its fertilizer value for crop production. The main negative component that determines the quality of sewage sludge is the presence of heavy metals in them. The statistical data on the content of heavy metals in sewage sludge from various countries are presented. The social aspect determines the availability of agricultural areas, appropriate technologies, demand for a certain type of resource, as well as economic indicators of the result obtained. Conclusions. Currently, in world practice there is no consensus on the permissible content of pollutants in sewage sludge when they are used as fertilizers. The Russian standards are no exception, which require scientifically based revision to improve the requirements for the sewage sludge quality for their further use in the country's agriculture.

A comparative life-cycle assessment and cost analysis of biofilters amended with sludge-based activated carbon and commercial activated carbon for stormwater treatment

Environmental and economic issues resulting from the unsustainable management of sewage sludge from wastewater have necessitated the development of eco-friendly sewage sludge disposal methods, whereas stormwater effluent contains tremendous amounts of pollutants. This study compares the feasibility and environmental impacts associated with incorporating biofilters with sludge-based activated carbon (SBAC) versus commercial activated carbon (CAC) for stormwater treatment. The results demonstrate that the construction and disposal life-cycle stages are the dominant contributors to several environmental impact categories, including resource scarcity, carcinogenic toxicity, terrestrial ecotoxicity, and ozone formation indicators. Across multiple impact categories, the incorporation of biofilters with SBAC can reduce the negative environmental impacts associated with biofilter construction and disposal by 40% over a 50-year analysis period. In contrast, the most significant improvement is on construction-dominant indicators, where the decreased need for biofilter reconstruction results in a higher reduction in environmental impacts. Economically, amending the biofilter with SBAC can increase profits by up to 66% due to extending its lifespan. This study shows that SBAC has similar performance as CAC for lowering the negative environmental impacts resulting from biofilter construction, while increasing the overall net profits of the system. However, converting sewage sludge to an effective sorbent (SBAC) and incorporating SBAC into a biofilter to capture pollutants from stormwater is an economically and environmentally sustainable solution available to practitioners to manage sewage sludge and stormwater effluent. This solution protects the environment in a cost efficient, sustainable manner.

Sewage and faecal sludge management; revisiting discharge standards in India

Sewage and faecal sludge management; revisiting discharge standards in India

A novel strategy for efficiently transforming waste activated sludge into medium-chain fatty acid using free nitrous acid

The global energy crisis is approaching due to rapid population growth and overexploitation of fossil fuels. Therefore, the development and use of new and renewable energy sources is already in the extreme urgency. This work developed a novel technology to efficiently produce renewable liquid bioenergy from discarded wastes, by effectively transforming sewage sludge into high-value medium chain fatty acids (MCFA). The maximum MCFA yield in the anaerobic sludge fermentation was revealed to be 10.6 times of control when utilizing sewage sludge with 1.78 mg-N/L free nitrous acid (FNA) pretreatment. The carbon flow from sewage sludge into MCFA in the fermentation system was significantly enhanced with appropriate levels (0.71–1.78 mg-N/L) of FNA pretreatment. Compared to FNA pretreatment, however, its direct addition severely inhibited total products (i.e., carboxylates and complex alcohols) generation because of the toxicity on live cells (decreasing to 8.3 %–13.9 %) in sludge. Kinetic models (one-substrate and two-substrate) were utilized to investigate the mechanism of MCFA promotion by FNA pretreatment on anaerobic sludge fermentation, in which linear relationship analysis between FNA-derived organic release and the fitted parameters were also performed. The results indicated that the conversion of refractory materials into rapidly bioavailable substrates for MCFA production contributed to increasing MCFA production rate and potential. Moreover, the relative abundances of functional microorganisms related to hydrolysis-acidification and chain elongation process increased under FNA pretreatment, further favoring the MCFA production. This study provides a novel and effective technology of sludge energy recovery that can achieve the next-generation sustainable sewage sludge management.

