We study rigidity questions for pairs of Lie algebras [Formula: see text] admitting a post-Lie algebra structure. We show that if [Formula: see text] is semisimple and [Formula: see text] is arbitrary, then we have rigidity in the sense that [Formula: see text] and [Formula: see text] must be isomorphic. The proof uses a result on the decomposition of a Lie algebra [Formula: see text] as the direct vector space sum of two semisimple subalgebras. We show that [Formula: see text] must be semisimple and hence isomorphic to the direct Lie algebra sum [Formula: see text]. This solves some open existence questions for post-Lie algebra structures on pairs of Lie algebras [Formula: see text]. We prove additional existence results for pairs [Formula: see text], where [Formula: see text] is complete, and for pairs, where [Formula: see text] is reductive with [Formula: see text]-dimensional center and [Formula: see text] is solvable or nilpotent.
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