Greenhouse Gas Emissions-Based Development and Characterization of Optimal Scenarios for Municipal Solid and Sewage Sludge Waste Management in Astana City

Landfilling is the most applied solid waste management method in developing countries, which leads to a large amount of greenhouse gas (GHG) emissions. It is thus imperative to develop strategies for evaluating different economically viable waste management scenarios to mitigate GHG emissions. According to the Paris Agreement, Kazakhstan planned to decrease GHG emissions by 25% by 2050 as compared to 1990 levels, while reaching carbon neutrality by 2060. In this context, we herein propose four different scenarios for municipal solid waste (MSW) treatment and three scenarios for sewage sludge (SS) treatment with the aim of evaluating the GHG potential for Astana, the capital city of Kazakhstan, using the (solid waste management) SWM-GHG calculator developed by the Institute for Energy and Environmental Research. The MSW treatment scenarios include: (A) 15% recycling of secondary materials and 85% landfilling of remaining MSW; (B) 30% recycling of secondary materials; 70% sanitary landfilling with biogas collection; (C) 30% recycling and 70% biological stabilization and landfilling without biogas collection; and (D) 30% recycling, 20% composting, and 50% (waste-to-energy) WtE incineration. The sewage sludge management scenarios include (1) 100% landfilling; (2) 100% WtE incineration; and (3) co-incineration of sewage sludge and coal. The results reveal that more complex scenarios lead to extensive ecological benefits; however, there are economic constraints. Based on the analysis of the proposed scenarios, we recommend the optimal strategy for MSW treatment to be 30% recycling with biological stabilization that has a total cost of EUR 16.7 million/year and overall GHG emissions of −120 kt of CO2 eq/year. In terms of sewage sludge management, the addition of coal to sewage sludge simplifies the combustion process due to the higher heat capacity. Considering lower cost and higher energy recovery, it is recommended as a favorable process.

Investigation of combustion performance of tannery sewage sludge using thermokinetic analysis and prediction by artificial neural network

The disposal and the management of sewage sludge from tanneries is a challenging issue for the leather industries because of their adverse effect on the environment. In this study the detailed characterization and assessment using kinetic and thermodynamic parameters of the tannery sewage sludge in combustion environment was employed. Isoconversional model-free methods like Ozawa-Flynn-Wall (OFW), Friedman and Kissinger-Akahira-Sunose (KAS) were employed to investigate the kinetics and the thermodynamic parameters in the air environment. Activation energies (Ea) for the Friedman, KAS and OFW were reported. The DTG curves at the heating rate of 5, 10, 20 and 40 °C/min show the diversified conversions in three major stages. The Ea values for the model ranges are Friedman (148.96 kJ/mol-395.23 kJ/mol), KAS (169.65 kJ/mol-383.75 kJ/mol) and OFW (176.44 kJ/mol-377.85 kJ/mol). The average Ea for the Friedman is 226.04 kJ/mol while for KAS and OFW the average Ea is 230.71 kJ/mol and 230.11 kJ/mol. Moreover, the values of ΔH, ΔG, and ΔS were analysed. Furthermore, the frequency distribution by applying the DAEM model is investigated, and there are six pseudo-components involved in the frequency distribution for combustion. For the thermal degradation prediction of the sewage sludge from the tannery, an artificial neural network (ANN) of the MLP-3-7-1 model was used. This model shows that there is good agreement between the experimental and the predicted values. Overall, this study highlights the importance of the ANN for the prediction of combustion behaviour of biomass with more accuracy.

How Can Sewage Sludge Use in Sustainable Tunisian Agriculture Be Increased?

In recent years, farmers in Beja, an agricultural governorate in northwestern Tunisia, have expressed their willingness to use urban sewage sludge as agricultural fertilizer, especially with the unavailability of chemical fertilizers and the soil type of the region that is poor in organic matter. However, there is an imbalance between the important farmers’ demand versus the limited quantity of sludge produced by the Beja wastewater treatment plants (WWTPs). In the face of this, this study aims to identify the problems related to the agricultural reuse of sludge in Beja and propose solutions to solve them. The quality of the sludge produced by the five Beja WWTPs was assessed based on physicochemical and microbiological parameters. The data were collected using the Delphi method, with 15 experts representing different positions on the issue treated. The SWOT-AHP methodology was used to define the strategies promoting the sustainable use and management of urban sewage sludge for sustainable agricultural development in Beja. Results showed that there were no problems with compliance with the Tunisian standards NT 106.20 for the sludge produced. A set of twelve practical conclusions was identified, constituting the strategies of Strengths–Opportunities, Strengths–Threats, Weaknesses–Opportunities, and Weaknesses–Threats deduced from the SWOT-AHP.

Fifty years of sewage sludge management research: Mapping researchers' motivations and concerns

Sewage sludge management is torn between a desire for pollution prevention and reuse of a valuable resource. Reconciling these interests in sustainable management is a challenge for researchers. This study focuses on how research on sewage sludge management practices has evolved and scrutinizes how this research is interlinked with concerns and societal issues such as contaminants, economic efficiency, and legislation. Based on published academic papers on sewage sludge management between 1971 and 2019, this study found four trends in research focused on sewage sludge management: a decreasing interest in disposal (landfilling and sea dumping), a dominant interest in land application, a growing interest in sewage sludge as product, and a stable interest in energy recovery. Research on disposal focuses on increasing sludge volumes, legislative changes, and economic challenges with an interest in waste co-treatment. Research on land application concerns nutrient use and contaminants, mainly heavy metals. Research on sewage sludge as a product focuses on the extraction of certain resources and less on use of sewage sludge specifically. Research on energy recovery of sewage sludge focuses on volume reduction rather than contaminants. Two-thirds of the papers are detailed studies aiming to improve single technologies and assessing single risks or benefits. As management of sewage sludge is multifaceted, the narrow focus resulting from detailed studies promotes some concerns while excluding others. Therefore, this study highlights potential gaps such as the combination of nutrient use and disposal and energy recovery and nutrient use.

Recovery of Cellulose, Extracellular Polymeric Substances and Microplastics from Sewage Sludge: A Review

Wastewater treatment plants are considered to be not only as treatment facilities, but also essential elements of the circular economy. Wastewater treatment plants can be essential chains of the circular economy cycle. Despite this, sewage sludge management and utilization are mostly limited to biodegradation and further agricultural uses or incineration. The recovery of valuable products is mainly limited to nitrogen and phosphorus compounds. Fewer analyses focus on generating, recovering, and removing various polymers from sewage sludge, such as cellulose or extracellular polymeric substances (EPS). On the other hand, sewage sludge also contains polymeric pollutants, such as microplastics. The recovery and use of biopolymers is significant considering the problems connected with the presence and effects of artificial polymers (microplastics) in the environment. Despite the technical possibilities, not many technical scale installations are operated. Law regulations should make some incentives to develop the technologies and sell the recovered polymers in the market not as waste material, but as a valuable product. This paper presents state-of-the-art technologies for selected polymers’ recovery from sludge, including technical parameters of the processes and possible applications of recovered products, but it also considers the possibility of microplastics’ removal from this waste material.

Sewage Sludge Quality and Management for Circular Economy Opportunities in Lombardy

From the perspective of a circular economy that prioritizes resource reuse and recovery, sewage sludge could be a source of nutrients for agricultural soils or a source of energy, depending on its characteristics. Lombardy is the region with the highest quantity of sludge production and management in Italy. A methodology was developed to: extract and analyze quantitative data on sewage sludge (EWC 190805) production and management (2017–2018); collect and analyze qualitative data from publicly available documents in tender processes for sewage sludge management (2014–2020). Sludge from Lombardy’s wastewater treatment facilities displayed average qualities that were useful for recovery in agriculture after additional stabilization treatments. Sludge showed generally low heating values and elevated water content and should require additional treatments to be used in mono-combustion. The study discovered that there is still work to be done in sludge recovery in agriculture in Lombardy, taking biosolid quality into account. Sludge, on the other hand, can be converted into energy. The methodology for collecting and analyzing site-specific data presented here can be applied to other areas. The findings can assist and guide decision-makers in developing future regional sewage sludge management strategies.

Efficient degradation of m-cresol during catalytic wet peroxide oxidation with biochar derived from the pyrolysis of persulfate-ZVI treated sludge

Sludge dewatering is crucial for cutting the cost of sludge post-disposal in wastewater treatment plants. Response surface methodology (RSM) was used in this study to sufficiently investigate the interaction among persulfate, zero-valent iron (ZVI) and reaction time on the sludge dewatering. Under the experimental condition at the central point in RSM, the sludge moisture content was reduced to 54%. The sludge-based biochar obtained from the pyrolysis of persulfate-ZVI treated sludge at the central point in RSM was marked as SC-M and tested for catalytic activity. With the catalyst SC-M, the removal rates of m-cresol and total organic carbon (TOC) were 98.1% and 84.2%, respectively. The persulfate-ZVI treatment for sludge dewatering facilitated increasing the proportion of iron species in SC-M, which contributed to its high catalytic activity. M-cresol degradation with SC-M was a two-period reaction including an induction period and a rapid reaction with the apparent activation energy at a low level. This study integrates the sludge dewatering by persulfate-ZVI treatment and m-cresol degradation by catalytic oxidation with the biochar SC-M prepared from the dewatered iron-rich sludge, providing an effective, economic and environment-friendly approach for sewage sludge utilization and management.

Treatment of heavy metal-polluted sewage sludge using biochar amendments and vermistabilization.

Heavy metal contamination of sewage sludge hampers its recycling. Contaminated sewage sludge was amended with different proportions of biochar and vermistabilized. Biochar produced from wheat straw was added at four proportions (0%, 2%, 4%, and 6%). Ten earthworms Eisenia fetida were added, and the sludge was vermistabilized for 60days. Heavy metal and nutrient concentrations and the accumulation of metals to E. fetida were measured. The treatment with 4% biochar was the most efficient in reducing the concentrations of heavy metals. The concentration of Cd decreased 55%, Cr 28%, Cu 30%, and Pb 21%. The concentrations of plant nutrients increased: total N 43%, total P 92%, and total K 60%. E. fetida accumulated all heavy metals in their internal tissues. The survival and reproductive rate of E. fetida improved during the vermistabilization process. We interpret that the biochar alone did not improve the decomposition process, but the main actors were the earthworms E. fetida. The most efficient proportion of biochar was 4%, not the highest tested (6%). We recommend 4% biochar to be used in the vermistabilization of heavy metal-contaminated municipal sewage sludge. The study benefits both the management of heavy metal-contaminated sewage sludge and agriculture where the final vermistabilization product can be used to improve crop production.

Sewage Sludge Management at District Level: Reduction and Nutrients Recovery via Hydrothermal Carbonization

In this study, two scenarios of a municipal wastewater treatment plant (WWTP) are presented, which include the integration of the hydrothermal carbonization (HTC) process into the sludge line as a post-treatment of the anaerobic digestion (AD) process. The objective of the simulation is to investigate the performances of AD + HTC treatment to reduce sludge production and improve nutrient and energy recovery. For this purpose, the scheme of an under-construction WWTP was considered, named Trento 3 (Trento, Italy) and with a treatment capacity of 300,000 PE. In the first scenario, the HTC process was fed with thickened sludge from the Trento 3 WWTP, while in the second scenario, dewatered sludge from other local WWTPs was also used as feedstock for the HTC process. Both scenarios allowed to obtain a considerable sludge reduction ranging from 70 to 75% with a notably increase in the biogas production up to 47%, due to the recycling of HTC liquor (HTCL) to the anaerobic digester. Considering nutrients recovery, all the phosphorus and nitrogen present in the HTCL could be used for struvite precipitation with an average yearly gain of 1 million euros. Moreover, the introduction of HTC in the Trento 3 WWTP could allow a reduction in the sludge management costs of up to 2 M€/year.Graphical

Application of circular economy in wastewater treatment using biochar based adsorbent derived from sewage sludge

The Circular Economy intends to reuse wastewater and recover resources and energy from the sludge in the wastewater sector. The conversion of sewage sludge into biochar by pyrolysis technique is a sustainable, environmentally friendly option for sewage sludge management. In the current work, biochar was produced by co-pyrolyzing sewage sludge and coconut shell, and it was then utilized as an adsorbent to eliminate methylene blue (the model pollutant) from wastewater. The sewage sludge is abundant in functional groups and metal ions, and the addition of coconut shells increased the porosity of the adsorbent. The biochar produced by mixing coconut shell and sewage sludge in the ratio1:1 showed higher adsorption capacity compared to biochar obtained from pure sewage sludge; hence the co-pyrolyzed biochar was used for further studies. The morphology and functional groups present on biochar were examined using SEM and FTIR analysis. The kinetics and mechanism of methylene blue adsorption was adequately explained by the pseudo-second-order kinetic model. Using the Langmuir isotherm model, the maximal adsorption capacity of the methylene blue dye on biochar was observed to be 31.64 mg/g.

Risk Analysis of Heavy Metals Migration from Sewage Sludge of Wastewater Treatment Plants.

More and more attention in sewage sludge management is being devoted to its environmental utilization. This approach is justified both from economic and environmental points of view. However, as with any method, there are certain possibilities and limitations. The goal of the natural utilization of sewage sludge is to recover the valuable agronomic properties and fertilizing potential of the sludge. The main aspect limiting the possibility of using sludge as a fertilizer is the heavy metal content. In this paper, an analysis of the risk of environmental contamination in the case of application of sewage sludge with different forms of sludge treatment was carried out. Risk indices such as Igeo and PERI, based on the comparison of total metal content in sludge and soil, as well as RAC and ERD indices, which take into account the mobility of metals in soil, were calculated. It was shown that high levels of potential risk and geoaccumulation indicators do not necessarily disqualify the use of sewage sludge, the key aspect is the form of mobility in which the heavy metals are found in the sludge, and this should be the only aspect taken into account for the possibility of their environmental use.